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    Electrophotographic organophotoreceptors with novel charge transport compounds
    1.
    发明申请
    Electrophotographic organophotoreceptors with novel charge transport compounds 失效
    具有新型电荷传输化合物的电子照相有机光感受器

    公开(公告)号：US20050074683A1

    公开(公告)日：2005-04-07

    申请号：US10994430

    申请日：2004-11-22

    申请人： Nusrallah Jubran ,  Hwan Lee ,  Kam Law

    发明人： Nusrallah Jubran ,  Hwan Lee ,  Kam Law

    IPC分类号： C07D209/86 ,  C07D455/04 ,  G03G5/06 ,  G03G5/10

    CPC分类号： G03G5/0648 ,  C07D209/86 ,  C07D455/04 ,  G03G5/0614 ,  G03G5/0616 ,  G03G5/0625 ,  G03G5/0629 ,  G03G5/0637 ,  G03G5/0642 ,  G03G5/0646 ,  G03G5/065 ,  G03G5/0661

    摘要： Charge transport compounds are described that have a multiple number of hydrazone-bridged (N,N-disubstituted)arylamine groups connected by a central bridging group. Examples of charge transport compounds of this invention are those having the following generic formula: (R-Q)n-Y where R is an (N,N-disubstituted)arylamine group; Q comprises an aromatic hydrazone linking group; Y comprises a bridging group between R-Q- groups; and n is an integer between 2 and 6. An organic photoreceptor includes (a) that compound and (b) a charge generating compound; and (c) an electrically conductive substrate.

    摘要翻译： 描述了具有通过中心桥连基团连接的多个腙桥连（N，N-二取代的）芳胺基团的电荷转运化合物。 本发明的电荷输送化合物的实例是具有以下通式的那些：（R-Q）n-Y，其中R是（N，N-二取代的）芳基胺基; Q包括芳族腙连接基团; Y包含R-Q-基团之间的桥连基团; n为2〜6的整数。有机感光体包括（a）该化合物和（b）产生电荷的化合物; 和（c）导电基板。

    Electrophotographic organophotoreceptors with novel charge transport materials
    3.
    发明申请
    Electrophotographic organophotoreceptors with novel charge transport materials 有权
    具有新型电荷传输材料的电子照相有机光感受器

    公开(公告)号：US20050123849A1

    公开(公告)日：2005-06-09

    申请号：US10983020

    申请日：2004-11-05

    申请人： Kam Law ,  Nusrallah Jubran ,  Zbigniew Tokarski ,  Alan Katritzky ,  Ritu Jain ,  Rexiat Maimait

    发明人： Kam Law ,  Nusrallah Jubran ,  Zbigniew Tokarski ,  Alan Katritzky ,  Ritu Jain ,  Rexiat Maimait

    IPC分类号： C07C251/84 ,  C07C317/34 ,  C07D207/34 ,  C07D231/38 ,  C07D249/18 ,  C07D257/06 ,  C07D333/48 ,  G03G5/06 ,  G03G5/10 ,  G03G9/12 ,  G03G15/10 ,  C07D231/18

    CPC分类号： C07D231/38 ,  C07C251/84 ,  C07C317/34 ,  C07C2603/18 ,  C07D207/34 ,  C07D249/18 ,  C07D257/06 ,  C07D333/48 ,  G03G5/0616 ,  G03G5/0618 ,  G03G5/062 ,  G03G5/0661

    摘要： This invention relates to a novel organophotoreceptor that includes: (a) a charge transport material comprising a fluorenone hydrazone having a) least two fluorenone alkylsulfonylphenylhydrazone groups, b) at least two fluorenone pyrrolylhydrazone groups, c) at least two fluorenone benzotriazolylhydrazone groups, d) at least two fluorenone sulfolanylhydrazone groups, e) at least two fluorenone pyrazolylhydrazone groups, f) at least two fluorenone naphthylhydrazone groups, g) at least two fluorenone tetrazolylhydrazone groups, h) at least two fluorenone stilbenylhydrazone groups, or i) at least two fluorenone(9H-fluoren-9-ylidene)benzylhydrazone groups. Some of these fluoreneones may be represented by the formula where n is an integer between 2 and 6, inclusive; R1 is hydrogen, alkyl, or aryl; R2 is alkylsulfonylphenyl or one of its derivatives; X is a linking group having the formula —(CH2)m—, branched or linear. The compounds may form electrostatic imaging systems in combination with (b) a charge generating compound; and (c) an electrically conductive substrate.

