摘要:
Stabilizers consisting of (a) 2,5,7,8-tetramethyl-2-(2'-stearyloxyethyl)-chroman and (b) glyceryl stearate, glyceryl hydroxystearate, partial esters of stearic acid with condensates of glycerol and trimethylolpropane, triglyceryl stearate and/or tetraglyceryl stearate, with or without further conventional additives, the weight ratio of (a) to (b) being from 10:1 to 1:10, give improved stabilization to discoloration and superior stability during processing when used in plastics such as polyethylene or polypropylene.
摘要:
2,3-Dihydrobenz-4-oxa-1-thiins of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, methyl or methoxy, and R.sup.2 and R.sup.3 together may furthermore be a fused benzene ring, R.sup.4 is hydrogen or an m-valent aliphatic hydrocarbon radical which may be interrupted by sulfur and /or carry thiol groups as substituents, or is halogen when n is zero, X is --O--, --S-- or --O--CO--, m is 1 or 2 and n is zero or 1, are useful as antioxidants for organic materials.
摘要:
Maleimide/.alpha.-olefin copolymers are composed of structural units I ##STR1## where R.sup.1 is a tetramethylpiperidinyl radical of the formula II ##STR2## R.sup.3 is hydrogen, C.sub.1 -C.sub.6 -alkyl, formyl, C.sub.2 -C.sub.6 -alkanoyl, C.sub.1 -C.sub.12 -alkoxy, C.sub.5 - or C.sub.6 -cycloalkoxy, cyanomethyl, 2-hydroxyethyl, benzyl or a radical of the formula --CR.sup.4 =CH--CO--OR.sup.5, R.sup.4 is hydrogen, C.sub.1 -C.sub.6 -alkyl or a radical of the formula --CO--OR.sup.5, and R.sup.5 is C.sub.5 -C.sub.18 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.7 -C.sub.18 -aralkyl, phenyl or tolyl, and up to 8 mol %, based on II, of R.sup.1 may furthermore be hydrogen, C.sub.1 -C.sub.22 -alkyl or C.sub.5 -C.sub.8 -cycloalkyl, and R.sup.2 is a mixture of C.sub.14 -C.sub.28 -alkyl groups, where two of these alkyl groups, which may differ by no more than two carbon atoms, each account for at least 30% of this mixture, having an average molecular weight of from 1,000 to 50,000. The copolymers described are suitable as light stabilizers and stabilizers for organic material, in particular plastics and coatings.
摘要:
Stabilizer mixtures for stabilizing plastics comprising one part by weight of a chroman derivative (I) of the general formula ##STR1## where R= ##STR2## where Z=C.sub.7 -C.sub.30 -alkyl, --CH.sub.2 CH.sub.2 --S--[C.sub.1 -C.sub.30 -alkyl] or ##STR3## and from 5 to 14 parts by weight of an organic phosphite of the general formula (II) ##STR4## where R.sup.1, R.sup.2 and R.sup.3 are identical of different alkyl and/or aryl or of an organic phosphonite of the formula (III) ##STR5## where +is C(CH.sub.3).sub.3, a mixing ratio (a):(b) of from 1:6 to 1:10 being preferred.
摘要:
Furan-3-carbohydroxamates of the formula ##STR1## where R.sup.1 is alkyl, unsubstituted or substituted cycloalkyl or unsubstituted or substituted phenyl, R.sup.2 is methyl or ethyl, R.sup.3 and R.sup.4 independently of one another are each hydrogen, bromine, chlorine, unsubstituted or substituted alkyl, or --CH.sub.2 --COOR.sup.5, where R.sup.5 is unsubstituted or substituted alkyl, and Me is divalent nickel or cobalt, stabilize plastics against the action of light, oxygen and heat. The compounds (I) have only slight intrinsic color.
摘要:
Novel furancarboxylic acid derivatives of the general formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 independently of one another are each hydrogen, C.sub.1 -C.sub.8 -alkyl, cyclohexyl or phenyl, but not more than two of these radicals are simultaneously hydrogen, and R.sup.4 is a radical of the formula --NR.sup.5 R.sup.6, ##STR2## or OR.sup.6, where A is a bridge member, R.sup.5 is hydrogen, C.sub.2 -C.sub.6 -alkenyl, C.sub.5 -C.sub.7 -cycloalkyl or C.sub.1 -C.sub.12 -alkyl which may or may not be interrupted by 1, 2 or 3 oxygen atoms, and R.sup.6 is a radical of the formula ##STR3## where R.sup.7, R.sup.8, R.sup.9 and R.sup.10 are each C.sub.1 -C.sub.4 -alkyl, or R.sup.7 and R.sup.8 or R.sup.9 and R.sup.10 together form a tetramethylene or pentamethylene bridge, and R.sup.11 is hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.3 -C.sub.8 -alkenyl, C.sub.2 -C.sub.4 -hydroxyalkyl or aralkyl, and their salts are useful as light stabilizers for organic polymers, in particular olefin polymers.
摘要:
Described is a stabilizer composition comprising a 3-arylacrylic ester, a polymeric compound having a molecular weight of at least 2000 which carries, on a polymeric framework, side groups having secondary amine functions, all substituents positioned to the amine nitrogen being other than hydrogen, a chroman derivative, and an organic phosphite and/or phosphonite. The stabilizer composition is particularly suitable for stabilizing thermoplastic polyurethane against light, oxygen and heat.
摘要:
Isoindolinone derivatives of the formula I, in which the variables have the following meanings: R1 is hydrogen, COOR4, COR4, CONR4R5, CN, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, aryl or heteroaryl, substituted or unsubstituted; R1 and R2 together are C7-C10-bicycloalkyl or C7-C10-bicycloalkenyl; R3 is hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, C1-C12-alkoxy, C1-C20-alkoxycarbonyl, C1-C12-alkylamino, C1-C12-dialkylamino, aryl or heteroaryl, substituted or unsubstituted, substituents which confer solubility in water, selected from the group consisting of carboxylate, sulfonate or ammonium radicals; R4 and R5 independently of one another are hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl; aryl or heteroaryl, substituted or unsubstituted; are used as stabilizers for organic materials.
摘要:
A molding material comprises styrene/butadiene block copolymers obtainable by anionic polymerization and from 0.01 to 1% by weight, based on the polymer, of .alpha.-tocopherol.
摘要:
A polyalky-piperidinyl-containing .beta.-aminoacrylic ester derivative represented by the formula I ##STR1## is useful in stabilizing plastic and paints against light, oxygen and heat.