公开(公告)号：US20050272629A1

公开(公告)日：2005-12-08

申请号：US10524029

申请日：2003-08-13

申请人： Motomitsu Hasumi ,  Toshiki Nishi ,  Teruo Kubota ,  Shu Yamaguchi ,  Hideichi Nitta ,  Hiroyuki Yamashita

发明人： Motomitsu Hasumi ,  Toshiki Nishi ,  Teruo Kubota ,  Shu Yamaguchi ,  Hideichi Nitta ,  Hiroyuki Yamashita

IPC分类号： C11D3/12 ,  C11D3/37 ,  C11D11/00 ,  C11D17/00 ,  C11D17/06

CPC分类号： C11D11/0088 ,  C11D17/0039 ,  C11D17/06

摘要： A detergent particle comprising a base detergent particle, a base layer comprising a fine powder, prepared by treating a surface of the base detergent particle with a fine powder dispersion, in which a fine powder is dispersed in a binder, wherein the base layer is formed on the surface of the base detergent particle, and a surface coating comprising a surface modifier, which is formed on the base layer; a process for preparing a detergent particle, comprising the steps of treating a surface of a base detergent particle with a fine powder dispersion in which the fine powder is dispersed in a binder as a dispersion medium to form a base layer on the surface of the base detergent particle; and surface-coating the base layer with a surface modifier; and a fine powder dispersion for forming a base layer comprising a binder and a fine powder, wherein the fine powder is dispersed in the binder. The detergent composition comprising the detergent particle of the present invention can be used as laundry detergents, laundry bleaching agents, cleaning agents for hard surfaces such as detergents for automatic dishwashers, pipe cleaners, and the like.

摘要翻译： 一种洗涤剂颗粒，其包含基础洗涤剂颗粒，包含细粉末的基底层，其通过用细粉末分散体处理基础洗涤剂颗粒的表面而制备，其中细粉末分散在粘合剂中，其中形成基底层 在基础洗涤剂颗粒的表面上，以及包含表面改性剂的表面涂层，其形成在基底层上; 一种制备洗涤剂颗粒的方法，包括以细粉分散体处理基础洗涤剂颗粒表面的步骤，其中细粉末作为分散介质分散在粘合剂中以在基材的表面上形成基层 洗涤剂颗粒; 并用表面改性剂表面涂覆基层; 以及用于形成包含粘合剂和细粉末的基底层的细粉末分散体，其中细粉末分散在粘合剂中。 包含本发明的洗涤剂颗粒的洗涤剂组合物可用作衣物洗涤剂，衣物漂白剂，硬表面清洁剂，例如用于自动洗碗机的洗涤剂，管道清洁剂等。

公开(公告)号：US07115548B1

公开(公告)日：2006-10-03

申请号：US09889497

申请日：2000-01-14

申请人： Shu Yamaguchi ,  Hideichi Nitta ,  Kyoko Okada ,  Kimihiro Mizusawa ,  Jun Kozuka ,  Toshiharu Noguchi ,  Hiroyuki Yamashita

发明人： Shu Yamaguchi ,  Hideichi Nitta ,  Kyoko Okada ,  Kimihiro Mizusawa ,  Jun Kozuka ,  Toshiharu Noguchi ,  Hiroyuki Yamashita

IPC分类号： C11D17/06 ,  C11D3/08

CPC分类号： C11D17/065 ,  C11D1/83

摘要： A high-density detergent composition comprises 10 to 60% by weight of a surfactant composition having a weight ratio of an anionic surfactant to a nonionic surfactant of 4:10 or more and 10:0 or less, wherein the high-density detergent composition has a bulk density of from 600 to 1200 g/L, and has a total summation of a product of a mass base frequency Wi and a dissolving rate Vi of each group of classified granules obtained by classifying detergent granules by using a classifier, which satisfies the following formula: Σ(Wi·Vi)≧95(%), and wherein a mass base frequency of the classified granules having a size of less than 125 μm is 0.1 or less, wherein the classifier comprises sieves each having a sieve-opening 2000 μm, 1410 μm, 1000 μm, 710 μm, 500 μm, 355 μm, 250 μm, 180 μm, and 125 μm, and a receiver.

