公开(公告)号：US5242574A

公开(公告)日：1993-09-07

申请号：US776299

申请日：1991-12-06

申请人： Paul Broutin ,  Christian Busson ,  Antoine Montoya ,  Jerome Weill

发明人： Paul Broutin ,  Christian Busson ,  Antoine Montoya ,  Jerome Weill

IPC分类号： B01J19/24 ,  C10G9/18 ,  C10G9/20 ,  F28D9/00 ,  F28F19/02 ,  F28F21/08

CPC分类号： F28F21/087 ,  B01J19/2485 ,  C10G9/203 ,  F28D9/0037 ,  F28F19/02 ,  Y10S585/95

摘要： A process and reactor are disclosed for the thermal cracking of a charge containing at least one hydrocarbon with at least one carbon atom, in which the charge is circulated in a metal reaction zone which includes a pyrolysis zone whose external wall is in thermal exchange relationship with a heating liquid. The reaction zone consists of an alloy containing, by weight, 66-82% nickel, 14-18% chromium, and 4-6% aluminum. This alloy, which has already been preoxidized, may be covered, at least in the reaction zone, with at least one layer formed by an oxide of at least one metal and/or at least one metal carbide and/or at least one metal nitride and/or at least one metal silicide. The invention finds application for vapor-phase cracking and dehydrogenation of hydrocarbon charges.

摘要翻译： PCT No.PCT / FR90 / 00392 Sec。 371 1991年12月6日第 102（e）日期1991年12月6日PCT提交1990年6月5日PCT公布。 出版物WO90 / 15119 公开了一种用于热分解含有至少一种具有至少一个碳原子的烃的方法和反应器，其中电荷在金属反应区中循环，所述金属反应区包括热解区，其外部 壁与加热液体具有热交换关系。 反应区由含有重量百分比为66-82％镍，14-18％铬和4-6％铝的合金组成。 已经预氧化的该合金可以至少在反应区中被至少一层由至少一种金属和/或至少一种金属碳化物的氧化物形成的层和/或至少一种金属氮化物 和/或至少一种金属硅化物。 本发明应用于烃电荷的气相裂化和脱氢。

公开(公告)号：US5321191A

公开(公告)日：1994-06-14

申请号：US972782

申请日：1992-11-09

申请人： Jacques Alagy ,  Paul Broutin ,  Christian Busson ,  Jerome Weill

发明人： Jacques Alagy ,  Paul Broutin ,  Christian Busson ,  Jerome Weill

IPC分类号： C10G9/24 ,  C07C4/04

CPC分类号： C10G9/24 ,  Y10S585/921 ,  Y10S585/926

摘要： A process for the thermal pyrolysis of hydrocarbons in a reactor (1) of elongate shape comprising at a first end supply means (5) for a gaseous mixture containing at least one hydrocarbon, at the opposite end discharge means (10) for the effluents produced and between these two ends supply means (9) for effluent cooling fluid, the reactor comprising in a first part (first end side) a plurality of electric heating means (3) enclosed by casings (4) disposed in substantially mutually parallel layers perpendicular to the axis of the reactor, in such a way as to define between the casings and/or the casings and the walls (22), spaces or passages for circulation of the gaseous mixtures and/or effluents. The heating means heat the passages in successive, individual, transverse sections which are substantially perpendicular to the axis of the reactor. The reactor comprises means for introducing into the casings (4) a gas G known as a casing gas which preferably contains water vapour and/or hydrogen. The permeability of the casings is sufficient to permit diffusion, at least at certain points, of at least a part of the gas G from inside the casings to the outside of the casings, the gas G then being diluted in the gaseous mixture.

