Sulfonamide herbicides
    2.
    发明授权
    Sulfonamide herbicides 失效
    磺酰胺除草剂

    公开(公告)号:US5559081A

    公开(公告)日:1996-09-24

    申请号:US232297

    申请日:1994-05-06

    摘要: Herbicidal sulfonamides of the formula: ##STR1## and salts thereof, where: A represents a substituted or unsubstituted benzene ring, or a 5- or 6-membered substituted or unsubstituted heteroaromatic ring; Q is --O--, --S-- or a group --CXX'--; X and X', which may be the same or different, are each hydrogen, halogen, cyano, an optionally-substituted alkyl group, or a group --OR.sup.a, --SR.sup.a, or --COR.sup.b ; or one of X and X' represents hydroxy and the other is as defined above; or X and X' together represent .dbd.O or .dbd.S; R.sup.a is an optionally-substituted alkyl, aryl or acyl group; R.sup.b is an optionally-substituted alkyl or aryl group, or a group --OR.sup.c or --NR.sup.c R.sup.d ; R.sup.c and R.sup.d, which may be the same or different, are each hydrogen, or an optionally-substituted alkyl or aryl group; Y is nitrogen or a group CR.sup.9 ; R.sup.1 is an optionally-substituted alkyl, alkenyl, alkynyl, cycloalkyl, aryl, heterocyclyl, benzoheterocyclyl or amino group; R.sup.2 is hydrogen, an optionally-substituted alkyl or carboxylic acyl group, or a group --SO.sub.2 R.sup.1 ; R.sup.3 and R.sup.4, which may be the same or different, are each hydrogen, halo, an optionally substituted alkyl, alkoxy, cycloalkyl or amino group, or an optionally-substituted heterocyclyl group; and R.sup.9 represents hydrogen or an optionally-substituted alkyl group.

    摘要翻译: PCT No.PCT / EP92 / 02558 Sec。 371日期:1994年5月6日 102(e)日期1994年5月6日PCT提交1992年11月2日PCT公布。 第WO93 / 09099号公报 日期:1993年5月13日具有下式的除草磺酰胺:其中:A表示取代或未取代的苯环,或5或6元取代或未取代的杂芳环; Q是-O - , - S-或基团-CXX'-; X和X'可以相同或不同,各自为氢,卤素,氰基,任选取代的烷基或基团-OR,-SRa或-CORb; 或X和X'之一表示羟基,另一个如上所定义; 或X和X'代表= O或= S; R a是任选取代的烷基,芳基或酰基; Rb是任选取代的烷基或芳基,或基团-OR c或-NR c R d; Rc和R d可以相同或不同,各自为氢或任选取代的烷基或芳基; Y为氮或CR9基; R 1是任选取代的烷基,烯基,炔基,环烷基,芳基,杂环基,苯并杂环基或氨基; R 2是氢,任选取代的烷基或羧基酰基,或基团-SO 2 R 1; R 3和R 4可以相同或不同,各自为氢,卤素,任选取代的烷基,烷氧基,环烷基或氨基,或任选取代的杂环基; 并且R 9表示氢或任选取代的烷基。

    Process for preparing pyrogallol
    3.
    发明授权
    Process for preparing pyrogallol 失效
    连苯三酚的制备方法

    公开(公告)号:US4172960A

    公开(公告)日:1979-10-30

    申请号:US862989

    申请日:1977-12-20

    摘要: Pyrogallol is prepared by (A) reacting a halo compound of formula ##STR1## where X represents Br or I, R.sup.1 represents hydrogen, secondary or tertiary alkyl of up to 10 carbon atoms, carboxy or alkoxycarbonyl of 2-5 carbon atoms and R.sup.2 represents hydrogen or alkyl of 1-4 carbon atoms, with an alkali metal alkoxide of formula ROM where M represents an alkali metal and R represents alkyl of 1-4 carbon atoms, to replace each X by OR, and then (B) dealkylating each OR and each OR.sup.2 where R.sup.2 represents alkyl of 1-4 carbon atoms and removing the R.sup.1 group where this is not hydrogen.

    摘要翻译: 通过(A)使式(IMAGE)的卤代化合物(其中X代表Br或I,R1代表氢,至多10个碳原子的仲或叔烷基,2-5个碳原子的羧基或烷氧基羰基)和R2代表 氢或1-4个碳原子的烷基与式ROM的碱金属醇盐,其中M表示碱金属,R表示1-4个碳原子的烷基,以将每个X替换为OR,然后(B)将每个OR 和每个OR 2,其中R 2表示1-4个碳原子的烷基,并除去其中不是氢的R 1基团。