    摘要翻译： 本发明涉及一种新型有机光感受器，其包括：（a）电荷传输材料，其包含芴酮腙，其具有a）至少两个芴酮烷基磺酰基苯腙基团，b）至少两个芴酮吡咯基腙基团，c）至少两个芴酮苯并三唑基腙基团，d） 至少两个芴酮砜基腙基团，e）至少两个芴酮吡唑基腙基团，f）至少两个芴酮萘基腙基团，g）至少两个芴酮四唑腙基团，h）至少两个芴酮茋基腙基团，或i）至少两个芴酮 （9H-芴-9-亚基）苄腙基团。 这些芴酮中的一些可以由下式表示：其中n是2和6之间的整数，包括端值在内; R 1是氢，烷基或芳基; R 2是烷基磺酰基苯基或其衍生物之一; X是具有下式的连接基团 - （CH 2 CH 2）m - 支链或直链。 所述化合物可以与（b）产生电荷的化合物组合形成静电成像系统; 和（c）导电基板。

    Organophotoreceptor with charge transport material having fluorenone hydrazone groups
    4.
    发明申请
    Organophotoreceptor with charge transport material having fluorenone hydrazone groups 审中-公开
    具有芴酮腙基团的电荷传输材料的有机光感受器

    公开(公告)号：US20050069794A1

    公开(公告)日：2005-03-31

    申请号：US10671172

    申请日：2003-09-25

    申请人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Kam Law

    发明人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Kam Law

    IPC分类号： C07C251/84 ,  C07C317/22 ,  C07C327/26 ,  C07C327/30 ,  C07D285/12 ,  C07D285/125 ,  G03G5/06 ,  G03G9/12 ,  G03G5/05

    CPC分类号： G03G5/0616 ,  C07C251/84 ,  C07C317/22 ,  C07C327/26 ,  C07C2603/18 ,  C07D285/125 ,  G03G5/0603 ,  G03G5/0607 ,  G03G5/0609 ,  G03G5/0614 ,  G03G5/0618 ,  G03G5/062 ,  G03G5/0633

    摘要： Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where n is an integer between 2 and 6, inclusive; R1 and R2 are, independently, an alkyl group, an alkaryl group, or an aryl group with the proviso that neither R1 nor R2 is a naphthyl group, a stilbenyl group, alkylsulfonylphenyl group or a (9H-fluoren-9-ylidene)benzyl group; R3 and R4 are, independently, H, halogen, carboxyl, hydroxyl, thiol, cyano, nitro, aldehyde group, ketone group, an ether group, an ester group, a carbonyl group, an alkyl group, an alkaryl group, or an aryl group; X is a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups can be optionally replaced by O, S, C═O, O=S=O, a heterocyclic group, an aromatic group, urethane, urea, an ester group, a NR5 group, a CHR6 group, or a CR7R8 group where R5, R6, R7, and R8 are, independently, H, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; and Y comprises a bond, C, N, O, S, a branched or linear —(CH2)p— group where p is an integer between 0 and 10, an aromatic group, a cycloalkyl group, a heterocyclic group, or a NR9 group where R9 is hydrogen atom, an alkyl group, or aryl group, wherein Y has a structure selected to form n bonds with the corresponding X groups; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.