摘要翻译： 高密度洗涤剂组合物包含10至60重量％的具有阴离子表面活性剂与非离子表面活性剂的重量比为4:10或更高至10：0或更低的表面活性剂组合物，其中高密度洗涤剂组合物具有 堆积密度为600〜1200g / L，并且通过使用分级机对通过使用分级机分级洗涤剂颗粒而获得的各组分级颗粒的质量基准频率Wi和溶解速率Vi的乘积的总和，满足 下式：Sigma（Wi.Vi）> = 95（％），其中尺寸小于125μm的分级颗粒的质量基础频率为0.1或更小，其中分选机包括各自具有筛孔 2000个妈妈，1410个妈妈，1000个妈妈，710个妈妈，500个妈妈，355个妈妈，250个妈妈，180个妈妈和125个妈妈，以及一个接收者。

公开(公告)号：US06818605B1

公开(公告)日：2004-11-16

申请号：US10009684

申请日：2001-12-13

申请人： Takeshi Ban ,  Teruo Kubota ,  Shu Yamaguchi ,  Hiroyuki Saijo ,  Hiroyuki Yamashita

发明人： Takeshi Ban ,  Teruo Kubota ,  Shu Yamaguchi ,  Hiroyuki Saijo ,  Hiroyuki Yamashita

IPC分类号： C11D1700

CPC分类号： C11D3/046 ,  C11D3/08 ,  C11D3/10 ,  C11D3/12 ,  C11D3/128 ,  C11D17/065

摘要： The present invention relates to a granular detergent composition having easy measurability and distributivity suitable for spoon measurement, a bulk density thereof being 500 g/L or more, containing a surfactant, a water-insoluble inorganic compound and a water-soluble salt, wherein the granular detergent composition has a variance of powder dropping rate V of 1.0 or less, an inserting pressure P of 80 gf/cm or less, a &Dgr; dropping ratio D of 14% of les, and an index K of from 30 to 230, the index K being represented by the equation: K=P×exp (0.135×D), wherein P stands for an inserting pressure (gf/cm), and D stands for a &Dgr; dropping ratio (%); and a process for preparing the same.

摘要翻译： 本发明涉及一种粒状洗涤剂组合物，其具有容易测量和分布适用于勺子测量，其堆积密度为500g / L或更高，含有表面活性剂，水不溶性无机化合物和水溶性盐，其中 颗粒状洗涤剂组合物的粉末滴下速度V的变化为1.0以下，插入压力P为80gf / cm以下，Δ滴加比D为14％，指数K为30〜230， 指数K由下式表示：K = Pxexp（0.135×D），其中P表示插入压力（gf / cm），D表示Δ下降率（％）。 及其制备方法。

公开(公告)号：US06521585B1

公开(公告)日：2003-02-18

申请号：US09068476

申请日：1998-05-06

申请人： Hiroyuki Yamashita ,  Shu Yamaguchi ,  Teruo Kubota ,  Katsuhiko Kasai ,  Shigeru Tamura ,  Masaki Tsumadori

发明人： Hiroyuki Yamashita ,  Shu Yamaguchi ,  Teruo Kubota ,  Katsuhiko Kasai ,  Shigeru Tamura ,  Masaki Tsumadori

IPC分类号： C11D1100

CPC分类号： C11D3/08 ,  C11D1/04 ,  C11D1/143 ,  C11D1/146 ,  C11D1/29 ,  C11D1/72 ,  C11D1/83 ,  C11D3/1273 ,  C11D3/128 ,  C11D11/0082 ,  C11D11/04 ,  C11D17/065

摘要： Detergent formulations incorporating crystalline alkali metal silicate granules provide enhanced performance in removing sebum dirt stains at low dosages of detergent in the wash. The detergent formulations are prepared by combining an alkali metal silicate having a high pH value with a nonionic surfactant and an acid precursor of an anionic surfactant capable of having a lamellar orientation. The formulation is granulated by tumbling in an agitating mixer while increasing the bulk density at elevated temperatures to yield alkali metal silicate granules having a bulk density of from 0.6 to 1.2 g/ml.

摘要翻译： 掺入结晶碱金属硅酸盐颗粒的洗涤剂配方提供了在洗涤剂中低剂量洗涤剂中除去皮脂污垢的增强性能。 洗涤剂配方通过将具有高pH值的碱金属硅酸盐与非离子表面活性剂和能够具有层状取向性的阴离子表面活性剂的酸前体组合来制备。 通过在搅拌混合器中翻转而将制剂造粒，同时在升高的温度下增加堆积密度，得到体积密度为0.6至1.2g / ml的碱金属硅酸盐颗粒。

公开(公告)号：US06534474B1

公开(公告)日：2003-03-18

申请号：US09701781

申请日：2000-12-04

申请人： Kyoko Okada ,  Teruo Kubota ,  Hitoshi Takaya ,  Shu Yamaguchi ,  Hiroyuki Yamashita

发明人： Kyoko Okada ,  Teruo Kubota ,  Hitoshi Takaya ,  Shu Yamaguchi ,  Hiroyuki Yamashita

