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公开(公告)号：US09920187B2
公开(公告)日：2018-03-20
申请号：US15128335
申请日：2015-03-20
Applicant: NOK Corporation
Inventor： Takafumi Aiba , Hideyuki Murakami , Kenichi Uchida , Akira Morio , Hiroaki Sato
CPC classification number: C08K7/06 , C08K3/04 , C08K7/10 , C08K2201/003 , C08K2201/006 , C08K2201/011 , C08L15/00 , F16H55/56 , F16J15/3284 , C08L15/005
Abstract: An object of the present invention is to provide an HNBR composition and an HNBR crosslinked body excellent in abrasion resistance and pressure resistance. The object is achieved by an HNBR composition containing 3 to 20 parts by weight of carbon fibers or wollastonite as a hard filler per 100 parts by weight of a hydrogenated nitrile rubber and containing 72 to 87 parts by weight of a carbon black having an average particle diameter of 40 to 50 nm, an iodine adsorption of 35 to 49 g/kg, and a DBP oil absorption of 100 to 160 ml/100 g, as well as an HNBR crosslinked body acquired by crosslinking the HNBR composition.
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Patent Agency Ranking
公开(公告)号：US09404003B2
公开(公告)日：2016-08-02
申请号：US14400486
申请日：2013-04-05
Applicant: NOK Corporation
Inventor： Ayako Aoyagi , Kenichi Uchida
CPC classification number: C09D109/02 , C08G65/332 , C08K5/17 , C08K5/544 , C08L15/005 , C08L71/02 , C09K3/10 , C09K2200/0612 , F16J15/102
Abstract: A polyamine curable, highly saturated nitrile rubber composition comprising 100 parts by weight of a polyamine curable, highly saturated nitrile rubber having an α,β-ethylenically unsaturated nitrile monomer unit, a diene-based monomer unit, an α,β-ethylenically unsaturated dicarboxylic acid monoester monomer unit, and an α,β-ethylenically unsaturated carboxylic acid ester monomer unit other than the α,β-ethylenically unsaturated dicarboxylic acid monoester monomer unit, and having an α,β-ethylenically unsaturated nitrile monomer unit content of 22.0 to 24.5 wt. %, preferably 22.5 to 24.5 wt. %, and an iodine value of 120 or less, and 4 to 31 parts by weight of an aliphatic carboxylic acid diester compound of polyalkylene glycol. The polyamine curable, highly saturated nitrile rubber composition is used as a cure molding material of a sealing material that can be suitably used even in an environment in which the sealing material is exposed to polycyclic aromatic compound.
Abstract translation: 包含100重量份具有α，β-烯键式不饱和腈单体单元，二烯系单体单元，α，β-烯键式不饱和二羧酸的多胺可固化高饱和丁腈橡胶的多胺可固化高饱和丁腈橡胶组合物 酸单酯单体单元和α，β-烯属不饱和二羧酸单酯单元以外的α，β-烯属不饱和羧酸酯单体单元，α，β-烯键式不饱和腈单体单元含量为22.0〜24.5 重量 ％，优选22.5〜24.5wt。 ％，碘值为120以下，4〜31重量份的聚亚烷基二醇的脂肪族羧酸二酯化合物。 多胺可固化，高饱和的丁腈橡胶组合物用作密封材料的固化模塑材料，即使在密封材料暴露于多环芳香族化合物的环境中也可适用。
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公开(公告)号：US09403972B2
公开(公告)日：2016-08-02
申请号：US14400062
申请日：2013-04-05
Applicant: NOK CORPORATION
Inventor： Ayako Aoyagi , Kenichi Uchida
CPC classification number: C08L15/005 , C08G65/3322 , C08K3/36 , C08K5/17 , C08K5/544 , C08L71/02 , C08L2205/025 , C08L2205/03 , C09K3/10 , C09K2200/0612 , F16J15/102
Abstract: Disclosed is a polyamine curable, highly saturated nitrile rubber composition having excellent cold resistance in the presence of a polycyclic aromatic compound; the composition comprising 100 parts by weight of a polyamine curable, highly saturated nitrile rubber having an α,β-ethylenically unsaturated nitrile monomer unit, a diene-based monomer unit, an α,β-ethylenically unsaturated dicarboxylic acid monoester monomer unit, and an α,β-ethylenically unsaturated carboxylic acid ester monomer unit other than the α,β-ethylenically unsaturated dicarboxylic acid monoester monomer unit, and having an α,β-ethylenically unsaturated nitrile monomer unit content of 21.0 to 23.0 wt. %, preferably 21.0 to 22.5 wt. %, more preferably 21.0 to 22.0 wt. %, and an iodine value of 120 or less, and 4 to 31 parts by weight of an aliphatic carboxylic acid diester compound of polyalkylene glycol. The polyamine curable, highly saturated nitrile rubber composition is used as a cure molding material of a sealing material that can be suitably used in an environment in which the sealing material is immersed in polycyclic aromatic compound-containing fuel oil.
