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    Fuels for internal combustion engines
    4.
    发明授权
    Fuels for internal combustion engines 有权
    内燃机燃料

    公开(公告)号：US06858048B1

    公开(公告)日：2005-02-22

    申请号：US10124665

    申请日：2002-04-17

    申请人： Robert M. Jimeson ,  Mark C. Radosevich ,  Rex R. Stevens

    发明人： Robert M. Jimeson ,  Mark C. Radosevich ,  Rex R. Stevens

    IPC分类号： C10L1/182 ,  C10L10/02 ,  C10L1/18

    CPC分类号： C10L1/1822 ,  C10L10/02 ,  C10L10/10

    摘要： Mixed alcohols can be used as a fuel additive in gasoline, diesel, jet fuel or as a neat fuel in and of itself. The mixed alcohols can contain C1-C5 alcohols, or in the alternative, C1-C8, or higher, alcohols in order to boost energy content. The C1-C5 mixed alcohols contain more ethanol than methanol with amounts of propanol, butanol and pentanol. C1-C8 mixed alcohols contain the same, with amounts of hexanol, heptanol and octanol. A gasoline-based fuel includes gasoline and the mixed alcohols. A diesel based fuel includes diesel and the mixed alcohols. A jet fuel includes kerosene and the mixed alcohols. The neat fuel of the mixed alcohols has an octane number of at least 109 and the Reid Vapor Pressure is no greater than 5 psi. The gross heat of combustion is at least 12,000 BTU's/lb.

    摘要翻译： 混合醇可用作汽油，柴油，喷气燃料中的燃料添加剂或本身作为纯燃料。 混合的醇可以含有C 1 -C 5醇，或者替代地，C1-C8或更高级的醇，以提高能量含量。 C1-C5混合醇含有比甲醇多的乙醇，其量为丙醇，丁醇和戊醇。 C1-C8混合醇含有相同的量，其量为己醇，庚醇和辛醇。 汽油燃料包括汽油和混合醇。 基于柴油的燃料包括柴油和混合醇。 喷气燃料包括煤油和混合醇。 混合醇的纯净燃料的辛烷值至少为109，里德蒸气压不大于5psi。 燃烧的总热量至少为12000BTU / lb。

    Mixed alcohols production from syngas
    5.
    发明授权
    Mixed alcohols production from syngas 失效
    从合成气生产混合醇

    公开(公告)号：US4752623A

    公开(公告)日：1988-06-21

    申请号：US942933

    申请日：1986-12-17

    申请人： Rex R. Stevens ,  Mark M. Conway

    发明人： Rex R. Stevens ,  Mark M. Conway

    IPC分类号： B01J23/85 ,  C07C29/156 ,  C07C27/06

    CPC分类号： B01J23/8872 ,  B01J23/85 ,  C07C29/156 ,  Y02P20/52

    摘要： Mixed alcohols are produced from carbon monoxide and hydrogen gases using an easily prepared catalyst/co-catalyst metal catalyst. The catalyst metals are molybdenum, tungsten or rhenium. The co-catalyst metals are cobalt, nickel or iron. The catalyst is promoted with a Fischer-Tropsch promoter like an alkali or alkaline earth series metal or a smaller amount of thorium and is further treated by sulfiding. The composition of the mixed alcohols fraction can be selected by selecting the extent of intimate contact among the catalytic components.

    摘要翻译： 使用易于制备的催化剂/助催化剂金属催化剂，由一氧化碳和氢气产生混合的醇。 催化剂金属是钼，钨或铼。 助催化剂金属是钴，镍或铁。 用诸如碱金属或碱土系列金属或较少量的钍的费 - 托促进剂促进催化剂，并进一步通过硫化处理。 可以通过选择催化组分之间紧密接触的程度来选择混合醇馏分的组成。

    Method for adjusting methanol to higher alcohol ratios
    6.
    发明授权
    Method for adjusting methanol to higher alcohol ratios 失效
    调节甲醇至高酒精比例的方法

    公开(公告)号：US4675344A

    公开(公告)日：1987-06-23

    申请号：US830907

    申请日：1986-02-18

    申请人： Mark M. Conway ,  Craig B. Murchison ,  Rex R. Stevens

    发明人： Mark M. Conway ,  Craig B. Murchison ,  Rex R. Stevens

    IPC分类号： C07C29/153 ,  C07C27/06

    CPC分类号： C07C29/153

    摘要： A method for controlling the ratio of methanol to higher alcohols produced in a process for making mixed alcohols by contacting a hydrogen- and carbon monoxide-containing feed with a molybdenum- or tungsten-containing catalyst, said method comprising adjusting a concentration of a sulfur releasing substance in the feed.

