公开(公告)号：US4738769A

公开(公告)日：1988-04-19

申请号：US478428

申请日：1983-03-24

申请人： Christian Busson ,  Jacques Alagy ,  Jean-Paul Euzen ,  Pierre Galtier

发明人： Christian Busson ,  Jacques Alagy ,  Jean-Paul Euzen ,  Pierre Galtier

IPC分类号： B01J8/12 ,  C10G9/28 ,  C10G47/24

CPC分类号： B01J8/12 ,  C10G2400/20

摘要： A process for converting liquid or semi-liquid hydrocarbon charges to lighter fractions comprises a first step (a) heating droplets jets of the charge introduced into a pyrolysis chamber by surrounding them with parallel jets of hot solid particles, of relatively large size, of a heat carrier material, not substantially in contact with the droplet jets, so as to maintain a temperature of 700.degree.-1600.degree. C., and introducing a gas so as to obtain a pressure from 1 to 150 bars. A second step involves (b) separating the gaseous fraction from the solid particles. Thereafter (c) at least a portion of the solid particles are heated and fed back to step (a). The gaseous fraction is (d) cooled by means of a cold gas so as to recover light hydrocarbons therefrom.

摘要翻译： 将液体或半液体碳氢化合物装料转化成轻馏分的方法包括第一步骤（a）通过用相当大尺寸的热固体颗粒的平行射流包围引入到热解室中的电荷的液滴射流， 热载体材料，基本上不与液滴射流接触，以保持700〜-1600℃的温度，并引入气体以获得1至150巴的压力。 第二步涉及（b）从固体颗粒中分离气态馏分。 此后（c）将至少一部分固体颗粒加热并反馈到步骤（a）。 气态馏分（d）通过冷气体冷却，以从其中回收轻质烃。

公开(公告)号：US07182923B2

公开(公告)日：2007-02-27

申请号：US10259796

申请日：2002-09-30

申请人： Lenglet Eric ,  Luc Nougier ,  Stéphane Bertholin ,  Jacques Alagy ,  Michel Cohen ,  Jean Luc Le Peutrec

发明人： Lenglet Eric ,  Luc Nougier ,  Stéphane Bertholin ,  Jacques Alagy ,  Michel Cohen ,  Jean Luc Le Peutrec

IPC分类号： B01J19/00 ,  B01J8/00

CPC分类号： B01J19/24 ,  B01J19/0053 ,  B01J19/0073 ,  B01J2219/00081 ,  B01J2219/00085 ,  B01J2219/00157 ,  B01J2219/0263 ,  B01J2219/0277 ,  Y10S585/921

摘要： A device has a reaction chamber with at least one feed inlet (5) and at least one evacuation outlet (10). An outside jacket (2a) that is resistant to internal pressure is positioned around the device and contains at least one module (44) through which a reagent and formed products circulate. The module (44) has walls (11) and (12) made of refractory material that are included in a sealed jacket (40). The sealed jacket (40) is connected by a flexible connection to the jacket (2a) and to a heat exchanger that is also linked to the module (44) and to the jacket (2a) by a flexible connection.

摘要翻译： 装置具有具有至少一个进料入口（5）和至少一个排出口（10）的反应室。 耐内压的外护套（2a）位于装置周围，并且包含至少一个模块（44），试剂和成形产品通过该模块（44）循环。 模块（44）具有被包括在密封套（40）中的耐火材料制成的壁11和12）。 密封护套（40）通过柔性连接连接到护套（2a）并且通过柔性连接与也连接到模块（44）和护套（2a）的热交换器连接。

