公开(公告)号：US09321928B2

公开(公告)日：2016-04-26

申请号：US13472876

申请日：2012-05-16

申请人： Naoyuki Toyoda ,  Masaya Shibatani ,  Hidekazu Moriyama ,  Minoru Yamada ,  Taketoshi Kagose ,  Toshiyuki Kobayashi ,  Tomohiro Ogawa ,  Masaru Terada ,  Homare Kuribayashi ,  Koki Hirata

发明人： Naoyuki Toyoda ,  Masaya Shibatani ,  Hidekazu Moriyama ,  Minoru Yamada ,  Taketoshi Kagose ,  Toshiyuki Kobayashi ,  Tomohiro Ogawa ,  Masaru Terada ,  Homare Kuribayashi ,  Koki Hirata

IPC分类号： C09D11/101 ,  C09D11/30 ,  B22F1/00 ,  C09D11/322 ,  C09D11/107

CPC分类号： C09C1/62 ,  B22F1/0014 ,  B22F1/0062 ,  B22F2301/052 ,  B22F2302/45 ,  B22F2303/01 ,  B22F2304/058 ,  B22F2304/10 ,  B22F2998/10 ,  B22F2999/00 ,  C09C1/644 ,  C09D11/101 ,  C09D11/107 ,  C09D11/30 ,  C09D11/322 ,  C09D11/38 ,  C23C26/00 ,  Y10T428/24901 ,  Y10T428/24909 ,  B22F1/0018 ,  B22F2304/056

摘要： The invention provides metal powder constituted from metal particles. Each of the metal particles comprises a base particle having a surface and a metal material constituting at least the surface of the base particle. The base particle is subjected to a surface treatment with a fluorine type phosphoric acid ester. Further, the invention also provides an ultraviolet ray curable ink jet composition to be ejected by using an ink jet method. The ultraviolet ray curable ink jet composition comprises a polymerizable compound and metal powder constituted from metal particles. The metal particles of the metal powder are subjected to a surface treatment with a fluorine type phosphoric acid ester.

摘要翻译： 本发明提供了由金属颗粒构成的金属粉末。 每个金属颗粒包括具有至少构成基础颗粒表面的表面和金属材料的基础颗粒。 用氟型磷酸酯对基础颗粒进行表面处理。 此外，本发明还提供了通过使用喷墨法喷射的紫外线固化型喷墨组合物。 紫外线固化型喷墨组合物包含可聚合化合物和由金属颗粒构成的金属粉末。 金属粉末的金属颗粒用氟型磷酸酯进行表面处理。

公开(公告)号：US08895638B2

公开(公告)日：2014-11-25

申请号：US13471785

申请日：2012-05-15

申请人： Naoyuki Toyoda ,  Minoru Yamada ,  Masaya Shibatani ,  Toshiyuki Kobayashi ,  Hidekazu Moriyama ,  Taketoshi Kagose

发明人： Naoyuki Toyoda ,  Minoru Yamada ,  Masaya Shibatani ,  Toshiyuki Kobayashi ,  Hidekazu Moriyama ,  Taketoshi Kagose

IPC分类号： C09D11/10 ,  C09D11/101 ,  C09D7/12

CPC分类号： C09D11/38 ,  C08K5/3432 ,  C09D7/67 ,  C09D7/68 ,  C09D11/101 ,  C09D133/08 ,  Y10T428/24802 ,  Y10T428/24909

摘要： An ultraviolet ray curable ink jet composition of the present invention is characterized by being adapted to be ejected using an ink jet method and containing: a polymerizable compound; metal particles subjected to a surface treatment; and a substance A having a partial structure represented by the following formula (1), where R1 is a hydrogen atom, an oxygen radical, a hydrocarbon group or an alkoxy group, and each of R2, R3, R4 and R5 is independently a hydrogen atom or a hydrocarbon group.

摘要翻译： 本发明的紫外线固化型喷墨组合物的特征在于，使用喷墨法喷射并含有：聚合性化合物; 经过表面处理的金属颗粒; 和具有由下式（1）表示的部分结构的物质A，其中R 1是氢原子，氧原子，烃基或烷氧基，R 2，R 3，R 4和R 5各自独立地为氢 原子或烃基。

公开(公告)号：US08602519B2

公开(公告)日：2013-12-10

申请号：US13176223

申请日：2011-07-05

申请人： Taketoshi Kagose ,  Satoru Miura

发明人： Taketoshi Kagose ,  Satoru Miura

IPC分类号： B41J2/015 ,  B41J2/01

CPC分类号： B41J11/002 ,  B41J2/01 ,  B41J11/0015 ,  B41M7/0081 ,  C09D11/101 ,  C09D11/322

摘要： An ink jet recording method uses an ink jet recording apparatus including a plurality of heads arranged in parallel in a first direction, each of which ejects droplets of a different radiation-curable ink composition onto a recording medium, and first light sources provided for corresponding heads so as to be disposed at a predetermined side of the corresponding heads. The first light sources emit active radiation to irradiate the droplets on the recording medium. The method includes ejecting droplets of the ink compositions from the heads onto the recording medium, and performing a first irradiation by irradiating the droplets of each ink composition with the active radiation from the corresponding first light source at an irradiation energy within 500 ms after the droplets have landed. The irradiation energy is in the range of 5% to 10% of the energy E90 at which the ink composition is 90% cured.

