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    Process for the production of high purity isobutene combining reactive distillation with hydroisomerization, distillation and skeletal isomerization
    1.
    发明授权
    Process for the production of high purity isobutene combining reactive distillation with hydroisomerization, distillation and skeletal isomerization 失效
    生产高纯度异丁烯的方法，其结合反应蒸馏与加氢异构化，蒸馏和骨架异构化

    公开(公告)号：US5969203A

    公开(公告)日：1999-10-19

    申请号：US996122

    申请日：1997-12-22

    申请人： Michel Dorbon ,  Jean-Alain Chodorge ,  Jean Cosyns ,  Jean-Charles Viltard ,  Blaise Didillon

    发明人： Michel Dorbon ,  Jean-Alain Chodorge ,  Jean Cosyns ,  Jean-Charles Viltard ,  Blaise Didillon

    IPC分类号： B01J23/40 ,  B01J23/755 ,  C07B61/00 ,  C07C5/27 ,  C07C7/04 ,  C07C11/09 ,  C07C1/00 ,  C07C5/22

    CPC分类号： C07C11/09 ,  C07C5/2791 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/755 ,  Y02P20/127 ,  Y10S203/06

    摘要： The invention relates to a process for producing high purity isobutene from a hydrocarbon cut essentially comprising olefinic hydrocarbons containing 4 carbon atoms per molecule including isobutene, also butene-1 and butene-2 compounds in a ratio which substantially corresponds to the thermodynamic equilibrium. The process comprises passing the cut into a distillation zone (3) associated with a hydroisomerization reaction zone, the bottom product of the distillation zone comprising butene-2 compoundw being passed into a second distillation zone (4), preferably an extractive distillation zone, to obtain a first effluent comprising butene-2 compounds as its major portion and a second effluent comprising normal-butane as its major portion, the major portion of the first effluent being passed into a skeletal isomerization zone (2) where the linear butenes are at least partially isomerized to isobutene, at least part of the principal effluent from the skeletal isomerization zone being recycled upstream of the reactive distillation zone (1).

    摘要翻译： 本发明涉及从基本上包含每分子含有4个碳原子的烯烃的烃馏分生产高纯度异丁烯的方法，包括异丁烯，以及基本上对应于热力学平衡的比例的丁烯-1和丁烯-2化合物。 该方法包括将切片通入与加氢异构化反应区相关联的蒸馏区（3），蒸馏区的底部产物包含丁烯-2化合物，其进入第二蒸馏区（4），优选萃取蒸馏区，至 获得包含丁烯-2化合物作为其主要部分的第一流出物和包含正丁烷作为其主要部分的第二流出物，第一流出物的主要部分进入骨架异构化区（2），其中线性丁烯至少为 部分异构化为异丁烯，来自骨架异构化区的至少部分主要流出物被循环在反应蒸馏区（1）的上游。

    Process for obtaining butene-1
    6.
    发明授权
    Process for obtaining butene-1 有权
    获得丁烯-1的方法

    公开(公告)号：US06242662B1

    公开(公告)日：2001-06-05

    申请号：US09229958

    申请日：1999-01-14

    申请人： Michel Dorbon ,  François Hugues ,  Jean-Charles Viltard ,  Blaise Didillon ,  Alain Forestiere

    发明人： Michel Dorbon ,  François Hugues ,  Jean-Charles Viltard ,  Blaise Didillon ,  Alain Forestiere

    IPC分类号： C07C525

    CPC分类号： C07C11/08 ,  C07C5/2556 ,  C07C7/04 ,  C07C2523/40 ,  C07C2523/755

    摘要： For obtaining butene-1 from butene-2, a charge containing at least one of the isomers of butene-2 is introduced into a distillation zone linked to a hydro-isomerization zone. Part of the effluent from the bottom of the distillation column is removed from the distillation zone, heated in a heat exchanger and passed into an external hydro-isomerization zone. The hydro-isomerization effluent is removed from the hydro-isomerization zone, cooled in a heat exchanger, and then reintroduced into the distillation zone. Effluent containing butene-1 is withdrawn from the top of the column of the distillation zone.

    摘要翻译： 为了从丁烯-2获得丁烯-1，将含有至少一种丁烯-2异构体的电荷引入连接到加氢异构化区的蒸馏区。 将蒸馏塔底部的一部分流出物从蒸馏区除去，在热交换器中加热并进入外部加氢异构化区。 将加氢异构化流出物从加氢异构化区域除去，在热交换器中冷却，然后再引入蒸馏区。 含有丁烯-1的流出物从蒸馏区的塔顶排出。

    Process for converting hydrocarbons by treatment in a distillation zone comprising withdrawing a stabilized distillate, associated with a reaction zone, and its use for hydrogenating benzene
    7.
    发明授权
    Process for converting hydrocarbons by treatment in a distillation zone comprising withdrawing a stabilized distillate, associated with a reaction zone, and its use for hydrogenating benzene 有权
    通过在蒸馏区中处理来转化烃的方法，包括萃取与反应区相关的稳定的馏出物及其用于苯化氢的用途

