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    Polymerisable materials which are based on hardenable siloxane compounds
    2.
    发明授权
    Polymerisable materials which are based on hardenable siloxane compounds 有权

    公开(公告)号：US06566413B1

    公开(公告)日：2003-05-20

    申请号：US09868525

    申请日：2001-09-19

    申请人： Wolfgang Weinmann ,  Joachim Zech ,  Oswald Gasser ,  Rainer Guggenberger ,  Gunther Eckhardt ,  Peter Bissinger ,  Wolfgang Soglowek

    发明人： Wolfgang Weinmann ,  Joachim Zech ,  Oswald Gasser ,  Rainer Guggenberger ,  Gunther Eckhardt ,  Peter Bissinger ,  Wolfgang Soglowek

    IPC分类号： C08F246

    CPC分类号： A61K6/083 ,  C07F7/21 ,  C08L51/085

    摘要： The invention relates to novel cyclic siloxane compounds of the following general formula (I): in which: n=0, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10 preferably 1, 2, 3, 4, 5; A=H or C1-C15 alk(en)yl, C3-C15 cycloalk(en)yl, C6-C12 aryl, C8-C18 alkaryl, where, in the said radicals, in each case one or more C atoms can be replaced by O, C═O, O(C═O), SiR2 and/or NR, R being an aliphatic radical with 1 to 7 C atoms, in which one or more C atoms can be replaced by O, C═O, and/or O(C═O); B=E or a linear, branched or polycyclic aliphatic- or aromatic-groups-containing hydrocarbon radical which links 2 to 10 of the cyclosiloxane radicals defined above, less B, to one another and contains 2 to 50 C atoms and additionally 0 to 30 other atoms from the group O, N, S, P, Si, Cl, F, Br, I and from which correspondingly 1 to 9, preferably 1 to 4 of the above defined cyclosiloxane radicals, less B, are pending; E=A or a polymerizable group G—Q—L, where on average up to 50% or less of the groups E correspond to representatives of A; G=C1-10 alk(en)ylene; Q=O, N—A or a di- or polyvalent linear, branched or cyclic alcohol, amine or aminoalcohol radical with 2 to 10 C atoms; L=an organic radical, containing a C═C double bond, with 2 to 10 C atoms; and with the proviso that no annelated siloxane ring systems can occur in (I), and also dental compositions which contain the compounds of formula (I) and/or compounds of formula (II): in which: T=independently of each other H or C1-C10 alk(en)yl, C3-C10 cycloalk(en)yl, C6-C12 aryl or C8-C8 alkaryl; N=a polymerizable group R1—R2—R3; b=0 to 500, where the proportion b may be at most 50% of the repeat units (b+c); c=1 to 1000; R1=C1-C10 alk(en)ylene; R2=O, N—T or a di- or polyvalent linear, branched or cyclic alcohol, amine or aminoalcohol radical with 2 to 10 C atoms; R3=an organic radical, containing a C═C double bond, with 3 to 10 C atoms; V=SiMe2T, SiEt2T, SiMePhT, SiPh2T.

    Hydrolyzable silanes and polymerizable silanes with low viscosity and use thereof
    4.
    发明授权
    Hydrolyzable silanes and polymerizable silanes with low viscosity and use thereof 有权
    可水解硅烷和可聚合硅烷，具有低粘度和可用硅烷

    公开(公告)号：US06852822B1

    公开(公告)日：2005-02-08

    申请号：US10031612

    申请日：2000-07-12

    申请人： Peter Bissigner ,  Oswald Gasser ,  Rainer Guggenberger ,  Wolfgang Soglowek

    发明人： Peter Bissigner ,  Oswald Gasser ,  Rainer Guggenberger ,  Wolfgang Soglowek

    IPC分类号： A61K6/027 ,  A61K6/00 ,  A61K6/02 ,  A61K6/04 ,  A61K6/083 ,  A61K6/093 ,  C07F7/18 ,  C08G77/20 ,  C08G77/48 ,  C09D183/04 ,  C09K3/10

    CPC分类号： A61K6/0017 ,  A61K6/0023 ,  A61K6/083 ,  A61K6/093 ,  C07F7/1804 ,  C08L51/085

    摘要： The invention provides processes for making low viscosity condensates, condensates per se, and processes for making polymers from these condensates. The invention also encompasses the polymer products of these processes, especially articles for dental use. The condensates per se of the invention are of hydrolyzable silanes. The condensates can contain one or more elements selected from the group consisting of B, AI, P, Sn, Pb, the transition metals, the lanthanides and the actinides. Processes of the invention for making polymers from the condensates optionally include use of compounds that can be polymerized ionically or by radical reactions in addition to the hydrolyzable silanes. Curing of the polymers is optionally performed by photochemical, thermal or by redox-induction methods.

