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    Method of catalytic crosslinking of polymers and two-pack composition used therein
    1.
    发明授权
    Method of catalytic crosslinking of polymers and two-pack composition used therein 有权
    聚合物的催化交联方法和其中使用的双组分组合物

    公开(公告)号：US06306991B1

    公开(公告)日：2001-10-23

    申请号：US09636680

    申请日：2000-08-11

    申请人： Gordon Charles Fischer ,  Gary Robert Larson

    发明人： Gordon Charles Fischer ,  Gary Robert Larson

    IPC分类号： C08F3002

    CPC分类号： C08J3/24 ,  C08F8/06 ,  C08F2810/20 ,  C08J2333/04 ,  C08F2220/1825 ,  C08F212/14 ,  C08F212/08 ,  C08F220/06 ,  C08F2220/283

    摘要： A method of crosslinking an oxidative polymer having oxidatively crosslinkable functional groups and a two-pack composition used therein. The oxidatively crosslinkable functional groups on the oxidative polymer are crosslinked by contacting the oxidative polymer with a catalytic amount of an oxidizing enzyme, such as horseradish peroxidase. The present invention is further directed to a two-pack coating composition which includes a polymeric component and a catalytic component, which are mixed together prior to use.

    摘要翻译： 交联具有氧化交联性官能团的氧化聚合物的方法和其中使用的双组分组合物。 氧化聚合物上的氧化交联性官能团通过使氧化聚合物与催化量的氧化酶如辣根过氧化物酶接触来交联。 本发明还涉及包含聚合物组分和催化组分的双组分涂料组合物，其在使用之前混合在一起。

    Modular cytomimetic biomaterials, transport studies, preparation and utilization thereof
    2.
    发明授权
    Modular cytomimetic biomaterials, transport studies, preparation and utilization thereof 失效
    模块化细胞模拟生物材料，运输研究，其制备和利用

    公开(公告)号：US06699952B2

    公开(公告)日：2004-03-02

    申请号：US10452997

    申请日：2003-06-02

    申请人： Elliot L. Chaikof ,  Kacey G. Marra ,  John H. Chon

    发明人： Elliot L. Chaikof ,  Kacey G. Marra ,  John H. Chon

    IPC分类号： C08F3002

    CPC分类号： B82Y30/00 ,  A61L33/0082 ,  B82Y5/00 ,  C07F9/10 ,  C08F30/02 ,  Y10T428/1352 ,  Y10T428/2984

    摘要： A modular cytomimetic biocompatible biomaterial, comprising a phospholipid or phospholipid derivative comprising various functional groups (e.g., lipid, peptide, sugar) having specific chemical properties which can function as a modular surface design unit to be incorporated or appended to a desired substrate (e.g., a polymer or a metal) on which it is then polymerized in situ, thereby contributing new or specified biochemical characteristics to the polymerized and stabilized biomaterial.

    摘要翻译： 包括具有特定化学性质的各种官能团（例如，脂质，肽，糖）的磷脂或磷脂衍生物的模块化细胞生物相容性生物材料，其可以用作待掺入或附加到期望底物的模块化表面设计单元（例如， 聚合物或金属），然后在其上原位聚合，从而为聚合和稳定的生物材料提供新的或指定的生化特性。

    Polymeric phosphinic acids and salts thereof
    3.
    发明授权
    Polymeric phosphinic acids and salts thereof 失效
    聚合次膦酸及其盐

    公开(公告)号：US06569974B1

    公开(公告)日：2003-05-27

    申请号：US09532193

    申请日：2000-03-22

    申请人： Martin Sicken ,  Norbert Weferling ,  Hans-Peter Schmitz

    发明人： Martin Sicken ,  Norbert Weferling ,  Hans-Peter Schmitz

    IPC分类号： C08F3002

    CPC分类号： C07F9/305 ,  C07F9/485

    摘要： The invention relates to polymeric phosphinic acids and their salts of the formula (I) in which X is hydrogen or a 1/m metal of valency m, R1 and R2 are identical or different and are hydrogen, a carboxyl group, a carboxylic acid derivative, an unsubstituted or substituted alkyl group having 1 to 10 carbon atoms, phenyl, benzyl or alkyl-substituted aromatics, R3 and R4 are identical or different and are hydrogen or a vinyl group of the formula (VI)  in which R1 and R2 have the abovementioned meaning, and {overscore (u)} is the average number of monomer units. The invention also relates to a process for the preparation of the abovementioned compounds and their use.

    摘要翻译： 本发明涉及式（I）的聚合物次膦酸及其盐，其中X是氢或1价金属的价态m，R 1和R 2相同或不同，为氢，羧基，羧酸衍生物， 具有1-10个碳原子的未取代或取代的烷基，苯基，苄基或烷基取代的芳族化合物，R 3和R 4相同或不同，为氢或式（Ⅵ）的乙烯基，其中R 1和R 2具有上述 意思和{超核（u是单体单元的平均数）本发明还涉及制备上述化合物的方法及其用途。

    Optically active phosphine derivative having at least two vinyl groups, polymer produced using the same as monomer, and transition metal complexes of these
    6.
    发明授权
    Optically active phosphine derivative having at least two vinyl groups, polymer produced using the same as monomer, and transition metal complexes of these 有权
    具有至少两个乙烯基的光活性膦衍生物，使用与单体相同的聚合物，以及它们的过渡金属络合物

    公开(公告)号：US06248848B1

    公开(公告)日：2001-06-19

    申请号：US09603991

    申请日：2000-06-27

    申请人： Kyoko Tamao ,  Yohei Itoi

    发明人： Kyoko Tamao ,  Yohei Itoi

    IPC分类号： C08F3002

    CPC分类号： B01J31/2495 ,  B01J31/1658 ,  B01J2231/321 ,  B01J2531/0266 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/828 ,  C07B2200/07 ,  C07C45/505 ,  C07F9/65744 ,  C08F12/08 ,  C08F12/36 ,  C08F30/02 ,  C08F30/04 ,  Y02P20/582 ,  C07C47/228

    摘要： A 2′-diarylphosphino-1,1′-biphenylen-2-yloxy(6,6′-divinyl-1,1′-binaphthalene-2,2′-diyloxy)phosphine derivative is disclosed, which is represented by general formula (I): wherein Ar is an optionally substituted phenyl or naphthyl; R1 and R2 each independently is a hydrogen atom, a lower alkyl, a lower alkoxy, etc.; and R3 is a lower alkyl, a lower alkoxy, etc.; provided that R2 and R3 may be bonded to each other to form a hydrocarbon ring, which may have one or more substituents selected from lower alkyl groups, halogen atoms, vinyl, etc. Also disclosed are a polymer having structural units derived from the phosphine derivative and a transition metal complex obtained by causing a transition metal compound to act on the phosphine derivative.

    摘要翻译： 公开了一种2'-二芳基膦基-1,1'-联苯-2-基氧基（6,6'-二乙烯基-1,1'-联萘-2,2'-二氧基）膦衍生物，其由通式 （I）：其中Ar是任选取代的苯基或萘基; R1和R2各自独立地为氢原子，低级烷基，低级烷氧基等; 和R3是低级烷基，低级烷氧基等; 条件是R 2和R 3可以彼此键合以形成可以具有一个或多个选自低级烷基，卤素原子，乙烯基等的取代基的烃环。还公开了具有衍生自膦衍生物的结构单元的聚合物 以及通过使过渡金属化合物作用于膦衍生物而获得的过渡金属络合物