公开(公告)号：US20110251298A1

公开(公告)日：2011-10-13

申请号：US12979750

申请日：2010-12-28

申请人： Taketoshi Kagose ,  Toshiyuki Miyabayashi ,  Satoru Miura ,  Toru Saito ,  Hiroki Nakane ,  Jun Ito ,  Hiroyuki Kajimoto ,  Chigusa Sato ,  Hiroaki Kida

发明人： Taketoshi Kagose ,  Toshiyuki Miyabayashi ,  Satoru Miura ,  Toru Saito ,  Hiroki Nakane ,  Jun Ito ,  Hiroyuki Kajimoto ,  Chigusa Sato ,  Hiroaki Kida

IPC分类号： C09D11/10 ,  B41J2/015

CPC分类号： C09D11/101 ,  B41J11/002 ,  B41M7/0072 ,  C09D11/30

摘要： A radiation-curable ink composition contains (A) aminoacrylate at 1 mass % to 10 mass %, inclusive, (B) phenoxyethyl acrylate at 20 mass % to 50 mass %, inclusive, and (C) tetraethylene glycol diacrylate at 1 mass % to 20 mass %, inclusive, in its reaction component, as well as (E) bis(2,4,6-trimethylbenzoyl)-phenylphosphine oxide at 3 parts by mass to 8 parts by mass, inclusive, (F) 2,4,6-trimethylbenzoyl-diphenyl-phosphine oxide at 3 parts by mass to 5 parts by mass, inclusive, in 100 parts by mass of the reaction component, and (G) diethylthioxanthone at 1 part by mass to 3 parts by mass, inclusive, in 100 parts by mass of the reaction component.

摘要翻译： 辐射固化型油墨组合物含有（A）1质量％〜10质量％的氨基丙烯酸酯，（C）20质量％〜50质量％的（B）丙烯酸苯氧基乙酯，（C）1质量％以下的四甘醇二丙烯酸酯， （E）双（2,4,6-三甲基苯甲酰基） - 苯基氧化膦，为3质量份〜8质量份，（F）为2,4质量份， （三甲基苯甲酰基 - 二苯基膦）氧化物，在100质量份的反应组分中含有3质量份〜5质量份，和（G）1质量份〜3质量份的（G）二乙基噻吨酮， 100质量份反应组分。

公开(公告)号：US08820906B2

公开(公告)日：2014-09-02

申请号：US13049415

申请日：2011-03-16

申请人： Satoru Miura ,  Taketoshi Kagose

发明人： Satoru Miura ,  Taketoshi Kagose

IPC分类号： B41J2/01

CPC分类号： B41J2/04573 ,  B41J2/04586 ,  B41J2/07 ,  B41J2/1433 ,  B41J2/2107 ,  C09D11/101 ,  C09D11/106 ,  C09D11/30 ,  C09D11/322

摘要： An ink composition has a viscosity of 25 mPa·s to 35 mPa·s at 20° C., wherein a, b, and c are 800 or more, 7.4 to 14, and 0.16 to 0.22, respectively, when a cylindrical portion is formed by expanding the ink composition so as to have a free surface parallel to the expanding direction of the ink composition, the rate of change in width of the cylindrical portion with time is measured in the expanding direction thereof, and the rate of change in width of the cylindrical portion with time is fit to a quadratic function given by the following equation: S=−at2−bt+c  (1) where S is the rate of change in width of the cylindrical portion and t is the time in seconds.