公开(公告)号：US5270016A

公开(公告)日：1993-12-14

申请号：US913336

申请日：1992-07-15

申请人： Jacques Alagy ,  Paul Broutin ,  Christian Busson ,  Jerome Weill

发明人： Jacques Alagy ,  Paul Broutin ,  Christian Busson ,  Jerome Weill

IPC分类号： B01J12/00 ,  B01J19/24 ,  C07C2/76

CPC分类号： C07C2/76 ,  B01J12/005 ,  B01J19/24 ,  B01J2219/00135 ,  Y10S585/913

摘要： Apparatus suitable for the thermal conversion of methane to hydrocarbons of higher molecular weight, comprising an elongated reactor 1 provided with an inlet 5 for supplying a gas mixture containing methane (process gas) and an outlet at the opposite end, the reactor over a first part towards the inlet end having a plurality of electric heaters 3 surrounded by sheaths 4. The heaters, e.g., electric resistors, which are spaced apart and are substantially parallel with respect to one another, are arranged in substantially parallel rows perpendicular to the axis of the reactor so as to permit circulation of the process gas and/or effluent between the sheaths and/or between the sheaths and walls 22 separating two consecutive rows. The heaters heat the passages by successive independent cross sections substantially perpendicular to the axis of the reaction. Towards the outlet end, the reactor further comprises an injector for supplying cooling fluid, which cools the effluent. The reactor also has a hydrogen inlet for introducing a gas containing hydrogen into the space surrounding the heaters inside the sheaths 4 at an appropriate pressure. The reactor and the sheaths 4 are designed so that hydrogen is diffused from inside the sheaths to outside them and can then be diluted in the process gas.

摘要翻译： 适用于将甲烷热转化成较高分子量的烃的装置，包括一个细长的反应器1，该反应器1设有一个入口5，入口5用于提供含有甲烷（工艺气体）的气体混合物和另一端的出口，第一部分 朝向入口端具有由护套4围绕的多个电加热器3。间隔开并且相对于彼此大致平行的加热器，例如电阻器，被布置成垂直于 反应器，以允许工艺气体和/或流出物在护套之间和/或分离两个连续的行的护套和壁22之间循环。 加热器通过基本上垂直于反应轴线的连续的独立横截面来加热通道。 朝向出口端，反应器还包括用于供应冷却流体的喷射器，其冷却流出物。 反应器还具有氢气入口，用于以适当的压力将含氢的气体引入护套4内的加热器周围的空间。 反应器和护套4被设计成使得氢气从鞘内部​​扩散到外部，然后可以在工艺气体中稀释。

公开(公告)号：US3935100A

公开(公告)日：1976-01-27

申请号：US484228

申请日：1974-06-28

申请人： Jacques Alagy ,  Christian Busson ,  Maurice Cessou

发明人： Jacques Alagy ,  Christian Busson ,  Maurice Cessou

IPC分类号： C01B17/16 ,  C01B17/58 ,  C02F1/52 ,  C02F1/58 ,  C02F1/66 ,  C02B1/34 ,  C02C5/06

CPC分类号： C02F1/66 ,  C01B17/58 ,  C02F1/5236 ,  C02F1/586

摘要： Process for treating a waste water containing sulfuric acid and/or ammonium sulfate comprising (1) reacting said water with barium sulfide to form barium sulfate, (2) reacting the latter with carbon containing inorganic impurities, at high temperature, thereby forming barium sulfide, at least a major portion of which is recycled to step (1), and a gas which is separated, (3) dissolving in water a minor portion of the barium sulfide produced in step (2), separating the insoluble impurities therefrom and recycling at least one portion of the resulting purified solution to step (1).

摘要翻译： 包括（1）使所述水与硫化钡反应形成硫酸钡，（2）使其与含碳的无机杂质在高温下反应，从而形成硫化钡， 其至少大部分被再循环到步骤（1），和分离的气体，（3）将在步骤（2）中生产的少量硫化钡溶解在水中，将不溶性杂质从其中分离出来，并在 将所得纯化溶液的至少一部分至步骤（1）。

公开(公告)号：US5321191A

公开(公告)日：1994-06-14

申请号：US972782

申请日：1992-11-09

申请人： Jacques Alagy ,  Paul Broutin ,  Christian Busson ,  Jerome Weill

发明人： Jacques Alagy ,  Paul Broutin ,  Christian Busson ,  Jerome Weill

IPC分类号： C10G9/24 ,  C07C4/04

CPC分类号： C10G9/24 ,  Y10S585/921 ,  Y10S585/926

摘要： A process for the thermal pyrolysis of hydrocarbons in a reactor (1) of elongate shape comprising at a first end supply means (5) for a gaseous mixture containing at least one hydrocarbon, at the opposite end discharge means (10) for the effluents produced and between these two ends supply means (9) for effluent cooling fluid, the reactor comprising in a first part (first end side) a plurality of electric heating means (3) enclosed by casings (4) disposed in substantially mutually parallel layers perpendicular to the axis of the reactor, in such a way as to define between the casings and/or the casings and the walls (22), spaces or passages for circulation of the gaseous mixtures and/or effluents. The heating means heat the passages in successive, individual, transverse sections which are substantially perpendicular to the axis of the reactor. The reactor comprises means for introducing into the casings (4) a gas G known as a casing gas which preferably contains water vapour and/or hydrogen. The permeability of the casings is sufficient to permit diffusion, at least at certain points, of at least a part of the gas G from inside the casings to the outside of the casings, the gas G then being diluted in the gaseous mixture.