IPC分类号： C11D183

CPC分类号： C11D17/06 ,  C11D1/83 ,  C11D3/3707 ,  C11D10/045

摘要： The surfactant composition of the present invention is a surfactant composition which is capable of being formulated for use in a non-liquid detergent composition, the surfactant composition comprising a) a nonionic surfactant having a melting point of 30° C. or less; b) an anionic surfactant having sulfonate group; and c) an immobilization agent for a) component, wherein b) component is formulated in an amount of from 0 to 300 parts by weight, based on 100 parts by weight of a) component, and wherein c) component is formulated in an amount of from 1 to 100 parts by weight, based on 100 parts by weight of a) component, and wherein the surfactant composition has (1) a temperature range that a viscosity of the composition is 10 Pa·s or less at a temperature equal to or higher than a pour point of the surfactant composition; and (2) a temperature range that a penetrating hardness of the composition is 100 g/cm2 or more in a temperature range between a temperature lower than the pour point of the surfactant composition and a temperature higher than the melting point of a) component.

摘要翻译： 本发明的表面活性剂组合物是能够配制用于非液体洗涤剂组合物的表面活性剂组合物，所述表面活性剂组合物包含a）熔点为30℃以下的非离子表面活性剂; b）具有磺酸盐基团的阴离子表面活性剂; 和c）a）组分的固定剂，其中b）组分的配制量为0至300重量份，基于100重量份的a）组分，并且其中c）组分配制成一定量 1至100重量份，基于100重量份的a）组分，并且其中表面活性剂组合物具有（1）组合物的粘度在等于或等于10℃的温度下为10Pa·s以下的温度范围 或高于表面活性剂组合物的倾点; 和（2）在比表面活性剂组合物的倾点低的温度和高于a）成分的熔点的温度的温度范围内组合物的穿透硬度为100g / cm 2以上的温度范围。

公开(公告)号：US06376453B1

公开(公告)日：2002-04-23

申请号：US09355032

申请日：1999-07-22

申请人： Teruo Kubota ,  Hitoshi Takaya ,  Shu Yamaguchi ,  Hiroyuki Yamashita ,  Shuji Takana

发明人： Teruo Kubota ,  Hitoshi Takaya ,  Shu Yamaguchi ,  Hiroyuki Yamashita ,  Shuji Takana

IPC分类号： C11D1700

CPC分类号： C11D11/02 ,  C11D3/0052 ,  C11D17/065

摘要： To provide detergent particles having high-speed dissolution capable of dissolving quickly in water after supplying the detergent particles in water, and a method for preparing the detergent particles, and a detergent composition comprising the detergent particles. Detergent particles having an average particle size of from 150 to 500 &mgr;m and a bulk density of 500 g/liter or more, wherein the detergent particles comprising a detergent particle being capable of releasing a bubble from an inner portion of the detergent particles in a process of dissolving the detergent particle in water, the bubble having a size of one-tenth or more of a particle size of the detergent particle, and wherein the detergent particles have a dissolution rate as calculated by Equation (1) of 90% or more, under conditions where the detergent particles are supplied in water at 5° C.; stirred for 60 seconds under the test stirring conditions; and filtered with a standard sieve having a sieve-opening of 74 &mgr;m as defined by JIS Z 8801, or wherein the detergent particles have a dissolution rate of 82% or more, the detergent particles stirred for 30 seconds and calculated in the same manner as above.

摘要翻译： 提供具有高速溶解性能的洗涤剂颗粒，以及包含洗涤剂颗粒的洗涤剂组合物，其中洗涤剂颗粒在将洗涤剂颗粒供给到水中之后能迅速溶解在水中。 平均粒度为150〜500μm，体积密度为500g / l以上的洗涤剂粒子，其中，含有洗涤剂粒子的洗涤剂粒子能够以洗涤剂粒子的内部从内部释放气泡 将洗涤剂颗粒溶解在水中，气泡的尺寸为洗涤剂颗粒的粒径的十分之一以上，其中洗涤剂颗粒具有90％以上的等式（1）计算的溶解速率， 在洗涤剂颗粒在5℃的水中供应的条件下进行。 在试验搅拌条件下搅拌60秒; 用JIS Z 8801定义的筛孔为74μm的筛子进行过滤，或者其中洗涤剂颗粒的溶解率为82％以上，洗涤剂颗粒搅拌30秒，并以与 以上。

公开(公告)号：US07067469B2

公开(公告)日：2006-06-27

申请号：US10661643

申请日：2003-09-15

申请人： Yuhki Yanagisawa ,  Nobuyoshi Yamaguchi ,  Shu Yamaguchi ,  Hitoshi Takaya ,  Hiroyuki Yamashita

