公开(公告)号：US5219932A

公开(公告)日：1993-06-15

申请号：US784886

申请日：1991-10-30

申请人： Naoki Yamamoto ,  Akira Yanagase ,  Tadashi Iwasaki ,  Masakazu Itoh

发明人： Naoki Yamamoto ,  Akira Yanagase ,  Tadashi Iwasaki ,  Masakazu Itoh

IPC分类号： C08F285/00 ,  C08L51/08

CPC分类号： C08L51/085 ,  C08F285/00 ,  Y10S525/903

摘要： A thermoplastic resin comprises a graft copolymer obtained by graft-polymerizing one or more kinds of vinyl monomer onto a compound rubber, wherein that compound rubber is obtained by inseparably entangling a polyalkyl(meth)acrylate rubber and a modified polyorganosiloxane rubber, the modification being obtained by radical polymerization of 1 to 15 parts by weight of at least one monomer selected from the group consisting of a polyfunctional unsaturated compound having at least one (meth) acryloyloxy group and a polyfunctional unsaturated compound having a cyanuric acid or isocyanuric acid skeleton in the presence of a polyorganosiloxane rubber.

公开(公告)号：US5543460A

公开(公告)日：1996-08-06

申请号：US465130

申请日：1995-06-05

申请人： Naoki Yamamoto ,  Akira Yanagase ,  Tadashi Iwasaki ,  Masakazu Itoh

发明人： Naoki Yamamoto ,  Akira Yanagase ,  Tadashi Iwasaki ,  Masakazu Itoh

IPC分类号： C08F285/00 ,  C08F291/02 ,  C08L51/00 ,  C08L51/04 ,  C08L51/08 ,  C08L77/00 ,  C08L101/00 ,  C08G77/04

CPC分类号： C08L51/04 ,  C08F285/00 ,  C08F291/02 ,  C08L101/00 ,  C08L51/003 ,  C08L51/085 ,  C08L77/00

摘要： Graft copolymer particles obtained by graft-polymerizing one or more kinds of vinyl monomer onto a compound rubber comprising a polyorganosiloxane component and an alkyl (meth)acrylate rubber component, which graft copolymer particle has a number average particle size of 0.01 to 0.07 .mu.m, the volume of particles larger than 0.10 .mu.m being 20% or less of the whole particle volume, a method for producing the above graft copolymer particle, wherein one or more kinds of vinyl monomer are graft-polymerized onto a compound rubber obtained by polymerizing an alkyl (meth)acrylate rubber component comprising alkyl (meth)acrylate and a polyfunctional alkyl (meth)acrylate with a polyorganosiloxane having a number average particle size of 0.003 to 0.06 .mu.m, the volume of particles larger than 0.10 .mu.m being 20% or less of the whole particle volume, and thermoplastic resin compositions comprising the above graft copolymer and various thermoplastic resins.The present invention provides graft copolymer particles and their thermoplastic resin composition which can give molded products having both excellent pigment colorability and extremely high impact resistance.

摘要翻译： 通过将一种或多种乙烯基单体接枝聚合到包含聚有机硅氧烷组分和（甲基）丙烯酸烷基酯（甲基）丙烯酸烷基酯）组分的复合橡胶上获得的接枝共聚物颗粒，该接枝共聚物颗粒的数均粒径为0.01至0.07μm， 大于0.10μm的粒子的体积为整个粒子体积的20％以下，制造上述接枝共聚物粒子的方法，其中将一种或多种乙烯基单体接枝聚合到通过聚合 （甲基）丙烯酸烷基酯（甲基）丙烯酸烷基酯橡胶组分和多官能烷基（甲基）丙烯酸酯与数均粒径为0.003至0.06μm的聚有机硅氧烷，大于0.10μm的颗粒体积为20％或 整个颗粒体积较小，以及包含上述接枝共聚物和各种热塑性树脂的热塑性树脂组合物。 本发明提供接枝共聚物颗粒及其热塑性树脂组合物，其可以得到具有优异颜料着色性和极高抗冲击性的成型体。

