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    Nonaqueous compositions and additives therefor
    2.
    发明授权
    Nonaqueous compositions and additives therefor 有权
    非水组合物及其添加剂

    公开(公告)号：US06540942B2

    公开(公告)日：2003-04-01

    申请号：US09977824

    申请日：2001-10-15

    Applicant: Miguel A. Dones ,  Ramesh L. Narayan

    Inventor： Miguel A. Dones ,  Ramesh L. Narayan

    IPC: C08F246

    CPC classification number: C08L71/02 ,  C08G59/04 ,  C08G65/337 ,  C08G2650/06 ,  C08G2650/16 ,  C08K5/00 ,  C08L63/00 ,  C08L2205/05 ,  C09D7/63 ,  C08L2666/04 ,  C08L71/00

    Abstract: Nonaqueous compositions comprising at least one product of the reaction between A) a linking agent of formula I R4(Y)3  (I) Wherein each Y group is a halogen atom or one Y group is a halogen atom and two Y groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R4 group to form an epoxy group, and R4 is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) a compound of formula II R3(EO)n(PO)m(BO)pX  (II) Wherein R3 is substituted or unsubstituted, saturated or unsaturated, organic oxy or thio group having from 1 to 36 carbon atoms or a primary or secondary amino group having from 1 to 36 carbon atoms; n is a number of from 0 to 50; m is a number of from 0 to 50; p is a number of from 0 to 50; and X is hydrogen, or X can be a mercapto group, an amino group, or a C1-C6 alkylamino group in place of a terminal —OH group, provided that when X is mercapto, amino or a C1-C6 alkylamino, the sum of n, m, and p must be at least 1; and the mole ratio of I:II is from about 0.1:1 to about 5:1.

    Abstract translation: 包含A）每个Y基团之间的式（I）的交联剂的至少一种产物的非水性组合物是卤素原子或一个Y基团是卤素原子，两个Y基团表示环氧氧原子，其与两个相邻碳原子连接 R4基团中的原子形成环氧基，R4是含有3〜10个碳原子的烷撑三基; 和B）式II化合物其中R 3是取代或未取代的饱和或不饱和的具有1至36个碳原子的有机氧基或硫基或具有1至36个碳原子的伯或仲氨基; n为0〜50的数; m是从0到50的数字; p是从0到50的数字; 并且X是氢，或X可以是巯基，氨基或C1-C6烷基氨基代替末端-OH基团，条件是当X是巯基，氨基或C1-C6烷基氨基时，总和 n，m和p必须至少为1; 且I：II的摩尔比为约0.1:1至约5:1。

    Polyester oligomer acrylates
    4.
    发明授权
    Polyester oligomer acrylates 失效
    聚酯低聚物丙烯酸酯

    公开(公告)号：US5912381A

    公开(公告)日：1999-06-15

    申请号：US733682

    申请日：1996-10-17

    Applicant: Ramesh Narayan ,  Miguel A. Dones ,  Michael McDermott

    Inventor： Ramesh Narayan ,  Miguel A. Dones ,  Michael McDermott

    IPC: C07C69/76 ,  C07C271/22 ,  C08F20/28 ,  C08F299/04 ,  C08G63/47 ,  C09D4/00 ,  C09D11/10 ,  C09D167/07

    CPC classification number: C07C69/76 ,  C08G63/47 ,  C09D167/07

    Abstract: A compound having the formula:((CH.sub.2 .dbd.CR.sup.1 --C(O)O--) .sub.x R.sup.2 --(O--C(O)R.sup.3).sub.y --O--C(O)).sub.n --R.sup.4 --(C(O)OM) .sub.mwherein:R.sup.1 is hydrogen or methyl,R.sup.2 is an alkylene group or substituted alkylene group (typically having less than six carbon atoms, more typically two or three carbon atoms),R.sup.3 is an alkylene group or substituted alkylene group (typically having less than ten carbon atoms, more typically from four to six carbon atoms),R.sup.4 is an aromatic radical (e.g. the residue of an aromatic polycarboxylic polyanhydride having a functionality of one half the sum of n and m),n and m are integers from two to four (typically two or three),x is an integer from one to three, andy is an integer from one to five.Among the compounds which fall within the above formula are those in which R.sup.1 is hydrogen, R.sup.2 is an ethylene group, R.sup.3 is a pentamethylene group, and R.sup.4 is the residue of benzene tetracarboxylic dianhydride or benzophenone tetracarboxylic dianhydride, n and m are each two, x is one, and y is two. This invention also relates to a polymerizable composition comprising a compound as set forth above and to a method of coating a substrate comprising polymerizing a composition comprised of the compound set forth above while in contact with a substrate.