Abstract translation: 公开了一种多胺可固化，高饱和的丁腈橡胶组合物，其在多环芳族化合物的存在下具有优异的耐寒性; 所述组合物包含100重量份具有α，β-烯属不饱和腈单体单元，二烯系单体单元，α，β-烯属不饱和二羧酸单酯单元单元的多胺可固化高饱和丁腈橡胶，和 α-烯属不饱和二羧酸单酯单元以外的α，β-烯属不饱和羧酸酯单体单元，α，β-烯属不饱和腈单体单元含量为21.0〜23.0重量％。 ％，优选21.0〜22.5重量％ ％，更优选21.0〜22.0重量％ ％，碘值为120以下，4〜31重量份的聚亚烷基二醇的脂肪族羧酸二酯化合物。 多胺可固化，高饱和的丁腈橡胶组合物用作密封材料的固化模塑材料，其可以适用于将密封材料浸入含多芳族化合物的燃料油的环境中。
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公开(公告)号：US20150353720A1
公开(公告)日：2015-12-10
申请号：US14831440
申请日：2015-08-20
Applicant: NOK Corporation
Inventor： Takuya Yamanaka , Kenichi Uchida
CPC classification number: C08L95/00 , C08K3/04 , C08K3/34 , C08K5/01 , C08K5/14 , C08K2201/006 , C08L27/12 , C08L27/18 , C08L2201/02 , C08L2555/54 , C09K3/1009 , C09K15/04 , C08K3/346 , C08K13/02 , C08L27/20
Abstract: A fluororubber composition comprising 100 parts by weight of a peroxide-crosslinkable tetrafluoroethylene-vinylidene fluoride-hexafluoropropene ternary copolymer rubber having a fluorine content of 64 wt. % or more, (A) 5 to 90 parts by weight of carbon black having a specific surface area of 5 to 20 m2/g, (B) 5 to 40 parts by weight of a fine bituminous powder, (C) at least one of 1 to 20 parts by weight of hydrophilicity-imparted talc and/or 1 to 30 parts by weight of hydrophilicity-imparted clay, and (D) 0.5 to 6 parts by weight of an organic peroxide; the fluororubber composition being used as a molding material for fuel oil sealing materials to be in contact with fuel oil. The fluororubber composition provides a sealing materials having excellent metal corrosion resistance, without compounding an acid acceptor comprising a metal oxide.
Abstract translation: 一种氟橡胶组合物，其包含100重量份的氟含量为64重量％的可过氧化物交联的四氟乙烯 - 偏二氟乙烯 - 六氟丙烯三元共聚物橡胶。 ％以上，（A）5〜90重量份比表面积为5〜20m 2 / g的炭黑，（B）5〜40重量份的细沥青粉，（C）至少1个 1〜20重量份亲水性赋予滑石和/或1〜30重量份亲水性赋予粘土，（D）0.5〜6重量份有机过氧化物; 氟橡胶组合物用作燃料油密封材料与燃料油接触的成型材料。 氟橡胶组合物提供具有优异的金属耐腐蚀性的密封材料，而不需要包含金属氧化物的酸受体。
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5.发明申请公开(公告)号：US20150175784A1
公开(公告)日：2015-06-25
申请号：US14400062
申请日：2013-04-05
Applicant: NOK CORPORATION
Inventor： Ayako Aoyagi , Kenichi Uchida
IPC: C08L15/00
CPC classification number: C08L15/005 , C08G65/3322 , C08K3/36 , C08K5/17 , C08K5/544 , C08L71/02 , C08L2205/025 , C08L2205/03 , C09K3/10 , C09K2200/0612 , F16J15/102
Abstract: Disclosed is a polyamine curable, highly saturated nitrile rubber composition having excellent cold resistance in the presence of a polycyclic aromatic compound; the composition comprising 100 parts by weight of a polyamine curable, highly saturated nitrile rubber having an α,β-ethylenically unsaturated nitrile monomer unit, a diene-based monomer unit, an α,β-ethylenically unsaturated dicarboxylic acid monoester monomer unit, and an α,β-ethylenically unsaturated carboxylic acid ester monomer unit other than the α,β-ethylenically unsaturated dicarboxylic acid monoester monomer unit, and having an α,β-ethylenically unsaturated nitrile monomer unit content of 21.0 to 23.0 wt. %, preferably 21.0 to 22.5 wt. %, more preferably 21.0 to 22.0 wt. %, and an iodine value of 120 or less, and 4 to 31 parts by weight of an aliphatic carboxylic acid diester compound of polyalkylene glycol. The polyamine curable, highly saturated nitrile rubber composition is used as a cure molding material of a sealing material that can be suitably used in an environment in which the sealing material is immersed in polycyclic aromatic compound-containing fuel oil.