摘要翻译： 一种用于在细长形状的反应器（1）中热解烃的方法，该方法包括在第一端供应装置（5），用于含有至少一种烃的气态混合物，在相对的端部排出装置（10）用于所产生的流出物 并且在这两个端部之间，用于流出物冷却流体的供应装置（9），所述反应器包括在第一部分（第一端侧）中的多个电加热装置（3），所述多个电加热装置（3）由壳体（4）包围， 反应器的轴线以限定壳体和/或壳体和壁（22）之间的方式，用于气态混合物和/或流出物循环的空间或通道。 加热装置加热基本上垂直于反应器轴线的连续的，单独的横向部分中的通道。 反应器包括用于将优选含有水蒸气和/或氢气的称为外壳气体的气体G引入壳体（4）的装置。 壳体的渗透性足以允许至少在某些点处将气体G的至少一部分从壳体内部扩散到壳体的外部，然后将气体G稀释在气体混合物中。

公开(公告)号：US5186910A

公开(公告)日：1993-02-16

申请号：US582426

申请日：1990-09-12

申请人： Jacques Alagy ,  Paul Broutin ,  Christian Busson ,  Yves Gougne ,  Jerome Weill

发明人： Jacques Alagy ,  Paul Broutin ,  Christian Busson ,  Yves Gougne ,  Jerome Weill

IPC分类号： B01F3/02 ,  B01J4/04 ,  B01J8/04 ,  B01J12/00 ,  B01J19/00 ,  B01J19/24 ,  B01J35/04 ,  C01B3/36 ,  C01B3/38 ,  C01B32/40 ,  C01B32/50

CPC分类号： C01B3/363 ,  B01J12/005 ,  B01J19/2415 ,  B01J4/04 ,  C01B3/36 ,  B01J2208/00495 ,  B01J2219/00162

摘要： An oxidation reactor having elongated shape includes in combination, a mixing member including a pipe for feeding oxidizing gas and a pipe for feeding oxidizable charge; a reaction member, arranged subjacent the mixing member, and a discharge member associated with a discharge pipe for the products of the reaction. The reaction member includes a central zone which has a first lining and the reactor includes at least one peripheral zone which has a second lining, passages in the second lining being smaller than passages in the first lining so that the pressure loss in the second lining is greater than that of the first lining. The second lining forms a sleeve surround the first lining and this sleeve is formed of at least one refractory heat insulating material. The oxidation reactor is provided with an external sleeve steel jacket, a concrete wall and a steel element surrounding the mixing member arranged above the reaction member. The reaction member includes a series of single elements which form juxtaposed channels.

摘要翻译： 具有细长形状的氧化反应器组合包括：混合构件，包括用于供给氧化气体的管和用于供给可氧化电荷的管; 布置在混合部件的下方的反应部件和与反应产物的排出管相关联的排出部件。 反应构件包括具有第一衬里的中心区，反应器包括具有第二衬里的至少一个周边区，第二衬里中的通道小于第一衬里中的通道，使得第二衬里中的压力损失为 大于第一衬里。 第二衬里形成围绕第一衬里的套筒，并且该套筒由至少一个难熔绝热材料形成。 氧化反应器设置有外部套筒钢护套，混凝土壁和围绕设置在反作用构件上方的混合构件的钢构件。 反应构件包括形成并列通道的一系列单一元件。

公开(公告)号：US5160501A

公开(公告)日：1992-11-03

申请号：US700706

申请日：1991-05-16

申请人： Jacques Alagy ,  Paul Broutin ,  Christian Busson ,  Jerome Weill

发明人： Jacques Alagy ,  Paul Broutin ,  Christian Busson ,  Jerome Weill

IPC分类号： B01J12/00 ,  B01J19/24 ,  C07C2/76

CPC分类号： B01J19/24 ,  B01J12/005 ,  C07C2/76 ,  B01J2219/00135 ,  Y10S585/911 ,  Y10S585/913 ,  Y10S585/924 ,  Y10S585/926 ,  Y10S585/943

摘要： Method and apparatus for thermal conversion of methane to hydrocarbons of higher molecular weight, comprising a reactor 1 of elongated shape, connected at a first end to means 5 for supplying gas mixture containing methane (process gas), and connected at the opposite end to discharge means 10, the reactor having a plurality of electric heating means 3 surrounded by sheaths 4 over a first part (towards the first end). The heating means, which are substantially parallel, are arranged in sheets which are substantially parallel and perpendicular to the axis of the reactor, so that spaces or passages for circulation of the process gas and/or effluent are defined between the sheaths and/or between the sheaths and the walls 22 separating two consecutive sheets. The heating means are adapted to heat the passages by successive independent cross sections substantially perpendicular to the axis of the reactor. In a second part 8 (towards the opposite end) adjoining the first part, the reactor further comprises means 9 for cooling the effluent, connected to the means for supplying cooling fluid. The reactor also has means for introducing a gas containing hydrogen into the space surrounding the heating means inside the sheaths 4, at an appropriate pressure. The reactor and particularly the sheaths 4 are designed so that hydrogen is diffused from inside the sheaths to outside them and can then be diluted in the process gas.

