公开(公告)号：US20140370417A1

公开(公告)日：2014-12-18

申请号：US14374130

申请日：2013-01-23

Applicant: NITTO DENKO CORPORATION

Inventor： Koso Matsuda ,  Hideyuki Emori ,  Megumu Nagasawa ,  Hiroyuki Nishii ,  Takashi Suzuki

IPC: H01M8/10 ,  B01J19/08

CPC classification number: H01M8/1039 ,  B01J19/081 ,  C08J5/2287 ,  C08J7/123 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/1032 ,  H01M8/1088 ,  H01M2008/1095 ,  H01M2300/0082 ,  Y02P70/56

Abstract: A method of the present invention for producing an anion exchange membrane includes the steps of: (i) irradiating a first polymer film with radiation; and (ii) graft-polymerizing a monomer containing a site into which a functional group having anion conducting ability can be introduced and an unsaturated carbon-carbon bond onto the radiation-irradiated first polymer film so as to form a second polymer film containing grafted chains. This method further includes the subsequent steps of: (a) subjecting the second polymer film to a treatment including irradiation with radiation so as to introduce a crosslinked structure into the grafted chains; and (b) introducing the functional group having anion conducting ability into the site.

Abstract translation: 本发明的用于制备阴离子交换膜的方法包括以下步骤：（i）用辐射照射第一聚合物膜; 和（ii）将含有具有阴离子导电性的官能团的单体的单体的接枝聚合，并将不饱和碳 - 碳键接合到辐射照射的第一聚合物膜上，以形成含有接枝链的第二聚合物膜 。 该方法还包括以下步骤：（a）对第二聚合物膜进行处理，包括用辐射照射，以将交联结构引入到接枝链中; 和（b）将具有阴离子导电能力的官能团引入该部位。

公开(公告)号：US10593980B2

公开(公告)日：2020-03-17

申请号：US15557302

申请日：2016-03-11

Applicant: NITTO DENKO CORPORATION

Inventor： Takashi Suzuki ,  Hiroyuki Nishii ,  Koso Matsuda ,  Mizuki Yamamoto ,  Takeshi Nakano

IPC: H01M8/1018 ,  H01M8/1053 ,  H01M8/1004 ,  H01M8/1023 ,  H01M4/86 ,  H01M4/88 ,  H01B1/12 ,  H01B1/20 ,  C08F8/00 ,  C08F8/24 ,  C08F112/14 ,  C08F212/08 ,  B32B27/30

Abstract: Provided is an ionomer resin including a copolymer containing the following first structural unit. L1 to L5 are each independently a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkanol group having 1 to 4 carbon atoms, or a specific functional group including an anion-exchange group, and an example of the functional group is —Z2-M1-Z1(R1)(R2)(R3). R1 to R3 are directly bonded to Z1 and are each independently an alkyl group having 1 to 8 carbon atoms or an alkanol group having 1 to 8 carbon atoms. M1 is a linear hydrocarbon chain having 3 to 8 carbon atoms, Z1 is a nitrogen atom or a phosphorus atom, and Z2 is a nitrogen atom bonded to one hydrogen atom, an oxygen atom, or a sulfur atom. L6 is a hydrogen atom, a methyl group, or an ethyl group.

公开(公告)号：US10512907B2

公开(公告)日：2019-12-24

申请号：US15557316

申请日：2016-03-11

Applicant: NITTO DENKO CORPORATION

Inventor： Mizuki Yamamoto ,  Takeshi Nakano ,  Koso Matsuda ,  Hiroyuki Nishii ,  Takashi Suzuki

IPC: H01M8/00 ,  B01J41/14 ,  C08F261/04 ,  H01M4/86 ,  B01J41/05 ,  B32B27/08 ,  B32B27/30 ,  H01B1/12 ,  H01M8/1018

Abstract: Provided is a resin including a copolymer having a first structural unit and/or second structural unit and a structural unit having a polar group. R1, R2, R5, and R6 are each independently a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, R3 and R4 are each independently a hydrogen atom or an alkyl group having 1 to 18 carbon atoms, A1 is a saturated carbon chain having 3 to 7 carbon atoms or a structure resulting from substitution of a heteroatom for a part of the carbon atoms of the saturated carbon chain, m and n are each independently 0 or 1, and X1 and X2 are each independently a halide ion, a hydroxide ion, or an anion of an organic or inorganic acid.

