公开(公告)号：US20110183566A1

公开(公告)日：2011-07-28

申请号：US13056173

申请日：2009-07-29

申请人： Michel Feder ,  Yassine Maadadi

发明人： Michel Feder ,  Yassine Maadadi

IPC分类号： D03D25/00 ,  C09K3/18 ,  B32B9/04 ,  D04H13/00

CPC分类号： D06M11/79 ,  C08G77/16 ,  C08L83/04 ,  C09D183/04 ,  D06M15/643 ,  Y10T428/31663 ,  Y10T442/2861 ,  Y10T442/3976 ,  Y10T442/696 ,  C08L83/00

摘要： Crosslinkable or crosslinked silicone compositions, forming water-repellent and release coating for a flexible heat sensitive support of paper or polymer, and comprising crosslinking polyorganosiloxanes (POSs) bearing ≡Si—H units and unsaturated, preferably ≡Si-Vi, vinyl-containing POSs, capable of reacting with the crosslinker by polyaddition, in the presence of platinum in order to form the crosslinked release coating on the flexible support. The object is enabling the coating composition to crosslink instantaneously to produce, on various flexible supports (paper, e.g. glassine, or polymer, e.g. polyester such as polyethylene terephthalate PET), a crosslinked silicone coating leaving the coating machine, with excellent attachment (adhesion) and mechanical strength or cohesion—“Rub-off”—properties. The invention uses, per 100 parts by weight of silicone base, of 1 to 40 parts by weight of an additive comprising from 1 or 5 to 80% by weight of particulate filler, preferably nanoscale filler, in a silicone oil reacting with the crosslinker.

摘要翻译： 可交联或交联的硅氧烷组合物，形成用于纸或聚合物的柔性热敏载体的防水和脱模涂层，并且包括交联含有≡Si-H单元的聚有机硅氧烷（POS）和不饱和的，优选≡Si-Vi，含乙烯基的POS 能够在铂的存在下通过加聚与交联剂反应，以便在柔性载体上形成交联的剥离涂层。 目的是使涂料组合物瞬间交联，在各种柔性载体（纸，例如玻璃纤维或聚合物，如聚酯如聚对苯二甲酸乙二酯PET）上生产出离开涂布机的交联硅氧烷涂层，具有优异的附着力（粘合性） 机械强度或凝聚力 - “脱落” - 性能。 本发明每100重量份的硅氧烷基使用1至40重量份的添加剂，该添加剂包含1至5重量％至80重量％的颗粒填料，优选纳米级填料，在与交联剂反应的硅油中。

公开(公告)号：US08927627B2

公开(公告)日：2015-01-06

申请号：US13056173

申请日：2009-07-29

申请人： Michel Feder ,  Yassine Maadadi

发明人： Michel Feder ,  Yassine Maadadi

IPC分类号： C08K9/00 ,  C08K9/06 ,  B32B27/02 ,  B32B9/04 ,  D06M11/79 ,  C08L83/04 ,  C09D183/04 ,  D06M15/643 ,  C08G77/16

CPC分类号： D06M11/79 ,  C08G77/16 ,  C08L83/04 ,  C09D183/04 ,  D06M15/643 ,  Y10T428/31663 ,  Y10T442/2861 ,  Y10T442/3976 ,  Y10T442/696 ,  C08L83/00

摘要： Crosslinkable or crosslinked silicone compositions, forming water-repellent and release coating for a flexible heat sensitive support of paper or polymer, and comprising crosslinking polyorganosiloxanes (POSs) bearing ≡Si—H units and unsaturated, preferably ≡Si-Vi, vinyl-containing POSs, capable of reacting with the crosslinker by polyaddition, in the presence of platinum in order to form the crosslinked release coating on the flexible support. The object is enabling the coating composition to crosslink instantaneously to produce, on various flexible supports (paper, e.g. glassine, or polymer, e.g. polyester such as polyethylene terephthalate PET), a crosslinked silicone coating leaving the coating machine, with excellent attachment (adhesion) and mechanical strength or cohesion—“Rub-off”—properties. The invention uses, per 100 parts by weight of silicone base, of 1 to 40 parts by weight of an additive comprising from 1 or 5 to 80% by weight of particulate filler, preferably nanoscale filler, in a silicone oil reacting with the crosslinker.

