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1.发明授权Macroscopic aggregates of microcrystalline zeolites for static water softening applications 失效用于静态水软化应用的微晶沸石的宏观聚集体公开(公告)号：US06685910B2
公开(公告)日：2004-02-03
申请号：US09737062
申请日：2000-12-14
IPC分类号： C01B3918
CPC分类号： C02F1/42 , B01J39/14 , C01B39/02 , C01B39/50 , C02F5/00 , Y10S423/21 , Y10S423/24
摘要： Novel morphologies are provided for aluminosilicate zeolite ion-exchange materials useful for static water softening. The zeolites are provided in the form of large aggregates composed of submicron zeolite crystals. Rapid exchange rates, high hardness ion capacity and increased attrition resistance characterize the zeolite ion exchangers.
摘要翻译： 提供了用于静态水软化的硅铝酸盐沸石离子交换材料的新型形态。 沸石以亚微米沸石晶体组成的大聚集体的形式提供。 沸石离子交换剂的快速交换速率，高硬度离子容量和增加的耐磨耗特性。
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公开(公告)号：US06416732B1
公开(公告)日：2002-07-09
申请号：US09533707
申请日：2000-03-23
IPC分类号： C01B3902
CPC分类号： C01B39/02 , C11D3/128 , Y10S423/21 , Y10S423/24
摘要： Aluminosilicate zeolites are formed in a novel reaction medium which contains a silicate source and an aluminum source in an aqueous alkaline solution and which reaction medium further includes an additional electrolyte salt. The addition of the electrolyte salt provides nucleation sites for the zeolite so as to form very small crystals. In high silica reaction environments, it is possible to form high aluminum zeolites which contain occluded silicate and wherein the morphology of the zeolites comprise macroscopic aggregates of microcrystalline zeolites. The addition of the electrolyte salt can also decrease the reaction time or temperature needed for crystallization.
摘要翻译： 铝硅酸盐沸石在新型反应介质中形成，该反应介质在碱性水溶液中含有硅酸盐源和铝源，该反应介质还包含另外的电解质盐。 电解质盐的添加为沸石提供了成核位点，从而形成非常小的晶体。 在高二氧化硅反应环境中，可形成含有封闭硅酸盐的高铝沸石，其中沸石的形态包括微晶沸石的宏观聚集体。 电解质盐的添加也可以降低结晶所需的反应时间或温度。
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公开(公告)号：US06413492B1
公开(公告)日：2002-07-02
申请号：US09533606
申请日：2000-03-23
IPC分类号： C01B3902
CPC分类号： C11D3/128 , C01B39/02 , Y10S423/21 , Y10S423/24
摘要： The present invention relates to a method of forming an aluminosilicate zeolite having a Si/Al≦1.1. The method comprises forming a reaction mixture by mixing a source of silica, and a source of aluminum in an aqueous alkaline solution having a pH of at least 12.0, wherein the Si/Al of said mixture is greater than 1.0.
摘要翻译： 本发明涉及一种形成Si / Al <= 1.1的硅铝酸盐沸石的方法。 该方法包括通过在pH为至少12.0的碱性水溶液中混合二氧化硅源和铝源形成反应混合物，其中所述混合物的Si / Al大于1.0。
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公开(公告)号：US06395067B1
公开(公告)日：2002-05-28
申请号：US09663827
申请日：2000-09-15
IPC分类号： B01D5322
CPC分类号： B01D67/0051 , B01D53/228 , B01D71/024 , B01D71/028 , B01D2323/12 , B01J29/89 , B01J2229/64
摘要： Porous titanium silicate molecular sieves are produced in the form of a membrane capable of separating fluid molecular mixtures.
摘要翻译： 多孔硅酸钛分子筛以能够分离流体分子混合物的膜的形式生产。
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公开(公告)号：US5948383A
公开(公告)日：1999-09-07
申请号：US30418
申请日：1998-02-25
CPC分类号： C01B39/50 , B01J39/14 , C02F1/42 , C11D3/128 , C02F2001/425 , Y10S423/21 , Y10S423/24
摘要： This invention relates to zeolitic molecular sieve compositions characterized by outstanding capability to complex multivalent cations, especially calcium. In particular, the invention relates to novel zeolitic molecular sieve compositions, especially those based on molecular sieves having a high alumina-to-silica ratio, in which crystals of the zeolite are modified by the inclusion of occluded silicate.
