Abstract:
The present disclosure provides a carbon-silicon composite including: a first carbon matrix; and carbonized Si-block copolymer core-shell particles dispersed uniformly in the first carbon matrix. The present disclosure also provides a lithium secondary battery anode and a lithium secondary battery, which include the carbon-silicon composite.
Abstract:
The Si-block copolymer core-shell nanoparticles include: a Si core; and a block copolymer shell including a block having relatively relatively high affinity for Si and a block having relatively low affinity for Si and forming a spherical micelle structure around the Si core. Since the Si-block copolymer core-shell nanoparticles exhibit excellent dispersibility and stability in a mixed solution including the same, the Si-block copolymer core-shell nanoparticles are easily applied to an anode active material for lithium secondary battery by carbonization thereof. In addition, since the anode active material for lithium secondary battery using the Si-block copolymer core-shell nanoparticles includes carbonized Si-block copolymer core-shell nanoparticles and pores, the anode active material has long lifespan, high capacity and high energy density, and the block copolymer shell of the carbonized Si-block copolymer core-shell nanoparticles can improve lifespan of lithium secondary battery by buffering volumetric change thereof during charge and discharge.
Abstract:
The present invention relates to a carbon-silicon composite and an anode active material for a secondary battery comprising the same, and more particularly, a carbon-silicon composite in which silicon (Si)-block copolymer core-shell particles are uniformly dispersed and embedded in a carbonaceous substance.
Abstract:
The Si-block copolymer core-shell nanoparticles include: a Si core; and a block copolymer shell including a block having relatively relatively high affinity for Si and a block having relatively low affinity for Si and forming a spherical micelle structure around the Si core. Since the Si-block copolymer core-shell nanoparticles exhibit excellent dispersibility and stability in a mixed solution including the same, the Si-block copolymer core-shell nanoparticles are easily applied to an anode active material for lithium secondary battery by carbonization thereof. In addition, since the anode active material for lithium secondary battery using the Si-block copolymer core-shell nanoparticles includes carbonized Si-block copolymer core-shell nanoparticles and pores, the anode active material has long lifespan, high capacity and high energy density, and the block copolymer shell of the carbonized Si-block copolymer core-shell nanoparticles can improve lifespan of lithium secondary battery by buffering volumetric change thereof during charge and discharge.
Abstract:
Disclosed herein are a manufacturing method of a carbon-silicon composite, the manufacturing method including: (a) preparing a silicon-carbon-polymer matrix slurry including a silicon slurry, carbon particles, a monomer of polymer, and a cross-linking agent; (b) performing a heat treatment process on the silicon-carbon-polymer matrix slurry to manufacture a silicon-carbon-polymer carbonized matrix; (c) pulverizing the silicon-carbon-polymer carbonized matrix to manufacture a silicon-carbon-polymer carbonized matrix structure; and (d) mixing the silicon-carbon-polymer carbonized matrix structure with a first carbon raw material and performing a carbonization process to manufacture a carbon-silicon composite, the carbon-silicon composite, an anode for a secondary battery manufactured by applying the carbon-silicon composite, and a secondary battery including the anode for a secondary battery.
Abstract:
Disclosed herein are a manufacturing method of a carbon-silicon composite, including: (a) preparing a slurry solution including silicon (Si)-block copolymer core-shell particles; (b) mixing the slurry solution with a carbon raw material to manufacture a mixed solution; (c) performing a primary carbonization process on the mixed solution, followed by pulverization, to manufacture a primary carbon-silicon composite; and (d) performing a secondary carbonization process on the primary carbon-silicon composite, followed by pulverization, to manufacture a secondary carbon-silicon composite, the carbon-silicon composite, an anode for a secondary battery manufactured by applying the carbon-silicon composite, and a secondary battery including the anode for a secondary battery.
Abstract:
Disclosed herein are an anode active material and a secondary battery comprising the same, and more specifically, an anode active material comprising a graphite carbon material coated with an amorphous carbon material comprising metal particles, and a secondary battery comprising the same.
Abstract:
Disclosed herein are a manufacturing method of a carbon-silicon composite, comprising: (a) preparing a silicon-polymer matrix slurry comprising a silicon slurry, a monomer, and a cross-linking agent; (b) performing a heat treatment on the silicon-polymer matrix slurry to manufacture a silicon-polymer carbonized matrix; (c) pulverizing the silicon-polymer carbonized matrix to manufacture silicon-polymer carbonized particles; and (d) mixing the silicon-polymer carbonized particles with a first carbon raw material, and then performing a carbonization process, the carbon-silicon composite, an anode for a secondary battery manufactured by applying the carbon-silicon composite, and a secondary battery comprising the anode for a secondary battery.
Abstract:
The present invention relates to a negative electrode for a secondary battery and a method for manufacturing the negative electrode, and more particularly, to a negative electrode for a secondary battery which exhibits excellent charge/discharge characteristics and lifespan characteristics by including a carbon-silicon composite and graphite at a predetermined particle size ratio.
Abstract:
The present disclosure relates to a composition for preparing a silicon-carbon composite having nano-Si particulates and electrically conductive materials dispersed in an amorphous carbon, the silicon-carbon composite prepared therefrom, an electrode for secondary battery comprising the silicon-carbon composite, and a method for producing the silicon-carbon composite.