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    Alkoxyamines Containing a Radically Polymerizable Group
    3.
    发明申请
    Alkoxyamines Containing a Radically Polymerizable Group 有权
    含有可自由基聚合的烷氧基胺

    公开(公告)号：US20070232768A1

    公开(公告)日：2007-10-04

    申请号：US11596436

    申请日：2005-05-17

    申请人： Peter Nesvadba ,  Andreas Kramer ,  Lucienne Bugnon

    发明人： Peter Nesvadba ,  Andreas Kramer ,  Lucienne Bugnon

    IPC分类号： C08F4/00 ,  C07D211/94 ,  C07D241/08 ,  C07F9/40

    CPC分类号： C07D241/08 ,  C07D211/94

    摘要： The instant invention relates to novel alkoxyamine initiators/regulators containing an ethylenically unsaturated, radically polymerizable group. The compounds are useful for the preparation of complex polymeric architectures. Further aspects of the invention are a polymerizable composition and a polymerization process comprising the alkoxyamine initiators/regulators, a macroinitiator obtainable by said polymerization process and a process for polymerizing with the macroinitiator.

    摘要翻译： 本发明涉及含有烯属不饱和的，可自由基聚合的基团的新的烷氧基胺引发剂/调节剂。 该化合物可用于制备复合聚合物结构。 本发明的其它方面是可聚合组合物和包含烷氧基胺引发剂/调节剂的聚合方法，通过所述聚合方法获得的大分子引发剂和与大分子引发剂聚合的方法。

    1-Alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
    4.
    发明申请
    1-Alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators 有权
    1-烷氧基 - 聚烷基 - 哌啶衍生物及其作为聚合调节剂的用途

    公开(公告)号：US20050131177A1

    公开(公告)日：2005-06-16

    申请号：US11035915

    申请日：2005-01-14

    申请人： Andreas Kramer ,  Peter Nesvadba

    发明人： Andreas Kramer ,  Peter Nesvadba

    IPC分类号： C07D211/46 ,  C07D211/74 ,  C07D211/94 ,  C07D401/04 ,  C07D405/12 ,  C07D471/10 ,  C07D487/06 ,  C07D491/107 ,  C07D491/113 ,  C08F2/38 ,  C08F4/00 ,  C08K5/3435 ,  C07D211/54 ,  C08F210/00 ,  C07D41/02 ,  C07D43/02

    CPC分类号： C07D211/46 ,  C07D211/74 ,  C07D211/94 ,  C08F4/00

    摘要： The present invention relates to 1-alkoxy-polyalkyipiperidine derivatives containing a structural element of formula (I) G1, G2, G3, G4 are Independently C1-C6alkyl with the proviso that at least one is not methyl or G1 and G2 or G3 and G4, or G1 and G2 and G3 and G4 together form a C5-C12cycloalkyl group; G5, G6 independently are H, C1-C18alkyl, phenyl, naphthyl or a group COOC1-C18alkyl and X represents a group such that the free radical Xe derived from X is capable of initiating polymerization of ethylenically unsaturated monomers, with the proviso that compounds A1 and A2 are excluded Further subjects of the invention are a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) a 1-alkoxy-polyalkyl-piperidine derivative, a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-polyalkyl-piperidine derivatives for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator X•, as well as a process for polymerization are also subjects of the present invention.

    摘要翻译： 本发明涉及含有式（I）的基团的1-烷氧基 - 聚烷基哌啶衍生物G 1，G 2，G 3， G 4独立地是C 1 -C 6烷基，条件是至少一个不是甲基或G 1 N 和G 2或G 3和G 4，或G 1和G 2， SUB和G 3和G 4一起形成C 5 -C 12 - 环烷基; G 5，G 6独立地是H，C 1 -C 18烷基，苯基，萘基或基团 C 1 -C 12烷基，X代表衍生自X的游离基Xe能够引发烯属不饱和单体的聚合，条件是化合物A1 和A2被排除本发明的其它主题是一种可聚合组合物，其包含a）至少一种烯属不饱和单体和b）1-烷氧基 - 聚烷基 - 哌啶衍生物，聚合烯属不饱和单体的方法，以及使用1-烷氧基 - 聚烷基 - 哌啶衍生物用于受控聚合。 中间体N-氧基衍生物，具有烯属不饱和单体的N-氧基衍生物和自由基引发剂X的组合物以及聚合方法也是本发明的主题。

