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公开(公告)号:US09708202B2
公开(公告)日:2017-07-18
申请号:US14412218
申请日:2013-03-27
申请人: Nanjing University , Nanjing University Yancheng Environmental Protection Technology and Engineering Research Institute
发明人: Aimin Li , Lichun Fu , Fuqiang Liu , Qing Zhou , Jianjun Dai , Zhaoyang Lu , Yan Li , Chendong Shuang , Jinnan Wang , Weiwei Zhao
IPC分类号: C02F9/00 , C02F1/461 , C02F1/28 , C02F1/42 , C02F1/52 , C02F3/06 , C02F101/20 , C02F101/22 , C02F103/16
CPC分类号: C02F1/461 , C02F1/285 , C02F1/42 , C02F1/5245 , C02F3/06 , C02F9/00 , C02F2101/20 , C02F2101/22 , C02F2103/16 , C02F2201/46105 , Y02W10/15
摘要: An efficient combined advanced treatment method of electroplating wastewater is disclosed, which belongs to the technical field of electroplating wastewater treatment. The method includes: after pretreatments including cyanide breaking, dechromization and coagulating sedimentation, introducing the electroplating wastewater to a contact oxidation tank for biochemical treatment, and settling the effluent from the contact oxidation tank down in an inclined pipe of a secondary sedimentation tank to realize the separation of the sludge from water; charging the effluent to a coagulating sedimentation tank, and undergoing coagulating sedimentation with the aid of a flocculant and a coagulant aid added; feeding the effluent, as an influent, to a resin adsorption tank for adsorption with a magnetic resin; and after passing through a filter, flowing the effluent after adsorption to a fixed bed resin adsorption unit, so as to realize the discharge up to standard and recycle of the effluent.
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公开(公告)号:US09879220B2
公开(公告)日:2018-01-30
申请号:US15114225
申请日:2015-07-13
申请人: Nanjing University , Nanjing University Yancheng Environmental Protection Technology and Engineering Research Institute
发明人: Jinnan Wang , Chen Chen , Dadao Wang , Shuyan Tian
CPC分类号: C12N1/20 , C02F1/285 , C02F3/06 , C02F3/108 , C02F3/341 , C02F2101/306 , C02F2209/40 , C02F2303/16 , C02F2305/06 , Y02W10/15
摘要: Implementations herein relate to systems and methods for removal of tebuconazole from water using a duplex reactor. Water samples containing tebuconazole enter a double sandwich of the duplex reactor, and then enter a reactor inner shell of the duplex reactor through a water distributor. In the duplex reactor, the tebuconazole is removed by adsorption resins loaded with microorganisms. After the removal, a concentration of the tebuconazole in adsorption effluent is below the standard limit of the national pesticide wastewater discharge. The microorganisms loaded on the resins use organic carbon (e.g., tebuconazole) in water as a carbon source and degrade tebuconazole that is absorbed by the resins. The systems and methods not only solve problems associated with conventional techniques (e.g., poor water quality fluctuations and lacking of time long degradation), but also address issues associated with resin adsorption methods (e.g., secondary pollution derived from resins regeneration).
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公开(公告)号:US11065610B2
公开(公告)日:2021-07-20
申请号:US16629316
申请日:2018-12-13
申请人: Nanjing University , Nanjing University&Yancheng Academy of Environmental Protection Technology and Engineering
发明人: Jinnan Wang , Suqian Xu , Zhibin Wen , Lifang Chen , Weilin Bian
IPC分类号: B01J37/08 , B01J27/24 , B01J35/08 , B01J35/10 , B01J37/10 , C02F1/72 , C02F101/30 , C02F101/34 , C02F101/36 , C02F101/38
摘要: A method for preparing a Fenton catalytic material includes the following steps: (1) placing a nitrogen-containing compound in a muffle furnace for calcination, then dissolving the product in deionized water to form a suspension solution; (2) dissolving aluminum nitrate nonahydrate, copper nitrate trihydrate and glucose in deionized water to form a solution; (3) adding the suspension solution in a dropwise manner to the solution, then performing a closed hydrothermal reaction, washing with water, centrifuging and drying to obtain a solid; and (4) placing the prepared solid in a muffle furnace for calcination to obtain the Fenton catalytic material. The catalytic material presents a complete ball-flower shaped mesoporous structure, has a large specific surface area and dual reaction centers to expose more catalytic active sites, so that H2O2 is reduced at the electron-rich center as much as possible to generate hydroxyl radicals during the reaction.
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公开(公告)号:US20160347636A1
公开(公告)日:2016-12-01
申请号:US15114225
申请日:2015-07-13
申请人: NANJING UNIVERSITY , NANJING UNIVERSITY YANCHENG ENVIRONMENTAL PROTECT- ION TECHNOLOGY AND ENGINEERING RESEARCH INSTITUTE
发明人: Jinnan Wang , Chen Chen , Dadao Wang , Shuyan Tian
CPC分类号: C12N1/20 , C02F1/285 , C02F3/06 , C02F3/108 , C02F3/341 , C02F2101/306 , C02F2209/40 , C02F2303/16 , C02F2305/06 , Y02W10/15
摘要: Implementations herein relate to systems and methods for removal of tebuconazole from water using a duplex reactor. Water samples containing tebuconazole enter a double sandwich of the duplex reactor, and then enter a reactor inner shell of the duplex reactor through a water distributor. In the duplex reactor, the tebuconazole is removed by adsorption resins loaded with microorganisms. After the removal, a concentration of the tebuconazole in adsorption effluent is below the standard limit of the national pesticide wastewater discharge. The microorganisms loaded on the resins use organic carbon (e.g., tebuconazole) in water as a carbon source and degrade tebuconazole that is absorbed by the resins. The systems and methods not only solve problems associated with conventional techniques (e.g., poor water quality fluctuations and lacking of time long degradation), but also address issues associated with resin adsorption methods (e.g., secondary pollution derived from resins regeneration).
