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    Halogenated oxime derivatives and the use therof as latent acids
    3.
    发明申请
    Halogenated oxime derivatives and the use therof as latent acids 有权
    卤代肟衍生物和作为潜伏酸使用

    公开(公告)号：US20090042114A1

    公开(公告)日：2009-02-12

    申请号：US12154333

    申请日：2008-05-22

    申请人： Hitoshi Yamato ,  Toshikage Asakura ,  Akira Matsumoto ,  Peter Murer ,  Tobias Hintermann

    发明人： Hitoshi Yamato ,  Toshikage Asakura ,  Akira Matsumoto ,  Peter Murer ,  Tobias Hintermann

    IPC分类号： C07D209/82 ,  C07C317/12 ,  G03F7/004 ,  C07D335/04

    CPC分类号： C07C251/48 ,  B33Y70/00 ,  C07C381/00 ,  C07C2603/18 ,  C07C2603/20 ,  C07C2603/40 ,  C07D209/86 ,  C07D307/91 ,  C07D333/76 ,  G03F7/0007 ,  G03F7/0045 ,  G03F7/0046 ,  G03F7/0382 ,  G03F7/0392

    摘要： Compounds of the formula I or II wherein R1 is C1-C10haloalkylsulfonyl, halobenzenesulfonyl, C2-C10haloalkanoyl, halobenzoyl; R2 is halogen or C1-C10haloalkyl; Ar1 is phenyl, biphenylyl, fluorenyl, naphthyl, anthracyl, phenanthryl, or heteroaryl, all of which are optionally substituted; Ar′1 is for example phenylene, naphthylene, diphenylene, heteroarylene, oxydiphenylene, phenylene-D-D1-D-phenylene or —Ar″1-A1-Y1-A1-Ar″1—; wherein these radicals optionally are substituted; Ar″1 is phenylene, naphthylene, anthracylene, phenanthrylene, or heteroarylene, all optionally substituted; A1 is for example a direct bond, —O—, —S—, or —NR6—; Y1 inter alia is C1-C18alkylene; X is halogen; D is for example —O—, —S— or —NR6—; D1 inter alia is C1-C18alkylene; are particularly suitable as photolatent acids in ArF resist technology.

    摘要翻译： 式I或II的化合物，其中R 1是C 1 -C 10卤代烷基磺酰基，卤代苯磺酰基，C 2 -C 10卤代烷酰基，卤代苯甲酰基; R2是卤素或C1-C10卤代烷基; Ar1是苯基，联苯基，芴基，萘基，蒽基，菲基或杂芳基，它们都是任选被取代的; Ar'1例如为亚苯基，亚萘基，亚二苯基，亚杂芳基，氧联二苯基，亚苯基-D-D1-D-phenylene或-Ar''1-A1-Y1-A1-Ar'1,1- 其中这些基团任选被取代; Ar 1是亚苯基，亚萘基，亚蒽基，亚菲基或亚杂芳基，全部被取代; A1是例如直接键，-O - ， - S - 或-NR 6 - ; Y1特别是C 1 -C 18亚烷基; X是卤素; D是例如-O - ， - S-或-NR 6 - ; D1特别是C 1 -C 18亚烷基; 在ArF抗蚀剂技术中特​​别适合作为光潜酸。

    Open-chain alkoxyamines and their corresponding nitroxides for controlled low temperature radical polymerization
    4.
    发明申请
    Open-chain alkoxyamines and their corresponding nitroxides for controlled low temperature radical polymerization 失效
    开链烷氧基胺及其相应的氮氧化物用于控制低温自由基聚合

    公开(公告)号：US20050124814A1

    公开(公告)日：2005-06-09

    申请号：US10506700

    申请日：2003-02-25

    申请人： Tobias Hintermann ,  Peter Nesvadba ,  Andreas Kramer ,  Jochen Fink

    发明人： Tobias Hintermann ,  Peter Nesvadba ,  Andreas Kramer ,  Jochen Fink

    IPC分类号： C07D333/40 ,  C07C219/22 ,  C07C239/20 ,  C07C291/00 ,  C07C321/28 ,  C07D265/32 ,  C07D265/34 ,  C08F4/00 ,  C07D401/00

    CPC分类号： C08F4/00

    摘要： The present invention relates to open chain alkoxyamine compounds, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) at least one open chain alkoxyamine compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of open chain alkoxyamine compounds for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator X, as well as a process and their use for polymerization are also subjects of the present invention.

