公开(公告)号：US06890698B2

公开(公告)日：2005-05-10

申请号：US10104121

申请日：2002-03-21

申请人： Mitsuru Naruse ,  Yoshikazu Kaneko

发明人： Mitsuru Naruse ,  Yoshikazu Kaneko

IPC分类号： B41M5/337 ,  B41M5/30 ,  B41M5/323 ,  B41M5/40 ,  B41M5/42 ,  B41M5/44 ,  C09D129/04 ,  G03F7/004

CPC分类号： B41M5/42 ,  B41M5/323 ,  B41M5/3372 ,  B41M5/3375 ,  B41M5/423 ,  B41M5/426 ,  B41M5/44 ,  B41M2205/04 ,  C09D129/04 ,  C08L2666/36

摘要： A thermosensitive recording material having a support, a thermosensitive coloring layer provided on the support and containing a leuco dye and a color developer for developing the leuco dye upon application of heat, and a protective layer provided on the thermosensitive coloring layer and containing polyvinyl alcohol having reactive carbonyl groups, a hydrazide compound which crosslinks the polyvinyl alcohol through the reactive carbonyl groups, and a basic filler. The protective layer may be formed by applying a coating composition containing polyvinyl alcohol having reactive carbonyl groups, a hydrazide compound which crosslinks the polyvinyl alcohol through the reactive carbonyl groups, and a basic filler onto a thermosensitive coloring layer provided on a support, and drying the applied coating composition to crosslink the polyvinyl alcohol.

摘要翻译： 具有支持体的热敏记录材料，设置在载体上的含有无色染料的热敏着色层和用于在加热时显影无色染料的显色剂，以及设置在热敏着色层上的含有聚乙烯醇的保护层， 反应性羰基，通过反应性羰基交联聚乙烯醇的酰肼化合物和碱性填料。 保护层可以通过将含有具有反应性羰基的聚乙烯醇的涂料组合物，通过反应性羰基将聚乙烯醇交联的酰肼化合物和碱性填料施加到设置在载体上的热敏着色层上而形成，并干燥 涂覆组合物以交联聚乙烯醇。

公开(公告)号：US06710015B2

公开(公告)日：2004-03-23

申请号：US10178770

申请日：2002-06-25

申请人： Yoshikazu Kaneko ,  Yasutomo Mori ,  Mitsuru Naruse ,  Kunio Hayakawa ,  Mitsunobu Morita

发明人： Yoshikazu Kaneko ,  Yasutomo Mori ,  Mitsuru Naruse ,  Kunio Hayakawa ,  Mitsunobu Morita

IPC分类号： B41M520

CPC分类号： B41M5/44 ,  B41M2205/04 ,  B41M2205/38

摘要： A thermosensitive recording material having a support, a thermosensitive recording layer containing a leuco dye and a color developer, and an intermediate layer interposed therebetween. The intermediate layer contains hollow particles having a hollowness of 60 to 98%, a maximum particle diameter (D100) of 5.0 to 10.0 &mgr;m and a ratio D100/D50 of the maximum particle diameter (D100) to the median volume equivalent particle diameter (D50) in the range of 1.5 to 3.0. The hollow particles may be composed of a crosslinked polymer of a chlorine-free vinyl monomer.

摘要翻译： 具有载体的热敏记录材料，含有无色染料的热敏记录层和彩色显影剂，以及介于其间的中间层。 中间层含有空心粒度为60〜98％，最大粒径（D100）为5.0〜10.0μm，最大粒径（D100）与中等体积当量粒径（D50）的比D100 / D50 ）在1.5至3.0的范围内。 中空颗粒可以由无氯乙烯基单体的交联聚合物组成。

公开(公告)号：US20210292541A1

公开(公告)日：2021-09-23

申请号：US17198563

申请日：2021-03-11

申请人： Satoshi OGAWA ,  Tomoharu Miki ,  Mitsuru Naruse

发明人： Satoshi OGAWA ,  Tomoharu Miki ,  Mitsuru Naruse

IPC分类号： C08L53/00 ,  B33Y10/00 ,  B33Y70/00 ,  B29C64/153

摘要： Provided is a resin powder containing a polyolefin-based resin, wherein the average circularity of the resin powder is 0.950 or greater, a logarithmically converted value Log R of the volume resistivity R of the resin powder is 11.5 or less, and the degree of compression of the resin powder is 1.45 or less. An embodiment where the volume average particle diameter of the resin powder is 10 micrometers or greater but 150 micrometers or less, an embodiment where the resin powder further contains an antistatic agent, an embodiment where the antistatic agent is water-insoluble, and an embodiment where the content of the antistatic agent is 0.5% by mass or greater but less than 20% by mass relative to the total amount of the resin powder are preferable.

