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公开(公告)号：US5179192A
公开(公告)日：1993-01-12
申请号：US763245
申请日：1991-09-20
CPC分类号： C09K19/3809 , C08G63/605
摘要： An improved polyester exhibiting melt anisotropy and excellent thermal stability is provided which consists essentially of the structural units (I) to (III) wherein: ##STR1## wherein Ar.sub.1 is 1,4-phenylene, Ar.sub.2 is a mixed system of 2,6-naphthalene and 2,7-naphthalene, and Ar.sub.3 is an aromatic ring containing 6 or more carbon atoms, the unit (I) accounting for 15 to 90 mole percent and the unit (II) for 20 to 70 mole percent of the total amount of the structural units, and the percentage of 2,7-naphthalene to the total amount of Ar.sub.2 in the unit (II) being between 10 and 90 mole percent.
摘要翻译： 提供了具有熔融各向异性和优异的热稳定性的改进聚酯，其基本上由结构单元（I）至（III）组成，其中：其中Ar 1是1,4-亚苯基，Ar 2是 2,6-萘和2,7-萘的混合体系，Ar 3为含有6个以上碳原子的芳香环，单元（I）占15〜90摩尔％，单元（II）为20〜 结构单元总量的70摩尔％，和单元（II）中的Ar 2的总量的2,7-萘的百分比为10〜90摩尔％。
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2.发明授权Resin having excellent heat resistance and exhibiting anisotropy in molten state 失效具有优异的耐热性和在熔融状态下具有各向异性的树脂
公开(公告)号：US4864013A
公开(公告)日：1989-09-05
申请号：US249988
申请日：1988-09-27
CPC分类号： C08G69/44 , C08G63/605 , C09K19/3809
摘要： A polyester copolymer comprise 20 to 80 percent by mole of hydroxy-benzoic acid units, 1 to 40 percent by mole of naphthalene units and 1 to 40 percent by mole of dihydroxy-diphenylketone units. It is improved in the heat resistance and is specified by exhibiting the anisotropy in the molten state.
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公开(公告)号：US5183878A
公开(公告)日：1993-02-02
申请号：US763238
申请日：1991-09-20
IPC分类号： C08K3/00 , C08G63/181 , C08G63/189 , C08G63/19 , C08G63/199 , C08G63/60 , C08L67/00 , C08L67/02
CPC分类号： C08G63/605 , C08G63/189 , C08G63/19
摘要： An improved easily processable wholly aromatic polyester exhibiting melt anisotropy and excellent thermal stability is provided which consists essentially of the structural units (i) to (iii) wherein: ##STR1## and wherein Ar.sub.1 is 1,4-phenylene, Ar.sub.2 is 2,6-naphthalene and 2,7-naphthalene, and Ar.sub.3 is 1,4-phenylene and/or 4,4'-biphenylene.
摘要翻译： 提供了显示熔体各向异性和优异的热稳定性的改进的易加工的全芳族聚酯，其主要由结构单元（i）至（iii）组成，其中：（ⅰ）为OAr 3 O，并且其中Ar 1为1， 4-亚苯基，Ar 2是2,6-萘和2,7-萘，Ar 3是1,4-亚苯基和/或4,4'-亚联苯基。
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4.发明授权Polyester resin exhibiting optical anisotropy in molten state containing minor amounts of 6-oxy-2-naphthoyl units 失效在含有少量6-氧-2-萘甲酰基单元的熔融状态下表现出光学各向异性的聚酯树脂
公开(公告)号：US4983713A
公开(公告)日：1991-01-08
申请号：US374750
申请日：1989-07-03
CPC分类号： C09K19/3809 , C08G63/605
摘要： A novel polyester resin is provided which exhibits an anisotropic melt phase. The polymer comprises recurring 4-oxybenzoyl units, 6-oxy-2-naphthoyl units, aromatic dicarboxy units, and aromatic diol units as described in appropriate concentrations. The resulting polyester exhibits excellent melt processability in combination with good mechanical properties and a good retention of properties at elevated temperatures.