    摘要翻译： 本发明涉及开链烷氧基胺化​​合物，可聚合组合物，其包含a）至少一种烯键式不饱和单体和b）至少一种开链烷氧基胺化​​合物。 本发明的另外的方面是用于聚合烯键式不饱和单体的方法，以及使用开链烷氧基胺化​​合物用于受控聚合。 中间体N-氧基衍生物，具有烯键式不饱和单体的N-氧基衍生物和自由基引发剂X的组合物以及其聚合的方法和用途也是本发明的主题。

    PHOTO-LATENT TITANIUM-OXO-CHELATE CATALYSTS
    5.
    发明申请
    PHOTO-LATENT TITANIUM-OXO-CHELATE CATALYSTS 有权
    紫外 - 钛 - 氧化钛催化剂

    公开(公告)号：US20140018461A1

    公开(公告)日：2014-01-16

    申请号：US14007688

    申请日：2012-04-02

    申请人： Tobias Hintermann ,  Antoine Carroy ,  Caroline Lordelot ,  Didier Bauer ,  Rachel Kohli Steck ,  Marc Faller

    发明人： Tobias Hintermann ,  Antoine Carroy ,  Caroline Lordelot ,  Didier Bauer ,  Rachel Kohli Steck ,  Marc Faller

    IPC分类号： C08G18/22 ,  C09D175/16 ,  C08G18/68

    CPC分类号： C09D175/16 ,  B01J31/0208 ,  B01J31/2234 ,  B01J2231/14 ,  B01J2231/48 ,  B01J2531/46 ,  C08G18/222 ,  C08G18/6229 ,  C08G18/68 ,  C08G18/792 ,  C09J175/04 ,  Y02P20/52

    摘要： A titanium-oxo-chelate catalyst formulation, comprising: (i) at least one compound of the formula (I), wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11 and R12 independently of each other are for example hydrogen, halogen, C1-C20alkyl, C6-C14aryl which is unsubstituted or substituted; or R1, R2 and R3 and/or R4, R5 and R6 and/or R7, R8 and R9 and/or R10, R11 and R12 together with the C-atom to which they are attached each form a C6-C14aryl group which is unsubstituted or substituted; or R1 and R2 and/or R4 and R5 and/or R7 and R8 and/or R10 and R11 together with the C-atom to which they are attached form a 5- to 7-membered carbocyclic ring; at least one chelate ligand compound of the formula (IIa), (IIb) or (IIc), wherein R1, R2, R3, R4, R5 and R6 are defined as above for formula (I), is suitable as photolatent catalyst formulation for polymerizing compounds, which are capable to crosslink in the presence of a Lewis acid.

    摘要翻译： 一种钛 - 氧代 - 螯合催化剂制剂，其包含：（i）至少一种式（I）化合物，其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10，R 11和R 12独立地 彼此是例如氢，卤素，未取代或取代的C 1 -C 20烷基，C 6 -C 14芳基; 或R 1，R 2和R 3和/或R 4，R 5和R 6和/或R 7，R 8和R 9和/或R 10，R 11和R 12与它们所连接的C原子一起形成C 6 -C 14芳基， 未取代或取代的; 或R 1和R 2和/或R 4和R 5和/或R 7和R 8和/或R 10和R 11与它们所连接的C原子一起形成5-至7-元碳环; 至少一种式（IIa），（IIb）或（IIc）的螯合配体化合物，其中R 1，R 2，R 3，R 4，R 5和R 6如上文对式（I）所定义，适用于作为光催化剂制剂 聚合化合物，其能够在路易斯酸存在下交联。

    Halogenated oxime derivatives and the use therof as latent acids
    6.
    发明授权
    Halogenated oxime derivatives and the use therof as latent acids 有权
    卤代肟衍生物和作为潜伏酸使用