    摘要翻译： 一种控制通过使含氢和一氧化碳的进料与含钼或钨的催化剂接触来制备混合醇的方法中产生的甲醇与高级醇的比例的方法，所述方法包括调节硫的释放浓度 饲料中的物质。

    Process for conducting etherification reactions using as catalysts strong-acid, cation-exchange resins prepared under high temperature conditions
    7.
    发明授权
    Process for conducting etherification reactions using as catalysts strong-acid, cation-exchange resins prepared under high temperature conditions 失效
    使用在高温条件下制备的强酸，阳离子交换树脂作为催化剂进行醚化反应的方法

    公开(公告)号：US5663455A

    公开(公告)日：1997-09-02

    申请号：US542154

    申请日：1995-10-12

    申请人： William I. Harris ,  Rex R. Stevens

    发明人： William I. Harris ,  Rex R. Stevens

    IPC分类号： C07C41/06 ,  C07C43/04

    CPC分类号： C07C41/06

    摘要： An improved process for conducting an etherification reaction has been discovered. The process employs a macroporous strong-acid, cation-exchange resin catalyst prepared at a temperature of about 120.degree. C. or higher with a reduced amount of divinylbenzene crosslinker. The etherification catalysts produced in the invention display equivalent or superior catalytic activity than conventional catalysts and are less expensive to produce than conventional catalysts due to reduced amounts of crosslinker.

    摘要翻译： 已经发现了进行醚化反应的改进方法。 该方法采用在约120℃或更高温度下用减少量的二乙烯基苯交联剂制备的大孔强酸阳离子交换树脂催化剂。 本发明中生产的醚化催化剂显示与常规催化剂相当或优异的催化活性，并且由于交联剂的量减少而比常规催化剂生产成本低。

    Process for producing alcohols from synthesis gas
    8.
    发明授权
    Process for producing alcohols from synthesis gas 失效
    从合成气生产醇的方法

    公开(公告)号：US4752622A

    公开(公告)日：1988-06-21

    申请号：US903878

    申请日：1986-09-03

    申请人： Rex R. Stevens

    发明人： Rex R. Stevens

    IPC分类号： B01J23/85 ,  C07C29/156 ,  C07C27/06

    CPC分类号： B01J23/8872 ,  B01J23/85 ,  B01J23/882 ,  C07C29/156 ,  Y02P20/52

    摘要： A process for making alcohols comprising contacting a mixture of hydrogen and carbon monoxide with a catalyst comprising:(1) as a first component, at least one element selected from the group consisting of molybdenum and tungsten in free or combined form;(2) as a second component, at least one element selected from the group consisting of iron, cobalt and nickel in free or combined form;(3) as a third component, a promoter comprising an alkali or alkaline earth element in free or combined form; and optionally(4) as a fourth component, a support;to form an alcohol fraction boiling in the range of motor gasoline in at least 20 percent CO.sub.2 free carbon selectivity.

    摘要翻译： 一种制备醇的方法，包括使氢和一氧化碳的混合物与催化剂接触，所述催化剂包括：（1）作为第一组分，选自游离或组合形式的钼和钨的至少一种元素; （2）作为第二组分，选自游离或组合形式的选自铁，钴和镍的至少一种元素; （3）作为第三组分，包含游离或组合形式的碱金属或碱土金属元素的促进剂; 和任选的（4）作为第四组分，载体; 以在至少20％的CO 2游离碳选择性中形成在汽油范围内沸腾的醇馏分。

    Purification of effluent from wood pulp bleach plant
    10.
    发明授权
    Purification of effluent from wood pulp bleach plant 失效
    净化木浆漂白厂废水

    公开(公告)号：US4895662A

    公开(公告)日：1990-01-23

    申请号：US351342

    申请日：1989-05-15

    申请人： Rex R. Stevens

    发明人： Rex R. Stevens

    IPC分类号： B01D15/00 ,  B01J20/26 ,  C02F1/28

    CPC分类号： B01J20/26 ,  B01D15/00 ,  C02F1/285 ,  Y10S210/917 ,  Y10S210/928

    摘要： A process for purifying a waste effluent from the bleaching of wood pulp by contacting the effluent with an adsorbent resin, wherein the adsorbent resin is a macroporous copolymer being post-crosslinked in a swollen state in the presence of a Friedel-Crafts catalyst and functionalized with hydrophilic groups prior to contact with the waste effluent.

    摘要翻译： 一种用于通过使流出物与吸附剂树脂接触来净化来自木浆漂白的废物流出物的方法，其中所述吸附树脂是在Friedel-Crafts催化剂存在下以膨胀状态后交联的大孔共聚物，并用 在与废液接触之前的亲水基团。