摘要翻译： 可交联或交联的硅氧烷组合物，形成用于纸或聚合物的柔性热敏载体的防水和脱模涂层，并且包括交联含有≡Si-H单元的聚有机硅氧烷（POS）和不饱和的，优选≡Si-Vi，含乙烯基的POS 能够在铂的存在下通过加聚与交联剂反应，以便在柔性载体上形成交联的剥离涂层。 目的是使涂料组合物瞬间交联，在各种柔性载体（纸，例如玻璃纤维或聚合物，如聚酯如聚对苯二甲酸乙二酯PET）上生产出离开涂布机的交联硅氧烷涂层，具有优异的附着力（粘合性） 机械强度或凝聚力 - “脱落” - 性能。 本发明每100重量份的硅氧烷基使用1至40重量份的添加剂，该添加剂包含1至5重量％至80重量％的颗粒填料，优选纳米级填料，在与交联剂反应的硅油中。

公开(公告)号：US08859635B2

公开(公告)日：2014-10-14

申请号：US13169215

申请日：2011-06-27

申请人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

发明人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

IPC分类号： C08L83/04 ,  C09D183/04 ,  C08G77/20 ,  C08G77/00 ,  C08G77/18 ,  C08G77/14

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/14 ,  C08G77/18 ,  C08G77/20 ,  C08G77/70 ,  C08G77/80 ,  C09D183/04 ,  Y10T428/31511 ,  C08L83/00

摘要： Silicone composites subject to reticulation or reticulated, particularly for creating a coating or water-repellent and anti-adhesive film for flexible substrates such as paper or similar in the form of natural or synthetic polymer films. These compounds contain reticulating polyorganosiloxanes that have SiH units and unsaturated polyorganosiloxanes, preferably vinylated, suitable for reacting with the reticulating agent in an addition reaction and in the presence of platinum to form the reticulated anti-adhesive coating on the flexible substrate, plus at least one additive (D) to promote adhesion to it. A new liquid silicone compound can be applied without using a solvent, which is beneficial, that can be reticulated instantly to produce an anti-adhesive and/or water-repellent coating for the flexible substrate, giving very high quality reticulated silicone coatings, particularly in terms of sticking/adhering to the substrate, being harder to rub off and the anti-adhesion profile (sufficiently increase detaching force at high speed.

摘要翻译： 经过网状或网状的硅氧烷复合材料，特别是为天然或合成聚合物膜形式的柔性基材如纸或类似物形成涂层或防水防粘膜。 这些化合物含有网状聚有机硅氧烷，其具有SiH单元和不饱和聚有机硅氧烷，优选为乙烯基化，适于在加成反应中和在铂存在下与网状化合物反应，以在柔性基材上形成网状抗粘剂涂层，加上至少一种 添加剂（D）以促进其粘附。 可以在不使用溶剂的情况下施加新的液体硅氧烷化合物，这是有利的，其可以立即网状地制备用于柔性基材的抗粘合剂和/或防水涂料，提供非常高质量的网状硅氧烷涂料，特别是在 粘附/粘附在基材上的问题，难以擦去和防粘附特性（足以高速地提高分离力）。

公开(公告)号：US20110257288A1

公开(公告)日：2011-10-20

申请号：US13169215

申请日：2011-06-27

申请人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

发明人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

IPC分类号： C09D183/04 ,  B05D3/10 ,  C07F7/08

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/14 ,  C08G77/18 ,  C08G77/20 ,  C08G77/70 ,  C08G77/80 ,  C09D183/04 ,  Y10T428/31511 ,  C08L83/00

摘要： Silicone composites subject to reticulation or reticulated, particularly for creating a coating or water-repellent and anti-adhesive film for flexible substrates such as paper or similar in the form of natural or synthetic polymer films. These compounds contain reticulating polyorganosiloxanes that have SiH units and unsaturated polyorganosiloxanes, preferably vinylated, suitable for reacting with the reticulating agent in an addition reaction and in the presence of platinum to form the reticulated anti-adhesive coating on the flexible substrate, plus at least one additive (D) to promote adhesion to it. A new liquid silicone compound can be applied without using a solvent, which is beneficial, that can be reticulated instantly to produce an anti-adhesive and/or water-repellent coating for the flexible substrate, giving very high quality reticulated silicone coatings, particularly in terms of sticking/adhering to the substrate, being harder to rub off and the anti-adhesion profile (sufficiently increase detaching force at high speed.

