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    Process for preparing ruthenium-phosphine complex
    1.
    发明授权
    Process for preparing ruthenium-phosphine complex 失效
    制备钌膦配合物的方法

    公开(公告)号：US5919962A

    公开(公告)日：1999-07-06

    申请号：US933973

    申请日：1997-09-19

    申请人： Noboru Sayo ,  Kazushi Mashima ,  Kyoko Tamao ,  Tetsuo Ota

    发明人： Noboru Sayo ,  Kazushi Mashima ,  Kyoko Tamao ,  Tetsuo Ota

    IPC分类号： B01J31/24 ,  C07B53/00 ,  C07B61/00 ,  C07F9/50 ,  C07F15/00 ,  C07F9/02

    CPC分类号： C07F15/0053

    摘要： Disclosed is a ruthenium-phosphine complex represented by formula (I):�{RuX(L)}.sub.2 (.mu.-X).sub.3 !.sup.- �R.sub.2 NH.sub.2 !.sup.+(I)wherein R is hydrogen, an alkyl group having 1 to 5 carbon atoms, a cycloalkyl group, a substituted or unsubstituted phenyl group or a substituted or unsubstituted benzyl group; X is halogen; and L is an optically active or inactive tertiary phosphine. A process for preparing the complex (I) is also disclosed, which comprises (A) reacting a ruthenium complex represented by formula: �RuX(arene)(L)!X (wherein arene is a substituted or unsubstituted phenyl group) and an ammonium salt represented by formula (III): R.sub.2 NH.HX, or (B) reacting a ruthenium complex represented by formula: �RuX.sub.2 (arene)!.sub.2, a tertiary phosphine represented by L, and an ammonium salt (III). The complex (I) useful as a catalyst for general syntheses or asymmetric syntheses can be obtained easily in good yield.

    摘要翻译： 公开了由式（I）表示的钌膦配合物：[{RuX（L）} 2（mu -X）3] - [R 2 NH 2] +（I）其中R是氢，具有1至5个碳原子的烷基 原子，环烷基，取代或未取代的苯基或取代或未取代的苄基; X是卤素; L是光学活性或无活性的叔膦。 还公开了制备络合物（I）的方法，其包括（A）使由式[RuX（芳烃）（L）] X（其中芳烃为取代或未取代的苯基）和铵 由式（III）表示的盐：R2NH.HX，或（B）使由式[RuX2（芳烃）] 2表示的钌络合物，由L表示的叔膦和铵盐（III）反应。 可以容易地以良好的收率获得用作一般合成或不对称合成的催化剂的络合物（I）。

    Phosphine compound, complex containing the phosphine compound as ligand, process for producing optically active aldehyde using the phosphine compound or the complex, and 4-[(R)-1'-formylethyl]azetidin-2-one derivatives
    3.
    发明授权
    Phosphine compound, complex containing the phosphine compound as ligand, process for producing optically active aldehyde using the phosphine compound or the complex, and 4-[(R)-1'-formylethyl]azetidin-2-one derivatives 失效
    膦化合物，含膦化合物作为配体的络合物，使用膦化合物或络合物制备旋光醛的方法，以及4 - [（R）-1'-甲酰基乙基]氮杂环丁-2-酮衍生物

    公开(公告)号：US5530150A

    公开(公告)日：1996-06-25

    申请号：US323492

    申请日：1994-10-12

    申请人： Hidemasa Takaya ,  Nozomu Sakai ,  Kyoko Tamao ,  Satoshi Mano ,  Hidenori Kumobayashi ,  Tetsuo Tomita ,  Takao Saito ,  Kazuhiko Matsumura ,  Yasushi Kato ,  Noboru Sayo

    发明人： Hidemasa Takaya ,  Nozomu Sakai ,  Kyoko Tamao ,  Satoshi Mano ,  Hidenori Kumobayashi ,  Tetsuo Tomita ,  Takao Saito ,  Kazuhiko Matsumura ,  Yasushi Kato ,  Noboru Sayo