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公开(公告)号：US5221729A
公开(公告)日：1993-06-22
申请号：US763423
申请日：1991-09-20
CPC分类号： C08G63/605 , H05K1/0373
摘要： A polyester exhibiting melt anisotropy and improved thermal stability is provided which consists essentially of structural units represented by the formulas (i) to (iii), wherein: ##STR1## wherein Ar.sub.1 is 1,4-phenylene and/or 2,6-naphthalene, Ar.sub.2 is 2,6-naphthalene and/or 2,7-naphthalene, and X.sub.3 is an aliphatic hydrocarbon containing 2 to 8 carbon atoms.
摘要翻译： 提供了具有熔融各向异性和改善的热稳定性的聚酯，其基本上由式（i）至（iii）表示的结构单元组成，其中：（ⅲ）是OX 3 O，其中Ar 1是1,4- 亚苯基和/或2,6-萘，Ar 2为2,6-萘和/或2,7-萘，X3为含有2〜8个碳原子的脂肪族烃。
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6.发明授权Polyester resin exhibiting anisotropy in a molten state and resin composition 失效聚酯树脂在乳液状态和树脂组合物中展现各向异性
公开(公告)号：US5086158A
公开(公告)日：1992-02-04
申请号：US604240
申请日：1990-10-29
CPC分类号： C08G63/605
摘要： A novel polyester is provided which forms an anisotropic melt phase in combination with good heat resistance and melt-processability. The polyester is formed from a combination of appropriate concentrations of four essential constituent units (as described). In a particularly preferred embodiment the polyester is derived from p-acetoxybenzoic acid, 4,4'-diacetoxydiphenyl, 2,2-propylidenebis(1,4-phenylene), and terephthalic acid. The resulting polyester is well suited to injection molding to form superior three-dimensional articles, fibers and films.
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公开(公告)号：US5132068A
公开(公告)日：1992-07-21
申请号：US584329
申请日：1990-09-19
申请人： Toshio Nakane , Yukihiko Kageyama , Hiroaki Konuma , Kenji Hijikata , Kenji Hijikata , Kuniaki Kawaguchi
发明人： Toshio Nakane , Yukihiko Kageyama , Hiroaki Konuma , Kenji Hijikata , Kenji Hijikata , Kuniaki Kawaguchi
IPC分类号： B29C71/02 , B29K67/00 , B29L7/00 , C08G63/191 , C08G63/199 , C08G63/672 , C08J5/18
CPC分类号： C08J5/18 , C08G63/672 , C08J2367/02 , Y10S264/907
摘要： A process for producing a transparent film includes forming a melt from a copolyester having structural units represented by the following formulas I and II, respectively: ##STR1## wherein R groups may be the same or different from each other are each selected from the group consisting of--CH.sub.2 CH.sub.2, --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --, --CH--CH.sub.2 --, ##STR2## and the molar fraction ratio of the structural units of formula II to the total structural units of formulas I and II is between 0.02 to 0.020, which a melt of the copolyester is formed into a film, rapidly quenched to solidify the copolyester and impart low crystallinity thereto. The solidified film is aged at a temperature of 60 degree centigrade or below, and then heat-treated at a temperature between the glass transition point (Tg) of the copolyester and no greater than 2.degree. C. below the melting point of the copolyester minus 2.
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公开(公告)号：US5043215A
公开(公告)日：1991-08-27
申请号：US515363
申请日：1990-04-30
申请人： Toshio Nakane , Kenji Hijikata , Yukihiko Kageyama , Michiro Naka
发明人： Toshio Nakane , Kenji Hijikata , Yukihiko Kageyama , Michiro Naka
IPC分类号： C08G63/682 , C08K5/3412 , C08K5/3432 , H01B3/42
CPC分类号： H01B3/422 , C08G63/6826 , C08K5/3412 , C08K5/3432 , Y10T428/2938
摘要： A halogen-containing polyester resin composition having an improved stable flexibility and flame retardency which comprises a bislactam compound and a flame-resisting aromatic polyester copolymers containing halogen at a ratio of 0.5 to 30% by weight, said copolymers being by the poly-condensation of(A) aromatic dicarboxylic acids or ester-forming derivatives thereof;(B) aliphatic glycols or ester-forming derivatives thereof; and(C) halogen-containing ester-forming compounds, said bislactam compound being present in a ratio of 0.1 to 10% by weight based on the total quantity of the composite.
