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公开(公告)号：US4713362A
公开(公告)日：1987-12-15
申请号：US866531
申请日：1986-05-22
CPC分类号： C01B23/00 , B01D53/02 , B01J20/18 , C01B13/027 , C01B3/56 , C01B2203/042 , C01B2203/0465 , C01B2203/047 , C01B2203/048 , C01B2210/0082
摘要： A selective zeolitic adsorbent is prepared by activating a zeolitic composition having at least a portion, preferably at least 50%, of the exchangeable ion capacity occupied by a cation having a charge density of 2.0 or greater, preferably a divalent cation with a charge density of 2.0 or greater, such as calcium or magnesium by thoroughly dehydrating the exchanged zeolite. Additionally, separation ability of the zeolitic adsorbent can be further increased by reacting the thoroughly dehydrated zeolite in an oxidizing atmosphere.
摘要翻译： 通过活化沸石组合物制备选择性沸石吸附剂，所述沸石组合物具有至少一部分，优选至少50％的电荷密度为2.0或更大的阳离子所占据的可交换离子能力，优选电荷密度为 2.0或更大，例如通过使交换的沸石彻底脱水来脱离钙或镁。 此外，通过在氧化气氛中使完全脱水的沸石反应，可以进一步提高沸石吸附剂的分离能力。
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2.发明授权Selective adsorption process using an oxidized ion-exchanged dehydrated chabizite adsorbent 失效选择性吸附方法采用氧化离子交换脱水型硫酸盐吸附剂
公开(公告)号：US4744805A
公开(公告)日：1988-05-17
申请号：US69331
申请日：1987-07-01
CPC分类号： C01B13/027 , B01D53/02 , B01J20/18 , C01B23/00 , C01B3/56 , C01B2203/042 , C01B2203/0465 , C01B2203/047 , C01B2203/048 , C01B2210/0082
摘要： The present invention relates to a process for the selective adsorption and separation of one or more constituents from a gas stream in a gas chromatograph, wherein the gas stream is contacted with a dehydrated chabazite adsorbent having a residual water content of less than 1.5 wt. % and having at least 50% of any exchangeable ion capacity exchanged with a polyvalent metal cation and wherein the dehydrated chabazite has been reacted with an oxidizing atmosphere either during or following dehydration. The process of the present invention both anticipates separation of the constituents due to either a difference in the heats of adsorption of the constituents or a size exclusion effect.
摘要翻译： 本发明涉及一种在气相色谱仪中从气流中选择性吸附和分离一种或多种成分的方法，其中气流与残留含水量小于1.5重量％的脱水菱沸石吸附剂接触。 并且具有与多价金属阳离子交换的任何可交换离子能力的至少50％，并且其中脱水的菱沸石在脱水期间或之后与氧化气氛反应。 本发明的方法既预期由于组分的吸附热差异或尺寸排阻效应导致组分的分离。
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3.发明授权Selective chromatographic process using an ion-exchanged, dehydrated chabazite adsorbent 失效使用离子交换的脱水菱沸石吸附剂进行选择性色谱法
公开(公告)号：US4747854A
公开(公告)日：1988-05-31
申请号：US66789
申请日：1987-06-25
CPC分类号： B01J20/186 , Y10S95/902
摘要： The present invention relates to a process for the selective adsorption and separation of one or more constituents from a gas stream in a gas chromatograph, wherein the gas stream is contacted with a dehydrated chabazite adsorbent having a residual water content of less than 1.5 wt % and having at least 50% of any exchangeable ion capacity exchanged with a polyvalent metal cation. The process of the present invention both anticipates separation of the constituents due to either a difference in the heats of adsorption of the constituents or a size exclusion effect.
摘要翻译： 本发明涉及在气相色谱仪中从气流中选择性吸附和分离一种或多种成分的方法，其中气流与残留含水量小于1.5重量％的脱水菱沸石吸附剂接触， 具有与多价金属阳离子交换的任何可交换离子容量的至少50％。 本发明的方法既预期由于组分的吸附热差异或尺寸排阻效应导致组分的分离。
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公开(公告)号：US4603040A
公开(公告)日：1986-07-29
申请号：US716429
申请日：1985-03-27
CPC分类号： B01J29/082 , C01B39/22 , B01J37/0018 , Y10S423/21
摘要： Maximum Aluminum X-type zeolite is prepared in the form of essentially binderless aggregates. In the optimal case, the composition possesses the maximum theoretical zeolite cation content in a wide-pored zeolite as a solid, massive body.
