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公开(公告)号：US20120316297A1
公开(公告)日：2012-12-13
申请号：US13200144
申请日：2011-09-19
申请人： Peter Phung Minh Hoang , Benjamin Milton Shaw , Victoria Ker , Cliff Robert Baar , Lee Douglas Henderson , Charles Ashton Garret Carter , Yan Jiang
发明人： Peter Phung Minh Hoang , Benjamin Milton Shaw , Victoria Ker , Cliff Robert Baar , Lee Douglas Henderson , Charles Ashton Garret Carter , Yan Jiang
IPC分类号： C08F110/02 , C08F210/16 , C08F4/54 , C08F4/18 , C08F4/00 , C08F4/76
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65916 , C08F110/02 , C08F210/16 , C08F2410/01 , C08F2420/04 , Y10S526/943 , C08F2500/03 , C08F2500/10 , C08F2500/12 , C08F2500/26 , C08F210/14 , C08F2/34 , C08F10/00 , C08F4/6592
摘要： Olefin polymerization is carried out with a supported phosphinimine catalyst which has been treated with a long chain substituted amine compound.
摘要翻译： 烯烃聚合用已经用长链取代的胺化合物处理的负载的膦亚胺催化剂进行。
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公开(公告)号：US08952111B2
公开(公告)日：2015-02-10
申请号：US13200144
申请日：2011-09-19
申请人： Peter Phung Minh Hoang , Benjamin Milton Shaw , Patrick Lam , Victoria Ker , Cliff Robert Baar , Lee Douglas Henderson , Charles Ashton Garret Carter , Yan Jiang
发明人： Peter Phung Minh Hoang , Benjamin Milton Shaw , Patrick Lam , Victoria Ker , Cliff Robert Baar , Lee Douglas Henderson , Charles Ashton Garret Carter , Yan Jiang
IPC分类号： C08F4/649 , C08F4/642 , C08F4/6592 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/659
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65916 , C08F110/02 , C08F210/16 , C08F2410/01 , C08F2420/04 , Y10S526/943 , C08F2500/03 , C08F2500/10 , C08F2500/12 , C08F2500/26 , C08F210/14 , C08F2/34 , C08F10/00 , C08F4/6592
摘要： Olefin polymerization is carried out with a supported phosphinimine catalyst which has been treated with a long chain substituted amine compound.
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公开(公告)号：US20120259070A1
公开(公告)日：2012-10-11
申请号：US13429590
申请日：2012-03-26
IPC分类号： C08L23/20 , C08F4/6592 , C08L81/06 , C08F4/76
CPC分类号： C08F210/16 , B01J31/188 , B01J31/2243 , B01J2531/40 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F2420/04 , C08F2/005 , C08F210/14 , C08F4/6592 , C08F4/65904 , C08F4/64048
摘要： A dual catalyst system comprising a phosphinimine ligand containing catalyst and phenoxide ligand (preferably a salicylaldimine) on a support treated with a metal salt has improved reactor continuity in a dispersed phase reaction in terms of initial activation and subsequent deactivation The resulting catalyst has a lower consumption of ethylene during initiation and a lower rate of deactivation. Preferably the catalyst is used with an antistatic agent.
摘要翻译： 在由金属盐处理的载体上含有含膦基亚胺配体的催化剂和苯酚配体（优选水杨醛亚胺）的双催化剂体系在初始活化和随后的失活方面改善了分散相反应中的反应器连续性。所得催化剂具有较低的消耗 的乙烯和较低的失活速率。 优选地，催化剂与抗静电剂一起使用。
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公开(公告)号：US20120259080A1
公开(公告)日：2012-10-11
申请号：US13430070
申请日：2012-03-26
CPC分类号： C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F210/16 , C08F2420/04 , C08F210/14 , C08F4/6592 , C08F10/06 , C08F2/002
摘要： A supported catalyst system comprising a phosphinimine ligand containing catalyst on an alumina support treated with a metal salt has improved reactor continuity in a dispersed phase reaction in terms of initial activation and subsequent deactivation. The resulting catalyst has a lower consumption of ethylene during initiation and a lower rate of deactivation. Preferably the catalyst is used with an antistatic agent.
摘要翻译： 包含在金属盐处理的氧化铝载体上的含有次膦基亚胺配体的催化剂载体的催化剂体系在初始活化和随后的失活方面改善了分散相反应中的反应器连续性。 所得催化剂在引发期间乙烯消耗量较低，失活速率较低。 优选地，催化剂与抗静电剂一起使用。
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公开(公告)号：US08846811B2
公开(公告)日：2014-09-30
申请号：US13429590
申请日：2012-03-26
IPC分类号： C08L23/20 , C08L81/06 , C08F4/6592 , C08F4/76 , C08F210/16 , C08F10/00 , C08F4/659
CPC分类号： C08F210/16 , B01J31/188 , B01J31/2243 , B01J2531/40 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F2420/04 , C08F2/005 , C08F210/14 , C08F4/6592 , C08F4/65904 , C08F4/64048
摘要： A dual catalyst system comprising a phosphinimine ligand containing catalyst and phenoxide ligand (preferably a salicylaldimine) on a support treated with a metal salt has improved reactor continuity in a dispersed phase reaction in terms of initial activation and subsequent deactivation The resulting catalyst has a lower consumption of ethylene during initiation and a lower rate of deactivation. Preferably the catalyst is used with an antistatic agent.