发明人： Yuhki Yanagisawa ,  Nobuyoshi Yamaguchi ,  Shu Yamaguchi ,  Hitoshi Takaya ,  Hiroyuki Yamashita

IPC分类号： C11D17/00

CPC分类号： C11D3/0052 ,  C11D17/0047 ,  C11D17/065

摘要： A solid-shaped detergent comprising particles for detergent, wherein the particles have a dissolution rate of 90% or more, under conditions where the particles are supplied in water at 5° C.; stirred for 60 seconds under the stirring conditions that 1 g of the particles are supplied to a 1-L beaker having an inner diameter of 105 mm which is charged with 1 L of hard water having 71.2 mg CaCO3/L, wherein a molar ratio of Ca/Mg is 7/3, and stirred with a stirring bar of 35 mm in length and 8 mm in diameter at a rotational speed of 800 rpm; and filtered with a standard sieve having a sieve-opening of 74 μm as defined by JIS Z 8801, wherein the dissolution rate of the particles is calculated by the Equation (1): Dissolution Rate (%)=[1−(T/S)]×100,  (1) wherein S is a weight (g) of the particles supplied; and T is a dry weight (g) of insoluble remnants of the particles remaining on the sieve when an aqueous solution prepared under the above stirring conditions is filtered with the sieve.

摘要翻译： 一种固体形洗涤剂，其包含用于洗涤剂的颗粒，其中颗粒在5℃的水中供应的条件下，其溶解速率为90％以上。 在搅拌条件下搅拌60秒，将1g的颗粒供给到内径为105mm的1L的烧杯中，该烧杯装入1L的具有71.2mg CaCO 3的硬水， / L，其中Ca / Mg的摩尔比为7/3，并以800rpm的转速与长35mm，直径8mm的搅拌棒一起搅拌; 并用JIS Z 8801定义的筛孔为74μm的筛孔进行过滤，其中通过式（1）计算出颗粒的溶解速度：<？in-line-formula description =“In-line 公式“end =”lead“？>溶解速率（％）= [1-（T / S）] x100，（1）<？在线公式描述=”在线公式“end =”tail“？ >其中S是所供应颗粒的重量（g）; 当用筛子过滤在上述搅拌条件下制备的水溶液时，T是残留在筛上的颗粒的不溶性残留物的干重（g）。

公开(公告)号：US5961662A

公开(公告)日：1999-10-05

申请号：US793870

申请日：1997-03-11

申请人： Shu Yamaguchi ,  Noriaki Ushio ,  Akiko Ishikura ,  Katsuhiko Kasai ,  Masaki Tsumadori ,  Hiroyuki Yamashita

发明人： Shu Yamaguchi ,  Noriaki Ushio ,  Akiko Ishikura ,  Katsuhiko Kasai ,  Masaki Tsumadori ,  Hiroyuki Yamashita

IPC分类号： C11D3/08 ,  C11D3/12 ,  C11D3/33 ,  C11D3/36 ,  C11D3/37

CPC分类号： C11D3/365 ,  C11D3/08 ,  C11D3/126 ,  C11D3/1273 ,  C11D3/128 ,  C11D3/33 ,  C11D3/361 ,  C11D3/364 ,  C11D3/3761

摘要： A washing method is described which has excellent washing power and a low surfactant concentration. The described clothes washing method comprises the use of a phosphorus-free clothes detergent composition comprising (a) one or more surfactants, (b) one or more alkali metal silicates, and (c) one or more metal ion capturing agents other than the alkali metal silicate (b). The above detergent composition is added to water in an amount sufficient to produce a washing liquid having the following washing conditions (1) a pH of not less than 10.60; (2) containing a material having an ion capturing capacity in an amount sufficient for theoretically changing the water hardness of said water to be not more than 0.5.degree. DH; and (3) having a surfactant concentration of from 0.07 to 0.17 g/L.

摘要翻译： PCT No.PCT / JP95 / 01750 Sec。 371日期1997年3月10日 102（e）1997年3月10日PCT PCT 1995年9月1日PCT公布。 公开号WO96 / 08552 日期：1996年3月21日描述了具有优异洗涤力和低表面活性剂浓度的洗涤方法。 所描述的衣物洗涤方法包括使用无磷衣物洗涤剂组合物，其包含（a）一种或多种表面活性剂，（b）一种或多种碱金属硅酸盐，和（c）除碱之外的一种或多种金属离子捕获剂 金属硅酸盐（b）。 将上述洗涤剂组合物以足以产生具有以下洗涤条件的洗涤液的量加入到水中（1）pH不小于10.60; （2）含有足以使所述水的理论上将所述水的硬度变化为0.5℃以下的离子捕捉能力的材料; 和（3）表面活性剂浓度为0.07至0.17g / L。