Abstract translation: 公开了一种多胺可固化，高饱和的丁腈橡胶组合物，其在多环芳族化合物的存在下具有优异的耐寒性; 所述组合物包含100重量份具有α，b-烯属不饱和腈单体单元的聚胺可固化的高饱和丁腈橡胶，二烯基单体单元，α，b-烯属不饱和二羧酸单酯单体单元， 和除α，β-烯键式不饱和二羧酸单酯单元以外的α，β-烯键式不饱和羧酸酯单体单元，并且具有21.0至23.0重量％的α，b-烯属不饱和腈单体单元含量。 ％，优选21.0〜22.5重量％ ％，更优选21.0〜22.0重量％ ％，碘值为120以下，4〜31重量份的聚亚烷基二醇的脂肪族羧酸二酯化合物。 多胺可固化，高饱和的丁腈橡胶组合物用作密封材料的固化模塑材料，其可以适用于将密封材料浸入含多芳族化合物的燃料油的环境中。
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公开(公告)号：US20150166811A1
公开(公告)日：2015-06-18
申请号：US14400486
申请日：2013-04-05
Applicant: NOK Corporation
Inventor： Ayako Aoyagi , Kenichi Uchida
IPC: C09D109/02
CPC classification number: C09D109/02 , C08G65/332 , C08K5/17 , C08K5/544 , C08L15/005 , C08L71/02 , C09K3/10 , C09K2200/0612 , F16J15/102
Abstract: A polyamine curable, highly saturated nitrile rubber composition comprising 100 parts by weight of a polyamine curable, highly saturated nitrile rubber having an α,β-ethylenically unsaturated nitrile monomer unit, a diene-based monomer unit, an α,β-ethylenically unsaturated dicarboxylic acid monoester monomer unit, and an α,β-ethylenically unsaturated carboxylic acid ester monomer unit other than the α,β-ethylenically unsaturated dicarboxylic acid monoester monomer unit, and having an α,β-ethylenically unsaturated nitrile monomer unit content of 22.0 to 24.5 wt. %, preferably 22.5 to 24.5 wt. %, and an iodine value of 120 or less, and 4 to 31 parts by weight of an aliphatic carboxylic acid diester compound of polyalkylene glycol. The polyamine curable, highly saturated nitrile rubber composition is used as a cure molding material of a sealing material that can be suitably used even in an environment in which the sealing material is exposed to polycyclic aromatic compound.
Abstract translation: 一种多胺可固化，高饱和的丁腈橡胶组合物，其包含100重量份的具有α，b-烯属不饱和腈单体单元的多胺可固化，高度饱和的丁腈橡胶，二烯基单体单元，α和bgr-烯属 不饱和二羧酸单酯单体单元和除α，β-烯键式不饱和二羧酸单酯单元以外的α，β-烯属不饱和羧酸酯单体单元，并具有α，b-烯属不饱和腈单体单元 含量为22.0〜24.5重量％ ％，优选22.5〜24.5wt。 ％，碘值为120以下，4〜31重量份的聚亚烷基二醇的脂肪族羧酸二酯化合物。 多胺可固化，高饱和的丁腈橡胶组合物用作密封材料的固化模塑材料，即使在密封材料暴露于多环芳香族化合物的环境中也可适用。
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