摘要翻译： 经过网状或网状的硅氧烷复合材料，特别是为天然或合成聚合物膜形式的柔性基材如纸或类似物形成涂层或防水防粘膜。 这些化合物含有网状聚有机硅氧烷，其具有SiH单元和不饱和聚有机硅氧烷，优选为乙烯基化，适于在加成反应中和在铂存在下与网状化合物反应，以在柔性基材上形成网状抗粘剂涂层，加上至少一种 添加剂（D）以促进其粘附。 可以在不使用溶剂的情况下施加新的液体硅氧烷化合物，这是有利的，其可以立即网状地制备用于柔性基材的抗粘合剂和/或防水涂料，提供非常高质量的网状硅氧烷涂料，特别是在 粘附/粘附在基材上的问题，难以擦去和防粘附特性（足以高速地提高分离力）。

公开(公告)号：US08093339B2

公开(公告)日：2012-01-10

申请号：US12304554

申请日：2007-06-27

申请人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

发明人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

IPC分类号： C08L83/04

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/14 ,  C08G77/18 ,  C08G77/20 ,  C08G77/70 ,  C08G77/80 ,  C09D183/04 ,  Y10T428/31511 ,  C08L83/00

摘要： Silicone composites subject to reticulation or reticulated, particularly for creating a coating or water-repellent and anti-adhesive film for flexible substrates such as paper or similar in the form of natural or synthetic polymer films. These compounds contain reticulating polyorganosiloxanes that have SiH units and unsaturated polyorganosiloxanes, preferably vinylated, suitable for reacting with the reticulating agent in an addition reaction and in the presence of platinum to form the reticulated anti-adhesive coating on the flexible substrate, plus at least one additive (D) to promote adhesion to it. A new liquid silicone compound can be applied without using a solvent, which is beneficial, that can be reticulated instantly to produce an anti-adhesive and/or water-repellent coating for the flexible substrate, giving very high quality reticulated silicone coatings, particularly in terms of sticking/adhering to the substrate, being harder to rub off and the anti-adhesion profile (sufficiently increase detaching force at high speed.

摘要翻译： 经过网状或网状的硅氧烷复合材料，特别是为天然或合成聚合物膜形式的柔性基材如纸或类似物形成涂层或防水防粘膜。 这些化合物含有网状聚有机硅氧烷，其具有SiH单元和不饱和聚有机硅氧烷，优选为乙烯基化，适于在加成反应中和在铂存在下与网状化合物反应，以在柔性基材上形成网状抗粘剂涂层，加上至少一种 添加剂（D）以促进其粘附。 可以在不使用溶剂的情况下施加新的液体硅氧烷化合物，这是有利的，其可以立即网状地制备用于柔性基材的抗粘合剂和/或防水涂料，提供非常高质量的网状硅氧烷涂料，特别是在 粘附/粘附在基材上的问题，难以擦去和防粘附特性（足以高速地提高分离力）。

公开(公告)号：US20100028685A1

公开(公告)日：2010-02-04

申请号：US12304554

申请日：2007-06-27

申请人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

发明人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

IPC分类号： B32B27/08 ,  C09D183/06 ,  C07F7/00 ,  B05D3/02

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/14 ,  C08G77/18 ,  C08G77/20 ,  C08G77/70 ,  C08G77/80 ,  C09D183/04 ,  Y10T428/31511 ,  C08L83/00

摘要： Silicone composites subject to reticulation or reticulated, particularly for creating a coating or water-repellent and anti-adhesive film for flexible substrates such as paper or similar in the form of natural or synthetic polymer films. These compounds contain reticulating polyorganosiloxanes that have SiH units and unsaturated polyorganosiloxanes, preferably vinylated, suitable for reacting with the reticulating agent in an addition reaction and in the presence of platinum to form the reticulated anti-adhesive coating on the flexible substrate, plus at least one additive (D) to promote adhesion to it. A new liquid silicone compound can be applied without using a solvent, which is beneficial, that can be reticulated instantly to produce an anti-adhesive and/or water-repellent coating for the flexible substrate, giving very high quality reticulated silicone coatings, particularly in terms of sticking/adhering to the substrate, being harder to rub off and the anti-adhesion profile (sufficiently increase detaching force at high speed.