    IPC分类号： C07F9/02 ,  C07F15/00

    CPC分类号： C07F9/02 ,  C07F15/00

    摘要： A phosphine compound represented by one of the formulas: ##STR1## wherein R.sup.1 and R.sup.2, which may be the same or different, each represent a phenyl group or a phenyl group substituted with a halogen atom or a lower alkyl group or taken together form a divalent hydrocarbon group; and R.sup.3 and R.sup.4, which may be the same or different, each represent a lower alkyl group, a phenyl group or a phenyl group substituted with a halogen atom, a lower alkyl group or a lower alkoxy group or taken together form a divalent hydrocarbon group, and wherein R.sup.6 and R.sup.6' which may be the same or different, each represent a hydrogen atom, a lower alkyl group or a lower alkoxy group; R.sup.5, R.sup.5', R.sup.11 and R.sup.11' which may be the same or different, each represent a hydrogen atom, a lower alkyl group, a lower alkoxy group or a halogen atom; or a pair of R.sup.5 and R.sup.6 or a pair of R.sup.5' and R.sup.6' may form a ring; R.sup.7 and R.sup.8, which may be the same or different, each represent a phenyl group or a phenyl group substituted with a lower alkyl group, a halogen atom or a lower alkoxy group; and R.sup.9 and R.sup.10, which may be the same or different, each represent a phenyl group or a phenyl group substituted with a lower alkyl group, a lower alkoxy group or a halogen atom; or R.sup.9 and R.sup.10 may be taken together to form a divalent hydrocarbon group.

    摘要翻译： 由下式之一表示的膦化合物：其中R 1和R 2可以相同或不同，各自表示苯基或苯基（III），其中R 1和R 2可以相同或不同， 被卤素原子或低级烷基取代或一起形成二价烃基; 和可以相同或不同的R 3和R 4各自表示低级烷基，苯基或被卤素原子，低级烷基或低级烷氧基取代的苯基或一起形成二价烃基 并且其中可以相同或不同的R6和R6'各自表示氢原子，低级烷基或低级烷氧基; R5，R5'，R11和R11'可以相同或不同，分别表示氢原子，低级烷基，低级烷氧基或卤素原子; 或一对R 5和R 6或一对R 5'和R 6'可以形成环; R 7和R 8可以相同或不同，表示苯基或被低级烷基，卤原子或低级烷氧基取代的苯基; 和R 9和R 10可以相同或不同，各自表示苯基或被低级烷基，低级烷氧基或卤素原子取代的苯基; 或者R 9和R 10可以一起形成二价烃基。

    Optically active phosphine derivative having at least two vinyl groups, polymer produced using the same as monomer, and transition metal complexes of these
    5.
    发明授权
    Optically active phosphine derivative having at least two vinyl groups, polymer produced using the same as monomer, and transition metal complexes of these 有权
    具有至少两个乙烯基的光活性膦衍生物，使用与单体相同的聚合物，以及它们的过渡金属络合物

    公开(公告)号：US06248848B1

    公开(公告)日：2001-06-19

    申请号：US09603991

    申请日：2000-06-27

    申请人： Kyoko Tamao ,  Yohei Itoi

    发明人： Kyoko Tamao ,  Yohei Itoi

    IPC分类号： C08F3002

    CPC分类号： B01J31/2495 ,  B01J31/1658 ,  B01J2231/321 ,  B01J2531/0266 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/828 ,  C07B2200/07 ,  C07C45/505 ,  C07F9/65744 ,  C08F12/08 ,  C08F12/36 ,  C08F30/02 ,  C08F30/04 ,  Y02P20/582 ,  C07C47/228

    摘要： A 2′-diarylphosphino-1,1′-biphenylen-2-yloxy(6,6′-divinyl-1,1′-binaphthalene-2,2′-diyloxy)phosphine derivative is disclosed, which is represented by general formula (I): wherein Ar is an optionally substituted phenyl or naphthyl; R1 and R2 each independently is a hydrogen atom, a lower alkyl, a lower alkoxy, etc.; and R3 is a lower alkyl, a lower alkoxy, etc.; provided that R2 and R3 may be bonded to each other to form a hydrocarbon ring, which may have one or more substituents selected from lower alkyl groups, halogen atoms, vinyl, etc. Also disclosed are a polymer having structural units derived from the phosphine derivative and a transition metal complex obtained by causing a transition metal compound to act on the phosphine derivative.