摘要翻译： 在由金属盐处理的载体上含有含膦基亚胺配体的催化剂和苯酚配体（优选水杨醛亚胺）的双催化剂体系在初始活化和随后的失活方面改善了分散相反应中的反应器连续性。所得催化剂具有较低的消耗 的乙烯和较低的失活速率。 优选地，催化剂与抗静电剂一起使用。
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公开(公告)号：US08802584B2
公开(公告)日：2014-08-12
申请号：US13430909
申请日：2012-03-27
CPC分类号： C08F210/16 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F210/14 , C08F4/659
摘要： A supported catalyst system comprising a phosphinimine ligand containing catalyst on a porous inorganic support treated with a metal salt has improved reactor continuity in a dispersed phase reaction in terms of initial activation and subsequent deactivation. The resulting catalyst has a lower consumption of ethylene during initiation and a lower rate of deactivation. Preferably the catalyst is used with an antistatic agent.
摘要翻译： 包含在金属盐处理的多孔无机载体上的含有膦亚胺配体的催化剂的负载催化剂体系在初始活化和随后的失活方面改善了分散相反应中的反应器连续性。 所得催化剂在引发期间乙烯消耗量较低，失活速率较低。 优选地，催化剂与抗静电剂一起使用。
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公开(公告)号：US09115224B2
公开(公告)日：2015-08-25
申请号：US13430070
申请日：2012-03-26
CPC分类号： C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F210/16 , C08F2420/04 , C08F210/14 , C08F4/6592 , C08F10/06 , C08F2/002
摘要： A supported catalyst system comprising a phosphinimine ligand containing catalyst on an alumina support treated with a metal salt has improved reactor continuity in a dispersed phase reaction in terms of initial activation and subsequent deactivation. The resulting catalyst has a lower consumption of ethylene during initiation and a lower rate of deactivation. Preferably the catalyst is used with an antistatic agent.
摘要翻译： 包含在金属盐处理的氧化铝载体上的含有次膦基亚胺配体的催化剂载体的催化剂体系在初始活化和随后的失活方面改善了分散相反应中的反应器连续性。 所得催化剂在引发期间乙烯消耗量较低，失活速率较低。 优选地，催化剂与抗静电剂一起使用。
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公开(公告)号：US20120259081A1
公开(公告)日：2012-10-11
申请号：US13430909
申请日：2012-03-27
CPC分类号： C08F210/16 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F210/14 , C08F4/659
摘要： A supported catalyst system comprising a phosphinimine ligand containing catalyst on a porous inorganic support treated with a metal salt has improved reactor continuity in a dispersed phase reaction in terms of initial activation and subsequent deactivation. The resulting catalyst has a lower consumption of ethylene during initiation and a lower rate of deactivation. Preferably the catalyst is used with an antistatic agent.
摘要翻译： 包含在金属盐处理的多孔无机载体上的含有膦亚胺配体的催化剂的负载催化剂体系在初始活化和随后的失活方面改善了分散相反应中的反应器连续性。 所得催化剂在引发期间乙烯消耗量较低，失活速率较低。 优选地，催化剂与抗静电剂一起使用。
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公开(公告)号：US08252955B2
公开(公告)日：2012-08-28
申请号：US12584173
申请日：2009-09-01
CPC分类号： B01J31/188 , B01J31/143 , B01J2231/20 , B01J2531/46 , B01J2531/56 , B01J2531/62 , B01J2531/66 , B01J2531/847 , B01J2540/22 , C07C2/32 , C07C2/36 , C07C2531/14 , C07C2531/22 , C07C2531/24 , C07F9/46
摘要： A new P—N—P ligand is useful in ethylene oligomerizations. In combination with i) a source of chromium and ii) an activator such as methylalumoxane; the ligand of this invention may be used to prepare an oligomer product that contains a mixture of hexenes and octenes. The hexenes and octenes produced with this ligand contain very low levels of internal olefins when produced under preferred reaction conditions.
摘要翻译： 新的P-N-P配体可用于乙烯低聚。 与i）铬源和ii）活化剂如甲基铝氧烷; 本发明的配体可用于制备含有己烯和辛烯的混合物的低聚物产物。 当在优选的反应条件下产生时，用该配体产生的己烯和辛烯含有非常低水平的内烯烃。
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公开(公告)号：US20100081777A1
公开(公告)日：2010-04-01
申请号：US12584170
申请日：2009-09-01
CPC分类号： C07F9/46 , B01J31/189 , B01J2231/20 , B01J2531/007 , B01J2531/62 , C07C2/32 , C07C2/36 , C07C2531/14 , C07C2531/22 , C07C2531/24 , C08F4/69 , C08F10/00 , C08F110/02 , C08F2500/02 , C08F4/69146 , C08F4/69267
摘要： A new P—N—P ligand is useful in ethylene oligomerizations. In combination with i) a source of chromium and ii) an activator such as methylalumoxane; the ligand of this invention may be used to prepare an oligomer product that contains a mixture of hexenes and octenes. The hexenes and octenes produced with this ligand contain very low levels of internal olefins when produced under preferred reaction conditions.
摘要翻译： 新的P-N-P配体可用于乙烯低聚。 与i）铬源和ii）活化剂如甲基铝氧烷; 本发明的配体可用于制备含有己烯和辛烯的混合物的低聚物产物。 当在优选的反应条件下产生时，用该配体产生的己烯和辛烯含有非常低水平的内烯烃。
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