    Abstract translation: 具有下式的化合物：（（CH 2 = CR 1 -C（O）O-）xR 2 - （OC（O）R 3）y OC（O））n -R 4 - （C（O）OM）m其中： 或甲基，R 2是亚烷基或取代的亚烷基（通常具有少于6个碳原子，更典型地为2或3个碳原子），R 3是亚烷基或取代的亚烷基（通常具有少于10个碳原子，更典型地 4至6个碳原子），R 4是芳族基团（例如具有n和m的和的一半的官能度的芳族多羧酸聚酐的残基），n和m是2至4的整数（通常为2或3个 ），x为1〜3的整数，y为1〜5的整数。 在上述式中的化合物中，R 1为氢，R 2为亚乙基，R 3为五亚甲基，R 4为苯四甲酸二酐或二苯甲酮四羧酸二酐的残基，n和m分别为2， x是一个，y是两个。 本发明还涉及一种包含上述化合物的可聚合组合物和包衣基质的方法，包括在与基底接触的同时聚合由上述化合物组成的组合物。

    Radiation curable rheology modifiers
    5.
    发明授权
    Radiation curable rheology modifiers 失效
    可辐射固化流变改性剂

    公开(公告)号：US5889076A

    公开(公告)日：1999-03-30

    申请号：US636298

    申请日：1996-04-23

    Applicant: Miguel A. Dones ,  Theresa M. Miller

    Inventor： Miguel A. Dones ,  Theresa M. Miller

    IPC: C08L51/08 ,  C08F2/46 ,  C08F2/48 ,  C08F2/54 ,  C08F283/04 ,  C08G59/17 ,  C08L63/00 ,  C08L63/10 ,  C08L77/00 ,  C08L77/08 ,  C09D4/00 ,  C08J3/28 ,  C08F283/00

    CPC classification number: C08L77/08 ,  C08F283/04 ,  C08L63/10 ,  C09D4/00

    Abstract: A composition that is useful in the preparation of radiation curable coatings is provided. The composition comprises the reaction product of an epoxy component and an acid component comprised of an ethylenically unsaturated carboxylic acid or reactive derivative thereof, reacted in the presence of, or post-reaction blended with, a polyamide based on a polymerized fatty acid. The polyamide preferably has a number average molecular weight of less than about 10,000 g/mole. Also provided is a polymerizable composition comprised of the composition comprised of the reaction product, the polyamide, and a reactive diluent. A method of coating a substrate is also provided which comprises applying to a substrate a composition comprised of the reaction product and the polyamide and exposing said composition to radiation to cure said composition.

    Abstract translation: 提供了可用于制备可辐射固化涂层的组合物。 组合物包含环氧组分和由烯键式不饱和羧酸或其活性衍生物组成的酸组分的反应产物，其在与聚合的脂肪酸基于聚酰胺的存在下或反应后反应混合。 优选聚酰胺的数均分子量小于约10,000g / mol。 还提供了由包含反应产物，聚酰胺和反应性稀释剂的组合物组成的可聚合组合物。 还提供了涂覆基材的方法，其包括将由反应产物和聚酰胺组成的组合物施加到基底上，并将所述组合物暴露于辐射以固化所述组合物。

    Radiation curable rheology modifiers
    6.
    发明授权
    Radiation curable rheology modifiers 失效
    可辐射固化流变改性剂

    公开(公告)号：US5804671A

    公开(公告)日：1998-09-08

    申请号：US631291

    申请日：1996-04-08

    Applicant: Miguel A. Dones ,  Theresa M. Miller

    Inventor： Miguel A. Dones ,  Theresa M. Miller

    IPC: C08F283/04 ,  C08L63/10 ,  C08L77/08 ,  C09D4/00 ,  C08G69/48 ,  C08L77/00

    CPC classification number: C08L77/08 ,  C08F283/04 ,  C08L63/10 ,  C09D4/00

    Abstract: A composition that is useful in the preparation of radiation curable coatings is provided. The composition comprises the reaction product of an epoxy component comprised of a diepoxide and an acid component comprised of an ethylenically unsaturated carboxylic acid or reactive derivative thereof, reacted in the presence of a polyamide based on a polymerized fatty acid. The polyamide preferably has a number average molecular weight of less than about 10,000 g/mole. Also provided is a polymerizable composition comprised of the reaction product and a reactive diluent. A method of coating a substrate is also provided which comprises applying to a substrate a composition comprised of the reaction product and exposing said composition to radiation to cure said composition.

    Abstract translation: 提供了可用于制备可辐射固化涂层的组合物。 组合物包含由二环氧化物组成的环氧组分和由烯键式不饱和羧酸或其活性衍生物组成的酸组分在聚酰胺基于聚合脂肪酸存在下反应的反应产物。 优选聚酰胺的数均分子量小于约10,000g / mol。 还提供了由反应产物和反应性稀释剂组成的可聚合组合物。 还提供了一种涂覆基材的方法，其包括将由反应产物组成的组合物施加到基底上，并将所述组合物暴露于辐射以固化所述组合物。

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