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1.发明申请Inorganic Nanoparticle Deposited Catalyst For Hydrogenation And Manufacturing Method Of The Same, And Hydrogenation For Biomass Derived Hydrocarbon Compounds 有权用于氢化的无机纳米颗粒沉积催化剂及其制备方法，以及用于生物质衍生烃化合物的氢化公开(公告)号：US20150224484A1
公开(公告)日：2015-08-13
申请号：US14513529
申请日：2014-10-14
Applicant: POSTECH ACADEMY-INDUSTRY FOUNDATION
Inventor： Dong-Pyo Kim , Ajay K. Singh
IPC: B01J27/24 , C07C29/17 , C07C45/62 , C07C51/36 , C07D311/60 , B01J23/75 , C07C5/05 , C07C209/36 , C07C221/00 , B01J23/44 , B01J23/745 , B01J23/89 , C07C41/18 , C07C5/03
CPC classification number: B01J27/24 , B01J21/18 , B01J23/42 , B01J23/44 , B01J23/50 , B01J23/52 , B01J23/745 , B01J23/75 , B01J23/8906 , B01J23/8913 , B01J35/0013 , B01J35/002 , B01J35/0033 , B01J35/1019 , B01J37/031 , B01J37/16 , B01J37/343 , C07C1/22 , C07C5/03 , C07C5/08 , C07C29/172 , C07C37/002 , C07C41/01 , C07C41/18 , C07C45/62 , C07C51/36 , C07C209/36 , C07C221/00 , C07C231/10 , C07C2521/18 , C07C2523/89 , C07C2601/14 , C07C2603/18 , C07D311/60 , C10G3/45 , C10G3/50 , C10G3/55 , C10G2300/1011 , C10G2300/70 , C10G2400/02 , C10G2400/04 , C10G2400/06 , C10G2400/08 , Y02P20/52 , Y02P30/20 , C07C43/23 , C07C43/205 , C07C39/07 , C07C43/164 , C07C31/125 , C07C211/46 , C07C233/03 , C07C57/30 , C07C47/228 , C07C49/403 , C07C13/18 , C07C9/15 , C07C15/073
Abstract: A hydrogenation catalyst and a method of hydrogenating a hydrocarbon compound as a substrate using the same are provided. The hydrogenation catalyst includes inorganic nanoparticles and a nitrogen-doped reduced graphene oxide support for supporting the inorganic nanoparticles, and the hydrocarbon compound is derived from a biomass and contains a functional group. Therefore, the hydrogenation catalyst which exhibits a high conversion rate and high selectivity, is stable, and can be easily separated after a hydrogenation reaction, and whose catalytic activities are not significantly altered even when recovered and repeatedly recycled can be provided. The method of hydrogenating a hydrocarbon compound in which hydrogen can be directly produced in a reactor using formic acid as a hydrogen source without supplying additional hydrogen gas and simultaneously be used under normal pressure can also be provided.
Abstract translation: 提供氢化催化剂和使用其的氢化烃化合物作为底物的方法。 氢化催化剂包括无机纳米颗粒和用于支撑无机纳米颗粒的氮掺杂的还原型石墨烯氧化物载体，烃化合物衍生自生物质并含有官能团。 因此，显示高转化率和高选择性的氢化催化剂是稳定的，并且可以容易地在氢化反应之后分离，并且即使在回收和反复再循环时催化活性也不会显着改变。 也可以提供氢化氢化合物的方法，其中可以使用甲酸作为氢源在反应器中直接生产氢气，而不提供额外的氢气并同时在常压下使用。
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2.发明授权Inorganic nanoparticle deposited catalyst for hydrogenation and manufacturing method of the same, and hydrogenation for biomass derived hydrocarbon compounds 有权无机纳米颗粒沉积催化剂用于氢化及其制备方法相同，并对生物质衍生烃化合物进行氢化公开(公告)号：US09421527B2
公开(公告)日：2016-08-23
申请号：US14513529
申请日：2014-10-14
Applicant: POSTECH ACADEMY-INDUSTRY FOUNDATION
Inventor： Dong-Pyo Kim , Ajay K. Singh
IPC: B01J27/24 , C07C41/18 , C07C29/17 , C07C45/62 , C07C51/36 , C07D311/60 , C07C5/03 , C07C209/36 , C07C221/00 , B01J23/44 , B01J23/745 , B01J23/89 , B01J23/75 , C07C37/00 , C07C41/01 , C07C231/10 , B01J37/03 , B01J37/16 , B01J37/34 , B01J21/18 , B01J23/42 , B01J23/50 , B01J23/52 , B01J35/00 , C07C1/22 , C07C5/08
CPC classification number: B01J27/24 , B01J21/18 , B01J23/42 , B01J23/44 , B01J23/50 , B01J23/52 , B01J23/745 , B01J23/75 , B01J23/8906 , B01J23/8913 , B01J35/0013 , B01J35/002 , B01J35/0033 , B01J35/1019 , B01J37/031 , B01J37/16 , B01J37/343 , C07C1/22 , C07C5/03 , C07C5/08 , C07C29/172 , C07C37/002 , C07C41/01 , C07C41/18 , C07C45/62 , C07C51/36 , C07C209/36 , C07C221/00 , C07C231/10 , C07C2521/18 , C07C2523/89 , C07C2601/14 , C07C2603/18 , C07D311/60 , C10G3/45 , C10G3/50 , C10G3/55 , C10G2300/1011 , C10G2300/70 , C10G2400/02 , C10G2400/04 , C10G2400/06 , C10G2400/08 , Y02P20/52 , Y02P30/20 , C07C43/23 , C07C43/205 , C07C39/07 , C07C43/164 , C07C31/125 , C07C211/46 , C07C233/03 , C07C57/30 , C07C47/228 , C07C49/403 , C07C13/18 , C07C9/15 , C07C15/073
Abstract: A hydrogenation catalyst and a method of hydrogenating a hydrocarbon compound as a substrate using the same are provided. The hydrogenation catalyst includes inorganic nanoparticles and a nitrogen-doped reduced graphene oxide support for supporting the inorganic nanoparticles, and the hydrocarbon compound is derived from a biomass and contains a functional group. Therefore, the hydrogenation catalyst which exhibits a high conversion rate and high selectivity, is stable, and can be easily separated after a hydrogenation reaction, and whose catalytic activities are not significantly altered even when recovered and repeatedly recycled can be provided. The method of hydrogenating a hydrocarbon compound in which hydrogen can be directly produced in a reactor using formic acid as a hydrogen source without supplying additional hydrogen gas and simultaneously be used under normal pressure can also be provided.
Abstract translation: 提供氢化催化剂和使用其的氢化烃化合物作为底物的方法。 氢化催化剂包括无机纳米颗粒和用于支撑无机纳米颗粒的氮掺杂的还原型石墨烯氧化物载体，烃化合物衍生自生物质并含有官能团。 因此，显示高转化率和高选择性的氢化催化剂是稳定的，并且可以容易地在氢化反应之后分离，并且即使在回收和反复再循环时催化活性也不会显着改变。 也可以提供氢化氢化合物的方法，其中可以使用甲酸作为氢源在反应器中直接生产氢气，而不提供额外的氢气并同时在常压下使用。
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