公开(公告)号：US20150228995A1

公开(公告)日：2015-08-13

申请号：US14428569

申请日：2013-12-27

Applicant: NITTO DENKO CORPORATION

Inventor： Takeshi Nakano ,  Koso Matsuda ,  Hiroyuki Nishii

IPC: H01M8/10

CPC classification number: H01M8/1023 ,  C08F255/02 ,  C08J5/22 ,  H01M8/1007 ,  H01M8/103 ,  H01M8/1072 ,  H01M8/1088 ,  H01M2008/1095 ,  Y02P70/56 ,  C08F212/14

Abstract: The membrane electrode assembly (MEA) of the present invention is a fuel cell MEA including an anion exchange membrane and a catalyst layer disposed on the surface of the membrane. In the MEA, the anion exchange membrane is an anion-conducting polymer electrolyte membrane in which a graft chain having anion conducting ability is graft-polymerized on a substrate formed of a skived film of ultra-high molecular weight polyolefin. This MEA has various superior properties for achieving an improvement in the power output of an anion exchange PEFC compared to conventional MEAs.

Abstract translation: 本发明的膜电极组件（MEA）是包括阴离子交换膜和设置在膜表面上的催化剂层的燃料电池MEA。 在MEA中，阴离子交换膜是阴离子导电性聚合物电解质膜，其中具有阴离子导电能力的接枝链在由超高分子量聚烯烃的刮膜形成的基材上接枝聚合。 与常规MEA相比，该MEA具有各种优异的性能，用于实现阴离子交换PEFC的功率输出的改善。

公开(公告)号：US09620802B2

公开(公告)日：2017-04-11

申请号：US14428569

申请日：2013-12-27

Applicant: NITTO DENKO CORPORATION

Inventor： Takeshi Nakano ,  Koso Matsuda ,  Hiroyuki Nishii

IPC: H01M8/10 ,  H01M8/1023 ,  C08J5/22 ,  C08F255/02 ,  H01M8/1088 ,  H01M8/103 ,  H01M8/1072 ,  H01M8/1007 ,  H01M8/1018

CPC classification number: H01M8/1023 ,  C08F255/02 ,  C08J5/22 ,  H01M8/1007 ,  H01M8/103 ,  H01M8/1072 ,  H01M8/1088 ,  H01M2008/1095 ,  Y02P70/56 ,  C08F212/14

Abstract: The membrane electrode assembly (MEA) of the present invention is a fuel cell MEA including an anion exchange membrane and a catalyst layer disposed on the surface of the membrane. In the MEA, the anion exchange membrane is an anion-conducting polymer electrolyte membrane in which a graft chain having anion conducting ability is graft-polymerized on a substrate formed of a skived film of ultra-high molecular weight polyolefin. This MEA has various superior properties for achieving an improvement in the power output of an anion exchange PEFC compared to conventional MEAs.

公开(公告)号：US20150111128A1

公开(公告)日：2015-04-23

申请号：US14403792

申请日：2013-12-27

Applicant: NITTO DENKO CORPORATION

Inventor： Koso Matsuda ,  Takeshi Nakano ,  Hiroyuki Nishii

IPC: H01M8/10 ,  C08J5/22 ,  B29C35/08

CPC classification number: H01M8/1065 ,  B29C35/0805 ,  B29C35/0866 ,  B29C2035/085 ,  B29C2035/0877 ,  B29K2023/0683 ,  B29K2105/24 ,  C08J5/22 ,  C08J5/2243 ,  C08J2323/06 ,  C08J2351/06 ,  H01B1/122 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1072 ,  Y02P70/56

Abstract: The method for producing an anion exchange membrane according to the present invention includes the steps of irradiating a substrate composed of a hydrocarbon polymer with radiation and heat-treating the irradiated substrate so as to form a crosslinked structure between chains of the hydrocarbon polymer contained in the substrate; further irradiating the substrate, in which the crosslinked structure has been formed, with radiation and graft-polymerizing, onto the irradiated substrate, a monomer containing a site into which a functional group having anion conducting ability can be introduced and an unsaturated carbon-carbon bond so as to form a graft chain composed of the polymerized monomer; and introducing the functional group having anion conducting ability into the site of the formed graft chain.

Abstract translation: 根据本发明的阴离子交换膜的制造方法包括以下步骤：用辐射照射由烃类聚合物构成的基材，对被照射的基材进行热处理，以形成在 基质; 进一步向辐照基板上照射已形成有交联结构的基板，在其上引入含有具有阴离子导电性的官能团的单体和不饱和碳 - 碳键 以形成由聚合单体组成的接枝链; 并将具有阴离子导电能力的官能团引入所形成的接枝链的位点。