摘要翻译： 将甲烷热转化成较高分子量的烃的方法和装置，包括细长形状的反应器1，第一端连接到用于提供含有甲烷的气体混合物（工艺气体）的装置5，并在相对端连接以排出 装置10，反应器具有在第一部分（朝向第一端）上被护套4包围的多个电加热装置3。 基本上平行的加热装置被布置成基本上平行且垂直于反应器的轴线的片材，使得用于循环工艺气体和/或流出物的空间或通道限定在护套之间和/或之间 护套和墙壁22分隔两个连续的片材。 加热装置适于通过基本上垂直于反应器的轴线的连续的独立横截面来加热通道。 在邻接第一部分的第二部分8（朝向相对端），反应器还包括用于冷却流出物的装置9，连接到用于供应冷却流体的装置。 该反应器还具有用于在合适的压力下将含氢气体引入护套4内的加热装置周围空间的装置。 反应器，特别是护套4被设计成使得氢气从鞘内部​​扩散到外部，然后可以在工艺气体中稀释。

公开(公告)号：US5270016A

公开(公告)日：1993-12-14

申请号：US913336

申请日：1992-07-15

申请人： Jacques Alagy ,  Paul Broutin ,  Christian Busson ,  Jerome Weill

发明人： Jacques Alagy ,  Paul Broutin ,  Christian Busson ,  Jerome Weill

IPC分类号： B01J12/00 ,  B01J19/24 ,  C07C2/76

CPC分类号： C07C2/76 ,  B01J12/005 ,  B01J19/24 ,  B01J2219/00135 ,  Y10S585/913

摘要： Apparatus suitable for the thermal conversion of methane to hydrocarbons of higher molecular weight, comprising an elongated reactor 1 provided with an inlet 5 for supplying a gas mixture containing methane (process gas) and an outlet at the opposite end, the reactor over a first part towards the inlet end having a plurality of electric heaters 3 surrounded by sheaths 4. The heaters, e.g., electric resistors, which are spaced apart and are substantially parallel with respect to one another, are arranged in substantially parallel rows perpendicular to the axis of the reactor so as to permit circulation of the process gas and/or effluent between the sheaths and/or between the sheaths and walls 22 separating two consecutive rows. The heaters heat the passages by successive independent cross sections substantially perpendicular to the axis of the reaction. Towards the outlet end, the reactor further comprises an injector for supplying cooling fluid, which cools the effluent. The reactor also has a hydrogen inlet for introducing a gas containing hydrogen into the space surrounding the heaters inside the sheaths 4 at an appropriate pressure. The reactor and the sheaths 4 are designed so that hydrogen is diffused from inside the sheaths to outside them and can then be diluted in the process gas.

摘要翻译： 适用于将甲烷热转化成较高分子量的烃的装置，包括一个细长的反应器1，该反应器1设有一个入口5，入口5用于提供含有甲烷（工艺气体）的气体混合物和另一端的出口，第一部分 朝向入口端具有由护套4围绕的多个电加热器3。间隔开并且相对于彼此大致平行的加热器，例如电阻器，被布置成垂直于 反应器，以允许工艺气体和/或流出物在护套之间和/或分离两个连续的行的护套和壁22之间循环。 加热器通过基本上垂直于反应轴线的连续的独立横截面来加热通道。 朝向出口端，反应器还包括用于供应冷却流体的喷射器，其冷却流出物。 反应器还具有氢气入口，用于以适当的压力将含氢的气体引入护套4内的加热器周围的空间。 反应器和护套4被设计成使得氢气从鞘内部​​扩散到外部，然后可以在工艺气体中稀释。

公开(公告)号：US4433157A

公开(公告)日：1984-02-21

申请号：US377114

申请日：1982-05-11

申请人： Jerome Weill ,  Jacques Garapon ,  Bernard Sillion

发明人： Jerome Weill ,  Jacques Garapon ,  Bernard Sillion

IPC分类号： C07C51/567 ,  C08F8/46 ,  C10L1/198 ,  C07D307/60

CPC分类号： C10L1/198 ,  C07C51/567 ,  C08F8/22 ,  C08F8/46

摘要： A process for manufacturing an alkenyl dicarboxylic acid, anhydride comprises reacting at least one halogenated polyolefin with at least one unsaturated dicarboxylic acid anhydride in substantially stoichiometrical proportion, in the presence of a minor proportion of at least one organic compound containing at least one double bond bearing at least one electron attracting substituent.