    公开(公告)号：US08241822B2

    公开(公告)日：2012-08-14

    申请号：US12154333

    申请日：2008-05-22

    申请人： Hitoshi Yamato ,  Toshikage Asakura ,  Akira Matsumoto ,  Peter Murer ,  Tobias Hintermann

    发明人： Hitoshi Yamato ,  Toshikage Asakura ,  Akira Matsumoto ,  Peter Murer ,  Tobias Hintermann

    IPC分类号： C07C317/12 ,  G03F7/004

    CPC分类号： C07C251/48 ,  B33Y70/00 ,  C07C381/00 ,  C07C2603/18 ,  C07C2603/20 ,  C07C2603/40 ,  C07D209/86 ,  C07D307/91 ,  C07D333/76 ,  G03F7/0007 ,  G03F7/0045 ,  G03F7/0046 ,  G03F7/0382 ,  G03F7/0392

    摘要： Compounds of the formula I or II wherein R1 is C1-C10haloalkylsulfonyl, halobenzenesulfonyl, C2-C10haloalkanoyl, halobenzoyl; R2 is halogen or C1-C10haloalkyl; Ar1 is phenyl, biphenylyl, fluorenyl, naphthyl, anthracyl, phenanthryl, or heteroaryl, all of which are optionally substituted; Ar′1 is for example phenylene, naphthylene, diphenylene, heteroarylene, oxydiphenylene, phenylene-D-D1-D-phenylene or —Ar″1-A1-Y1-A1-Ar″1—; wherein these radicals optionally are substituted; Ar″1 is phenylene, naphthylene, anthracylene, phenanthrylene, or heteroarylene, all optionally substituted; A1 is for example a direct bond, —O—, —S—, or —NR6—; Y1 inter alia is C1-C18alkylene; X is halogen; D is for example —O—, —S— or —NR6—; D1 inter alia is C1-C18alkylene; are particularly suitable as photolatent acids in ArF resist technology.

    摘要翻译： 式I或II的化合物，其中R 1是C 1 -C 10卤代烷基磺酰基，卤代苯磺酰基，C 2 -C 10卤代烷酰基，卤代苯甲酰基; R2是卤素或C1-C10卤代烷基; Ar1是苯基，联苯基，芴基，萘基，蒽基，菲基或杂芳基，它们都是任选被取代的; Ar'1例如为亚苯基，亚萘基，亚二苯基，亚杂芳基，氧联二苯基，亚苯基-D-D1-D-亚苯基或-Ar“1-A1-Y1-A1-Ar” 其中这些基团任选被取代; Ar 1是亚苯基，亚萘基，亚蒽基，亚菲基或亚杂芳基，全部被取代; A1是例如直接键，-O - ， - S - 或-NR 6 - ; Y1特别是C 1 -C 18亚烷基; X是卤素; D是例如-O - ， - S-或-NR 6 - ; D1特别是C 1 -C 18亚烷基; 在ArF抗蚀剂技术中特​​别适合作为光潜酸。

    Photo-latent titanium catalysts
    7.
    发明授权
    Photo-latent titanium catalysts 有权

    公开(公告)号：US10207261B2

    公开(公告)日：2019-02-19

    申请号：US13395467

    申请日：2010-09-09

    申请人： Tobias Hintermann ,  Didier Bauer ,  Antoine Carroy ,  Caroline Lordelot ,  Rachel Kohli Steck

    发明人： Tobias Hintermann ,  Didier Bauer ,  Antoine Carroy ,  Caroline Lordelot ,  Rachel Kohli Steck