    Open-chain alkoxyamines and their corresponding nitroxides for controlled low temperature radical polymerization
    5.
    发明授权
    Open-chain alkoxyamines and their corresponding nitroxides for controlled low temperature radical polymerization 失效
    开链烷氧基胺及其相应的氮氧化物用于控制低温自由基聚合

    公开(公告)号：US07297819B2

    公开(公告)日：2007-11-20

    申请号：US10506700

    申请日：2003-02-25

    申请人： Tobias Hintermann ,  Peter Nesvadba ,  Andreas Kramer ,  Jochen Fink

    发明人： Tobias Hintermann ,  Peter Nesvadba ,  Andreas Kramer ,  Jochen Fink

    IPC分类号： C07C239/20 ,  C07D265/32 ,  C07D265/34 ,  C08F4/00

    CPC分类号： C08F4/00

    摘要： The present invention relates to open chain alkoxyamine compounds, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) at least one open chain alkoxyamine compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of open chain alkoxyamine compounds for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator X, as well as a process and their use for polymerization are also subjects of the present invention.

    摘要翻译： 本发明涉及开链烷氧基胺化​​合物，可聚合组合物，其包含a）至少一种烯键式不饱和单体和b）至少一种开链烷氧基胺化​​合物。 本发明的另外的方面是用于聚合烯键式不饱和单体的方法，以及使用开链烷氧基胺化​​合物用于受控聚合。 中间体N-氧基衍生物，具有烯键式不饱和单体的N-氧基衍生物和自由基引发剂X的组合物以及其聚合的方法和用途也是本发明的主题。

    2,2,6,6 Diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides
    6.
    发明授权
    2,2,6,6 Diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides 失效
    2,2,6,6二乙基 - 二甲基-1-烷氧基 - 哌啶化合物及其相应的1-氧化物

    公开(公告)号：US07160966B2

    公开(公告)日：2007-01-09

    申请号：US11048677

    申请日：2005-02-01

    申请人： Peter Nesvadba ,  Marie-Odile Zink ,  Andreas Kramer

    发明人： Peter Nesvadba ,  Marie-Odile Zink ,  Andreas Kramer

    IPC分类号： C08F2/38 ,  C08F2/50 ,  C08F4/00

    CPC分类号： C07D401/04 ,  C07D211/94 ,  C08F2/38 ,  C08F255/00 ,  C08F265/04 ,  C08F291/00 ,  C08F293/005 ,  C08F2220/1825 ,  C08F2438/02 ,  C08F220/34

    摘要： The present invention relates to selected 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 trimethyl piperidine derivatives which are substituted in the 4 position by an oxygen or nitrogen atom; a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) said piperidine derivatives. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,6 dimethyl piperidine derivatives which are substituted in the 4 position by an oxygen or nitrogen atom for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator, as well as a process for polymerization are also subjects of the present invention.

    摘要翻译： 本发明涉及在4位被氧或氮取代的选择的1-烷氧基-2,2-二乙基-6,6二甲基哌啶和1-烷氧基-2,6-二乙基-2,3,6-三甲基哌啶衍生物 原子; 一种可聚合组合物，其包含a）至少一种烯属不饱和单体和b）所述哌啶衍生物。 本发明的其它方面是使烯属不饱和单体聚合的方法，以及使用1-烷氧基-2,2-二乙基-6,6二甲基哌啶和1-烷氧基-2,6-二乙基-2,6-二甲基哌啶衍生物，其中 在4位被氧或氮原子取代用于受控聚合。 中间体N-氧基衍生物，具有烯键式不饱和单体的N-氧基衍生物和自由基引发剂的组合物以及聚合方法也是本发明的主题。