摘要翻译: 本文涉及用于使用双相反应器从水中除去戊唑醇的系统和方法。 含有戊唑醇的水样品进入双相反应器的双夹心,然后通过水分配器进入双相反应器的反应器内壳。 在双相反应器中,通过负载有微生物的吸附树脂除去戊唑醇。 去除后,吸附流出物中戊唑醇的浓度低于国家农药废水排放标准极限。 负载在树脂上的微生物使用水中的有机碳(例如,戊唑醇)作为碳源,并降解被树脂吸收的戊唑醇。 这些系统和方法不仅解决了与传统技术相关的问题(例如,水质差的波动和时间长的劣化),而且解决了与树脂吸附方法有关的问题(例如来自树脂再生的二次污染)。
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公开(公告)号:US10442712B2
公开(公告)日:2019-10-15
申请号:US15632211
申请日:2017-06-23
申请人: Nanjing University , Nanjing University & Yancheng Academy of Environmental Protection Technology and Engineering
发明人: Jinnan Wang , Chao Qi , Yaohua Lin
摘要: Embodiments herein relate to a membrane bioreactor for strengthening membrane fouling control and method thereof. The embodiments may solve problems associated with existing techniques in the field of water treatment. The membrane bioreactor may include a reactor wall, a membrane element, a collecting pipe, a water collecting pipe, a vacuum table, a suction pump, a cleaning unit, an air compressor, an aeration pipe, an aeration head, an inlet pipe, and a drain pipe. The existing techniques related to membrane fouling control has problems such as complexity to operate, difficulties to clean online, and uses of chemicals, which may cause secondary pollution. The embodiments relate to a device that includes a set of automatic mechanical transmission units. With cleaning parts installed at terminals of the device, the surface of the pollution layer of the flat membrane may be cleaned periodically to achieve in situ membrane fouling control, an increase of water production capacity and backwash cycle, and improvement of the efficiency of the membrane bioreactor.
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公开(公告)号:US20180370828A1
公开(公告)日:2018-12-27
申请号:US15632211
申请日:2017-06-23
申请人: Nanjing University , Nanjing University & Yancheng Academy Of Environmental Protection Technology and Engineerin
发明人: Jinnan Wang , Chao Qi , Yaohua Lin
摘要: Embodiments herein relate to a membrane bioreactor for strengthening membrane fouling control and method thereof. The embodiments may solve problems associated with existing techniques in the field of water treatment. The membrane bioreactor may include a reactor wall, a membrane element, a collecting pipe, a water collecting pipe, a vacuum table, a suction pump, a cleaning unit, an air compressor, an aeration pipe, an aeration head, an inlet pipe, and a drain pipe. The existing techniques related to membrane fouling control has problems such as complexity to operate, difficulties to clean online, and uses of chemicals, which may cause secondary pollution. The embodiments relate to a device that includes a set of automatic mechanical transmission units. With cleaning parts installed at terminals of the device, the surface of the pollution layer of the flat membrane may be cleaned periodically to achieve in situ membrane fouling control, an increase of water production capacity and backwash cycle, and improvement of the efficiency of the membrane bioreactor.
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公开(公告)号:US09950319B2
公开(公告)日:2018-04-24
申请号:US15511184
申请日:2015-07-13
申请人: NANJING UNIVERSITY , Nanjing Univ. Yancheng Environmental Protection Technology and Engineering Research Inst.
发明人: Jinnan Wang , Yi Wang , Xin Yang , Cheng Cheng , Chen Chen
IPC分类号: B01J41/13 , C08F8/44 , C08F212/36
CPC分类号: B01J41/13 , B01J41/05 , B01J41/07 , C08F8/32 , C08F8/44 , C08F12/24 , C08F12/28 , C08F212/36 , C08F12/18 , C08F8/12 , C08F8/02
摘要: The present disclosed are a high exchange-capacity anion exchange resin with dual functional-groups and method of synthesis thereof. The invention relates to the field of environmental function material synthesis and application. The resin is based on chloromethylated polystyrene-divinylbenzene polymer as matrix, and by primary amination and quaternization, yields an anion exchange resin with dual functional-groups having both a weak base anionic group and a strong base anionic group. The anion exchange resin not only has high adsorption capacity for water-born nitrate ions, but also can effectively squelch natural organic acids such as phytic acid in water, thus simultaneously removing nitrate ions and phytic acid organic matter from water. Therefore, the resin has a broad application potential in the fields of drinking water treatment, groundwater remediation, and advanced urban sewage treatment.
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