摘要翻译： 具有改进的稳定柔性和阻燃性的含卤聚酯树脂组合物，其包含双内酰胺化合物和含有0.5至30重量％比例的卤素的阻燃芳族聚酯共聚物，所述共聚物通过多缩合 （A）芳族二羧酸或其酯形成衍生物; （B）脂肪族二醇或其酯形成衍生物; 和（C）含卤素的酯形成化合物，所述双内酰胺化合物以基于复合材料的总量的0.1至10重量％的比例存在。
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公开(公告)号：US5006581A
公开(公告)日：1991-04-09
申请号：US130907
申请日：1987-12-11
申请人： Toshio Nakane , Kenji Hijikata , Yukihiko Kageyama
发明人： Toshio Nakane , Kenji Hijikata , Yukihiko Kageyama
IPC分类号： C08L67/00 , C08G59/00 , C08L63/00 , C08L67/02 , C08L75/04 , C08L77/00 , C08L83/10 , C08L101/00
CPC分类号： C08L75/04 , C08L101/00 , C08L63/00 , C08L67/02 , C08L77/00 , Y10S525/931
摘要： A synthetic resin composition, having a high toughness and a wear resistance, comprises a synthetic resin with solubility parameter .delta.9.5 cal1/2 cm.sup.31 3/2 or higher and a modifier with solubility parameter .delta.8.5 cal.sup.1/2 cm.sup.-3/2 or lower and dispersed therein, characterized in that a silicon containing copolyester, being a block copolymer consisting of 1.about.90% by weight of siloxane segment represented by the undermentioned general formula (A) and 99.about.1% by weight of polyester segment represented by the undermentioned general formula (B), the degree of polymerization of siloxane segment being 1.about.2,000, and that of polyester segment 1.about.1,000, is added to be mixed therewith as a dispersibility improver: ##STR1## (In this formula, m denotes a number of 1.about.2,000.) ##STR2## (In this formula, R.sub.1 designates one or two or more members selected from among aromatic divalent radicals having 6.about.12 carbon atoms or aliphatic divalent radicals having 4.about.20 carbon atoms, and R.sub.2 from among aromatic divalent radicals having 6.about.20 carbon atoms or aliphatic divalent radicals having 2.about.20 carbon atoms; and n stands for a number of 1.about.1,000).
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公开(公告)号：US4994543A
公开(公告)日：1991-02-19
申请号：US377053
申请日：1989-07-10
IPC分类号： C08K5/16 , C08G18/42 , C08G18/46 , C08G63/682 , C08K5/32 , C08L67/00 , C08L67/02 , C09D163/00 , C09D167/02 , H01B3/30 , H01B3/42 , H01B7/295
CPC分类号： H01B7/295 , C08G18/4607 , C09D167/02 , H01B3/302 , Y10T428/31605
摘要： A halogenated polyester resin composition is useful as coating for an electric wire and comprises a flame-retardant aromatic polyester copolymer having a halogen content of 0.5 to 30 wt. % which is produced by a polycondensation reaction of:(A) a mainly aromatic dicarboxylic acid or an ester-forming derivative thereof,(B) a mainly aliphatic glycol or an ester-forming derivative thereof, and(C) a halogenated ester-forming compoundand 0.1 to 10 wt. %, based on the total composition, of an isocyanate compound.
摘要翻译： 卤化聚酯树脂组合物可用作电线涂层，并且包含卤素含量为0.5至30重量％的阻燃芳族聚酯共聚物。 通过以下缩聚反应产生的％：（A）主要是芳族二羧酸或其成酯衍生物，（B）主要是脂族二醇或其成酯衍生物，和（C）卤代酯形成 化合物和0.1至10wt。 ％，基于总组合物的异氰酸酯化合物。
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