    1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
    8.
    发明授权
    1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators 有权
    1-烷氧基 - 聚烷基 - 哌啶衍生物及其作为聚合调节剂的用途

    公开(公告)号：US06927295B2

    公开(公告)日：2005-08-09

    申请号：US10422497

    申请日：2003-04-24

    申请人： Andreas Kramer ,  Peter Nesvadba

    发明人： Andreas Kramer ,  Peter Nesvadba

    IPC分类号： C07D211/46 ,  C07D211/74 ,  C07D211/94 ,  C07D401/04 ,  C07D405/12 ,  C07D471/10 ,  C07D487/06 ,  C07D491/107 ,  C07D491/113 ,  C08F2/38 ,  C08F4/00 ,  C08K5/3435 ,  C07D401/12

    CPC分类号： C07D211/46 ,  C07D211/74 ,  C07D211/94 ,  C08F4/00

    摘要： The present invention relates to 1-alkoxy-polyalkyl-piperidine derivatives containing a structural element of formula (I) G1, G2, G3, G4 are independently C1-C6alkyl with the proviso that at least one is not methyl or G1 and G2 or G3 and G4, or G1 and G2 and G3 and G4 together form a C5-C12cycloalkyl group; G5, G6 independently are H, C1-C18alkyl, phenyl, naphthyl or a group COOC1-C18alkyl and X represents a group such that the free radical X● derived from X is capable of initiating polymerization of ethylenically unsaturated monomers, with the proviso that compounds A1 and A2 are excluded Further subjects of the invention are a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) a 1-alkoxy-polyalkyl-piperidine derivative, a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-polyalkyl-piperidine derivatives for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator X●, as well as a process for polymerization are also subjects of the present invention.

    摘要翻译： 本发明涉及含有式（I）G 1，G 2，G 3，N 3的结构元件的1-烷氧基 - 多烷基 - 哌啶衍生物 >，G 4独立地是C 1 -C 6烷基，条件是至少一个不是甲基或G 1， / SUB>和G 2或G 3和G 4，或G 1和G 2 G 3和G 3和R 4一起形成C 5 -C 12环烷基; G 5，G 6独立地是H，C 1 -C 18烷基，苯基，萘基或基团 COOC 1 -C 18烷基，X表示衍生自X的自由基X●能够引发烯键式不饱和单体的聚合，条件是化合物 A1和A2被排除本发明的其它主题是可聚合组合物，其包含a）至少一种烯属不饱和单体和b）1-烷氧基 - 聚烷基 - 哌啶衍生物，聚合烯属不饱和单体的方法，以及1- 用于受控聚合的烷氧基 - 聚烷基 - 哌啶衍生物。 中间体N-氧基衍生物，具有烯属不饱和单体的N-氧基衍生物和自由基引发剂X - 的组合物以及聚合方法也是本发明的主题。

    Method of grafting ethylenically unsaturated carboxylic acid derivatives onto thermoplastic using hydroxylamine esters
    9.
    发明授权
    Method of grafting ethylenically unsaturated carboxylic acid derivatives onto thermoplastic using hydroxylamine esters 有权
    使用羟胺酯将烯属不饱和羧酸衍生物接枝到热塑性塑料上的方法

    公开(公告)号：US06900268B2

    公开(公告)日：2005-05-31

    申请号：US10477364

    申请日：2002-05-07

    申请人： Jochen Fink ,  Michael Roth ,  Rudolf Pfaendner ,  Peter Nesvadba ,  Andreas Kramer

    发明人： Jochen Fink ,  Michael Roth ,  Rudolf Pfaendner ,  Peter Nesvadba ,  Andreas Kramer