    公开(公告)号：US06261442B1

    公开(公告)日：2001-07-17

    申请号：US09285679

    申请日：1999-04-05

    申请人： Jean-Louis Ambrosino ,  Blaise Didillon ,  Pierre Marache ,  Jean-Charles Viltard ,  Gérald Witte

    发明人： Jean-Louis Ambrosino ,  Blaise Didillon ,  Pierre Marache ,  Jean-Charles Viltard ,  Gérald Witte

    IPC分类号： C10G700

    CPC分类号： C10G49/00 ,  C10G45/44

    摘要： The invention provides a process for converting a hydrocarbon feed in which said feed is treated in a distillation zone producing an overhead vapour distillate and a bottom effluent, associated with an at least partially external reaction zone comprising at least one catalytic bed, in which at least one reaction for converting at least a portion of at least one hydrocarbon is carried out in the presence of a catalyst and a gas stream comprising hydrogen, the feed for the reaction zone being drawn off at the height of at least one draw-off level and representing at least a portion of the liquid flowing in the distillation zone, at least part of the effluent from the reaction zone being re-introduced into the distillation zone at the height of at least one re-introduction level, so as to ensure continuity of the distillation, said process being characterized in that a liquid distillate is withdrawn from the distillation zone at the height of at least one withdrawal level, said level being located below the vapour distillate withdrawal level. This process can be used to reduce the benzene content in a hydrocarbon cut.

    摘要翻译： 本发明提供了一种转化烃进料的方法，其中所述进料在蒸馏区中处理，产生塔顶蒸馏馏出物和底部流出物，其与包含至少一个催化床的至少部分外部反应区相关联，其中至少 用于转化至少一种至少一种烃的一种反应是在催化剂和包含氢的气流的存在下进行的，反应区的进料在至少一个排出水平的高度被排出， 代表在蒸馏区中流动的液体的至少一部分，至少部分来自反应区的流出物在至少一个再引入水平的高度被重新引入蒸馏区，以确保连续性 所述方法的特征在于，在至少一个提取水平的高度处从蒸馏区中取出液体馏出物， g位于蒸汽馏出物提取水平以下。 该方法可用于降低烃馏分中的苯含量。

    Process for converting hydrocarbons by treatment in a distillation zone associated with a reaction zone, comprising re-contacting a vapor distillate with the feed, and its use for hydrogenating benzine
    8.
    发明授权
    Process for converting hydrocarbons by treatment in a distillation zone associated with a reaction zone, comprising re-contacting a vapor distillate with the feed, and its use for hydrogenating benzine 有权
    在与反应区相关联的蒸馏区中处理碳氢化合物的方法，包括使蒸气馏出物与进料重新接触，以及其用于苯化氢的用途

    公开(公告)号：US06238549B1

    公开(公告)日：2001-05-29

    申请号：US09459874

    申请日：1999-12-14

    申请人： Jean-Charles Viltard ,  Jean-Louis Ambrosino ,  Blaise Didillon

    发明人： Jean-Charles Viltard ,  Jean-Louis Ambrosino ,  Blaise Didillon

    IPC分类号： C10G700

    CPC分类号： C10G45/44 ,  C10G49/002

    摘要： The invention concerns a process for converting a hydrocarbon feed in which said feed is treated in a distillation zone producing an overhead vapor distillate and a bottom effluent, associated with an at least partially external reaction zone comprising at least one catalytic bed, in which at least one reaction for converting at least a portion of at least one hydrocarbon is carried out in the presence of a catalyst and a gas stream comprising hydrogen, the feed for the reaction zone being drawn off at the height of at least one draw-off level and representing at least a portion of the liquid flowing in the distillation zone, at least part of the effluent from the reaction zone being re-introduced into the distillation zone at the height of at least one re-introduction level, so as to ensure continuity of the distillation, said process being characterized in that at least a portion of the vapor distillate is re-contacted with at least a portion of the feed introduced into the distillation zone. This process can be used to reduce the benzene content in a hydrocarbon cut.

    摘要翻译： 本发明涉及一种用于转化烃进料的方法，其中所述进料在蒸馏区中处理，产生塔顶蒸馏馏出物和底部流出物，其与包含至少一个催化床的至少部分外部反应区相关联，其中至少 用于转化至少一种至少一种烃的一种反应是在催化剂和包含氢的气流的存在下进行的，反应区的进料在至少一个排出水平的高度被排出， 代表在蒸馏区中流动的液体的至少一部分，至少部分来自反应区的流出物在至少一个再引入水平的高度被重新引入蒸馏区，以确保连续性 蒸馏，所述方法的特征在于至少一部分蒸气馏出物与引入馏出物的进料的至少一部分重新接触 离子区。 该方法可用于降低烃馏分中的苯含量。