摘要翻译： 一种制备烯基二羧酸，酸酐的方法包括使至少一种卤代聚烯烃与至少一种不饱和二羧酸酐基本上以化学计量比例在少量比例的至少一种含有至少一个双键轴承的有机化合物的存在下反应 至少一个电子吸引取代基。

公开(公告)号：US4664675A

公开(公告)日：1987-05-12

申请号：US745985

申请日：1985-06-18

申请人： Bernard Torck ,  Pierre Amigues ,  Jerome Weill ,  Claude Gueguen ,  Michel Llinares ,  Henri Bourgognon

发明人： Bernard Torck ,  Pierre Amigues ,  Jerome Weill ,  Claude Gueguen ,  Michel Llinares ,  Henri Bourgognon

IPC分类号： C10G35/00 ,  C10G57/00 ,  C10L1/02 ,  C10L1/10

CPC分类号： C10L1/023

摘要： The invention concerns a process for upgrading olefinic gasolines containing C.sub.5 hydrocarbons, but free of C.sub.4 hydrocarbons, by etherification. It is characterized in that the tertiary olefins of the charge are reacted (1 and 2) with methanol; the reaction effluent being then extracted (3) with water, in order to separate an aqueous phase containing the major part of the unreacted methanol from a hydrocarbon phase containing the major part of the formed ethers. The aqueous phase is then introduced in a distillation zone (4) where water is separated from methanol and recycled to the extraction zone (3), whereas methanol is recycled to the etherification zone (1 and 2).

摘要翻译： 本发明涉及一种通过醚化提纯含有C5烃但不含C4烃的烯烃汽油的方法。 其特征在于电荷的叔烯烃与甲醇反应（1和2）; 然后将反应流出物用水萃取（3），以便将含有主要部分未反应的甲醇的水相与含有主要部分形成的醚的烃相分离。 然后将水相引入蒸馏区（4），其中将水从甲醇中分离并再循环至萃取区（3），而甲醇被再循环至醚化区（1和2）。

公开(公告)号：US4465609A

公开(公告)日：1984-08-14

申请号：US407218

申请日：1982-08-11

申请人： Jacques Denis ,  Jerome Weill ,  Alexandre Rojey

发明人： Jacques Denis ,  Jerome Weill ,  Alexandre Rojey

IPC分类号： C09K5/04

CPC分类号： C09K5/047

摘要： A method of operating a heat pump or a thermal engine with the vaporization and the condensation of a heat transfer fluid. The fluid is a chlorofluorinated hydrocarbon with 2 or 3 carbon atoms, a hydrogen atom, at least one chlorine atom per molecule and at most one chlorine atom per carbon atom, with the remainder consisting of fluorine, and said fluid having a critical temperature of at least 140.degree. C.

摘要翻译： 一种在传热流体的蒸发和冷凝下操作热泵或热发动机的方法。 流体是具有2或3个碳原子的氯氟化烃，氢原子，每分子至少一个氯原子和至多一个氯原子/碳原子，其余由氟组成，所述流体的临界温度为 至少140℃

公开(公告)号：US5755841A

公开(公告)日：1998-05-26

申请号：US631909

申请日：1996-04-12

申请人： Pierre Boucot ,  Paul Gateau ,  Jerome Weill

发明人： Pierre Boucot ,  Paul Gateau ,  Jerome Weill

IPC分类号： B01J8/04 ,  C01B3/02 ,  C01B3/36 ,  C01B3/38 ,  C07C1/04 ,  C07C29/151 ,  C07C31/04 ,  C01B3/24

CPC分类号： B01J8/0484 ,  B01J8/0453 ,  B01J8/0492 ,  C01B3/025 ,  C01B3/36 ,  C01B3/382 ,  C07C1/041 ,  C07C29/1516 ,  B01J2208/025 ,  C01B2203/142 ,  C01B2203/82