    IPC分类号： C08F8/46 ,  C08F8/32 ,  C08F255/00 ,  C08F291/00 ,  C08F2/38 ,  C08K5/32 ,  C08L51/06

    CPC分类号： C08F255/00 ,  C08F291/00 ,  C08F222/06

    摘要： The invention relates to a method of grafting unsaturated carboxylic acid derivatives onto thermoplastic polymers, which comprises heating a mixture of thermoplastic polymer, unsaturated carboxylic acid or carboxylic acid derivative and a hydroxy-lamine ester having at least one structural unit of formula (I) or (I′) wherein X is hydrogen, C1-C36alkyl, C2-C36alkenyl, C2-C18alkynyl, C6-C10aryl, —O—C1-C18alkyl —O—C6-C10aryl, —NH—C1-C18alkyl, —NH—C6-C10aryl, —N(C1-C6alkyl)2; X′ is a direct bond or C1-C36alkylene, C2-C36alkenylene, C2-C36alkynylene, —(C1-C6alkylene)-phenyl-(C1-C6alkylene) or a group in a processing apparatus for thermoplastic polymers, to above the softening point/melting point of the thermoplastic polymer and allowing the components of the mixture to react with one another

    摘要翻译： 本发明涉及将不饱和羧酸衍生物接枝到热塑性聚合物上的方法，其包括加热热塑性聚合物，不饱和羧酸或羧酸衍生物和具有至少一个式（I）结构单元的羟基 - （I'）其中X是氢，C 1 -C 36烷基，C 2 -C 36 - 烯基 C 2 -C 18炔基，C 6 -C 10芳基，-OC 1， C 1 -C 14烷基-C 1 -C 6 -C 10芳基，-NH-C 1 -C 烷基，-NH-C 6 -C 10芳基，-N（C 1 -C 3 - 亚芳基） > 6个烷基）2 1 -C 6亚烷基）或热塑性聚合物的加工装置中的基团，高于热塑性聚合物的软化点/熔点，并允许混合物的组分反应 彼此之间

    2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides
    10.
    发明授权
    2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides 失效
    2,2,6,6-二乙基 - 二甲基-1-烷氧基 - 哌啶化合物及其相应的1-氧化物

    公开(公告)号：US06891008B2

    公开(公告)日：2005-05-10

    申请号：US10348088

    申请日：2003-01-21

    申请人： Peter Nesvadba ,  Marie-Odile Zink ,  Andreas Kramer

    发明人： Peter Nesvadba ,  Marie-Odile Zink ,  Andreas Kramer

    IPC分类号： C07D211/94 ,  C07D401/04 ,  C08F2/38 ,  C08F2/46 ,  C08F4/00 ,  C08F220/18 ,  C08F255/00 ,  C08F265/04 ,  C08F291/00 ,  C08F293/00 ,  C07F2/38

    CPC分类号： C07D401/04 ,  C07D211/94 ,  C08F2/38 ,  C08F255/00 ,  C08F265/04 ,  C08F291/00 ,  C08F293/005 ,  C08F2220/1825 ,  C08F2438/02 ,  C08F220/34

    摘要： The present invention relates to selected 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 trimethyl piperidine derivatives which are substituted in the 4 position by an oxygen or nitrogen atom; a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) said piperidine derivatives. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,6 dimethyl piperidine derivatives which are substituted in the 4 position by an oxygen or nitrogen atom for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator, as well as a process for polymerization are also subjects of the present invention.

    摘要翻译： 本发明涉及在4位被氧或氮取代的选择的1-烷氧基-2,2-二乙基-6,6二甲基哌啶和1-烷氧基-2,6-二乙基-2,3,6-三甲基哌啶衍生物 原子; 一种可聚合组合物，其包含a）至少一种烯属不饱和单体和b）所述哌啶衍生物。 本发明的其它方面是使烯属不饱和单体聚合的方法，以及使用1-烷氧基-2,2-二乙基-6,6二甲基哌啶和1-烷氧基-2,6-二乙基-2,6-二甲基哌啶衍生物，其中 在4位被氧或氮原子取代用于受控聚合。 中间体N-氧基衍生物，具有烯键式不饱和单体的N-氧基衍生物和自由基引发剂的组合物以及聚合方法也是本发明的主题。