摘要:
Disclosed herein is a polymer comprising an amorphous syndiotactic rich polyolefin comprising greater than about 50 wt % C3-C40 alpha olefins and having about 50% to less than about 80% r dyads, based on the total number of r and m dyads present in the polymer; a heat of fusion of 10 joules/g or less according to the procedure described in ASTM E 794-85; and an ash content of 1 wt % or less. A functionalized amorphous syndiotactic rich polyolefin is also disclosed, along with methods to produce and a method to use the inventive polymer.
摘要翻译:本文公开了一种聚合物,其包含无定形间同立构聚烯烃,其包含大于约50重量%的C 3 -C 40α-烯烃,并且具有约50%至小于约80% 基于聚合物中存在的r和m二重峰的总数; 根据ASTM E 794-85中描述的程序,10焦耳/克或更小的熔化热; 灰分含量为1重量%以下。 还公开了官能化的无定形间同立构聚烯烃,以及制备方法和使用本发明聚合物的方法。
摘要:
Disclosed herein is a polymer comprising an amorphous syndiotactic rich polyolefin comprising greater than about 50 wt % C3-C40 alpha olefins and having about 50% to less than about 80% r dyads, based on the total number of r and m dyads present in the polymer; a heat of fusion of 10 joules/g or less according to the procedure described in ASTM E 794-85; and an ash content of 1 wt % or less. A functionalized amorphous syndiotactic rich polyolefin is also disclosed, along with methods to produce and a method to use the inventive polymer.
摘要翻译:本文公开的是包含含有大于约50重量%的C 3 -C 40α-烯烃并且具有约50%至小于约80%的二组分的无定形间同立构的聚烯烃的聚合物,基于存在于 聚合物; 根据ASTM E 794-85中描述的程序,10焦耳/克或更小的熔化热; 灰分含量为1重量%以下。 还公开了官能化的无定形间同立构聚烯烃,以及制备方法和使用本发明聚合物的方法。
摘要:
Embodiments of the present invention relate to article comprising 1) a functionalized component, 2) tackifier, and 3) an olefin polymer comprising one or more C3 to C40 olefins, optionally one or more diolefins, and less than 5 mole % of ethylene having a Dot T-Peel of 1 Newton or more, a branching index (g′) of 0.95 or less measured at the Mz of the polymer; and an Mw of 100,000 or less; where the functional component is selected from the group consisting of functionalized polymers, functionalized oligomers and beta nucleating agents; and where the Gardner color of the adhesive does not change by more than 7 Gardner units when the adhesive has been heat aged at 180° C. for 48 hours as compared to the Gardner color of the unaged composition.
摘要:
Embodiments of the present invention relate to article comprising 1) a functionalized component, 2) tackifier, and 3) an olefin polymer comprising one or more C3 to C40 olefins, optionally one or more diolefins, and less than 5 mole % of ethylene having a Dot T-Peel of 1 Newton or more, a branching index (g′) of 0.95 or less measured at the Mz of the polymer; and an Mw of 100,000 or less; where the functional component is selected from the group consisting of functionalized polymers, functionalized oligomers and beta nucleating agents; and where the Gardner color of the adhesive does not change by more than 7 Gardner units when the adhesive has been heat aged at 180° C. for 48 hours as compared to the Gardner color of the unaged composition.
摘要:
Embodiments of the present invention relate to article comprising 1) a functionalized component, 2) tackifier, and 3) an olefin polymer comprising one or more C3 to C40 olefins, optionally one or more diolefins, and less than 5 mole % of ethylene having a Dot T-Peel of 1 Newton or more, a branching index (g′) of 0.95 or less measured at the Mz of the polymer; and an Mw of 100,000 or less; where the functional component is selected from the group consisting of functionalized polymers, functionalized oligomers and beta nucleating agents; and where the Gardner color of the adhesive does not change by more than 7 Gardner units when the adhesive has been heat aged at 180° C. for 48 hours as compared to the Gardner color of the unaged composition.
摘要:
Disclosed herein is an adhesive composition comprising a blend functionalized with a functional group, wherein the blend comprises a C3 to C40 olefin polymer and an additive, the C3 to C40 olefin polymer comprising at least 50 mol % of one or more C3 to C40 olefins, and where the C3 to C40 olefin polymer has: a Dot T-Peel of 1 Newton or more on Kraft paper; an Mw of 10,000 to 100,000; and a branching index (g′) of 0.98 or less measured at the Mz of the polymer when the polymer has an Mw of 10,000 to 60,000, or a branching index (g′) of 0.95 or less measured at the Mz of the polymer when the polymer has an Mw of 10,000 to 100,000. A process of producing the adhesive composition, as well as methods of utilizing the adhesive composition are also disclosed.
摘要:
This invention relates to an isotactic propylene homopolymer having: more than 15 and less than 100 regio defects (sum of 2,1-erythro and 2,1-threo insertions and 3,1-isomerizations) per 10,000 propylene units; an Mw of 35000 g/mol or more; a peak melting temperature of greater than 149° C.; an mmmm pentad fraction of 0.85 or more; a heat of fusion of 80 J/g or more; and a peak melting temperature minus peak crystallization temperature (Tmp−Tcp) of less than or equal to (0.907 times Tmp) minus 99.64 (Tmp−Tcp
摘要:
Disclosed herein is an in-reactor produced multi-component copolymer comprises a semi-crystalline component having a crystallinity of 20% or more, and an amorphous component having a crystallinity of 5% or less. The copolymer comprises at least 80 wt % of units derived from propylene and from about 1 to about 20 wt % of units derived from at least one C6 to C12 alpha-olefin. The copolymer has a viscosity at 190° C. of at least 530 mPa sec and a heat of fusion between about 10 and about 70 J/g. An adhesive containing the copolymer exhibits a good balance of adhesive properties and mechanical strength.
摘要:
This invention relates to a process for polymerization, comprising (i) contacting, at a temperature greater than 35° C., one or more monomers comprising ethylene and/or propylene, with a catalyst system comprising a metallocene catalyst compound and an activator, (ii) converting at least 50 mol % of the monomer to polyolefin; and (iii) obtaining a branched polyolefin having greater than 50% allyl chain ends, relative to total unsaturated chain ends. The invention also relates to the branched polyolefins and functionalized branched polyolefins.
摘要:
Disclosed herein is an in-reactor produced multi-component copolymer comprises a semi-crystalline component having a crystallinity of 20% or more, and an amorphous component having a crystallinity of 5% or less. The copolymer comprises at least 80 wt % of units derived from propylene and from about 1 to about 20 wt % of units derived from at least one C6 to C12 alpha-olefin. The copolymer has a viscosity at 190° C. of at least 530 mPa sec and a heat of fusion between about 10 and about 70 J/g. An adhesive containing the copolymer exhibits a good balance of adhesive properties and mechanical strength.