摘要翻译： 一种用于在细长形状的反应器（1）中热解烃的方法，该方法包括在第一端供应装置（5），用于含有至少一种烃的气态混合物，在相对的端部排出装置（10）用于所产生的流出物 并且在这两个端部之间，用于流出物冷却流体的供应装置（9），所述反应器包括在第一部分（第一端侧）中的多个电加热装置（3），所述多个电加热装置（3）由壳体（4）包围， 反应器的轴线以限定壳体和/或壳体和壁（22）之间的方式，用于气态混合物和/或流出物循环的空间或通道。 加热装置加热基本上垂直于反应器轴线的连续的，单独的横向部分中的通道。 反应器包括用于将优选含有水蒸气和/或氢气的称为外壳气体的气体G引入壳体（4）的装置。 壳体的渗透性足以允许至少在某些点处将气体G的至少一部分从壳体内部扩散到壳体的外部，然后将气体G稀释在气体混合物中。

公开(公告)号：US5236663A

公开(公告)日：1993-08-17

申请号：US848584

申请日：1992-03-09

申请人： Jacques Alagy ,  Alain Forestiere ,  Jean-Francois Le Page ,  Marie C. Marion ,  Jean-Charles Viltard

发明人： Jacques Alagy ,  Alain Forestiere ,  Jean-Francois Le Page ,  Marie C. Marion ,  Jean-Charles Viltard

IPC分类号： B01D3/16 ,  B01D3/00 ,  B01D3/22 ,  B01J8/02 ,  B01J8/04 ,  B01J19/30 ,  B01J19/32 ,  B01J32/00 ,  C07C41/06 ,  C07C43/04

CPC分类号： B01J8/02 ,  B01D3/009 ,  B01J19/30 ,  B01J8/048 ,  B01J2219/30223 ,  B01J2219/30226 ,  B01J2219/30408 ,  B01J2219/30475 ,  Y10S203/06

摘要： A reaction-distillation apparatus is provided comprising at least one reaction-distillation zone including at least one bed of solid elements disposed on a fluid-permeable perforated support having perforations small enough to retain the elements wherein the bed of solid elements includes loose solid catalytic particles and at least one receptacle, containing at least one distillation packing body, the external jacket of which is permeable to fluids and the impermeable to the solid catalytic particles and packing body. The apparatus can be used for carrying out chemical reaction and concomitant fractionation of the reaction mixture, for example, to synthesize ethers from olefins and alcohols.

摘要翻译： 提供了一种反应 - 蒸馏装置，其包括至少一个反应 - 蒸馏区，其包括设置在流体可渗透的穿孔支架上的至少一个固体元件床，其具有足够小的孔，其中固体元素床包括松散的固体催化剂颗粒 以及至少一个容器，其包含至少一个蒸馏包装体，其外部护套可渗透流体，并且对于固体催化剂颗粒和包装体是不可渗透的。 该装置可用于进行化学反应并伴随分离反应混合物，例如从烯烃和醇合成醚。

公开(公告)号：US5186910A

公开(公告)日：1993-02-16

申请号：US582426

申请日：1990-09-12

申请人： Jacques Alagy ,  Paul Broutin ,  Christian Busson ,  Yves Gougne ,  Jerome Weill

发明人： Jacques Alagy ,  Paul Broutin ,  Christian Busson ,  Yves Gougne ,  Jerome Weill

IPC分类号： B01F3/02 ,  B01J4/04 ,  B01J8/04 ,  B01J12/00 ,  B01J19/00 ,  B01J19/24 ,  B01J35/04 ,  C01B3/36 ,  C01B3/38 ,  C01B32/40 ,  C01B32/50

CPC分类号： C01B3/363 ,  B01J12/005 ,  B01J19/2415 ,  B01J4/04 ,  C01B3/36 ,  B01J2208/00495 ,  B01J2219/00162

摘要： An oxidation reactor having elongated shape includes in combination, a mixing member including a pipe for feeding oxidizing gas and a pipe for feeding oxidizable charge; a reaction member, arranged subjacent the mixing member, and a discharge member associated with a discharge pipe for the products of the reaction. The reaction member includes a central zone which has a first lining and the reactor includes at least one peripheral zone which has a second lining, passages in the second lining being smaller than passages in the first lining so that the pressure loss in the second lining is greater than that of the first lining. The second lining forms a sleeve surround the first lining and this sleeve is formed of at least one refractory heat insulating material. The oxidation reactor is provided with an external sleeve steel jacket, a concrete wall and a steel element surrounding the mixing member arranged above the reaction member. The reaction member includes a series of single elements which form juxtaposed channels.

