公开(公告)号：US3867342A

公开(公告)日：1975-02-18

申请号：US44752674

申请日：1974-03-04

Applicant: PHILLIPS PETROLEUM CO

Inventor： GUILLORY JACK P ,  BECKER RALPH S ,  HUGHES WILLIAM B

IPC: C08K5/36 ,  C08F45/58

CPC classification number: C08K5/36 ,  C08L23/02

Abstract: The addition of a minor amount of a 2-hydroxy-4-alkoxythiobenzophenone or 2-mercapto-4-alkoxythiobenzophenone to olefin polymers produces an olefin polymer composition resistant to degradation by ultraviolet light.

Abstract translation: 向烯烃聚合物中加入少量的2-羟基-4-烷氧基硫代苯并菲酮或2-巯基-4-烷氧基硫代二苯甲酮产生耐紫外线降解的烯烃聚合物组合物。

公开(公告)号：US3691253A

公开(公告)日：1972-09-12

申请号：US3691253D

申请日：1970-10-12

Applicant: WILLIAM B HUGHES ,  ERNEST A ZUECH ,  PHILLIPS PETROLEUM CO

Inventor： HUGHES WILLIAM B ,  ZUECH ERNEST A

IPC: B01J31/16 ,  B01J31/18 ,  C07C6/04 ,  C07C6/06 ,  C07C3/62

CPC classification number: C07C6/04 ,  B01J31/16 ,  B01J31/18 ,  B01J31/1805 ,  C07C6/06

Abstract: A process for the conversion of olefinic hydrocarbons according to the olefin reaction including olefin disproportionation by contacting the olefinic hydrocarbon with a catalyst comprising a compound of vanadium or niobium complexed with NO and a selected complexing agent (e.g., benzoic acid) and combined with an organoaluminum compound (e.g., methylaluminum sesqui-chloride). The metal complexes which form a part of the catalysts are also claimed.

公开(公告)号：US3623966A

公开(公告)日：1971-11-30

申请号：US3623966D

申请日：1970-03-05

Applicant: PHILLIPS PETROLEUM CO

Inventor： HUGHES WILLIAM B

IPC: C07C255/45 ,  B01J1/10

CPC classification number: C07C255/45 ,  Y10S204/908

Abstract: Acrylonitrile is photodimerized to 1,2-dicyanocyclobutane in the presence of an activator of Mo(CO)6 or W(CO)6. Preferably, a promoter such as triphenylphosphine is employed in combination with the activator.

公开(公告)号：US3887441A

公开(公告)日：1975-06-03

申请号：US36403173

申请日：1973-05-25

Applicant: PHILLIPS PETROLEUM CO

Inventor： HUGHES WILLIAM B ,  FAHEY DARRYL R

IPC: C07F15/04 ,  C25B3/12 ,  C25B3/00

CPC classification number: C25B3/12 ,  C07F15/04

Abstract: A process for the synthesis of organonickel derivatives by electrochemical reduction of a nickel(II) complex followed by addition of a haloorganic compound which yields a different nickel(II) complex. The complexes have utility as catalysts for olefin dimerization.

Abstract translation: 通过电化学还原镍（II）络合物然后加入产生不同镍（II）络合物的卤代有机化合物来合成有机镍衍生物的方法。 该配合物可用作烯烃二聚化的催化剂。

公开(公告)号：US3668086A

公开(公告)日：1972-06-06

申请号：US3668086D

申请日：1970-07-28

Applicant: PHILLIPS PETROLEUM CO

Inventor： HUGHES WILLIAM B

IPC: B01J37/34 ,  C07C2/46 ,  B01K3/00

CPC classification number: C07C2/465 ,  B01J37/34 ,  C07C2531/24

Abstract: A method of generating soluble zero-valent nickel catalyst consisting of electrochemically reducing suitable nickel(II)ligand complexes wherein said electrochemical reduction can be achieved with or without the presence of an electrolyte.