摘要翻译： 经过网状或网状的硅氧烷复合材料，特别是为天然或合成聚合物膜形式的柔性基材如纸或类似物形成涂层或防水防粘膜。 这些化合物含有网状聚有机硅氧烷，其具有SiH单元和不饱和聚有机硅氧烷，优选为乙烯基化，适于在加成反应中和在铂存在下与网状化合物反应，以在柔性基材上形成网状抗粘剂涂层，加上至少一种 添加剂（D）以促进其粘附。 可以在不使用溶剂的情况下施加新的液体硅氧烷化合物，这是有利的，其可以立即网状地制备用于柔性基材的抗粘合剂和/或防水涂料，提供非常高质量的网状硅氧烷涂料，特别是在 粘附/粘附在基材上的问题，难以擦去和防粘附特性（足以高速地提高分离力）。

公开(公告)号：US20060122323A1

公开(公告)日：2006-06-08

申请号：US10518401

申请日：2003-06-17

申请人： Laurent Dumont ,  Michel Feder ,  Francis Layfaysse ,  Sylvie Robelin

发明人： Laurent Dumont ,  Michel Feder ,  Francis Layfaysse ,  Sylvie Robelin

IPC分类号： C08L83/04 ,  B01F3/08 ,  B32B27/04

CPC分类号： D06N3/128 ,  C03C25/40 ,  C08G77/12 ,  C08G77/14 ,  C08G77/16 ,  C08G77/20 ,  C08G77/26 ,  C08G77/70 ,  C08L83/04 ,  D06M15/643 ,  Y10T428/31663 ,  C08L83/00

摘要： An aqueous polyorganosiloxane (POS) emulsion which can easily be deposited on/applied to a fibrous substrate at high speed and at limited deposition rates, for example less than 40 g/m2. The emulsion contains (A) a POS with ≡Si-vinyl units, (B) a POS with ≡SiH units, (C) an adhesion promoter, (D) a catalyst, (E) at least one surfactant, (F) optionally a POS resin with ≡Si-vinyl units, (G) optionally a crosslinking inhibitor, (H) optionally a pH fixing agent, (I) optionally a formulating additive, (J) optionally a filler, and (K) water. Adhesion promoter (C) is selected from protective hydrocolloids, hydroxylated silanes and/or POS carrying at least one hydroxyl group and at least one salified amino group per molecule, and mixtures thereof, and is present in the range from 0.005 to 10% by weight, based on the silicone phase. Also disclosed is the corresponding coating process and the coated substrate.

摘要翻译： 一种水溶性聚有机硅氧烷（POS）乳液，其可以容易地以高速和有限的沉积速率沉积在/施加到纤维基材上，例如小于40g / m 2。 乳液含有（A）具有≡Si-乙烯基单元的POS，（B）具有≡SiH单元的POS，（C）粘合促进剂，（D）催化剂，（E）至少一种表面活性剂，（F） 具有≡Si-乙烯基单元的POS树脂，（G）任选的交联抑制剂，（H）任选的pH固定剂，（I）任选的配制添加剂，（J）任选的填料和（K）水。 粘合促进剂（C）选自保护性水胶体，羟基化硅烷和/或POS，每个分子具有至少一个羟基和至少一个成盐氨基，以及它们的混合物，并且其含量范围为0.005-10重量％ ，基于有机硅相。 还公开了相应的涂覆工艺和涂覆的基材。

公开(公告)号：US06995210B2

公开(公告)日：2006-02-07

申请号：US10312425

申请日：2001-06-29

申请人： Bernard Bouvy ,  Martial Deruelle ,  Michel Feder

发明人： Bernard Bouvy ,  Martial Deruelle ,  Michel Feder

IPC分类号： C08K3/20

CPC分类号： C08J3/215 ,  C08J2383/04

摘要： The invention concerns an aqueous dispersion of viscous silicone oils capable of being crosslinked into an elastomer by water elimination (condensation). The invention aims at obtaining an aqueous silicone dispersion corresponding to an optimal compromise in terms of adherence of the crosslinked elastomer on all types of supports, and the colloidal stability of the dispersion during preparation and storage. Said aqueous dispersion comprises a viscous silicone oil A, optionally a crosslinking agent B, optionally an adhesion promoter C (silane), a filler D, a catalyst E, an emulsifier F, optionally a functional additive G and water. Said dispersion is characterised in that the filler D is input into the process for obtaining the dispersion, in the form of an aqueous suspension of at least a hydrophilic compound (CaCO3SiO2, TiO2, Al2/H2O, organic polymer latex). The invention also concerns the preparation of said particularly stable dispersion since it has a residual emulsion rate T not less than 70%. The invention is useful for producing concentrated sealants and elastomer coating for insulating polymer foam (polyurethane).