    摘要翻译： 改进的有机光感受器包括在导电衬底上的导电衬底和光电导元件，光电导元件包括：（a）具有下式的电荷传输材料，其中n是2和6之间的整数，包括端值; R1和R2独立地是烷基，烷芳基或芳基，条件是R1和R2都不是萘基，茋基，烷基磺酰基苯基或（9H-芴-9-亚基）苄基 组; R 3和R 4独立地是H，卤素，羧基，羟基，硫醇，氰基，硝基，醛基，酮基，醚基，酯基，羰基，烷基，烷芳基或芳基 组; X是具有式 - （CH2）m-，分支或直链的连接基团，其中m是0和20之间的整数，包括1和20个，并且一个或多个亚甲基可以任选地被O，S，C = O，O = S = O，杂环基，芳基，氨基甲酸酯，脲，酯基，NR5基，CHR6基或CR7R8基，其中R5，R6，R7和R8独立地为H ，烷基，烷芳基，杂环基或芳基; 并且Y包含键，C，N，O，S，支链或线性 - （CH 2）p基团，其中p是0和10之间的整数，芳族基团，环烷基，杂环基或NR 9 基团，其中R9是氢原子，烷基或芳基，其中Y具有选择与相应的X基团形成n键的结构; 和（b）电荷产生化合物。 描述相应的电子照相设备和成像方法。

    Polymeric charge transport compositions for organophotoreceptors
    5.
    发明申请
    Polymeric charge transport compositions for organophotoreceptors 失效
    用于有机光感受器的聚合电荷转运组合物

    公开(公告)号：US20050191571A1

    公开(公告)日：2005-09-01

    申请号：US10789184

    申请日：2004-02-27

    申请人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Kam Law

    发明人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Kam Law

    IPC分类号： G03G5/04 ,  C07D331/02 ,  C07D409/06 ,  C07D409/12 ,  C07D417/12 ,  C08G61/12 ,  C08G73/02 ,  C08G73/06 ,  C08G73/08 ,  C08G75/08 ,  G03G5/06 ,  G03G5/07 ,  G03G9/12

    CPC分类号： G03G5/073 ,  C08G61/122 ,  C08G61/124 ,  C08G73/02 ,  C08G73/0273 ,  C08G73/0672 ,  G03G5/062 ,  G03G5/0625 ,  G03G5/071 ,  G03G5/075 ,  G03G5/076

    摘要： This invention includes an organophotoreceptor having an electrically conductive substrate and photoconductive element on the electrically conductive substrate, the photoconductive element having a) a polymeric charge transport composition with the formula where Y1 and Y2 are, each independently, a bond, a —CR1═N—NR2— group, or a —CR3═N—N═CR4— group; R, R′, R″, R1, R2, R3, and R4 comprise, each independently, H, an alkyl group, an alkenyl group, a heterocyclic group, an aromatic group, or a part of a ring group; X1 and X2 are, each independently, a linking group; T2 comprises a thiiranyl group, H, an alkyl group, an alkenyl group, or an aromatic group; Ar comprises an aromatic group; Z is a bridging group; and n is a distribution of integers between 1 and 100,000 with an average value at least 2; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging processes are also described.

    摘要翻译： 本发明包括在导电基材上具有导电基材和光电导元件的有机光感受器，光电导元件具有a）具有下式的聚合物电荷传输组合物：其中Y 1和Y 2， / SUB>各自独立地为键，-CR 1-N-NR 2 - 基或-CR 3 - NN-CR 4 - 基团; R，R'，R“，R 1，R 2，R 3和R 4包括 各自独立地为H，烷基，烯基，杂环基，芳族基或环基的一部分; X 1和X 2各自独立地为连接基团; T 2包括噻吩基，H，烷基，烯基或芳基; Ar包含芳族基团; Z是桥接组; 并且n是整数在1和100,000之间的平均值至少为2的分布; 和（b）电荷产生化合物。 还描述了相应的电子照相设备和成像过程。

    Sulfonyldiphenylene based charge transport compositions
    6.
    发明申请
    Sulfonyldiphenylene based charge transport compositions 有权
    基于磺酰基二亚苯基的电荷输送组合物

