Hydrogen storage electrode and process for producing the same
    1.
    发明授权
    Hydrogen storage electrode and process for producing the same 失效
    储氢电极及其制造方法

    公开(公告)号:US5387478A

    公开(公告)日:1995-02-07

    申请号:US92212

    申请日:1993-07-15

    摘要: A hydrogen storage electrode for use as an anode of an alkaline battery and a process for producing such electrode are disclosed. According to the process, firstly particles of hydrogen storage alloy powder with maximum particle size of 50 .mu.m is prepared. The alloy powder particles are then made into microcapsules by electroless plating with copper amounting to 10%-20% by weight with respect to the sum of the alloy powder and the plating copper. With an electric current collector placed in contact with the copper-plated alloy powder set in a die cavity of a molding press, the molding dies are closed to press and the copper-plated powder and the current collector for bonding them together thereby to form the hydrogen storage electrode. Pressure exerted during the pressing is applied to such an extent that the porosity of the resulting compact of the pressed alloy powder falls in the range of 10% to 25%.

    摘要翻译: 公开了一种用作碱性电池的阳极的储氢电极及其制造方法。 根据该方法,首先制备最大粒径为50微米的储氢合金粉末颗粒。 然后,合金粉末颗粒通过无电镀铜制成微胶囊,相对于合金粉末和电镀铜的总和为10重量%-20重量%。 在集电体与设置在成形机的模腔中的镀铜合金粉末接触的情况下,将模具封闭以进行压制,并将镀铜粉末和集电体接合在一起形成 储氢电极。 在压制过程中施加的压力被施加到所得压制合金粉末的压块的孔隙率在10%至25%的范围内。

    Ternary hydrogen storage alloy and process for production thereof
    7.
    发明授权
    Ternary hydrogen storage alloy and process for production thereof 有权
    三元储氢合金及其生产方法

    公开(公告)号:US06207104B1

    公开(公告)日:2001-03-27

    申请号:US09407066

    申请日:1999-09-28

    IPC分类号: C22C2800

    摘要: An AB2C2-type ternary hydrogen storage alloy comprising an AB2C2 phase as main ingredient, where A comprises at least one of a rare-earth element and Ca, B mainly comprises Mg, and C comprises at least one of transition metal elements of Cu, Ni, Co, Fe, Cr, Mn, Ti, V and Zn, and x and y represent values within the-ranges of 1.5≦x≦2.5 and 1.5 ≦y≦3.5, respectively; and an AB2C3-type ternary hydrogen storage alloy comprising an AB2C3 phase as a main ingredient, where A comprises at least one of a rare-earth element and Ca, B mainly comprises Mg, and C comprises at least one of transition metal elements of Cu, Ni, Co, Fe, Cr, Mn, Ti, V and Zn, each of which has large hydrogen storage capability and desorbing amount per unit weight and hydrogen storage characteristics excellent in reversibility of the hydrogen absorption and desorption and is provided by improving the stability in a hydride state of an alloy mainly comprising a lightweight metal element and increasing the hydrogen dissociation pressure of the hydride.

    摘要翻译: 一种包含AB2C2相作为主要成分的AB2C2型三元氢存储合金,其中A包括稀土元素和Ca,B中的至少一种,主要包括Mg,C包括Cu,Ni中的至少一种过渡金属元素 ,Co,Fe,Cr,Mn,Ti,V和Zn,x和y分别表示在1.5 <= x <= 2.5和1.5 <= y <= 3.5的范围内的值; 和包含AB2C3相作为主要成分的AB2C3型三元储氢合金,其中A包含稀土元素和Ca,B中的至少一种,主要包含Mg,C包括Cu的过渡金属元素中的至少一种 ,Ni,Co,Fe,Cr,Mn,Ti,V和Zn,其各自具有大的储氢能力和每单位重量的解吸量以及氢吸收和解吸的可逆性优异的氢储存特性,并且通过改善 主要包含轻金属元素的合金在氢化物状态下的稳定性,并且增加氢化物的氢解离压力。