公开(公告)号：US5268403A

公开(公告)日：1993-12-07

申请号：US9226

申请日：1993-01-26

申请人： Isao Sasaki ,  Naoki Yamamoto ,  Akira Yanagase

发明人： Isao Sasaki ,  Naoki Yamamoto ,  Akira Yanagase

IPC分类号： C08F285/00 ,  C08L51/04 ,  C08L71/12 ,  C08L83/10 ,  C08K5/53 ,  C08F283/12 ,  C08L33/06

CPC分类号： C08L51/04 ,  C08F285/00 ,  C08L71/123 ,  C08L71/126 ,  C08L83/10 ,  Y10S525/903

摘要： A polyphenylene ether resin composition comprising(A) a polyphenylene ether resin,(B) a polystyrene resin, and(C) a graft copolymer prepared by graft-polymerizing one or more vinyl monomers onto a compound rubber having an average particle diameter of 0.08 to 0.6 .mu.m and a structure wherein 10 to 90% by weight of a polyorganosiloxane rubber component and 90 to 10% by weight of a polyalkyl (meth)acrylate rubber component are tangled with each other so as not to separate, the total amount of the polyorganosiloxane rubber component and the polyalkyl (meth)acrylate rubber component being 100% by weight of the compound rubber. This resin composition provides molded products superior in impact resistance, heat resistance, mechanical strength, and surface appearance and is superior in moldability and flow properties.

公开(公告)号：US5212236A

公开(公告)日：1993-05-18

申请号：US728714

申请日：1991-07-11

申请人： Isao Sasaki ,  Naoki Yamamoto ,  Akira Yanagase

发明人： Isao Sasaki ,  Naoki Yamamoto ,  Akira Yanagase

IPC分类号： C08F285/00 ,  C08L51/04 ,  C08L71/12 ,  C08L83/10

CPC分类号： C08L51/04 ,  C08F285/00 ,  C08L71/123 ,  C08L71/126 ,  C08L83/10 ,  Y10S525/903

摘要： A polyphenylene ether resin composition comprising(A) a polyphenylene ether resin,(B) a polystyrene resin, and(C) a graft copolymer prepared by graft-polymerizing one or more vinyl monomers onto a compound rubber having an average particle diameter of 0.08 to 0.6 .mu.m and a structure wherein 10 to 90% by weight of a polyorganosiloxane rubber component and 90 to 10% by weight of a polyalkyl (meth)acrylate rubber component are tangled with each other so as not to separate, the total amount of the polyorganosiloxane rubber component and the polyalkyl (meth)acrylate rubber component being 100% by weight of the compound rubber. This resin composition provides molded products superior in impact resistance, heat resistance, mechanical strength, and surface appearance and is superior in moldability and flow properties.

摘要翻译： 一种聚苯醚树脂组合物，其包含（A）聚苯醚树脂，（B）聚苯乙烯树脂，和（C）通过将一种或多种乙烯基单体接枝聚合到平均粒径为0.08的复合橡胶上制备的接枝共聚物， 0.6μm的结构，其中10〜90重量％的聚有机硅氧烷橡胶组分和90〜10重量％的（甲基）丙烯酸烷基酯橡胶组分彼此缠结以使其不分离， 聚有机硅氧烷橡胶组分和聚（甲基）丙烯酸烷基酯橡胶组分为复合橡胶的100重量％。 该树脂组合物提供耐冲击性，耐热性，机械强度和表面外观优异的成型品，成型性和流动性优异。

公开(公告)号：US4894415A

公开(公告)日：1990-01-16

申请号：US95001

申请日：1987-09-10

申请人： Isao Sasaki ,  Naoki Yamamoto ,  Akira Yanagase

发明人： Isao Sasaki ,  Naoki Yamamoto ,  Akira Yanagase

IPC分类号： C08L25/06 ,  C08F285/00 ,  C08G77/42 ,  C08L51/00 ,  C08L51/04 ,  C08L51/06 ,  C08L51/08 ,  C08L71/00 ,  C08L71/12 ,  C08L83/04 ,  C08L83/10

CPC分类号： C08L51/04 ,  C08F285/00 ,  C08L71/123 ,  C08L71/126 ,  C08L83/10

摘要： A polyphenylene ether resin composition comprising(A) a polyphenylene ether resin,(B) a polystyrene resin, and(C) a graft copolymerprepared by graft-polymerizing one or more vinyl monomers onto a compound rubber having an average particle diameter of 0.08 to 0.6 .mu.m and a structure wherein 10 to 90% by weight of a polyorganosiloxane rubber component and 90 to 10% by weight of a polyalkyl (meth)acrylate rubber component are tangled with each other so as not to separate, the total amount of the polyorganosiloxane rubber component and the polyalkyl (meth)acrylate rubber component being 100% by weight of the compound rubber. This resin composition provides molded products superior in impact resistance, heat resistance, mechanical strength, and surface appearance and is superior in moldability and flow properties.

