公开(公告)号：US06235960B1

公开(公告)日：2001-05-22

申请号：US09310181

申请日：1999-05-12

Applicant: Eric Benazzi ,  Slavik Kasztelan ,  Nathalie George-Marchal

Inventor： Eric Benazzi ,  Slavik Kasztelan ,  Nathalie George-Marchal

IPC: C07C513

CPC classification number: C10G45/64 ,  B01J29/67 ,  B01J29/7284 ,  B01J29/7292 ,  B01J29/7484 ,  B01J29/7492 ,  B01J29/7884 ,  B01J29/7892 ,  B01J35/1061 ,  B01J35/1085 ,  B01J2229/26 ,  B01J2229/42

Abstract: A process for improving the pour point of a feed comprising paraffins containing more than 10 carbon atoms, in which the feed to be treated is brought into contact with a catalyst comprising at least one zeolite with structure type MTT, TON or FER or any possible combination of these three, at least one hydro-dehydrogenating element selected from elements from group VIB and group VIII of the periodic table, at least one deposited promoter element (boron, silicon, phosphorous), optionally at least one group VIIA element, optionally at least one group VIIB element, at a temperature in the range 170° C. to 500° C., a pressure in the range 1 to 250 bars and at an hourly space velocity in the range 0.05 to 100 h−1, in the presence of hydrogen in an amount of 50 to 2000 l/l of feed. The oils obtained have good pour points and high viscosity indices (VI). The process is also applicable to gas oils, and other feeds requiring a reduction in pour point. The invention also relates to a catalyst containing silicon and to its use for converting hydrocarbon-containing feeds.

Abstract translation: 一种用于改进含有多于10个碳原子的链烷烃的进料的倾点的方法，其中待处理的进料与包含至少一种结构类型为MTT，TON或FER的沸石或任何可能的组合的催化剂接触 这些三种中的至少一种选自元素周期表第VIB族和第VIII族元素的至少一种加氢脱氢元素，至少一种沉积的促进元素（硼，硅，磷），任选至少一种VIIA族元素，任选至少 一组VIIB元素，在170℃至500℃的温度范围内，压力范围为1至250巴，时间空间速度为0.05至100小时-1，在存在 量为50至2000升/升的进料的氢。 所得油具有良好的倾点和高粘度指数（VI）。 该方法也适用于需要降低倾点的瓦斯油和其它进料。本发明还涉及含硅的催化剂及其用于转化含烃物料的用途。

公开(公告)号：US06215036B1

公开(公告)日：2001-04-10

申请号：US09242058

申请日：1999-09-27

Applicant: Michel Dorbon ,  Blaise Didillon ,  Jean-Charles Viltard ,  Jean Cosyns ,  Charles Cameron ,  Heinz Unterberg ,  Günter Schümmer ,  William Brown

Inventor： Michel Dorbon ,  Blaise Didillon ,  Jean-Charles Viltard ,  Jean Cosyns ,  Charles Cameron ,  Heinz Unterberg ,  Günter Schümmer ,  William Brown

IPC: C07C513

CPC classification number: C07C11/09 ,  C07C5/2556 ,  C07C7/04 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/755 ,  C07C11/08

Abstract: A process for processing a feedstock comprising a major amount of olefinic hydrocarbons having 4 carbon atoms per molecule, including isobutene as well as but-1-ene and but-2-enes, wherein the process comprises processing said feedstock in a distillation zone associated with a hydroisomerization reaction zone located at least partly external to the distillation zone, said processing comprising drawing at the height of a draw-off level of the distillation zone at least part of the liquid flowing in the distillation zone, passing said liquid into the external hydroisomerization reaction zone to form a hydroisomerized effluent, and reintroducing at least part of the effluent from said reaction zone reintroduced into the distillation zone at one or more reintroduction level(s), so as to ensure the continuity of the distillation.

