公开(公告)号：US11492520B2

公开(公告)日：2022-11-08

申请号：US16650931

申请日：2018-09-18

Applicant: NITTO DENKO CORPORATION

Inventor： Takeshi Nakano ,  Keiji Hayashi ,  Souya Jo ,  Shogo Sasaki ,  Kenichi Kataoka

IPC: C09J7/38 ,  B32B7/12 ,  B32B27/36 ,  C09J133/08

Abstract: A reinforcing film comprises a pressure sensitive adhesive layer laminated and fixed on a principal surface of a film substrate. The pressure sensitive adhesive layer is formed of a photocurable composition containing a photocurable agent and a base polymer having a crosslinked structure. A frictional force of the pressure sensitive adhesive layer measured with a frictional force microscope at a frequency of 5 Hz is preferably 2 to 5 times a frictional force at a frequency of 0.1 Hz. After photocuring of the pressure sensitive adhesive layer, a frictional force of a photocured pressure sensitive adhesive layer measured with the frictional force microscope at a frequency of 5 Hz is preferably not less than 5 times a frictional force measured at a frequency of 0.1 Hz.

公开(公告)号：US09620802B2

公开(公告)日：2017-04-11

申请号：US14428569

申请日：2013-12-27

Applicant: NITTO DENKO CORPORATION

Inventor： Takeshi Nakano ,  Koso Matsuda ,  Hiroyuki Nishii

IPC: H01M8/10 ,  H01M8/1023 ,  C08J5/22 ,  C08F255/02 ,  H01M8/1088 ,  H01M8/103 ,  H01M8/1072 ,  H01M8/1007 ,  H01M8/1018

CPC classification number: H01M8/1023 ,  C08F255/02 ,  C08J5/22 ,  H01M8/1007 ,  H01M8/103 ,  H01M8/1072 ,  H01M8/1088 ,  H01M2008/1095 ,  Y02P70/56 ,  C08F212/14

Abstract: The membrane electrode assembly (MEA) of the present invention is a fuel cell MEA including an anion exchange membrane and a catalyst layer disposed on the surface of the membrane. In the MEA, the anion exchange membrane is an anion-conducting polymer electrolyte membrane in which a graft chain having anion conducting ability is graft-polymerized on a substrate formed of a skived film of ultra-high molecular weight polyolefin. This MEA has various superior properties for achieving an improvement in the power output of an anion exchange PEFC compared to conventional MEAs.

公开(公告)号：US20150111128A1

公开(公告)日：2015-04-23

申请号：US14403792

申请日：2013-12-27

Applicant: NITTO DENKO CORPORATION

Inventor： Koso Matsuda ,  Takeshi Nakano ,  Hiroyuki Nishii

IPC: H01M8/10 ,  C08J5/22 ,  B29C35/08

CPC classification number: H01M8/1065 ,  B29C35/0805 ,  B29C35/0866 ,  B29C2035/085 ,  B29C2035/0877 ,  B29K2023/0683 ,  B29K2105/24 ,  C08J5/22 ,  C08J5/2243 ,  C08J2323/06 ,  C08J2351/06 ,  H01B1/122 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1072 ,  Y02P70/56

Abstract: The method for producing an anion exchange membrane according to the present invention includes the steps of irradiating a substrate composed of a hydrocarbon polymer with radiation and heat-treating the irradiated substrate so as to form a crosslinked structure between chains of the hydrocarbon polymer contained in the substrate; further irradiating the substrate, in which the crosslinked structure has been formed, with radiation and graft-polymerizing, onto the irradiated substrate, a monomer containing a site into which a functional group having anion conducting ability can be introduced and an unsaturated carbon-carbon bond so as to form a graft chain composed of the polymerized monomer; and introducing the functional group having anion conducting ability into the site of the formed graft chain.

Abstract translation: 根据本发明的阴离子交换膜的制造方法包括以下步骤：用辐射照射由烃类聚合物构成的基材，对被照射的基材进行热处理，以形成在 基质; 进一步向辐照基板上照射已形成有交联结构的基板，在其上引入含有具有阴离子导电性的官能团的单体和不饱和碳 - 碳键 以形成由聚合单体组成的接枝链; 并将具有阴离子导电能力的官能团引入所形成的接枝链的位点。

公开(公告)号：US10512907B2

公开(公告)日：2019-12-24

申请号：US15557316

申请日：2016-03-11

Applicant: NITTO DENKO CORPORATION

Inventor： Mizuki Yamamoto ,  Takeshi Nakano ,  Koso Matsuda ,  Hiroyuki Nishii ,  Takashi Suzuki

IPC: H01M8/00 ,  B01J41/14 ,  C08F261/04 ,  H01M4/86 ,  B01J41/05 ,  B32B27/08 ,  B32B27/30 ,  H01B1/12 ,  H01M8/1018

Abstract: Provided is a resin including a copolymer having a first structural unit and/or second structural unit and a structural unit having a polar group. R1, R2, R5, and R6 are each independently a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, R3 and R4 are each independently a hydrogen atom or an alkyl group having 1 to 18 carbon atoms, A1 is a saturated carbon chain having 3 to 7 carbon atoms or a structure resulting from substitution of a heteroatom for a part of the carbon atoms of the saturated carbon chain, m and n are each independently 0 or 1, and X1 and X2 are each independently a halide ion, a hydroxide ion, or an anion of an organic or inorganic acid.