    摘要翻译： 本发明提供了制备低粘度缩合物，缩合物本身以及由这些缩合物制备聚合物的方法。 本发明还包括这些方法的聚合物产品，特别是用于牙科用途的制品。 本发明本身的缩合物是可水解的硅烷。 缩合物可以含有选自B，Al，P，Sn，Pb，过渡金属，镧系元素和锕系元素中的一种或多种元素。 用于从冷凝物制备聚合物的本发明的方法任选地包括除了可水解硅烷之外还可以使用可以离子化或通过自由基反应聚合的化合物。 聚合物的固化任选地通过光化学，热或氧化还原诱导方法进行。

    Formable composition and its use as filling material for dental root canals
    6.
    发明授权
    Formable composition and its use as filling material for dental root canals 失效
    成型组合物及其作为牙根管填充材料的用途

    公开(公告)号：US5520922A

    公开(公告)日：1996-05-28

    申请号：US323708

    申请日：1994-10-18

    申请人： Oswald Gasser ,  Rainer Guggenberger

    发明人： Oswald Gasser ,  Rainer Guggenberger

    IPC分类号： A61K6/027 ,  A61K6/00 ,  A61K6/06 ,  A61K6/083 ,  C04B28/28 ,  C08K3/16 ,  C08K3/22 ,  C08K3/40

    CPC分类号： A61K6/0038 ,  A61K6/0032 ,  A61K6/0276 ,  C04B28/28 ,  C08K3/16 ,  C08K3/22 ,  C08K3/40 ,  C04B2103/0004 ,  C04B2111/00836

    摘要： There are provided formable compositions which comprise:(A) 25 to 80% by weight of a glass ionomer cement, containing (a) an aluminum fluorosilicate glass, (b) at least one polymeric polyacid with an average molecular weight >500, (c) water and (d) optionally a chelating agent;(B) and 20 to 75% by weight of a fluoride and/or oxide and/or mixed fluoride and/or mixed oxide of heavy metal elements which are essentially insoluble at ambient temperatures in an aqueous solution containing the polymeric polyacid and/or an aqueous solution containing the chelating agent.The compositions are especially well suited as filling materials for dental root canals.

    摘要翻译： 提供了可成型组合物，其包含：（A）25至80重量％的玻璃离聚物粘合剂，其包含（a）氟硅酸铝玻璃，（b）至少一种平均分子量> 500的聚合多元酸（c ）水和（d）任选的螯合剂; （B）和20至75重量％的氟化物和/或氧化物和/或混合的氟化物和/或重金属元素的混合氧化物，其在环境温度下基本上不溶于含有聚合多元酸的水溶液和/或 含有螯合剂的水溶液。 该组合物特别适用于牙根管的填充材料。

    Polyether-impression material and method for its preparation and use
    7.
    发明授权
    Polyether-impression material and method for its preparation and use 失效
    聚酯材料及其制备和使用方法

    公开(公告)号：US5086148A

    公开(公告)日：1992-02-04

    申请号：US435994

    申请日：1989-11-14

    申请人： Peter Jochum ,  Oswald Gasser ,  Wolf-Dietrich Zahler ,  Gunther Lechner ,  Rainer Guggenberger ,  Klaus Ellrich

    发明人： Peter Jochum ,  Oswald Gasser ,  Wolf-Dietrich Zahler ,  Gunther Lechner ,  Rainer Guggenberger ,  Klaus Ellrich

    IPC分类号： A61K6/10 ,  C08G77/46 ,  C08K5/549 ,  C08L71/00 ,  C08L71/02

    CPC分类号： A61K6/10

    摘要： A polyether-impression material comprising components(a) a polyether, which has at least two optionally substituted vinyl- and/or allyl-end groups,(b) an SiH component,(c) a platinum catalyst, and optionally(d) the usual additivescharacterized in that the SiH-component (b) can be obtained by the reaction of at least a bi- functional, or polyfunctional, e.g., trifunctional, allyl- or vinyl-hydrocarbon compound, the hydrocarbon radical of which, without taking account of the allyl- or vinyl-groups and the optionally present alkylene ether groups, has 6 to 30 C-atom and contains at least one aromatically unsaturated, heterocyclic, or cycloaliphatic ring, with at least one mole per vinyl- or allyl-group of at least a bifunctional, or polyfunctional, e.g., trifunctional, SiH compound of the formula: ##STR1## in which e=0 to 8,g=0 to 8,h=0 to 4 andR.sup.4 and R.sup.10 are the same or different, and are each H, methyl or ethyl, with the proviso that at least 1 and at the most 5 of R.sup.4 to R.sup.10 are H, wherein g and h cannot simultaneously be O, and wherein at least the components (b) and (c) lie spatially separated from each other.

    摘要翻译： 一种聚醚压印材料，其包含组分（a）聚醚，其具有至少两个任选取代的乙烯基和/或烯丙基端基，（b）SiH组分，（c）铂催化剂和任选地（d） 通常的添加剂，其特征在于SiH组分（b）可以通过至少二官能或多官能的，例如三官能的烯丙基或乙烯基烃化合物，其烃基，而不考虑 的烯丙基或乙烯基和任选存在的亚烷基醚基具有6至30个C原子并且含有至少一个芳族不饱和的，杂环的或脂环族的环，每个乙烯基或烯丙基具有至少一个摩尔 至少一种双官能或多官能的例如三官能的下式的化合物：其中e = 0至8，g = 0至8，h = 0至4，R4和R10为 相同或不同，并且各自为H，甲基或乙基，条件是R 4的至少1和最多5个 至R 10为H，其中g和h不能同时为O，并且其中至少组分（b）和（c）在空间上彼此分离。