摘要翻译： 具有细长形状的氧化反应器组合包括：混合构件，包括用于供给氧化气体的管和用于供给可氧化电荷的管; 布置在混合部件的下方的反应部件和与反应产物的排出管相关联的排出部件。 反应构件包括具有第一衬里的中心区，反应器包括具有第二衬里的至少一个周边区，第二衬里中的通道小于第一衬里中的通道，使得第二衬里中的压力损失为 大于第一衬里。 第二衬里形成围绕第一衬里的套筒，并且该套筒由至少一个难熔绝热材料形成。 氧化反应器设置有外部套筒钢护套，混凝土壁和围绕设置在反作用构件上方的混合构件的钢构件。 反应构件包括形成并列通道的一系列单一元件。

公开(公告)号：US5160501A

公开(公告)日：1992-11-03

申请号：US700706

申请日：1991-05-16

申请人： Jacques Alagy ,  Paul Broutin ,  Christian Busson ,  Jerome Weill

发明人： Jacques Alagy ,  Paul Broutin ,  Christian Busson ,  Jerome Weill

IPC分类号： B01J12/00 ,  B01J19/24 ,  C07C2/76

CPC分类号： B01J19/24 ,  B01J12/005 ,  C07C2/76 ,  B01J2219/00135 ,  Y10S585/911 ,  Y10S585/913 ,  Y10S585/924 ,  Y10S585/926 ,  Y10S585/943

摘要： Method and apparatus for thermal conversion of methane to hydrocarbons of higher molecular weight, comprising a reactor 1 of elongated shape, connected at a first end to means 5 for supplying gas mixture containing methane (process gas), and connected at the opposite end to discharge means 10, the reactor having a plurality of electric heating means 3 surrounded by sheaths 4 over a first part (towards the first end). The heating means, which are substantially parallel, are arranged in sheets which are substantially parallel and perpendicular to the axis of the reactor, so that spaces or passages for circulation of the process gas and/or effluent are defined between the sheaths and/or between the sheaths and the walls 22 separating two consecutive sheets. The heating means are adapted to heat the passages by successive independent cross sections substantially perpendicular to the axis of the reactor. In a second part 8 (towards the opposite end) adjoining the first part, the reactor further comprises means 9 for cooling the effluent, connected to the means for supplying cooling fluid. The reactor also has means for introducing a gas containing hydrogen into the space surrounding the heating means inside the sheaths 4, at an appropriate pressure. The reactor and particularly the sheaths 4 are designed so that hydrogen is diffused from inside the sheaths to outside them and can then be diluted in the process gas.

摘要翻译： 将甲烷热转化成较高分子量的烃的方法和装置，包括细长形状的反应器1，第一端连接到用于提供含有甲烷的气体混合物（工艺气体）的装置5，并在相对端连接以排出 装置10，反应器具有在第一部分（朝向第一端）上被护套4包围的多个电加热装置3。 基本上平行的加热装置被布置成基本上平行且垂直于反应器的轴线的片材，使得用于循环工艺气体和/或流出物的空间或通道限定在护套之间和/或之间 护套和墙壁22分隔两个连续的片材。 加热装置适于通过基本上垂直于反应器的轴线的连续的独立横截面来加热通道。 在邻接第一部分的第二部分8（朝向相对端），反应器还包括用于冷却流出物的装置9，连接到用于供应冷却流体的装置。 该反应器还具有用于在合适的压力下将含氢气体引入护套4内的加热装置周围空间的装置。 反应器，特别是护套4被设计成使得氢气从鞘内部​​扩散到外部，然后可以在工艺气体中稀释。