公开(公告)号：US09597891B2

公开(公告)日：2017-03-21

申请号：US14674361

申请日：2015-03-31

申请人： Masayasu Nonogaki ,  Mitsuru Naruse ,  Akihiko Matsuyama ,  Keita Katoh ,  Kazukiyo Nagai ,  Yuusuke Koizuka

发明人： Masayasu Nonogaki ,  Mitsuru Naruse ,  Akihiko Matsuyama ,  Keita Katoh ,  Kazukiyo Nagai ,  Yuusuke Koizuka

IPC分类号： B41J2/21 ,  C09D143/02 ,  C09D139/06

CPC分类号： B41J2/2107 ,  C09D139/06 ,  C09D143/02

摘要： An inkjet ink contains water, a hydrosoluble organic solvent, a pigment, polyvinyl pyrolidone, and a copolymer, wherein the copolymer contains a structure unit represented by Chemical formula 1, where R1 represents a hydrogen atom or a methyl group, R2 is an alkyl group having one to four carbon atoms, M1+, M2+, M3+, and M4+ each, independently represent protons, alkali metal ions, or organic ammonium ions, and a structure unit represented by Chemical formula 2, where R3 represents a hydrogen atom or a methyl group, a structure unit represented by Chemical formula 3, where R4 represents a hydrogen atom or a methyl group, or a structure unit represented by Chemical formula 4, where R5 represents a hydrogen atom or a methyl group.

公开(公告)号：US09321926B2

公开(公告)日：2016-04-26

申请号：US14676168

申请日：2015-04-01

申请人： Keita Katoh ,  Shigeyuki Harada ,  Masayuki Fukuoka ,  Mitsuru Naruse ,  Masayasu Nonogaki ,  Akihiko Matsuyama ,  Kazukiyo Nagai ,  Yuusuke Koizuka

发明人： Keita Katoh ,  Shigeyuki Harada ,  Masayuki Fukuoka ,  Mitsuru Naruse ,  Masayasu Nonogaki ,  Akihiko Matsuyama ,  Kazukiyo Nagai ,  Yuusuke Koizuka

IPC分类号： C09D11/30 ,  C09D11/107 ,  C09D11/326

CPC分类号： C09D11/107 ,  C09D11/326

摘要： An ink for inkjet recording includes water; a hydrosoluble solvent; a pigment; and a copolymer including a phosphonic acid group. The copolymer including a phosphonic acid group includes structural units having the following formulae (1) and (2): wherein R1 represents a hydrogen atom or a methyl group; and M represents a hydrogen atom, an alkali metal or an organic ammonium; and wherein R2 represents a hydrogen atom or a methyl group; R3 represents an alkyl group having 1 to 4 carbon atoms; and each of n and m represents 0 or an integer of from 1 to 30, provided n+m is from 2 to 30.

摘要翻译： 用于喷墨记录的墨水包括水; 水溶性溶剂; 颜料; 和包含膦酸基的共聚物。 包括膦酸基的共聚物包括具有下式（1）和（2）的结构单元：其中R 1表示氢原子或甲基; M表示氢原子，碱金属或有机铵; 并且其中R 2表示氢原子或甲基; R3表示碳原子数1〜4的烷基。 n和m分别表示0或1〜30的整数，n + m为2〜30。

公开(公告)号：US09309427B2

公开(公告)日：2016-04-12

申请号：US14456287

申请日：2014-08-11

申请人： Akihiko Matsuyama ,  Mitsuru Naruse ,  Masayasu Nonogaki ,  Kazukiyo Nagai ,  Keita Katoh ,  Yuusuke Koizuka

发明人： Akihiko Matsuyama ,  Mitsuru Naruse ,  Masayasu Nonogaki ,  Kazukiyo Nagai ,  Keita Katoh ,  Yuusuke Koizuka

IPC分类号： C09D11/322 ,  C08L43/02 ,  C09D11/107 ,  C09D11/326 ,  C09D11/38

CPC分类号： C09D11/322 ,  C09D11/107 ,  C09D11/326 ,  C09D11/38 ,  Y10T428/24901

摘要： An ink composition contains a pigment; a copolymer comprising a phosphoric acid group or phosphonic acid group; a hydrosoluble solvent; and water, wherein the pigment is represented by the following chemical formula 1 and satisfies the following relation 1: Y/X≦0.20  Relation 1 where X represents a peak intensity at a Bragg (2θ±0.2°) angle in a range of 2θ of from 26.5° to 27.5° and Y represents a peak intensity at a Bragg (2θ±0.2°) angle in a range of 2θ of from 11.0° to 11.5° to a CuKα X-ray having a wavelength of 1.541 Å.