    摘要翻译： 公开了一种2'-二芳基膦基-1,1'-联苯-2-基氧基（6,6'-二乙烯基-1,1'-联萘-2,2'-二氧基）膦衍生物，其由通式 （I）：其中Ar是任选取代的苯基或萘基; R1和R2各自独立地为氢原子，低级烷基，低级烷氧基等; 和R3是低级烷基，低级烷氧基等; 条件是R 2和R 3可以彼此键合以形成可以具有一个或多个选自低级烷基，卤素原子，乙烯基等的取代基的烃环。还公开了具有衍生自膦衍生物的结构单元的聚合物 以及通过使过渡金属化合物作用于膦衍生物而获得的过渡金属络合物

    Optically active phosphine derivative having at least two vinyl groups, polymer produced using the same as monomer, and transition metal complexes of these
    6.
    发明授权
    Optically active phosphine derivative having at least two vinyl groups, polymer produced using the same as monomer, and transition metal complexes of these 失效
    具有至少两个乙烯基的光活性膦衍生物，使用与单体相同的聚合物，以及它们的过渡金属络合物

    公开(公告)号：US6143834A

    公开(公告)日：2000-11-07

    申请号：US38280

    申请日：1998-03-11

    申请人： Kyoko Tamao ,  Yohei Itoi

    发明人： Kyoko Tamao ,  Yohei Itoi

    IPC分类号： B01J31/24 ,  C07C45/50 ,  C07F9/6574 ,  C07F15/00 ,  C08F12/08 ,  C08F12/34 ,  C08F12/36 ,  C08F30/02 ,  C08F30/04 ,  C08F130/08 ,  C08C19/14 ,  C08F120/02

    CPC分类号： B01J31/2495 ,  B01J31/1658 ,  C07C45/505 ,  C07F9/65744 ,  C08F12/08 ,  C08F12/36 ,  C08F30/02 ,  C08F30/04 ,  B01J2231/321 ,  B01J2531/0266 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/828 ,  C07B2200/07 ,  Y02P20/582

    摘要： A transition metal complex of a polymer of 2'-diarylphosphino-1,1'-biphenylen-2-yloxy(6,6'-divinyl-1,1'-binaphthalene-2,2'-diyloxy)phosphine derivative is disclosed, which is represented by general formula (I): ##STR1## wherein Ar is an optionally substituted phenyl or naphthyl; R.sup.1 and R.sup.2 each independently is a hydrogen atom, a lower alkyl, a lower alkoxy, etc.; and R.sup.3 is a lower alkyl, a lower alkoxy, etc.; provided that R.sup.2 and R.sup.3 may be bonded to each other to form a hydrocarbon ring, which may have one or more substituents selected from lower alkyl groups, halogen atoms, vinyl, etc. Also disclosed are a polymer having structural units derived from the phosphine derivative and a transition metal complex obtained by causing a transition metal compound to act on the phosphine derivative or the polymer. A novel polymer-supported ligand is provided which, when used as a catalyst for asymmetric syntheses, gives satisfactory results concerning catalytic activity, enantiomer excess, etc.

    摘要翻译： 公开了2'-二芳基膦基-1,1'-联苯-2-基氧基（6,6'-二乙烯基-1,1'-联萘-2,2'-二氧基）膦衍生物的聚合物的过渡金属络合物， 其由通式（I）表示：其中Ar是任选取代的苯基或萘基; R1和R2各自独立地为氢原子，低级烷基，低级烷氧基等; 和R3是低级烷基，低级烷氧基等; 条件是R2和R3可以彼此键合以形成可以具有一个或多个选自低级烷基，卤素原子，乙烯基等的取代基的烃环。还公开了具有衍生自膦衍生物的结构单元的聚合物 以及通过使过渡金属化合物作用于膦衍生物或聚合物而获得的过渡金属络合物。 提供了一种新的聚合物负载型配体，当用作不对称合成催化剂时，可以获得令人满意的催化活性，对映体过量等结果。

    Optically active phosphine derivative having vinyl group, polymer produced using the same as monomer, and transition metal complexes of these
    7.
    发明授权
    Optically active phosphine derivative having vinyl group, polymer produced using the same as monomer, and transition metal complexes of these 失效
    具有乙烯基的光活性膦衍生物，使用与单体相同的聚合物，以及它们的过渡金属络合物