Abstract translation: 一种用于处理原料的方法，其包含主要量的每分子具有4个碳原子的烯烃，包括异丁烯以及丁-1-烯和2-烯，其中所述方法包括在与 位于至少部分位于蒸馏区外部的加氢异构化反应区，所述处理包括在蒸馏区的排出水平的高度抽出至少部分在蒸馏区中流动的液体，使所述液体进入外部加氢异构化 反应区以形成加氢异构化流出物，并且将来自所述反应区的至少一部分流出物重新引入到一个或多个再引入水平的蒸馏区中，以确保蒸馏的连续性。

公开(公告)号：US06573417B1

公开(公告)日：2003-06-03

申请号：US10008991

申请日：2001-11-05

Applicant: Lynn H. Rice

Inventor： Lynn H. Rice

IPC: C07C513

CPC classification number: C07C9/00 ,  C07C7/04 ,  C10G2400/02

Abstract: The fractional distillation performed as part of the isomerization of C5-C6 paraffins is heat integrated. A portion of a sidedraw recycle stream is employed to cool the feed to a deisohexanizer column and then returned to a lower portion of the column. This reduces the reflux demand of the column and the operating cost of the process.

Abstract translation: 作为C5-C6链烷烃异构化的一部分进行的分馏是热积分的。 采用一部分侧面循环料流将进料冷却至脱乙烷塔，然后返回塔的下部。 这减少了塔的回流需求和工艺的运行成本。

公开(公告)号：US06407303B1

公开(公告)日：2002-06-18

申请号：US09710627

申请日：2000-11-10

Applicant: Dennis E. O'Brien ,  Lynn H. Rice

Inventor： Dennis E. O'Brien ,  Lynn H. Rice

IPC: C07C513

CPC classification number: B01D3/141 ,  C07C7/12 ,  C07C9/16 ,  C07C13/10 ,  C07C13/18 ,  C07C2601/08 ,  C07C2601/14

Abstract: Construction and operational costs of simulated moving bed adsorptive separation process units are reduced by recovering desorbent from both the extract and raffinate streams of the process in a single integrated fraction column. Both streams are fractionated to recover desorbent, which is removed at one end of a dividing wall column, while separate extract and raffinate products are removed from the other end of the column. A specific embodiment includes the use of the integrated fractionation column in an isomerization application.

Abstract translation: 模拟移动床吸附分离工艺单元的结构和运行成本通过在单个集成分馏塔中回收来自萃取液和萃余液流的脱附剂而减少。 将两个流分馏以回收解吸剂，其在分隔壁塔的一端被除去，而从塔的另一端除去单独的提取物和萃余液产物。 具体实施方案包括在异构化应用中使用集成分馏塔。

公开(公告)号：US06395950B1

公开(公告)日：2002-05-28

申请号：US09710721

申请日：2000-11-10

Applicant: Lynn H. Rice

Inventor： Lynn H. Rice

IPC: C07C513

CPC classification number: C07C9/16 ,  B01D3/141 ,  C07C7/04

Abstract: Construction and operational costs of recovering the high-octane components of an isomerization raffinate product of a simulated moving bed adsorptive separation process units are reduced by employing a dividing wall column to perform the separation. The raffinate product stream is passed into the column at an intermediate point on the first side of the dividing wall, with the column delivering the low-octane raffinate components as a sidedraw from the opposite side of the dividing wall. A stream of higher octane components are removed both as an overhead stream and a bottoms stream. The sidedraw may be recycled to the isomerization zone.