摘要翻译： 油墨组合物含有颜料; 包含磷酸基或膦酸基的共聚物; 水溶性溶剂; 和水，其中颜料由以下化学式1表示，并且满足以下关系1：Y / X＆nlE; 0.20关系1其中X表示在2＆amp;该范围内的布拉格（2＆amp;±0.2°）角的峰强度 ; 为26.5°至27.5°，Y表示在2θ范围内的布拉格（2θ;±0.2°）角处的峰值强度; 从11.0°至11.5°的波长为1.541的CuKαX射线。

公开(公告)号：US09217091B2

公开(公告)日：2015-12-22

申请号：US14202322

申请日：2014-03-10

申请人： Keita Katoh ,  Mitsuru Naruse ,  Akihiko Matsuyama ,  Masayasu Nonogaki ,  Minoru Hakiri ,  Yuusuke Koizuka ,  Kazukiyo Nagai ,  Nobuyuki Sakamoto ,  Yosuke Matsuoka ,  Masatomo Takahashi

发明人： Keita Katoh ,  Mitsuru Naruse ,  Akihiko Matsuyama ,  Masayasu Nonogaki ,  Minoru Hakiri ,  Yuusuke Koizuka ,  Kazukiyo Nagai ,  Nobuyuki Sakamoto ,  Yosuke Matsuoka ,  Masatomo Takahashi

IPC分类号： C09D11/326 ,  C09D11/107

CPC分类号： C09D11/326 ,  C09D11/107

摘要： An inkjet recording ink, including: water; a water-soluble solvent; a pigment; and a phosphate group-containing copolymer, wherein the phosphate group-containing copolymer includes a structural unit represented by the following general formula (1) and a structural unit represented by the following structural formula (1): wherein, in the general formula (1), R1 represents either of a hydrogen atom and a methyl group; and M+ represents any of an alkali metal ion, an organic ammonium ion, an organic amine ion and a hydrogen ion, one-half or more of the M+ in the copolymer is an alkali metal ion, an organic ammonium ion or an organic amine, and the remainder is a hydrogen ion:

摘要翻译： 喷墨记录油墨，包括：水; 水溶性溶剂; 颜料; 和含磷酸酯基的共聚物，其中所述含磷酸酯基的共聚物包括由以下通式（1）表示的结构单元和由以下结构式（1）表示的结构单元：其中，在通式（1） ），R 1表示氢原子和甲基中的任一个; M +表示碱金属离子，有机铵离子，有机胺离子和氢离子中的任一种，共聚物中的M +的一半以上为碱金属离子，有机铵离子或有机胺， 其余为氢离子：

公开(公告)号：US20150307734A1

公开(公告)日：2015-10-29

申请号：US14674361

申请日：2015-03-31

申请人： Masayasu NONOGAKI ,  Mitsuru Naruse ,  Akihiko Matsuyama ,  Keita Katoh ,  Kazukiyo Nagai ,  Yuusuke Koizuka

发明人： Masayasu NONOGAKI ,  Mitsuru Naruse ,  Akihiko Matsuyama ,  Keita Katoh ,  Kazukiyo Nagai ,  Yuusuke Koizuka

IPC分类号： C09D143/02 ,  C09D139/06

CPC分类号： B41J2/2107 ,  C09D139/06 ,  C09D143/02

摘要： An inkjet ink contains water, a hydrosoluble organic solvent, a pigment, polyvinyl pyrolidone, and a copolymer, wherein the copolymer contains a structure unit represented by Chemical formula 1, where R1 represents a hydrogen atom or a methyl group, R2 is an alkyl group having one to four carbon atoms, M1+, M2+, M3+, and M4+ each, independently represent protons, alkali metal ions, or organic ammonium ions, and a structure unit represented by Chemical formula 2, where R3 represents a hydrogen atom or a methyl group, a structure unit represented by Chemical formula 3, where R4 represents a hydrogen atom or a methyl group, or a structure unit represented by Chemical formula 4, where R5 represents a hydrogen atom or a methyl group.