    公开(公告)号：US20050123848A1

    公开(公告)日：2005-06-09

    申请号：US10954454

    申请日：2004-09-30

    申请人： Kam Law ,  Nusrallah Jubran ,  Zbigniew Tokarski

    发明人： Kam Law ,  Nusrallah Jubran ,  Zbigniew Tokarski

    IPC分类号： G03G5/06 ,  C07C317/36 ,  G03G15/10

    CPC分类号： C07C317/36 ,  C07C2603/18 ,  G03G5/0605 ,  G03G5/0607 ,  G03G5/0612 ,  G03G5/0614 ,  G03G5/0616

    摘要： This invention relates to a novel electrophotographic imaging process that includes: (a) applying an electrical charge to a surface of an organophotoreceptor comprising: (i) a charge transport composition comprising molecules having the formula where the average n is between 1 and 1000; R1 and R2 are, independently, hydrogen, alkyl, unsaturated hydrocarbon, ether, cycloalkyl, or aryl; X is a bis(fluorene-4-carboxyl)alkane group; Y is a sulfonyldiphenylene; Z is X=O or two hydrogens; and Q is O or N—N(R1)—Y—N(R2)—NH2; (ii) a charge generating compound; and (iii) an electrically conductive substrate over which said charge transport composition and said charge generating compound are located; (b) imagewise exposing said surface of said organophotoreceptor to radiation to dissipate charge in selected areas and thereby form a pattern of charged and uncharged areas on said surface; (c) contacting said surface with a toner to create a toned image; and (d) transferring said toned image to a substrate.

    摘要翻译： 本发明涉及一种新颖的电子照相成像方法，其包括：（a）将电荷施加到有机光感受器的表面，包括：（i）电荷传输组合物，其包含具有下式的分子，其中平均n在1和1000之间; R 1和R 2分别独立地为氢，烷基，不饱和烃，醚，环烷基或芳基; X是双（芴-4-羧基）烷烃基团; Y是磺酰基二亚苯基; Z是X = O或两个氢; 并且Q是O或N-N（R 1 H 2）-Y-N（R 2 H 2）-NH 2; （ii）电荷产生化合物; 和（iii）所述电荷输送组合物和所述电荷产生化合物所在的导电基底; （b）将所述有机光感受器的所述表面成像曝光于辐射以在选定区域中散发电荷，从而在所述表面上形成带电和不带电区域的图案; （c）使所述表面与调色剂接触以产生调色图像; 和（d）将所述调色图像转印到基底上。

    Electrophotographic organophotoreceptors with novel charge transport materials
    8.
    发明申请
    Electrophotographic organophotoreceptors with novel charge transport materials 审中-公开
    具有新型电荷传输材料的电子照相有机光感受器

    公开(公告)号：US20050084784A1

    公开(公告)日：2005-04-21

    申请号：US10982547

    申请日：2004-11-04

    申请人： Kam Law ,  Nusrallah Jubran ,  Zbigniew Tokarski ,  Alan Katritzky ,  Ritu Jain ,  Rexiat Maimait ,  Anatoliy Vakulenko

    发明人： Kam Law ,  Nusrallah Jubran ,  Zbigniew Tokarski ,  Alan Katritzky ,  Ritu Jain ,  Rexiat Maimait ,  Anatoliy Vakulenko

    IPC分类号： G03G5/06 ,  G03G5/10 ,  G03G9/12 ,  G03G5/05

    CPC分类号： G03G5/0612 ,  G03G5/0616

    摘要： An organophotoreceptor that includes: (a) a charge transport material having the formula wherein A is selected from heterocyclic groups, naphthyl group, (9H-fluoren-9-ylidene)benzyl group, alkylsulfonylphenyl, or stilbenyl, B is selected from hydrogen, alkyl group, and an aryl group, with the proviso that when A is naphthyl, B is naphthyl; or where R1 is selected from the group consisting of N-pyrrolyl, N-pyrazolyl, N-tetrazolyl, N-indolyl, N-carbazolyl, N-triazolyl, N-imidazolyl, N-benzimidazolyl, N-indazolyl, and N-benzotriazolyl group, and R3 is a 9-fluorenone group. (b) a charge generating compound; and (c) an electrically conductive substrate