摘要翻译： 油墨组合物在20℃下的粘度为25mPa·s〜35mPa·s，其中a，b，c分别为800以上，7.4〜14，0.16〜0.22，当圆筒部为 通过使油墨组合物膨胀以具有与油墨组合物的膨胀方向平行的自由表面而形成，圆柱形部分的宽度随时间的变化率在其扩展方向上测量，宽度变化率 圆柱部分随时间拟合为由以下等式给出的二次函数：S = -at2-bt + c（1）其中S是圆筒部分的宽度变化率，t是以秒为单位的时间。

公开(公告)号：US08470904B2

公开(公告)日：2013-06-25

申请号：US12979912

申请日：2010-12-28

申请人： Chigusa Sato ,  Toshiyuki Miyabayashi ,  Satoru Miura ,  Toru Saito ,  Hiroki Nakane ,  Jun Ito ,  Taketoshi Kagose ,  Hiroaki Kida ,  Hiroyuki Kajimoto

发明人： Chigusa Sato ,  Toshiyuki Miyabayashi ,  Satoru Miura ,  Toru Saito ,  Hiroki Nakane ,  Jun Ito ,  Taketoshi Kagose ,  Hiroaki Kida ,  Hiroyuki Kajimoto

IPC分类号： C08F2/46 ,  B32B3/10

CPC分类号： C09D11/322 ,  C08F2/44 ,  C08F220/18 ,  C08F222/1006 ,  C08K3/04 ,  C08K5/3447 ,  C09D4/00 ,  C09D11/101 ,  C09D11/30 ,  C09D11/324 ,  C09D133/14 ,  Y10T428/24802

摘要： Provided are a radiation-curable ink composition including phenoxyethyl acrylate (A) in an amount of from 20 to 55 mass % of the total reaction components, a multifunctional acrylate (B) in an amount of from 20 to 50 mass % of the total reaction components, and a black pigment (F1); and a radiation-curable ink composition including phenoxyethyl acrylate (A) in an amount of from 20 to 55 mass % of the total reaction components, a multifunctional acrylate (B) in an amount of from 10 to 50 mass % of the total reaction components, and a yellow pigment (F2).

摘要翻译： 本发明提供一种辐射固化型油墨组合物，其含有总反应成分20〜55质量％的丙烯酸苯氧基乙酯（A），总反应性为20〜50质量％的多官能丙烯酸酯（B） 组分和黑色颜料（F1）; 和含有总反应成分的20〜55质量％的丙烯酸苯氧基乙酯（A）的辐射固化型油墨组合物，总反应成分的10〜50质量％的多官能丙烯酸酯（B） ，和黄色颜料（F2）。

公开(公告)号：US20110229647A1

公开(公告)日：2011-09-22

申请号：US13049415

申请日：2011-03-16

申请人： Satoru Miura ,  Taketoshi Kagose

发明人： Satoru Miura ,  Taketoshi Kagose

IPC分类号： B05D1/02 ,  C09D11/10 ,  B05D5/00

CPC分类号： B41J2/04573 ,  B41J2/04586 ,  B41J2/07 ,  B41J2/1433 ,  B41J2/2107 ,  C09D11/101 ,  C09D11/106 ,  C09D11/30 ,  C09D11/322

摘要： An ink composition has a viscosity of 25 mPa·s to 35 mPa·s at 20° C., wherein a, b, and c are 800 or more, 7.4 to 14, and 0.16 to 0.22, respectively, when a cylindrical portion is formed by expanding the ink composition so as to have a free surface parallel to the expanding direction of the ink composition, the rate of change in width of the cylindrical portion with time is measured in the expanding direction thereof, and the rate of change in width of the cylindrical portion with time is fit to a quadratic function given by the following equation: S=−at2−bt+c  (1) where S is the rate of change in width of the cylindrical portion and t is the time in seconds.

摘要翻译： 油墨组合物在20℃下的粘度为25mPa·s〜35mPa·s，其中a，b，c分别为800以上，7.4〜14，0.16〜0.22，当圆筒部为 通过使油墨组合物膨胀以具有与油墨组合物的膨胀方向平行的自由表面而形成，圆柱形部分的宽度随时间的变化率在其扩展方向上测量，宽度变化率 圆柱部分随时间拟合为由以下等式给出的二次函数：S = -at2-bt + c（1）其中S是圆筒部分的宽度变化率，t是以秒为单位的时间。

公开(公告)号：US09056986B2

公开(公告)日：2015-06-16

申请号：US13292219

申请日：2011-11-09

申请人： Taketoshi Kagose ,  Hiroki Nakane ,  Chigusa Sato ,  Hiroaki Kida ,  Toru Saito

发明人： Taketoshi Kagose ,  Hiroki Nakane ,  Chigusa Sato ,  Hiroaki Kida ,  Toru Saito

IPC分类号： B41J2/01 ,  C09D4/00 ,  B41J2/21 ,  C09D11/101 ,  C09D11/322

CPC分类号： C09D11/30 ,  B41J2/2107 ,  C09D4/00 ,  C09D11/101 ,  C09D11/107 ,  C09D11/322

摘要： Provided is a UV curable type ink-jet ink composition containing a monomer A which is expressed by the following general formula (I): CH2═CR1—COOR2—O—CH═CH—R3  (I) (in the formula, R1 is a hydrogen atom or methyl radical, R2 is a bivalent organic residue radical having a carbon number in a range of 2 to 20, and R3 is a hydrogen atom or a univalent organic residue radical having a carbon number in a range of 1 to 11), a compound B containing five or more (meth)acryloyl radicals per molecule, and a monofunctional (meth)acrylate C having an aromatic ring skeleton, wherein the monofunctional (meth)acrylate C which is in a range of 5 to 35 wt % with respect to the total weight of the ink composition is contained, wherein the compound B is in a range of 5 to 40 wt % with respect to the total weight of the ink composition, wherein the monomer A is in a range of 10 to 70 wt % with respect to the total weight of the ink composition.