摘要翻译： 喷墨油墨含有水，水溶性有机溶剂，颜料，聚乙烯基吡咯烷酮和共聚物，其中共聚物含有由化学式1表示的结构单元，其中R1表示氢原子或甲基，R2表示烷基 具有一至四个碳原子，M 1 +，M 2+，M 3+和M 4 +各自独立地表示质子，碱金属离子或有机铵离子，以及由化学式2表示的结构单元，其中R 3表示氢原子或甲基 ，由化学式3表示的结构单元，其中R4表示氢原子或甲基，或由化学式4表示的结构单元，其中R5表示氢原子或甲基。

公开(公告)号：US20150252203A1

公开(公告)日：2015-09-10

申请号：US14625051

申请日：2015-02-18

申请人： Akihiko Matsuyama ,  Shigeyuki Harada ,  Keita Katoh ,  Masayuki Fukuoka ,  Mitsuru Naruse ,  Kazukiyo Nagai ,  Yuusuke Koizuka ,  Masayasu Nonogaki

发明人： Akihiko Matsuyama ,  Shigeyuki Harada ,  Keita Katoh ,  Masayuki Fukuoka ,  Mitsuru Naruse ,  Kazukiyo Nagai ,  Yuusuke Koizuka ,  Masayasu Nonogaki

IPC分类号： C09D11/322 ,  C08K5/29 ,  C08K5/3437

CPC分类号： C09D11/322 ,  C08K5/29 ,  C08K5/3437 ,  C09B33/153 ,  C09B48/00 ,  C09B67/009 ,  C09D11/106 ,  C09D11/326 ,  Y10T428/24901

摘要： An ink composition contains a pigment, a polymer having a structure unit having a diphosphonic acid group, a hydrosoluble solvent, and water, and satisfies the following A and B.A: The pigment is represented by the following chemical formula 1a or chemical formula 1b. As for Chemical formula 1a, the pigment satisfies the relation 1: Y/X≦0.800, where X and Y represent peak intensities at a Bragg (2θ±0.2°) angle in a CuKα X-ray diffraction spectrum, when the pigment is represented by Chemical formula 1b, the pigment satisfies the relation 2: Y′/X′≦0.200, where X′ and Y′ represent peak intensities at a Bragg (2θ±0.2°) angle in a CuKα X-ray diffraction spectrum, B. the structure unit having a diphosphonic acid group is represented by Chemical formula 2.

摘要翻译： 油墨组合物含有颜料，具有二膦酸基的结构单元的聚合物，水溶性溶剂和水，并且满足以下A和B. A：颜料由以下化学式1a或化学式1b表示 。 对于化学式1a，颜料满足关系式1：Y / X＆nlE; 0.800，其中X和Y表示在CuKαX射线衍射光谱中的布拉格（2＆amp;±0.2°）角的峰强度，当颜料为 由化学式1b表示，颜料满足关系式2：Y'/ X'＆nlE; 0.200，其中X'和Y'表示在CuKαX射线衍射光谱中Bragg（2θ;±0.2°）角处的峰值强度 ，B.具有二膦酸基团的结构单元由化学式2表示。

公开(公告)号：US20150109382A1

公开(公告)日：2015-04-23

申请号：US14505667

申请日：2014-10-03

申请人： Mitsuru Naruse ,  Masayasu Nonogaki ,  Akihiko Matsuyama ,  Keita Katoh ,  Kazukiyo Nagai ,  Yuusuke Koizuka

发明人： Mitsuru Naruse ,  Masayasu Nonogaki ,  Akihiko Matsuyama ,  Keita Katoh ,  Kazukiyo Nagai ,  Yuusuke Koizuka

IPC分类号： C09D11/106 ,  C09D11/322 ,  C09D133/08 ,  B41J2/175

CPC分类号： C09D133/08 ,  B41J29/13 ,  C09D11/107 ,  C09D11/322 ,  C08F2220/185 ,  C08F230/02 ,  C08F2220/1891

摘要： An ink for inkjet recording includes water; a hydrosoluble organic solvent; a pigment; and a polymer including a first structural unit represented by the following formula (1): wherein R1 represents a hydrogen atom or a methyl group; and M+ represents at least one member selected from the group consisting of alkali metal ions, organic amine ions and hydrogen ions; and a second structural unit represented by the following formula (2) or (3): wherein each of R2 and R3 represents a methyl group or a hydrogen atom; n represents an integer of 18; x represents 0 or an integer of 2.

摘要翻译： 用于喷墨记录的墨水包括水; 水溶性有机溶剂; 颜料; 和包含由下式（1）表示的第一结构单元的聚合物：其中R1表示氢原子或甲基; M +表示选自碱金属离子，有机胺离子和氢离子中的至少一种; 和由下式（2）或（3）表示的第二结构单元：其中R 2和R 3各自表示甲基或氢原子; n表示18的整数; x表示0或2的整数。