摘要翻译： 最大的铝X型沸石以基本上无粘合剂聚集的形式制备。 在最佳情况下，该组合物具有在作为固体，大体积的广泛沸石中的最大理论沸石阳离子含量。
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公开(公告)号：US4481018A
公开(公告)日：1984-11-06
申请号：US441822
申请日：1982-11-15
申请人： Charles G. Coe , Steven M. Kuznicki
发明人： Charles G. Coe , Steven M. Kuznicki
CPC分类号： B01D53/04 , B01J20/186 , B01D2253/108 , B01D2256/10 , B01D2256/12 , B01D2257/102 , B01D2257/80
摘要： The invention relates to faujasite-containing compositions in which the original hydrogen or monovalent forms are ion exchanged to their polyvalent form and then thermally activated to promote dehydration and dehydroxylation of the faujasite while maintaining substantially the same zeolite content. The resulting compositions containing faujasites substantially in their dehydrated/dehydroxylated state have been found to have surprisingly high selectivities and capacities for the separation of air into nitrogen and oxygen.
摘要翻译： 本发明涉及含有八面沸石的组合物，其中原始氢或一价形式被离子交换为其多价形式，然后热活化以促进八面沸石的脱水和脱羟基化，同时保持基本相同的沸石含量。 已经发现得到的含有基本上脱水/脱羟基化状态的八面沸石的组合物具有惊人的高选择性和将空气分离成氮和氧的能力。
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公开(公告)号：US4544378A
公开(公告)日：1985-10-01
申请号：US614086
申请日：1984-05-24
申请人： Charles G. Coe , Steven M. Kuznicki
发明人： Charles G. Coe , Steven M. Kuznicki
CPC分类号： B01D53/0454 , B01D53/02 , B01J20/186 , B01D2253/108 , B01D2253/1085 , B01D2256/10 , B01D2256/12 , B01D2257/102 , B01D2257/104 , B01D53/04 , Y10S95/902
摘要： The invention relates to a process for adsorption of nitrogen from nitrogen-containing gases using faujasite-containing compositions in which the original hydrogen or monovalent forms are ion exchanged to their polyvalent form and then dehydrated in such a manner as to result in a preponderence of its polyvalent ions in a dehydrated/dehydroxylated state while maintaining substantially the same zeolite content. The resulting compositions, whose cations contained in the faujasitic portion are substantially in their dehydrated/dehydroxylated state, have been found to have surprisingly high selectivities and capacities for the separation of air into nitrogen and oxygen.
摘要翻译： 本发明涉及一种使用含有八面沸石的组合物从含氮气体中吸附氮的方法，其中原始氢或一价形式离子交换成其多价形式，然后脱水，从而导致其 多价离子处于脱水/脱羟基状态，同时保持基本相同的沸石含量。 已经发现所得到的组合物，其阳离子基本上处于脱水/脱羟基状态，具有令人惊奇的高选择性和将空气分离成氮和氧的能力。
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公开(公告)号：US08211295B2
公开(公告)日：2012-07-03
申请号：US12430295
申请日：2009-04-27
CPC分类号： C10G1/002 , B01J29/70 , C10G1/02 , C10G55/06 , C10G2300/206 , C10G2300/44
摘要： Bitumen within raw oilsands may be cracked and fully recovered by light hydrocarbon extraction following exposure to modified natural zeolite catalysts under cracking conditions. The recovered bitumen is reduced in viscosity, with lower boiling point distributions. Effective cracking of oilsands bitumen using economical, abundant and readily disposable natural zeolites represents a significant step towards a waterless and environment friendly extraction process.