公开(公告)号：US11945984B2

公开(公告)日：2024-04-02

申请号：US16650764

申请日：2018-09-18

Applicant: NITTO DENKO CORPORATION

Inventor： Takeshi Nakano ,  Keiji Hayashi ,  Souya Jo ,  Shogo Sasaki ,  Kenichi Kataoka

IPC: C09J7/38 ,  B32B37/12 ,  C09J133/06 ,  C09J133/08 ,  B32B27/26 ,  B32B27/30

CPC classification number: C09J7/385 ,  B32B37/12 ,  C09J133/066 ,  C09J133/08 ,  B32B27/26 ,  B32B27/30 ,  B32B2037/1253 ,  B32B2307/50 ,  B32B2307/51 ,  B32B2307/542 ,  B32B2405/00 ,  B32B2457/20 ,  C09J2433/00 ,  C09K2323/057 ,  C08F220/1804 ,  C08F226/10 ,  C08F220/20 ,  C08F220/14 ,  C08F220/1808 ,  C08F220/14 ,  C08F220/20 ,  C08F220/1804 ,  C08F220/06

Abstract: A reinforcing film comprises a pressure sensitive adhesive layer laminated and fixed on a principal surface of a film substrate. The pressure sensitive adhesive layer is formed of a photocurable composition containing a photocurable agent and a base polymer having a crosslinked structure. The gel fraction of the photocurable composition is preferably 60% or more. The shear storage elastic modulus at 25° C. of the pressure sensitive adhesive layer is preferably 1×104 to 1.2×105 Pa. The shear storage elastic modulus at 25° C. of the pressure sensitive adhesive layer after photocuring is preferably 1.5×105 to 2×106 Pa.

公开(公告)号：US20200031028A1

公开(公告)日：2020-01-30

申请号：US16522794

申请日：2019-07-26

Applicant: Nitto Denko Corporation

Inventor： Tatsuya Suzuki ,  Takeshi Nakano ,  Hiroki Ieda

IPC: B29C45/00

Abstract: Provided is a thermally conductive sheet with greater optical transmission. The thermally conductive sheet provided by this invention has a resin layer that comprises a resin and a thermally conductive filler. The resin has a refractive index np and the thermally conductive filler has a refractive index nf, satisfying the next relational expression −0.04≤(np−nf)≤0.04. According to a preferable embodiment, the thermally conductive filler content is 50 parts by weight or more and 250 parts by weight or less to 100 parts by weight of the resin.

公开(公告)号：US20150228995A1

公开(公告)日：2015-08-13

申请号：US14428569

申请日：2013-12-27

Applicant: NITTO DENKO CORPORATION

Inventor： Takeshi Nakano ,  Koso Matsuda ,  Hiroyuki Nishii

IPC: H01M8/10

CPC classification number: H01M8/1023 ,  C08F255/02 ,  C08J5/22 ,  H01M8/1007 ,  H01M8/103 ,  H01M8/1072 ,  H01M8/1088 ,  H01M2008/1095 ,  Y02P70/56 ,  C08F212/14

Abstract: The membrane electrode assembly (MEA) of the present invention is a fuel cell MEA including an anion exchange membrane and a catalyst layer disposed on the surface of the membrane. In the MEA, the anion exchange membrane is an anion-conducting polymer electrolyte membrane in which a graft chain having anion conducting ability is graft-polymerized on a substrate formed of a skived film of ultra-high molecular weight polyolefin. This MEA has various superior properties for achieving an improvement in the power output of an anion exchange PEFC compared to conventional MEAs.

Abstract translation: 本发明的膜电极组件（MEA）是包括阴离子交换膜和设置在膜表面上的催化剂层的燃料电池MEA。 在MEA中，阴离子交换膜是阴离子导电性聚合物电解质膜，其中具有阴离子导电能力的接枝链在由超高分子量聚烯烃的刮膜形成的基材上接枝聚合。 与常规MEA相比，该MEA具有各种优异的性能，用于实现阴离子交换PEFC的功率输出的改善。

公开(公告)号：US10593980B2

公开(公告)日：2020-03-17

申请号：US15557302

申请日：2016-03-11

Applicant: NITTO DENKO CORPORATION

Inventor： Takashi Suzuki ,  Hiroyuki Nishii ,  Koso Matsuda ,  Mizuki Yamamoto ,  Takeshi Nakano

IPC: H01M8/1018 ,  H01M8/1053 ,  H01M8/1004 ,  H01M8/1023 ,  H01M4/86 ,  H01M4/88 ,  H01B1/12 ,  H01B1/20 ,  C08F8/00 ,  C08F8/24 ,  C08F112/14 ,  C08F212/08 ,  B32B27/30

Abstract: Provided is an ionomer resin including a copolymer containing the following first structural unit. L1 to L5 are each independently a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkanol group having 1 to 4 carbon atoms, or a specific functional group including an anion-exchange group, and an example of the functional group is —Z2-M1-Z1(R1)(R2)(R3). R1 to R3 are directly bonded to Z1 and are each independently an alkyl group having 1 to 8 carbon atoms or an alkanol group having 1 to 8 carbon atoms. M1 is a linear hydrocarbon chain having 3 to 8 carbon atoms, Z1 is a nitrogen atom or a phosphorus atom, and Z2 is a nitrogen atom bonded to one hydrogen atom, an oxygen atom, or a sulfur atom. L6 is a hydrogen atom, a methyl group, or an ethyl group.