摘要翻译： 本发明涉及能够通过除水（冷凝）交联成弹性体的粘性硅油的水分散体。 本发明的目的在于获得一种对于在所有类型的载体上交联的弹性体的粘附性方面的最佳折中的水性硅氧烷分散体，以及在制备和储存期间分散体的胶体稳定性。 所述水性分散体包括粘性硅油A，任选的交联剂B，任选的粘合促进剂C（硅烷），填料D，催化剂E，乳化剂F，任选的功能性添加剂G和水。 所述分散体的特征在于，将填料D输入至少一种亲水性化合物（CaCO 3 SiO 2，TiO 2，Al 2 / H 2 O，有机聚合物胶乳）的水性悬浮液形式获得分散体的方法中。 本发明还涉及所述特别稳定的分散体的制备，因为其残留乳液速率T不小于70％。 本发明可用于生产用于绝缘聚合物泡沫（聚氨酯）的浓缩密封剂和弹性体涂层。

公开(公告)号：US5763505A

公开(公告)日：1998-06-09

申请号：US844308

申请日：1997-04-10

申请人： Paul-Joel Derian ,  Michel Feder ,  Jean-Pierre Paillet ,  Michel Peignier ,  Alain Senechal ,  Jean Ulrich

发明人： Paul-Joel Derian ,  Michel Feder ,  Jean-Pierre Paillet ,  Michel Peignier ,  Alain Senechal ,  Jean Ulrich

IPC分类号： C08J3/03

CPC分类号： C08J3/03 ,  C08J2383/04

摘要： A method for preparing oil-in-water emulsions of oils, gums or silicone resins by kneading a mixture of (1) a silicone phase (A) with a viscosity of at least 3 Pas or a consistency of at least 200, and (2) an aqueous phase comprising water, at least one surfactant (B) and optionally at least one water-soluble thickening polymer (C), wherein the relative amounts of water, (B) and optionally (C) are such that the aqueous phase preferably has at least as much viscosity or consistency as the silicone phase (A), said kneading being performed for a sufficient time and with sufficient shear to give an oil-in-water emulsion having a particle size of 0.1-5 .mu.m; and optionally by diluting the medium in water.

摘要翻译： 一种通过将（1）硅氧烷相（A）的粘度为至少3Pa·s或至少200的稠度的混合物和（2）的混合物来制备油，胶或硅树脂的水包油乳液的方法， ）包含水，至少一种表面活性剂（B）和任选的至少一种水溶性增稠聚合物（C）的水相，其中水，（B）和任选（C）的相对量使得水相优选 具有至少与硅氧烷相（A）一样多的粘度或稠度，所述捏合进行足够的时间和足够的剪切，得到粒径为0.1-5μm的水包油乳液; 并且任选地通过将介质稀释在水中。

公开(公告)号：US5145901A

公开(公告)日：1992-09-08

申请号：US419719

申请日：1989-10-11

申请人： Michel Feder

发明人： Michel Feder

IPC分类号： A61K47/34 ,  A01N25/08 ,  A61K9/32 ,  C08J3/03 ,  C08K5/5425 ,  C08K13/02 ,  C08L83/04 ,  C08L83/06

CPC分类号： C08J3/03 ,  C08K13/02 ,  C08K5/5425 ,  C08J2383/04

摘要： Aqueous dispersions of a silicone crosslinkable into elastomeric state by elimination of water therefrom, include:(A) 100 parts of an oil-in-water emulsion of an .alpha.,.omega.-(dihydroxy)polydiorganosiloxane, stabilized with an anionic and/or nonionic surfactant;(B) 0.1 to 20 parts of an alkenyloxysilane;(C) 0.01 to 3 parts of a metal curing catalyst; and(D) 0 to 250 parts of a nonsiliceous inorganic filler material;and such emulsion having a pH of from 7 to 13 and a solids content of at least 40%; the subject emulsions are especially adapted for the production of paints and of silicone elastomer seals, and for the coating of pharmaceuticals, agricultural chemicals and food packaging materials.

摘要翻译： 通过从其中除去水可以交联成弹性体状态的硅氧烷的水性分散体包括：（A）100份由阴离子和/或非离子表面活性剂稳定的α，ω-（二羟基）聚二有机硅氧烷的水包油乳液 ; （B）0.1〜20份的链烯氧基硅烷; （C）0.01〜3份金属固化催化剂; 和（D）0〜250份非皂类无机填料; 和这种乳液，其pH为7至13，固体含量为至少40％; 主题乳液特别适用于生产油漆和硅氧烷弹性体密封件，以及用于药物，农药和食品包装材料的涂覆。