摘要翻译： 本发明提供含有由以下通式（I）表示的单体A的UV固化型喷墨油墨组合物：CH 2 = CR 1 -COOR 2 -O-CH = CH-R 3（I）（式中，R 1为 氢原子或甲基，R2是碳原子数为2〜20的二价有机残基，R3为氢原子或碳数为1〜11的一价有机残基） ，每分子含有5个以上（甲基）丙烯酰基的化合物B和具有芳香环骨架的单官能（甲基）丙烯酸酯C，其中，所述单官能（甲基）丙烯酸酯C的含量为5〜35重量％ 含有相对于油墨组合物的总重量的化合物B的含量相对于油墨组合物的总重量为5〜40重量％，其中，单体A为10〜70重量％ 相对于油墨组合物的总重量。

公开(公告)号：US08901200B2

公开(公告)日：2014-12-02

申请号：US13025663

申请日：2011-02-11

申请人： Hiroaki Kida ,  Toshiyuki Miyabayashi ,  Satoru Miura ,  Toru Saito ,  Hiroki Nakane ,  Jun Ito ,  Taketoshi Kagose ,  Chigusa Sato ,  Hiroyuki Kajimoto

发明人： Hiroaki Kida ,  Toshiyuki Miyabayashi ,  Satoru Miura ,  Toru Saito ,  Hiroki Nakane ,  Jun Ito ,  Taketoshi Kagose ,  Chigusa Sato ,  Hiroyuki Kajimoto

IPC分类号： C08F2/46 ,  C08F2/48 ,  C08F2/44 ,  C09D11/30 ,  C09D4/00 ,  C09D11/101

CPC分类号： C09D11/30 ,  C09D4/00 ,  C09D11/101 ,  Y10T428/24802

摘要： A radiation-curable ink composition includes an acrylate monomer of which homopolymer has a glass transition temperature of not higher than 0° C. in an amount of 20% by mass or more and 65% by mass or less based on the total amount of reaction components; a monofunctional acrylate having an alicyclic structure; and a multifunctional acrylate having an alicyclic structure.

摘要翻译： 辐射固化型油墨组合物包含相对于反应总量为20质量％以上且65质量％以下的均聚物的玻璃化转变温度为0℃以下的丙烯酸酯单体 组件; 具有脂环结构的单官能丙烯酸酯; 和具有脂环结构的多官能丙烯酸酯。

公开(公告)号：US08616670B2

公开(公告)日：2013-12-31

申请号：US13074152

申请日：2011-03-29

申请人： Taketoshi Kagose ,  Satoru Miura

发明人： Taketoshi Kagose ,  Satoru Miura

IPC分类号： B41J29/38 ,  B41J2/01

CPC分类号： B41J11/002 ,  B41M7/0081

摘要： An image forming method, including: a first process for ejecting liquid droplets of a radiation curable ink composition onto a recording medium from an ejection head capable of ejecting the radiation curable ink composition using an ink jet recording device; and a second process for irradiating the liquid droplets with active radiation by an irradiation measure capable of emitting the active radiation, in which, among the liquid droplets of the radiation curable ink composition irradiated with the active radiation, a difference of the total irradiation energy of a liquid droplet having the highest total irradiation energy of the active radiation and a liquid droplet having the lowest total irradiation energy of the active radiation in the second process is 30% or more and 50% or lower of the irradiation energy (E90) [mJ/cm2] required for curing 90% of the radiation curable ink composition.

摘要翻译： 一种图像形成方法，包括：从能够使用喷墨记录装置喷射可辐射固化油墨组合物的喷射头将可辐射固化油墨组合物的液滴喷射到记录介质上的第一过程; 以及通过能够发射活性辐射的照射措施用活性辐射照射液滴的第二种方法，其中在辐射固化型油墨组合物的液滴中，用有源辐射照射的辐射固化型油墨组合物的液滴之间的总照射能量的差异 在第二过程中，有效辐射的总照射能量最高的总体照射能量和活性辐射总照射能量最低的液滴是照射能量（E90）的30％以上且50％以下[mJ / cm 2]，用于固化90％的可辐射固化油墨组合物。