摘要翻译： 原油中的沥青可以在裂化条件下暴露于改性天然沸石催化剂后通过轻质烃提取而裂解并完全回收。 回收的沥青的粘度降低，沸点分布较低。 使用经济，丰富且易于一次性使用的天然沸石对油料沥青的有效开裂代表了无水和环境友好的萃取过程的重要一步。
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公开(公告)号：US07645324B2
公开(公告)日：2010-01-12
申请号：US11326657
申请日：2006-01-06
申请人： Edward J. Rode , Andre J. J. Boulet , Aaron M. Pelman , Matthew L. Babicki , Bowie G. Keefer , James A. Sawada , Soheil Alizadeh-Khiavi , Surajit Roy , Andrea C. Gibbs , Steven M. Kuznicki
发明人： Edward J. Rode , Andre J. J. Boulet , Aaron M. Pelman , Matthew L. Babicki , Bowie G. Keefer , James A. Sawada , Soheil Alizadeh-Khiavi , Surajit Roy , Andrea C. Gibbs , Steven M. Kuznicki
IPC分类号： B01D53/02
CPC分类号： B01D53/02 , B01D53/0462 , B01D53/047 , B01D53/0473 , B01D2253/10 , B01D2253/108 , B01D2253/25 , B01D2253/304 , B01D2253/311 , B01D2256/10 , B01D2256/24 , B01D2257/504 , B01D2257/7022 , B01D2257/7025 , B01D2259/40005 , B01D2259/40007 , B01D2259/4148 , B01D2259/4575 , B01J20/28052 , Y02C10/08 , Y02C20/20
摘要： Improved adsorbent sheet based parallel passage adsorbent structures for enhancing the kinetic selectivity of certain kinetic-controlled adsorption processes, such as PSA, TSA and PPSA processes, and combinations thereof, are provided. The enhancements in kinetic selectivity made possible through the implementation of the present inventive improved adsorbent structures may unexpectedly enable significant intensification of selected kinetic adsorption processes relative to attainable performance with conventional adsorbent materials in beaded or extruded form. Such process intensification enabled by the present inventive adsorbent structures may provide for increased adsorption cycle frequencies, and increased gas flow velocities within the adsorbent beds, which may increase the productivity and/or recovery of a kinetic adsorption system incorporating the inventive adsorbent structures.
摘要翻译： 提供了改进的吸附片基平行通道吸附结构，用于增强某些动力学控制吸附过程（如PSA，TSA和PPSA方法）的动力学选择性及其组合。 通过实施本发明改进的吸附剂结构使得动力学选择性的增强可能出乎意料地能够使用常规的串联或挤出形式的吸附剂材料相对于可获得的性能而显着增强选定的动力学吸附过程。 通过本发明的吸附剂结构实现的这种过程强化可以提供增加的吸附循环频率和增加的吸附剂床内的气体流速，这可以增加并入本发明的吸附剂结构的动力学吸附系统的生产率和/或回收率。
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9.发明授权Small-pored crystalline titanium molecular sieve zeolites and their use in gas separation processes 有权小型结晶钛分子筛沸石及其在气体分离过程中的应用
公开(公告)号：US6068682A
公开(公告)日：2000-05-30
申请号：US210631
申请日：1998-12-11
IPC分类号： B01J20/18 , B01D53/047 , C01B39/02 , C01B39/08 , B01D53/04
CPC分类号： B01D53/02 , B01D53/047 , C01B39/085 , B01D2253/10 , B01D2253/106 , B01D2253/108 , B01D2253/25 , B01D2253/308 , B01D2256/10 , B01D2256/12 , B01D2256/16 , B01D2256/18 , B01D2256/24 , B01D2257/102 , B01D2257/104 , B01D2257/304 , B01D2257/502 , B01D2257/504 , B01D2257/7025 , B01D2258/06 , Y02C10/08 , Y02C20/20 , Y02P20/152 , Y02P20/156 , Y10S95/902
摘要： Novel gas separation agents with precisely and predictably controlled pore sizes within the range of 3-4 Angstrom units and their preparation from ETS-4 by exchange with cations, particularly multivalent cations such as strontium followed by drying and calcination to effect controlled pore shrinkage is disclosed. These novel materials have utility in gas separation processes particularly the separation of nitrogen from a mixture of the same with methane.
摘要翻译： 公开了具有精确和可预测控制孔尺寸在3-4埃单位范围内的新型气体分离剂，并且通过与阳离子，特别是多价阳离子如锶交换，然后进行干燥和煅烧以实现可控的孔收缩，从ETS-4制备。 。 这些新型材料在气体分离方法中具有实用价值，特别是将氮气与甲烷的混合物分离。
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公开(公告)号：US5453263A
公开(公告)日：1995-09-26
申请号：US248040
申请日：1994-05-24
CPC分类号： B01J29/89 , C01B39/085
摘要： A novel process for the preparation of a crystalline titanium molecular sieve zeolite identified as ETS-10 characterized by crystals of uniform morphology which is free from halide-containing reactants is disclosed.
摘要翻译： 公开了一种鉴定为ETS-10的结晶钛分子筛沸石的新方法，其特征在于不含卤化物反应物的均匀形态的晶体。
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