Abstract translation: 产生可溶性零价镍催化剂的方法，其由电化学还原合适的镍（II）配体配合物组成，其中所述电化学还原可以在或不存在电解质的情况下实现。

公开(公告)号：US3511885A

公开(公告)日：1970-05-12

申请号：US3511885D

申请日：1967-12-11

Applicant: PHILLIPS PETROLEUM CO

Inventor： HUGHES WILLIAM B

IPC: C07C5/52 ,  C07C1/00 ,  C07C3/00

CPC classification number: C07C5/52

公开(公告)号：US3697615A

公开(公告)日：1972-10-10

申请号：US3697615D

申请日：1971-02-08

Applicant: PHILLIPS PETROLEUM CO

Inventor： HUGHES WILLIAM B

IPC: C07C5/03 ,  C07C5/08 ,  C07C5/02 ,  C07C11/00

CPC classification number: C07C5/03 ,  C07C5/08 ,  C07C2531/22 ,  C07C2531/24

Abstract: Olefin hydrocarbons are hydrogenated by contacting the feed olefin hydrocarbon with a catalyst which is an admixture of a rhodium or an iridium halide complex and an aluminum or boron halide.

公开(公告)号：US3674661A

公开(公告)日：1972-07-04

申请号：US3674661D

申请日：1971-03-01

Applicant: PHILLIPS PETROLEUM CO

Inventor： HUGHES WILLIAM B

IPC: C07C2/36 ,  C07F15/04 ,  C07B29/06 ,  C07F9/02

CPC classification number: C07F15/045 ,  C07C2/36 ,  C07C2531/24 ,  C07C11/107

Abstract: The treatment of nickel(II) halide compounds by controlled potential electrolysis is disclosed for the production of nickel(I) halide phosphine compounds.

Abstract translation: 公开了通过控制电解电解处理卤化镍（II）化合物来制备卤化镍（I）化合物。

公开(公告)号：US3562178A

公开(公告)日：1971-02-09

申请号：US3562178D

申请日：1968-01-02

Applicant: PHILLIPS PETROLEUM CO

Inventor： HUGHES WILLIAM B ,  ZUECH ERNEST A

IPC: B01J31/16 ,  B01J31/18 ,  C07C6/04 ,  C07C6/06 ,  C07C3/62

CPC classification number: C07C6/04 ,  B01J31/16 ,  B01J31/18 ,  B01J31/1805 ,  C07C6/06

Abstract: A CATALYST ACTIVE FOR THE OLEFIN REACTION INCLUDING OLEFIN DISPROPORTIONATION COMPRISING A COMPOUND OF VANADIUM OR NOBIUM COMPLEXED WITH NO AND A SELECTED COMPLEXING AGENT (E.G., BENZOIC ACID) AND COMBINED WITH AN ORGANOALUMINUM COMPOUND (E.G., METHYLALUMINUM SESQUICHLORIDE).

公开(公告)号：US3558517A

公开(公告)日：1971-01-26

申请号：US3558517D

申请日：1969-03-24

Applicant: PHILLIPS PETROLEUM CO

Inventor： HUGHES WILLIAM B ,  ZUECH ERNEST A

IPC: B01J31/14 ,  B01J31/16 ,  B01J31/18 ,  B01J31/20 ,  B01J31/24 ,  C07C6/04 ,  C07C3/62

CPC classification number: C07C6/04 ,  B01J31/143 ,  B01J31/1895 ,  B01J31/20 ,  B01J31/2404 ,  B01J2231/543 ,  B01J2531/821 ,  B01J2531/825 ,  B01J2531/842

Abstract: A HOMOGENEOUS CATALYST ACTIVE FOR THE OLEFIN REACTION INCLUDING OLEFIN DISPROPORTIONATION COMPRISING A COMPOUND OF RUTHENIUM, IRON, OSMIUM, RHODIUM, OR IRIDIUM COMPLEXED WITH A SELECTED COMPLEXING AGENT (E.G. TRIPHENYLPHOSPHINE) AND COMBINED WITH AN ORGANOALUMINUM COMPOUND (E.G., METHYLALUMINUM SESQUIHALIDE).