    IPC分类号： B01J31/22 ,  B01J31/02 ,  C09D175/04 ,  C08G18/79 ,  C08G18/62 ,  C08G18/22

    摘要： The present invention provides a photolatent Ti-chelate catalyst formulation, comprising (i) at least one compound of the formula (I) wherein R1 is C1-C20alkyl or C2-C20alkyl which is interrupted by one or more non-consecutive O-atoms; Y is formula (II) or optionally substituted phenyl; Y1 is formula (III) or optionally substituted phenyl; Y2 is formula (IV) or optionally substituted phenyl; Y3 is formula (V) or optionally substituted phenyl; R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 independently of each other are hydrogen, halogen, optionally substituted C1-C20alkyl, or R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 independently of each other are optionally substituted C6-C14aryl, provided that only one of R2, R3, R4 is hydrogen and only one of R5, R6, R7 is hydrogen and only one of R8, R9, R10 is hydrogen and only one of R11, R12, R13 is hydrogen; and (ii) at least one chelate ligand compound of the formula IIa, IIb or IIc, wherein Y′ is formula (VI) or formula (VII); Y′1 is formula (VIII) or formula (IX); R′2, R′3, R′4, R′5, R′6 and R′7 independently of each other have on of the meanings as given for R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13; and R′14, R′15 and R′16 independently of each other have on of the meanings as given for R14, R15 and R16.

    Oxime Derivatives And Use Thereof As Latent Acids
    10.
    发明申请
    Oxime Derivatives And Use Thereof As Latent Acids 有权
    肟衍生物及其用作潜伏酸

    公开(公告)号：US20080085458A1

    公开(公告)日：2008-04-10

    申请号：US11632687

    申请日：2005-07-11

    申请人： Hitoshi Yamato ,  Toshikage Asakura ,  Tobias Hintermann

    发明人： Hitoshi Yamato ,  Toshikage Asakura ,  Tobias Hintermann

    IPC分类号： C07C291/06 ,  C07D209/56 ,  G03F1/00

    CPC分类号： C07C309/67 ,  B33Y70/00 ,  C07C309/65 ,  C07C309/73 ,  C07C309/74 ,  C07C309/75 ,  C07C381/00 ,  C07C2603/18 ,  C07C2603/20 ,  C07C2603/66 ,  C07D209/86 ,  C07F9/097 ,  G03F7/0007 ,  G03F7/0045 ,  G03F7/0382 ,  G03F7/0392 ,  Y10S430/12

    摘要： The invention pertain to novel photoacid generator compounds of the formula I, II or III wherein R1 is for example C1-C18alkylsulfonyl or phenylsulfonyl, phenyl-C1-C3alkylsulfonyl, naphthylsulfonyl, anthracylsulfonyl or phenanthrylsulfonyl, all optionally substituted, or R1 is a group X1, X2 and X3 independently of each other are O or S; R′1, is e.g. phenylenedisulfonyl, naphthylenedisulfonyl, diphenylenedisulfonyl, or oxydiphenylenedisulfonyl, all optionally substituted; R2 is halogen or C1-C10haloalkyl; X is halogen; Ar1 is for example biphenylyl or fluorenyl, or is substituted naphthyl; Ar′1 is heteroarylene, optionally substituted; R8, R9, R10 and R11 for example are C1-C6alkyl which is unsubstituted or substituted by halogen; or R8, R9 and R10 are phenyl which is unsubstituted or substituted by C1-C4alkyl or halogen; or R10 and R11 together are 1,2-phenylene or C2-C6alkylene which is unsubstituted or substituted by C1-C4alkyl or halogen.

    摘要翻译： 本发明涉及式I，II或III的新型光酸产生剂化合物，其中R 1是例如C 1 -C 18烷基磺酰基或 苯基磺酰基，苯基-C 1 -C 3烷基磺酰基，萘基磺酰基，蒽基磺酰基或菲基磺酰基，全部任意取代，或R 1是基团X， X 1，X 2和X 3 3彼此独立地为O或S; R'1，例如， 亚苯基二磺酰基，亚苯基二磺酰基，二苯基二磺酰基或氧基二苯基二磺酰基，全部任选被取代; R 2是卤素或C 1 -C 10卤代烷基; X是卤素; Ar 1是例如联苯基或芴基，或者是取代的萘基; Ar'1'是亚杂芳基，任选被取代; R 8，R 9，R 10和R 11是例如C 1〜N 未取代或被卤素取代的C 1 -C 6烷基; 或R 8，R 9和R 10是未被取代或被C 1 -C 3烷基取代的苯基， 烷基或卤素; 或R 10和R 11一起是1,2-亚苯基或C 2 -C 6 -C 6亚烷基，其是 未取代或被C 1 -C 4烷基或卤素取代。