摘要翻译： 本发明涉及沸石分子筛组合物，其特征在于复合多价阳离子，特别是钙的突出能力。 特别地，本发明涉及新型沸石分子筛组合物，特别是基于具有高氧化铝与二氧化硅比的分子筛的沸石分子筛组合物，其中沸石的晶体通过包含封闭的硅酸盐而被改性。
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6.发明授权Small-pored crystalline titanium molecular sieve zeolites and their use in gas separation processes 有权小型结晶钛分子筛沸石及其在气体分离过程中的应用
公开(公告)号：US6068682A
公开(公告)日：2000-05-30
申请号：US210631
申请日：1998-12-11
IPC分类号： B01J20/18 , B01D53/047 , C01B39/02 , C01B39/08 , B01D53/04
CPC分类号： B01D53/02 , B01D53/047 , C01B39/085 , B01D2253/10 , B01D2253/106 , B01D2253/108 , B01D2253/25 , B01D2253/308 , B01D2256/10 , B01D2256/12 , B01D2256/16 , B01D2256/18 , B01D2256/24 , B01D2257/102 , B01D2257/104 , B01D2257/304 , B01D2257/502 , B01D2257/504 , B01D2257/7025 , B01D2258/06 , Y02C10/08 , Y02C20/20 , Y02P20/152 , Y02P20/156 , Y10S95/902
摘要： Novel gas separation agents with precisely and predictably controlled pore sizes within the range of 3-4 Angstrom units and their preparation from ETS-4 by exchange with cations, particularly multivalent cations such as strontium followed by drying and calcination to effect controlled pore shrinkage is disclosed. These novel materials have utility in gas separation processes particularly the separation of nitrogen from a mixture of the same with methane.
摘要翻译： 公开了具有精确和可预测控制孔尺寸在3-4埃单位范围内的新型气体分离剂，并且通过与阳离子，特别是多价阳离子如锶交换，然后进行干燥和煅烧以实现可控的孔收缩，从ETS-4制备。 。 这些新型材料在气体分离方法中具有实用价值，特别是将氮气与甲烷的混合物分离。
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公开(公告)号：US06572776B2
公开(公告)日：2003-06-03
申请号：US09737063
申请日：2000-12-14
IPC分类号： C02F142
摘要： A method of water softening utilizes macrocrystalline aggregates consisting essentially of submicron crystals of aluminosilicate zeolite. The aggregates have a size of greater than 5 microns and are used in a static bed water softening device. Both regenerable and disposable water softening materials can be provided.
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公开(公告)号：US06340433B1
公开(公告)日：2002-01-22
申请号：US09663828
申请日：2000-09-15
IPC分类号： B01D6100
CPC分类号： B01D67/0051 , B01D71/024 , B01D71/028 , B01D2323/40 , B01D2325/10 , C02F1/44 , C02F2101/103 , C02F2101/22 , C02F2101/36
摘要： Aqueous streams containing organic and/or inorganic contaminants are purified by the removal of the contaminant by contacting the aqueous stream with a membrane formed from a porous, crystalline titanium silicate.
摘要翻译： 含有有机和/或无机污染物的水流通过使含水流与由多孔结晶硅酸钛形成的膜接触来除去污染物而被净化。
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公开(公告)号：US06451283B1
公开(公告)日：2002-09-17
申请号：US09533771
申请日：2000-03-23
IPC分类号： C01B3902
CPC分类号： C01B39/02 , C11D3/128 , Y10S423/21 , Y10S423/24
摘要： This invention relates to zeolitic molecular sieve compositions and hybrid zeolite-silica compositions characterized by novel morphology in which the zeolite is present as macroscopic aggregates of microcrystalline zeolite. The zeolitic compositions of this invention have outstanding capability to complex multivalent cations, especially calcium due to the high exchange kinetics of the microcrystalline zeolite component and yet have the ease of handling due to the macroscopic aggregate assemblage.
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10.发明授权Separation of nitrogen from mixtures thereof with methane utilizing barium exchanged ETS-4 失效使用钡交换的ETS-4将氮与其与甲烷的混合物分离
公开(公告)号：US5989316A
公开(公告)日：1999-11-23
申请号：US996298
申请日：1997-12-22
CPC分类号： C01B39/026 , B01D53/02 , B01J20/183 , B01J20/186 , B01J20/2803 , B01J20/28047 , B01D2253/106 , B01D2257/102 , B01D2257/7022 , B01D53/047
摘要： Barium-exchanged ETS-4 shows particular utility in gas separation processes involving the separation of nitrogen from a mixture of the same with methane.
摘要翻译： 钡交换的ETS-4在气体分离过程中显示出特别的用途，其涉及将氮气与甲烷的混合物分离。
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