    Process for converting hydrocarbons by treatment in a distillation zone comprising extracting a hydrocarbon cut as a side stream, associated with a reaction zone, and its use for hydrogenating benzene
    9.
    发明授权
    Process for converting hydrocarbons by treatment in a distillation zone comprising extracting a hydrocarbon cut as a side stream, associated with a reaction zone, and its use for hydrogenating benzene 有权
    通过在蒸馏区中处理来转化烃的方法，包括萃取与反应区相关的侧流的烃馏分及其用于苯化氢的用途

    公开(公告)号：US06365791B1

    公开(公告)日：2002-04-02

    申请号：US09376054

    申请日：1999-08-17

    申请人： Jean-Louis Ambrosino ,  Jean-Charles Viltard ,  Blaise Didillon

    发明人： Jean-Louis Ambrosino ,  Jean-Charles Viltard ,  Blaise Didillon

    IPC分类号： C07C500

    CPC分类号： C10G45/44

    摘要： The invention provides a process for converting hydrocarbons in which said feed is treated in a distillation zone associated with a reaction zone, the feed for the reaction zone being drawn off at the height of at least one draw-off level, the effluent from the reaction zone being re-introduced into the distillation zone at the height of a re-introduction level, said process being characterized in that a liquid effluent is also withdrawn from the distillation zone at the height of a withdrawal level, said liquid effluent being treated in a gas-liquid side separation zone (splitter), the gaseous effluent being re-introduced into the distillation zone and the liquid effluent being recovered as an intermediate cut. This process can be used to reduce the benzene content of a hydrocarbon cut and to recover a naphtha cut.

    摘要翻译： 本发明提供了一种转化烃的方法，其中所述进料在与反应区相关的蒸馏区中处理，反应区的进料在至少一个排出水平的高度被排出，反应的流出物 区域在再引入水平的高度被重新引入蒸馏区，所述方法的特征在于，在排出水平的高度处还从蒸馏区抽出液体流出物，所述液体流出物在 气 - 液侧分离区（分流器），气态流出物被重新引入蒸馏区，液体流出物作为中间馏分被回收。 该方法可用于降低烃馏分的苯含量并回收石脑油馏分。

    Process for converting hydrocarbons by treatment in a distillation zone comprising a circulating reflux, associated with a reaction zone, and its use for hydrogenating benzene
    10.
    发明授权
    Process for converting hydrocarbons by treatment in a distillation zone comprising a circulating reflux, associated with a reaction zone, and its use for hydrogenating benzene 有权
    通过在包含与反应区相关联的循环回流的蒸馏区中处理来转化烃的方法及其用于使苯氢化的方法

    公开(公告)号：US06174428B1

    公开(公告)日：2001-01-16

    申请号：US09285777

    申请日：1999-04-05

    申请人： Jean-Louis Ambrosino ,  Blaise Didillon ,  Pierre Marache ,  Jean-Charles Viltard ,  G{acute over (e)}rald Witte

    发明人： Jean-Louis Ambrosino ,  Blaise Didillon ,  Pierre Marache ,  Jean-Charles Viltard ,  G{acute over (e)}rald Witte

    IPC分类号： C10G700

    CPC分类号： C10G45/44 ,  C10G49/00

    摘要： The invention provides a process for converting a hydrocarbon feed in which said feed is treated in a distillation zone producing a bottom effluent and a vapour distillate, associated with an at least partially external reaction zone comprising at least one catalytic bed, in which at least one reaction for converting at least a portion of at least one hydrocarbon is carried out in the presence of a catalyst and a gas stream comprising hydrogen, the feed for the reaction zone being drawn off at the height of at least one draw-off level and representing at least a portion of the liquid flowing in the distillation zone, at least part of the effluent from the reaction zone being re-introduced into the distillation zone at the height of at least one re-introduction level, so as to ensure continuity of the distillation, and so as to withdraw a distillate from the distillation zone and to recover a bottom effluent from the bottom of the distillation zone, said process being characterized in that the temperature of the portion of effluent re-introduced into the distillation zone is lower than that of the feed to the reaction zone drawn off at the height of a draw-off level located below the re-introduction level. This process can be used to reduce the benzene content in a hydrocarbon cut.

    摘要翻译： 本发明提供了一种转化烃进料的方法，其中所述进料在蒸馏区中处理，产生底部流出物和蒸气馏出物，其与包含至少一个催化床的至少部分外部反应区相关联，其中至少一个 用于转化至少一部分至少一种烃的反应在催化剂和包含氢气的气流的存在下进行，反应区的进料在至少一个排出水平的高度被排出，并表示 在蒸馏区中流动的液体的至少一部分，至少部分来自反应区的流出物在至少一个再引入水平的高度被重新引入蒸馏区，以确保连续性 蒸馏并且从蒸馏区抽出馏出物并从蒸馏区的底部回收底部流出物，所述方法的特征在于t 重新引入蒸馏区的流出物部分的温度比在重新引入水平以下的排出水平高度排出的反应区的进料的温度低。 该方法可用于降低烃馏分中的苯含量。