    摘要翻译： 一种有机光感受器，其包括：（a）具有下式的电荷传输材料：其中A选自杂环基，萘基，（9H-芴-9-亚基）苄基，烷基磺酰基苯基或茋基，B选自氢，烷基 基团和芳基，条件是当A是萘基时，B是萘基; 或其中R 1选自N-吡咯基，N-吡唑基，N-四唑基，N-吲哚基，N-咔唑基，N-三唑基，N-咪唑基，N-苯并咪唑基， N-吲唑基和N-苯并三唑基，R 3是9-芴酮基团。 （b）电荷产生化合物; 和（c）导电基板

    Organophotoreceptor with a charge transport material having two azine groups
    9.
    发明申请
    Organophotoreceptor with a charge transport material having two azine groups 失效
    具有两个吖嗪基团的电荷传输材料的有机光感受器

    公开(公告)号：US20050069798A1

    公开(公告)日：2005-03-31

    申请号：US10670943

    申请日：2003-09-25

    申请人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Kam Law

    发明人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Kam Law

    IPC分类号： G03G5/06 ,  C07D209/86 ,  G03G9/12 ,  G03G5/05 ,  C07D209/82 ,  C07D209/88

    CPC分类号： G03G5/06

    摘要： Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula where n is an integer between 2 and 6, inclusive; R1 and R2 are, independently, H, halogen, carboxyl, hydroxyl, thiol, cyano, nitro, aldehyde group, ketone group, an ether group, an ester group, a carbonyl group, an alkyl group, an alkaryl group, or an aryl group; X is a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups can be optionally replaced by O, S, C═O, O═S═O, urethane, urea, an ester group, a NR3 group, a CHR4 group, or a CR5R6 group where R3, R4, R5, and R6 are, independently, H, an alkyl group, an alkaryl group, a heterocyclic group, or an aryl group; Y comprises a bond, C, N, O, S, a branched or linear —(CH2)p— group where p is an integer between 0 and 10, an aromatic group, a cycloalkyl group, a heterocyclic group, or a NR7 group where R7 is hydrogen atom, an alkyl group, or aryl group, wherein Y has a structure selected to form n bonds with the corresponding X groups; and Z is a fluorenylidene group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.

    摘要翻译： 改进的有机光感受器包括在导电衬底上的导电衬底和光电导元件，光电导元件包括：（a）具有下式的电荷传输材料，其中n是2和6之间的整数，包括端值; R 1和R 2独立地是H，卤素，羧基，羟基，硫醇，氰基，硝基，醛基，酮基，醚基，酯基，羰基，烷基，烷芳基或芳基 组; X是具有式 - （CH2）m-，分支或直链的连接基团，其中m是0和20之间的整数，包括1和20个，并且一个或多个亚甲基可以任选地被O，S，C = O，O = S = O，氨基甲酸乙酯，脲，酯基，NR 3基，CHR 4基或CR 5 R 6基，其中R 3，R 4，R 5和R 6独立地为H，烷基，烷芳基 ，杂环基或芳基; Y包括键，C，N，O，S，分支或线性 - （CH 2）p基团，其中p是0至10之间的整数，芳族基团，环烷基，杂环基或NR 7基团 其中R 7是氢原子，烷基或芳基，其中Y具有选择与相应X基团形成n键的结构; Z为亚芴基; 和（b）电荷产生化合物。 描述相应的电子照相设备和成像方法。

    Electrophotographic organophotoreceptors with novel charge transport compounds
    10.
    发明授权
    Electrophotographic organophotoreceptors with novel charge transport compounds 失效
    具有新型电荷传输化合物的电子照相有机光感受器

