Silicon-containing copolyester and method of producing the same
    5.
    发明授权
    Silicon-containing copolyester and method of producing the same 失效
    含硅共聚聚酯及其制造方法

    公开(公告)号:US4927895A

    公开(公告)日:1990-05-22

    申请号:US263698

    申请日:1988-10-28

    CPC classification number: C08G77/445 C08G63/00 C08G63/695

    Abstract: Silicon-containing copolyester are in the form of a block copolymers comprising,(i) between about 1 to 99% by weight of a siloxane segment which is at least one selected from the group consisting of siloxane segments expressed by the following general formulas; ##STR1## where R and R', which may be the same or different, are each hydrocarbon moieties having 1 to 10 carbon atoms, and m is an integer between 1 to 2000; and(ii) between about 99 to about 1% by weight of a polyester segment which is at least one selected from polyester segments of the following general formulas: ##STR2## where R.sub.1 is at least one radical selected from the group consisting of aromatic bivalent radicals having 6 to 12 carbon atoms and aliphatic bivalent radicals having 4 to 20 carbon atoms, R.sub.2 is at least one radical selected from the group consisting of aromatic bivalent radicals having 6 to 20 carbon atoms, and aliphatic bivalent radicals having 2 to 20 carbon atoms, and n is an integer between 1 and 1000. The block copolymers are advantageously prepared by reacting a polyester with a silicon oil having terminal reactive epoxy moieties.

    Abstract translation: 含硅共聚聚酯为嵌段共聚物的形式,其包含(i)约1至99重量%的硅氧烷链段,该硅氧烷链段是选自以下通式表示的硅氧烷链段中的至少一种: < IMAGE>其中R和R'可以相同或不同,各自为具有1-10个碳原子的烃部分,m为1至2000的整数; 和(ii)约99至约1重量%的聚酯链段,其为选自以下通式的聚酯链段中的至少一种:其中R 1为至少一个选自以下基团的基团: 由具有6至12个碳原子的芳族二价基团和具有4至20个碳原子的脂族二价基团组成,R 2为至少一个选自具有6至20个碳原子的芳族二价基团和选自具有2至6个碳原子的二价基团的基团 至20个碳原子,n为1至1000的整数。嵌段共聚物有利地通过使聚酯与具有末端反应性环氧部分的硅油反应制备。

    Aromatic polyester and polyester resin composition
    6.
    发明授权
    Aromatic polyester and polyester resin composition 失效
    芳香聚酯和聚酯树脂组合物

    公开(公告)号:US5391689A

    公开(公告)日:1995-02-21

    申请号:US98075

    申请日:1993-07-28

    CPC classification number: C08G63/19

    Abstract: A novel wholly aromatic polyester capable of forming an anisotropic melt phase is provided. Such polyester has been demonstrated to be capable of forming quality molded articles having a combination of excellent heat resistance and mechanical properties. The resulting polyester further is capable of readily being melt processed while using conventional equipment. Four essential recurring units are present in the polyester of the present invention wherein (I) is derived from 2,6-napthalenedicarboxylic acid and/or 4,4'-biphenyldicarboxylicacid; (II) is derived from another dicarboxylic acid (as defined) such as terephthalic acid; and (III) is derived from aromatic diols (as defined) such as 1,4-dihydroxybenzene and 4,4'-dihydroxybiphenyl; and (IV) is derived from another aromatic diol (as defined), such as 4,4'-dihydroxydiphenyl ether. In a preferred embodiment, an inorganic filler is dispersed therein. Molded articles exhibiting highly satisfactory tensile strengths, tensile elongations, and tensile moduli are made possible when melt processing the wholly aromatic polyester.

    Abstract translation: 提供了能够形成各向异性熔融相的新颖的全芳族聚酯。 已经证明这种聚酯能够形成具有优异的耐热性和机械性能的组合的优质模制品。 所得聚酯进一步在使用常规设备时能够容易地熔融加工。 在本发明的聚酯中存在四种必需的重复单元,其中(I)衍生自2,6-萘二甲酸和/或4,4'-联苯二羧酸; (II)衍生自另一种二羧酸(如定义)如对苯二甲酸; 和(III)衍生自芳族二醇(如定义)如1,4-二羟基苯和4,4'-二羟基联苯; 和(IV)衍生自另一种芳族二醇(如定义),例如4,4'-二羟基二苯醚。 在优选的实施方案中,无机填料分散在其中。 当熔融加工全芳族聚酯时,可以实现显示出非常令人满意的拉伸强度,拉伸伸长率和拉伸模量的模制品。

    Halogen-containing polyester resin composition and covered wire
    10.
    发明授权
    Halogen-containing polyester resin composition and covered wire 失效
    含卤素的聚酯树脂组合物和包线

    公开(公告)号:US4968777A

    公开(公告)日:1990-11-06

    申请号:US291229

    申请日:1988-12-28

    CPC classification number: H01B3/422 C09D167/02

    Abstract: A resin composition being useful for coating on electrically conductive lines comprises (A) a halogen-containing polyester having a halogen content of 0.5 to 30 wt. % and being a polycondensation product of (a), (b) and (c) wherein(a) is a component composed mainly of an aromatic dicarboxylic acid or an ester forming derivative thereof,(b) is a component composed mainly of an aliphatic glycol or an ester forming derivative thereof, and(c) is a component composed of an ester forming compound containing a halogen and 0.1 to 10 wt. %, based on the total composition, of (B) at least one carbodiimide compound.

    Abstract translation: 可用于涂覆在导电线上的树脂组合物包含(A)含卤素含量为0.5-30重量%的含卤聚酯。 %,并且是(a),(b)和(c)的缩聚产物,其中(a)是主要由芳族二羧酸或其酯形成衍生物组成的组分,(b)是主要由脂族 乙二醇或其酯形成衍生物,和(c)由含有卤素的酯形成化合物和0.1至10wt。 (B)至少一种碳化二亚胺化合物的总组成。

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