公开(公告)号：US4780196A

公开(公告)日：1988-10-25

申请号：US37353

申请日：1987-04-10

申请人： Jacques Alagy ,  Christian Busson ,  Pierre Chaverot

发明人： Jacques Alagy ,  Christian Busson ,  Pierre Chaverot

IPC分类号： C10G9/36 ,  B01J19/24 ,  C10G9/00 ,  C10G9/20 ,  F28F7/02

CPC分类号： C10G9/00 ,  B01J19/2425 ,  B01J19/2485 ,  C10G9/20 ,  F28F7/02 ,  B01J2219/00085 ,  B01J2219/00159

摘要： The invention relates to an improved hydrocarbon steam-cracking method intended to produce more particularly ethylene and propylene.The method is based on the utilization of a multi-channel system made of ceramic material, in which the charge and heat exchange fluids or refrigerants alternatively pass through the channels or rows of channels constituting the continuous assembly comprising a pyrolysis zone followed by a quenching zone.The method according to the invention is applicable to charges ranging from ethane to vacuum gas oils.

摘要翻译： PCT No.PCT / FR86 / 00215 Sec。 371日期：1987年4月10日 102（e）日期1987年4月10日PCT申请1986年6月20日PCT公开号 公开号WO87 / 00546 日本1987年1月29日。本发明涉及旨在生产更特别是乙烯和丙烯的改进的烃蒸汽裂解方法。 该方法基于利用由陶瓷材料制成的多通道系统，其中充电和热交换流体或制冷剂交替地通过构成连续组件的通道或排的通道，其包括热解区，随后是淬火区 。 根据本发明的方法适用于从乙烷到减压瓦斯油的电荷。

公开(公告)号：US5235117A

公开(公告)日：1993-08-10

申请号：US765276

申请日：1991-09-25

申请人： Jacques Alagy ,  Christian Busson ,  Lionel Asselineau

发明人： Jacques Alagy ,  Christian Busson ,  Lionel Asselineau

IPC分类号： C01B35/10 ,  C07B61/00 ,  C07C29/52 ,  C07C31/04 ,  C07C31/135

CPC分类号： C07C29/52 ,  C01B35/1036 ,  C01B35/1045 ,  C07C2101/14

摘要： For preparing at least one boric oxide in an anhydrous or hydrated form and of general formula B.sub.2 O.sub.3, xH.sub.2 O, in which x is a number from 0 to 3, a methyl borate hydrolyzate comprising boric oxide and methanol is introduced into a distillation column is introduced the product from, at least one compound (preferably a hydrocarbon such as, e.g., 2,3-dimethyl butane or 2-methyl pentane) forming a heteroazeotrope with methanol, said heteroazaeotrope having a boiling point below that of the azeotrope formed by methyl borate with methanol and at least one compound having a boiling point higher than that of methyl borate, said compound not forming an azeotrope with a boiling point below that of said heteroazeotrope and then at the head of the column said heteroazeotrope is recovered and at the bottom of the column a suspension containing at least one boric oxide.A description is also given of a process for the oxidation of at least one saturated hydrocarbon into a product incorporating the corresponding alcohol wherein oxidation is carried out with oxygen in the presence of a boric oxide with. The oxidation product is hydrolyzed into orthoboric acid and alcohol, which is recovered by separation from the organic phase. The aqueous phase containing the boric acid is fed into a methyl borate formation zone and the methyl borate is recovered in the form of its azeotrope with methanol. The recovery of the boric oxide from said azeotrope is performed in accordance with the aforementioned process, the recovered boric oxide being recycled to the oxidation stage.

摘要翻译： 为了制备至少一种无水或水合形式的氧化硼和通式B 2 O 3，xH 2 O，其中x为0至3的数，将包含氧化硼和甲醇的硼酸甲酯水解产物引入蒸馏塔 与来自与甲醇形成杂共聚物的至少一种化合物（优选例如2,3-二甲基丁烷或2-甲基戊烷的烃）形成的产物，所述杂氮杂异动物的沸点低于由硼酸甲酯形成的共沸物的沸点， 甲醇和沸点高于硼酸甲酯的沸点的至少一种化合物，所述化合物不形成沸点低于所述杂共生物的沸点的共沸物，然后在塔的头部回收所述杂共生物，并在其底部 柱中含有至少一种氧化硼的悬浮液。 还描述了将至少一种饱和烃氧化成掺入相应的醇的产物的方法，其中氧化在氧化硼存在下用氧气进行氧化。 将氧化产物水解成原硼酸和醇，通过与有机相分离回收。 将含有硼酸的水相加入到硼酸甲酯形成区中，以与甲醇共沸的形式回收硼酸甲酯。 根据上述方法从所述共沸物中回收氧化硼，回收的氧化硼被循环到氧化阶段。