摘要： The present invention relates to a process and to a device for manufacturing synthetic gas. The reactor in accordance with the invention comprises within a single housing: a non catalytic combustion chamber (1) comprising at least one fuel injection element (2) and at least one oxidizer injection element (3) so as to achieve a partial combustion in said chamber referred to as "sufficient residence time chamber", and at least one catalytic bed (4) into which the gases coming from combustion chamber (1) run, and further comprising at least one additional oxidizer injection element (6) and at least one fuel injection element (7). The reactor and the process in accordance with the invention may be applied to any chemical manufacturing utilizing synthetic gas.

摘要翻译： 本发明涉及一种制造合成气体的方法和装置。 根据本发明的反应器包括在单个壳体内：非催化燃烧室（1），其包括至少一个燃料喷射元件（2）和至少一个氧化剂注入元件（3），以便在所述 称为“足够的停留时间室”的室，以及至少一个催化床（4），来自燃烧室（1）的气体流入其中，并且还包括至少一个附加的氧化剂注入元件（6）和至少一个 燃料喷射元件（7）。 根据本发明的反应器和方法可以应用于利用合成气体的任何化学制造。

公开(公告)号：US5365005A

公开(公告)日：1994-11-15

申请号：US962453

申请日：1992-10-19

申请人： Jerome Weill ,  Laure Capogna ,  Veronique Arrondel ,  Jean-Jack Boumendil

发明人： Jerome Weill ,  Laure Capogna ,  Veronique Arrondel ,  Jean-Jack Boumendil

IPC分类号： B01J12/00 ,  B01J19/00 ,  B01J19/24 ,  C07C2/76 ,  C07C2/00

CPC分类号： B01J19/24 ,  B01J12/005 ,  B01J19/0013 ,  C07C2/76 ,  B01J2219/00135 ,  Y10S585/913 ,  Y10S585/921 ,  Y10S585/943

摘要： A process and apparatus for the thermal conversion of methane into hydrocarbons of higher molecular weight, comprising a reactor (1) of elongate form, connected on the one hand, at a first end, to means (5) for supplying gaseous mixture containing methane (process gas) and on the other, at the opposite end, to discharge means (10), the said reactor comprising on a first part (the first end side) a plurality of elements disposed in at least two layers, substantially parallel inter se and substantially perpendicular to the axis of the reactor, at least one of these layers comprising a series of sheaths (4) inside which there are electric heating means (3) which thus form a layer of heating elements, the said elements being disposed in such a way as to define between them and/or between the layers which they form and/or between them and the walls of the spaces or passages for the circulation of gaseous mixtures and/or effluents, the said heating means and the said sheaths being adapted to heat the said passages by successive independent cross-sections substantially at right-angles to the axis of the reactor, each cross-section comprising at least one transverse row of elements and the said reactor also comprising automatic heating control and modulation means connected to the said heating means and comprising in a second part (8) (the same side as the opposite end) contiguous with the first part, means (9) for cooling effluents and connected to the said cooling medium supply means.

摘要翻译： 一种用于将甲烷热转化成较高分子量的烃的方法和装置，其包括在第一端连接的细长形式的反应器（1），用于提供含有甲烷的气体混合物的装置（5） 另一方面，在另一端，排出装置（10），所述反应器包括在第一部分（第一端侧）上的多个元件，其设置在至少两层中，基本平行的间隔和 基本上垂直于反应器的轴线，这些层中的至少一个包括一系列护套（4），其中有电加热装置（3），因此形成一层加热元件，所述元件设置在 在它们之间和/或它们之间形成的层之间和/或它们之间以及/或它们与用于气体混合物和/或流出物的循环的空间或通道的壁之间限定的方式，所述加热装置和所述护套适于 通过基本上与反应器的轴线成直角的连续独立横截面来加热所述通道，每个横截面包括至少一个横向排的元件，并且所述反应器还包括自动加热控制和调制装置，其连接到所述 加热装置，并且包括与第一部分邻接的第二部分（8）（与相对端相同的一侧），用于冷却流出物并连接到所述冷却介质供应装置的装置（9）。