    公开(公告)号：US06749978B2

    公开(公告)日：2004-06-15

    申请号：US10449554

    申请日：2003-05-30

    申请人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Kam Law ,  Vytautas Getautis ,  Jonas Sidaravicius ,  Osvaldas Paliulis ,  Valentas Gaidelis ,  Vygintas Jankauskas

    发明人： Nusrallah Jubran ,  Zbigniew Tokarski ,  Kam Law ,  Vytautas Getautis ,  Jonas Sidaravicius ,  Osvaldas Paliulis ,  Valentas Gaidelis ,  Vygintas Jankauskas

    IPC分类号： G03G1502

    CPC分类号： C07D263/58 ,  C07C251/86 ,  C07D209/86 ,  C07D455/04 ,  G03G5/0614 ,  G03G5/0616 ,  G03G5/0625 ,  G03G5/0629 ,  G03G5/0637 ,  G03G5/0642 ,  G03G5/0646 ,  G03G5/065 ,  G03G5/0661

    摘要： Charge transport compounds are described that have a multiple number of hydrazone-bridged heterocyclic groups (especially julolidine groups, carbazole groups, triarylamine groups and (N,N-disubstituted)arylamine groups such as dialkarylamine groups (e.g. dimethylphenylamine; methylethylphenylamine, dipropylphenylamine, ethylepropylphenylamine, ethylbutylnaphthylamine, etc.), alkyldiarylamine groups (e.g. methyldiphenylamino, ethyldiphenylamino, etc), and triarylamino groups (e.g., triphenyl amino, trinaphthylamino, etc)) connected by a central bridging group. An example of charge transport compounds are those having the following generic formula: (R—Q)n−Y  Formula I wherein R is selected from the group consisting of julolidine ring groups, carbazole ring groups, and and (N,N-disubstituted)arylamine groups; Q comprises an aromatic hydrazone linking group, such as Y comprises a bridging group between R—Q— groups, such as a bond, carbon atom, nitrogen atom, oxygen atom, sulfur atom, a methylene group; Z is an aryl group, preferably a phenyl group or naphthyl group; X is a linking group, preferably a methylene group, and for example having the formula —(CH2)m— (branched or linear), where m is an integer between 0 and 20, inclusive, and one or more of the methylene groups is optionally replaced by an oxygen atom, a carbonyl group, urethane, urea, an ester group, a —NR6 group, a CHR7 group, or a CR8R9 group where R6, R7, R8, and R9 are, independently, H, an alkyl group, or aryl group; and n is an integer between 2 and 6, inclusive. An organic photoreceptor includes that compound and (b) a charge generating compound; and (c) an electrically conductive substrate.

    摘要翻译： 描述了具有多个腙桥连杂环基团（特别是多洛兰组，咔唑基团，三芳基胺基团和（N，N-二取代的）芳基胺基团如二烷基芳基基团的电荷转运化合物（例如二甲基苯胺;甲基乙基苯基胺，二丙基苯胺，乙基丙基苯胺， 乙基丁基萘胺等），烷基二芳基胺基（例如甲基二苯基氨基，乙基二苯基氨基等）和三芳基氨基（例如三苯基氨基，三萘基氨基等））通过中心桥连基团连接。 电荷输送化合物的实例是具有以下通式的那些：其中R选自久洛瑞因环基，咔唑环基和（N，N-二取代的）芳基胺基; Q包括芳族腙连接基团 例如Y包括RQ-基团之间的桥连基团，例如键，碳原子，氮原子，氧原子，硫原子，亚甲基基团; Z是芳基，优选苯基或萘基; X是连接基团，优选亚甲基，例如具有式 - （CH 2）m - （支链或直链）的基团，其中m是0和20之间的整数，包括端值在内，一个或多个亚甲基是 任选地被氧原子，羰基，氨基甲酸酯，脲，酯基，-NR 6基，CHR 7基或CR 8 R 9基团取代，其中R 6，R 7，R 8和R 9独立地是H，烷基 ，或芳基; n为2〜6的整数。 有机感光体包括该化合物和（b）电荷产生化合物; 和（c）导电基板。