公开(公告)号：USRE38411E1

公开(公告)日：2004-02-03

申请号：US09970688

申请日：2001-10-05

申请人： Shu Yamaguchi ,  Noriaki Ushio ,  Akiko Ishikura ,  Katsuhiko Kasai ,  Masaki Tsumadori ,  Hiroyuki Yamashita

发明人： Shu Yamaguchi ,  Noriaki Ushio ,  Akiko Ishikura ,  Katsuhiko Kasai ,  Masaki Tsumadori ,  Hiroyuki Yamashita

IPC分类号： C11D308

CPC分类号： C11D3/128 ,  C11D3/126 ,  C11D3/1273 ,  C11D3/33 ,  C11D3/361 ,  C11D3/364 ,  C11D3/365 ,  C11D3/3761 ,  C11D11/0017

摘要： A washing method is described which has excellent washing power and a low surfactant concentration. The described clothes washing method comprises the use of a phosphorus-free clothes detergent composition comprising (a) one or more surfactants, (b) one or more alkali metal silicates, and (c) one or more metal ion capturing agents other than the alkali metal silicate (b). The above detergent composition is added to water in an amount sufficient to produce a washing liquid having the following washing conditions (1) a pH of not less than 10.60; (2) containing a material having an ion capturing capacity in an amount sufficient for theoretically changing the water hardness of said water to be not more than 0.5° DH; and (3) having a surfactant concentration of from 0.07 to 0.17 g/L.

公开(公告)号：US06864221B1

公开(公告)日：2005-03-08

申请号：US09762948

申请日：2000-06-14

申请人： Shuji Takana ,  Hitoshi Takaya ,  Hiroki Yamaboshi ,  Yoichi Sugiyama ,  Hiroshi Kitagaito ,  Shu Yamaguchi ,  Hiroyuki Yamashita

发明人： Shuji Takana ,  Hitoshi Takaya ,  Hiroki Yamaboshi ,  Yoichi Sugiyama ,  Hiroshi Kitagaito ,  Shu Yamaguchi ,  Hiroyuki Yamashita

IPC分类号： C11D3/02 ,  C11D3/04 ,  C11D3/10 ,  C11D3/37 ,  C11D11/00 ,  C11D11/02 ,  C11D17/06

CPC分类号： C11D3/046 ,  C11D3/10 ,  C11D3/37 ,  C11D11/0082 ,  C11D11/02 ,  C11D17/065

摘要： The present invention relates to particles for supporting a surfactant and a process for preparing the same. Further, the present invention relates to high-density detergent particles using the particles for supporting a surfactant, and a process for preparing the same. According to the present invention, there can be obtained particles for supporting a surfactant which are excellent in the supporting ability (supporting capacity/supporting strength) for the liquid surfactant composition, and particles for supporting a surfactant which are excellent in the absorption properties (supporting rate) for the liquid surfactant composition, by spray-drying a preparation liquid obtainable by a process comprising the steps of preparing a first preparation liquid comprising a solution or slurry comprising a water-soluble polymer and a water-soluble salt; and subjecting the first preparation liquid to a treatment of increasing a number of water-soluble salt particles, thereby preparing a second preparation liquid having an increased number of water-soluble salt particles, as compared to the number of water-soluble salt particles which are present in the first preparation liquid. Further, since the liquid surfactant composition is supported by the particles for supporting a surfactant, detergent particles which are excellent in detergent performance, quality and the like can be efficiently obtained.

摘要翻译： 本发明涉及用于支撑表面活性剂的颗粒及其制备方法。 此外，本发明涉及使用用于支撑表面活性剂的颗粒的高密度洗涤剂颗粒及其制备方法。 根据本发明，可以获得支撑液体表面活性剂组合物的支持能力（支撑能力/支撑强度）优异的表面活性剂用颗粒和吸收性优异的支撑表面活性剂的颗粒（支撑 速率），通过喷雾干燥可通过包括以下步骤的方法获得的制备液：制备包含水溶性聚合物和水溶性盐的溶液或浆液的第一制备液; 并且对第一制备液进行处理以增加数量的水溶性盐颗粒，从而制备具有增加数量的水溶性盐颗粒的第二制备液，与水溶性盐颗粒的数量相比， 存在于第一准备液中。 此外，由于液体表面活性剂组合物被用于支撑表面活性剂的颗粒负载，所以可以有效地获得洗涤剂性能，质量等方面优异的洗涤剂颗粒。