公开(公告)号：US06555725B1

公开(公告)日：2003-04-29

申请号：US09992372

申请日：2001-11-06

Applicant: Robert Jay Wittenbrink ,  Charles John Mart ,  Janet Renee Clark ,  Jennifer Schaefer Feeley

Inventor： Robert Jay Wittenbrink ,  Charles John Mart ,  Janet Renee Clark ,  Jennifer Schaefer Feeley

IPC: C07C513

CPC classification number: C10G2/342 ,  B01J8/006 ,  B01J8/065 ,  B01J8/226 ,  B01J19/2485 ,  B01J2208/0084 ,  B01J2208/00849 ,  B01J2208/00884 ,  C10G45/58

Abstract: A slurry Fischer-Tropsch hydrocarbon synthesis process for synthesizing liquid hydrocarbons from synthesis gas in a hydrocarbon synthesis reactor also hydroisomerizes the synthesized hydrocarbon liquid, which comprises the slurry liquid, in one or more downcomer reactors immersed in the slurry body in the synthesis reactor. A monolithic catalyst is preferably used for the hydroisomerization, and slurry circulation down through the downcomer reactors from the surrounding slurry body, is achieved at least in part by density-difference driven hydraulics created by removing gas bubbles from the slurry passed into the downcomers. Preferably, catalyst particles are also removed before the slurry contacts the catalyst. Hydroisomerization occurs while the synthesis reactor is producing hydrocarbons, without interfering with the hydrocarbon synthesis reaction.

Abstract translation: 在烃合成反应器中从合成气中合成液态烃的浆料费 - 托烃合成方法还将合成的含有浆料液体的烃液体在浸入合成反应器中的淤浆体中的一个或多个降液管反应器中加氢异构化。 优选使用整体式催化剂用于加氢异构化，并且至少部分地通过从通过下降管的浆料中除去气泡产生的密度差驱动液压来实现从周围淤浆体向下通过降液管反应器的淤浆。 优选地，催化剂颗粒在浆料接触催化剂之前也被除去。 在合成反应器生产碳氢化合物的同时发生加氢异构化，而不干扰烃的合成反应。

公开(公告)号：US06297418B1

公开(公告)日：2001-10-02

申请号：US09495910

申请日：2000-02-02

Applicant: Hervé Cauffriez ,  Christine Travers

Inventor： Hervé Cauffriez ,  Christine Travers

IPC: C07C513

CPC classification number: B01J27/128 ,  B01J23/42 ,  B01J27/13 ,  B01J35/023 ,  B01J37/24 ,  C07C5/2791 ,  C07C2521/04 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/755 ,  C07C2523/89 ,  C07C9/00

Abstract: The invention concerns a catalyst containing at least one halogen, at least one metal from group VIII and a formed support comprising gamma alumina and optionally eta alumina, the catalyst being characterized in that the smallest average dimension of said support is in the range 0.8 mm to 2 mm and in that the halogen content is in the range 4.5% to 15% by weight. The invention also concerns the preparation of said catalyst, preferably with chlorination (in the case where the halogen is chlorine) in the presence of CCl4 or CHCl3. The invention also concerns the use of the catalyst for the isomerisation of normal C4-C6 paraffins.

Abstract translation: 本发明涉及含有至少一种卤素，至少一种来自VIII族的金属和形成的载体的催化剂，其包含γ氧化铝和任选的氧化铝，所述催化剂的特征在于所述载体的最小平均尺寸在0.8mm至 并且卤素含量在4.5％至15％（重量）的范围内。 本发明还涉及在CCl 4或CHCl 3存在下，优选用氯化（在卤素为氯的情况下）制备所述催化剂。 本发明还涉及催化剂用于正常C4-C6链烷烃异构化的用途。

公开(公告)号：US06198015B1

公开(公告)日：2001-03-06

申请号：US09034350

申请日：1998-03-04

Applicant: Christian Marcilly ,  Eric Benazzi ,  Nathalie George-Marchal

Inventor： Christian Marcilly ,  Eric Benazzi ,  Nathalie George-Marchal

IPC: C07C513

CPC classification number: C10G45/64 ,  B01J29/46

Abstract: The invention concerns a process for selective hydroisomerization of compounds with an n-alkane chain containing more than 10 carbon atoms, in which the compound to be treated is brought into contact with a catalyst comprising at least one hydro-dehydrogenating element and at least one molecular sieve having a one- or two-dimensional pore network, the accessible pore openings of which are delimited by 10 oxygen atoms, and a distance termed the bridging distance between the pores of less then 0.70 nm, and the zeolite is such that a catalyst which undergoes a standard n-heptadecane isomerization test has, for a conversion of 95%, a selectivity of at least 70% for isomerized products, and the catalyst contains at least 5% by weight of at least one hydro-dehydrogenating element selected from the group formed by non noble GVIII metals, GVIB metals, and niobium, and the catalyst preferably contains phosphorous. The sieve is preferably a NU-10, NU-23, NU-87, EU-13 or Theta-1 zeolite.