摘要翻译： 一种聚苯醚树脂组合物，其包含（A）聚苯醚树脂，（B）聚苯乙烯树脂，和（C）通过将一种或多种乙烯基单体接枝聚合到平均粒径为0.08的复合橡胶上制备的接枝共聚物， 0.6μm的结构，其中10〜90重量％的聚有机硅氧烷橡胶组分和90〜10重量％的（甲基）丙烯酸烷基酯橡胶组分彼此缠结以使其不分离， 聚有机硅氧烷橡胶组分和聚（甲基）丙烯酸烷基酯橡胶组分为复合橡胶的100重量％。 该树脂组合物提供耐冲击性，耐热性，机械强度和表面外观优异的成型品，成型性和流动性优异。

公开(公告)号：US4877687A

公开(公告)日：1989-10-31

申请号：US95671

申请日：1987-09-14

申请人： Kiyotaka Azegami ,  Suehiro Tayama ,  Naoki Yamamoto ,  Akira Yanagase ,  Hiroki Hatakeyama

发明人： Kiyotaka Azegami ,  Suehiro Tayama ,  Naoki Yamamoto ,  Akira Yanagase ,  Hiroki Hatakeyama

IPC分类号： B29C39/16 ,  B29C39/20 ,  B32B27/18 ,  C08J5/00 ,  C08J7/04

CPC分类号： C08J7/047 ,  C08J5/00 ,  Y10S428/922 ,  Y10S524/913 ,  Y10T428/31928 ,  Y10T428/31935

摘要： A synthetic resin molded article having good antistatic properties is disclosed, which is composed of a body of a synthetic resin (B) having a surface layer which is predominantly comprised of an antistatic polymer (A) and is integral with the body (B). The antistatic polymer (A) mainly composed of units of a quaternary ammonium base monomer of the formula: ##STR1##wherein R.sub.1 is H or methyl, R.sub.2 through R.sub.4 are H, unsubstituted or substituted (C.sub.1-9) alkyl, m is 1-10 and X.sup.- is an anion of a quaternizing agent. The molded article is made by forming a film of the antistatic polymer (A) on the molding surface of a casting mold, casting a polymerizable material to be formed into the synthetic resin (B) as the base material in the casting mold, and polymerizing the polymerizable material to form a body of the synthetic resin (B), simultaneously rendering the film of the polymer (A) integral with the body of the base material.

摘要翻译： 公开了一种具有良好抗静电性能的合成树脂模塑制品，其由具有主要由抗静电聚合物（A）组成并与主体（B）成一体的表面层的合成树脂（B）的主体组成。 主要由下式的季铵基单体的单元组成的抗静电聚合物（A）：其中R1是H或甲基，R2至R4是H，未取代或取代的（C1-9）烷基，m 是1-10，X-是季铵化剂的阴离子。 成型品通过在铸模的成型面上形成抗静电聚合物（A）的膜，将要形成的可聚合材料作为基体材料浇铸在合成树脂（B）中而制成，并且聚合 形成合成树脂（B）的主体的可聚合材料，同时使聚合物（A）的膜与基材的主体成一体。

公开(公告)号：US5140064A

公开(公告)日：1992-08-18

申请号：US674915

申请日：1991-03-26

申请人： Isao Sasaki ,  Naoki Yamamoto ,  Akira Yanagase

发明人： Isao Sasaki ,  Naoki Yamamoto ,  Akira Yanagase

IPC分类号： C08F283/00 ,  C08F291/02 ,  C08L23/10 ,  C08L51/00 ,  C08L51/08 ,  C08L57/00 ,  C08L81/02 ,  C08L81/06 ,  C08L101/00

CPC分类号： C08L81/02 ,  C08F283/00 ,  C08F291/02 ,  C08L101/00 ,  C08L23/10 ,  C08L51/085 ,  C08L57/00 ,  C08L81/06 ,  C08L51/00 ,  Y10S525/903

摘要： A thermoplastic resin composition superior in heat stability and impact resistance, which comprises 95-5% by weight of a thermoplastic polymer (A) selected from homopolymers and copolymers of ethylenic unsaturated monomers or from polymers of bifunctionally reactive compounds and 5-95% by weight of a compound-rubber-based graft copolymer which is produced by the graft polymerization of one or more vinyl monomers onto compound rubber particles having an average diameter of 0.08-0.6 .mu.m and structures in which 10-90% by weight of a polyorganosiloxane rubber component and 90-10% by weight of a polyalkyl(meth)acrylate rubber component are tangled together so as not to be separable from each other.