    公开(公告)号：US6022936A

    公开(公告)日：2000-02-08

    申请号：US38131

    申请日：1998-03-11

    申请人： Kyoko Tamao ,  Yohei Itoi

    发明人： Kyoko Tamao ,  Yohei Itoi

    IPC分类号： B01J31/24 ,  C07B53/00 ,  C07C45/50 ,  C07F9/6574 ,  C07F15/00 ,  C08F12/32 ,  C08F30/02 ,  C07F9/06

    CPC分类号： C07F15/0073 ,  C07B53/00 ,  C07C45/505 ,  C07F15/0006 ,  C07F9/65744 ,  Y02P20/582

    摘要： A 6-vinyl-2'-diarylphosphino-1,1'-binaphthalen-2-yloxy(biphenylene-2,2'-diyloxy)phosphine derivative is disclosed, which is represented by general formula (I): ##STR1## wherein Ar is an optionally substituted phenyl or naphthyl; R.sup.1 and R.sup.2 each independently is a hydrogen atom, a lower alkyl, a lower alkoxy, etc.; and R.sup.3 is a lower alkyl, a lower alkoxy, etc.; provided that R.sup.2 and R.sup.3 may be bonded to each other to form a hydrocarbon ring, which may have one or more substituents selected from lower alkyl groups, halogen atoms, vinyl, etc. Also disclosed are a polymer having structural units derived from the phosphine derivative and a transition metal complex obtained by causing a transition metal compound to act on the phosphine derivative or the polymer. A novel polymer-supported ligand is provided which, when used as a catalyst for asymmetric syntheses, gives satisfactory results concerning catalytic activity, enantiomer excess, etc.

    摘要翻译： 公开了由通式（I）表示的6-乙烯基-2'-二芳基膦基-1,1'-联萘-2-基氧基（联苯-2,2'-二氧基）膦衍生物：其中Ar是任选的 取代的苯基或萘基; R1和R2各自独立地为氢原子，低级烷基，低级烷氧基等; 和R3是低级烷基，低级烷氧基等; 条件是R 2和R 3可以彼此键合以形成可以具有一个或多个选自低级烷基，卤素原子，乙烯基等的取代基的烃环。还公开了具有衍生自膦衍生物的结构单元的聚合物 以及通过使过渡金属化合物作用于膦衍生物或聚合物而获得的过渡金属络合物。 提供了一种新的聚合物负载型配体，当用作不对称合成催化剂时，可以获得令人满意的催化活性，对映体过量等结果。

    Process for producing optically active polyketone
    8.
    发明授权
    Process for producing optically active polyketone 失效
    光学活性聚酮的制造方法

    公开(公告)号：US5631345A

    公开(公告)日：1997-05-20

    申请号：US614995

    申请日：1996-03-13

    申请人： Hidemasa Takaya, deceased ,  Kyoko Tamao ,  Naomasa Sato

    发明人： Hidemasa Takaya, deceased ,  Kyoko Tamao ,  Naomasa Sato

    IPC分类号： B01J20/291 ,  C07F9/6574 ,  C08G67/00 ,  C08G67/02 ,  G01N30/88

    CPC分类号： C08G67/02 ,  C07F9/65744

    摘要： A process for producing optically active polyketone which comprises allowing a mono-substituted ethylene to react with carbon monoxide in the presence of a palladium-phosphine complex formed from a phosphine represented by the following general formula (I) ##STR1## (wherein Ar.sup.1 is a phenyl group which may be substituted with one or more substituent groups selected from a lower alkyl group, a lower alkoxy group and a halogen) and a palladium salt. An isotactic (stereoregular) optically active polyketone having high molecular weight (Mn) in which the direction of a mono-substituted ethylene against ketone is a head to tail type (positional regularity) can be produced efficiently by a simple and easy process for the copolymerization of propylene, styrene or the like mono-substituted ethylene with carbon monoxide.

    摘要翻译： 一种制备光学活性聚酮的方法，其包括在由以下通式（I）表示的膦形成的钯 - 膦配合物的存在下使单取代的乙烯与一氧化碳反应（其中 Ar 1是可以被一个或多个选自低级烷基，低级烷氧基和卤素的取代基取代的苯基）和钯盐。 具有高分子量（Mn）的全同立构（有规立构）光学活性聚酮，其中单取代的乙烯对酮的方向是头 - 尾型（位置规则性）可以通过简单和容易的共聚方法有效地制备 丙烯，苯乙烯等单取代乙烯与一氧化碳。