Abstract translation: 本发明涉及一种使含有多于10个碳原子的正烷烃链选择性加氢异构化的方法，其中待处理化合物与包含至少一个加氢脱氢元素的催化剂和至少一个分子 具有一维或二维孔网的筛，其可及孔的开口由10个氧原子界定，并且称为孔之间的桥接距离小于0.70nm的距离，并且沸石使得催化剂 进行标准的正十七烷异构化试验对于异构化产物具有至少70％的选择性为95％的转化率，并且催化剂含有至少5重量％的至少一种选自组中的加氢脱氢元件 由非贵金属GVIII金属，GVIB金属和铌形成，并且催化剂优选含有磷。筛优选为NU-10，NU-23，NU-87，EU-13或Theta-1沸石。

公开(公告)号：US06586650B2

公开(公告)日：2003-07-01

申请号：US09897191

申请日：2001-07-02

Applicant: William C. Baird, Jr. ,  Darryl P. Klein ,  Michele S. Touvelle ,  Jingguang G. Chen ,  Gary B. McVicker

Inventor： William C. Baird, Jr. ,  Darryl P. Klein ,  Michele S. Touvelle ,  Jingguang G. Chen ,  Gary B. McVicker

IPC: C07C513

CPC classification number: B01J23/58 ,  C07C5/13 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/06 ,  C07C2523/12 ,  C07C2523/26 ,  C07C2523/42 ,  C07C2523/46

Abstract: A process for opening naphthenic rings of naphthenic ring-containing compounds, along with catalysts which can be used in that process. The naphthene ring opening catalyst is a catalyst comprising at least one Group VIII metal selected from Ir, Pt, Rh, and Ru, wherein these metals are supported on an alkali metal or alkaline-earth metal modified support in an amount effective for opening a naphthene ring-containing compound at a tertiary carbon site.

Abstract translation: 一种用于开环环烷环的环烷环化合物的方法，以及可用于该方法的催化剂。 环烷烃开环催化剂是包含至少一种选自Ir，Pt，Rh和Ru的Ⅷ族金属的催化剂，其中这些金属以有效打开环烷烃的量负载在碱金属或碱土金属改性的载体上 含碳化合物在叔碳位点。

公开(公告)号：US06380452B1

公开(公告)日：2002-04-30

申请号：US09731125

申请日：2000-12-06

Applicant: Mark M. Davis ,  William B. Dolan ,  Robert J. Schmidt ,  Paul J. Kuchar

Inventor： Mark M. Davis ,  William B. Dolan ,  Robert J. Schmidt ,  Paul J. Kuchar

IPC: C07C513

CPC classification number: B01D53/228 ,  C07C7/144 ,  C07C17/38

Abstract: A process for recovering halides from hydrocarbon containing streams is disclosed using a sulfonated hexafluro bis-A-polysulfone membrane of polymers and copolymers having the polymer repeat unit of the formula: in the polymer or copolymer. This process is applicable to recovering and recycling hydrogen chloride, which is used as a catalytic promoter, in hydrocarbon conversion processes such as isomerization and alkylation.

Abstract translation: 公开了一种使用聚合物和共聚物的磺化六氟双A聚砜膜，其具有下式的聚合物重复单元：在聚合物或共聚物中，从含烃物流中回收卤化物的方法。 该方法适用于在烃转化过程如异构化和烷基化中回收和循环用作催化促进剂的氯化氢。