摘要翻译： 热稳定性和耐冲击性优异的热塑性树脂组合物，其包含95-5重量％的选自乙烯性不饱和单体的均聚物和共聚物的热塑性聚合物（A）或由双功能反应性化合物的聚合物和5-95重量％ 通过将一种或多种乙烯基单体接枝聚合到平均直径为0.08-0.6μm的复合橡胶颗粒上而制备的复合橡胶基接枝共聚物，其中10-90重量％的聚有机硅氧烷橡胶 组分和90-10重量％的（甲基）丙烯酸烷基酯橡胶组分缠结在一起，以便彼此不可分离。

公开(公告)号：US5132359A

公开(公告)日：1992-07-21

申请号：US552081

申请日：1990-07-13

申请人： Isao Sasaki ,  Naoki Yamamoto ,  Akira Yanagase

发明人： Isao Sasaki ,  Naoki Yamamoto ,  Akira Yanagase

IPC分类号： C08F285/00 ,  C08L27/06 ,  C08L51/08

CPC分类号： C08L27/06 ,  C08F285/00 ,  C08L51/085 ,  Y10S525/903

摘要： A vinyl chloride resin composition having excellent impact resistance even at a low temperature and good weather resistance is disclosed. Such vinyl chloride resin composition comprises:(A) a vinyl chloride resin, and(B) a compound rubber type graft copolymerwherein one or more vinyl monomers are graft-polymerized onto a compound rubber that has an average particle diameter of 0.08 to 0.6 .mu.m and possesses such a structure that 1 to 10 wt. % of a polyorganosiloxane rubber component and 90 to 99 wt. % of a polyalkyl (meth)acrylate rubber component are entangled in an inseparable fashion, and the total amount of the polyorganosiloxane rubber component and the polyalkyl (meth)acrylate rubber component is 100 wt. %.

公开(公告)号：US4994522A

公开(公告)日：1991-02-19

申请号：US299433

申请日：1989-01-23

申请人： Isao Sasaki ,  Naoki Yamamoto ,  Akira Yanagase

发明人： Isao Sasaki ,  Naoki Yamamoto ,  Akira Yanagase

IPC分类号： C08F285/00 ,  C08L27/06 ,  C08L51/08

CPC分类号： C08L27/06 ,  C08F285/00 ,  C08L51/085 ,  Y10S525/903

摘要： A vinyl chloride resin composition having excellent impact resistance even at a low temperature and good weather resistance is disclosed. Such vinyl chloride resin composition comprises:(A) a vinyl chloride resin, and(B) a compound rubber type graft copolymer wherein one or more vinyl monomers are graft-polymerized onto a compound rubber that has an average particle diameter of 0.08 to 0.6 .mu.m and possesses such a structure that 1 to 99 wt. % of a polyorganosiloxane rubber component and 1 to 990 wt. % of a polyalkyl (meth)acrylate rubber component are entangled in an inseparable fashion, and the total amount of the polyorganosiloxane rubber component and the polyalkyl (meth)acrylate rubber component is 100 wt. %.

公开(公告)号：US5270375A

公开(公告)日：1993-12-14

申请号：US967543

申请日：1992-10-27

申请人： Naoki Yamamoto ,  Akira Yanagase ,  Hiroshi Mori ,  Akira Nakata

发明人： Naoki Yamamoto ,  Akira Yanagase ,  Hiroshi Mori ,  Akira Nakata

IPC分类号： C08L51/08 ,  C08L81/02 ,  C08K3/40

CPC分类号： C08L81/02 ,  C08L51/08

摘要： A polyarylene sulfide resin composition comprising 60-99 parts by weight of a polyarylenesulfide resin (A), 40-1 parts by weight of a polyorganosiloxane graft copolymer (B) prepared by grafting a vinyl monomer on a polyorganosiloxane rubber having a degree of swelling in a range of 3-50 measured using toluene as a solvent and an average particle size in a range of 0.15 .mu.m-0.5 .mu.m and being copolymerized with a graft-linking agent, where the total amount of the (A) component and the (B) component is 100 parts by weight, and 0-150 parts by weight of a reinforcing filler (C). A polyarylene sulfide resin composition according to the present invention is excellent in impact resistance, heat resistance, mechanical strength and moldability and useful for an engineering plastic.

摘要翻译： 包含60-99重量份的聚芳硫醚树脂（A）的聚芳硫醚树脂组合物，40-1重量份通过将乙烯基单体接枝在具有膨胀度的聚有机硅氧烷橡胶上制备的聚有机硅氧烷接枝共聚物（B） 使用甲苯作为溶剂测定的3-50的范围内，平均粒径在0.15μm〜0.5μm的范围内，并与接枝交联剂共聚，其中（A）成分和 （B）成分为100重量份，0-150重量份增强填料（C）。 本发明的聚芳硫醚树脂组合物的耐冲击性，耐热性，机械强度和成型性优异，对于工程塑料是有用的。