    Pyrimidine derivatives herbicides

    公开(公告)号:US5604181A

    公开(公告)日:1997-02-18

    申请号:US397123

    申请日:1995-03-08

    摘要: Herbicidal compounds of formula (I) and salts thereof, where A is --N.dbd. or --CH.dbd.; X is --OH, --OR.sup.10, --SH, --SR.sup.10, --SCN, NH.sub.2, --NHacyl, --CH.sub.2 OH, --CH.sub.2 OR.sup.9 or --CN; R.sup.1 and R.sup.2, which may be the same or different, each represent alkyl, alkoxy, haloalkyl, haloalkoxy, halo, alkylamino or dialkylamino; R.sup.3 is --CN, --COOR.sup.5, --CONR.sup.6 R.sup.7, --CSNH.sub.2, --CHO, --CH.dbd.Z, --CH(Oalkyl).sub.2, --CH.sub.2 OH, --CH.sub.2 OR.sup.9, --COSR.sup.4a, --CS.sub.2 R.sup.4a, or a substituted or unsubstituted 5- or 6-membered heterocyclic group linked via a ring carbon atom which is between two ring heteroatoms; R.sup.4 and R.sup.4a, which may be the same or different, are each H, or a substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, aryl, aralkyl or heteroaryl group; R.sup.5 is H, or a substituted or unsubstituted alkyl, alkenyl, alkynyl, cycoalkyl, aryl, aralkyl or heteroaryl group, or a group of formula (II) where B and D are each alkyl, or together with the carbon atom to which they are attached form a 5-, 6- or 7-membered carbocyclic or heterocyclic ring; R.sup.6 is a group as defined for R.sup.4a, and R.sup.7 is a group as defined for R.sup.4a or is --SO.sub.2 R.sup.8, --OH, --CN, --OR.sup.10, --NH.sub.2 or --NHR.sup.10 ; or R.sup.6 and R.sup.7 together form a ring; R.sup.8 is a substituted or unsubstituted alkyl alkenyl, alkynyl, cycloalkyl, aralkyl, aryl or heteroaryl group, or a group --NR.sup.4b R.sup.4c where R.sup.4b and R.sup.4c, which may be the same or different, are each a group as defined for R.sup.4a, or together form a ring; R.sup.9 is a substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, aralkyl or acyl group; R.sup.10 is a substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, aryl, aralkyl, heteroaryl or acyl group; Z is .dbd.NOR.sup.4a or .dbd.N--NR.sup.4d R.sup.12, where R.sup.4d is a group as defined for R.sup.4a, and R.sup.1 is a group as defined for R.sup.4a or is a substituted or unsubstituted acyl group, or R.sup.4d and R.sup.12 together form a ring; with the proviso that, when R.sup.4 is ortho-substituted phenyl or naphthyl, any ortho-substituent thereon is halogen, --NO.sub.2, --OH, --OR.sup.10, --SH, --SR.sup.8, --SOR.sup.8, --SO.sub.2 R.sup.8, --NH.sub.2, --NR.sup.6 R.sup.10, aryl or heteroaryl.

    Herbicides
    5.
    发明授权
    Herbicides 失效
    除草剂

    公开(公告)号:US5401710A

    公开(公告)日:1995-03-28

    申请号:US87691

    申请日:1993-07-09

    申请人: Peter S. Gates

    发明人: Peter S. Gates

    摘要: Herbicidal compositions which comprise one or more compounds of the formula: ##STR1## or salts thereof, where: A is --CH.dbd. or --N.dbd.;R.sup.1 is alkyl, alkoxy, halo or --NR.sup.7 R.sup.8 ;R.sup.2 is alkyl or alkoxy;R.sup.3 is hydrogen, alkenyl or alkynyl, or substituted or unsubstituted alkyl, alkanoyl or alkoxycarbonyl;R.sup.4 is hydrogen or substituted or unsubstituted alkyl;R.sup.5 is halo or substituted or unsubstituted alkyl or aryl; andX is --CO.sub.2 R.sup.6, --CONR.sup.7 R.sup.8 or --CN;in which R.sup.6, R.sup.7 and R.sup.8, which may be the same or different, each represent hydrogen, substituted or unsubstituted alkyl, or one of R.sup.7 and R.sup.8 represents substituted amino;in association with a suitable carrier and/or surface active agent, together with the compounds of formula I per se where R.sup.5 represents isopropyl, and/or X represents methoxycarbonyl, and salts thereof.

    摘要翻译: PCT No.PCT / GB92 / 00018 Sec。 371日期:1993年7月9日 102(e)日期1993年7月9日PCT提交1992年1月6日PCT公布。 WO92 / 11763 PCT出版物 日期:1992年7月23日。包含一种或多种下式的化合物或其盐的杀真菌组合物:其中:A为-CH =或-N =; R1是烷基,烷氧基,卤素或-NR7R8; R2是烷基或烷氧基; R3是氢,烯基或炔基,或取代或未取代的烷基,烷酰基或烷氧基羰基; R4是氢或取代或未取代的烷基; R5是卤素或取代或未取代的烷基或芳基; 且X为-CO 2 R 6,-CONR 7 R 8或-CN; 其中可以相同或不同的R 6,R 7和R 8各自表示氢,取代或未取代的烷基,或者R 7和R 8中的一个表示取代的氨基; 与合适的载体和/或表面活性剂以及其中R 5表示异丙基的式I化合物,和/或X表示甲氧基羰基,以及其盐。

    Herbicidally-active sulphonates
    7.
    发明授权

    公开(公告)号:US4162154A

    公开(公告)日:1979-07-24

    申请号:US875189

    申请日:1978-02-03

    摘要: The invention provides herbicidally-active sulphonates of the formula ##STR1## wherein X represents a group --CHR.sup.3 --OR.sup.4 and Y represents a group --OR.sup.5, or X and Y together represent a group --CHR.sup.3 --O-- or a group --CHR.sup.3 --O--Z--O--, the free oxygen atom of which is attached to the benzene ring; R.sup.1, R.sup.2 and R.sup.3, which may be the same or different, each represent hydrogen or C 1 to 6 alkyl, or R.sup.1 and R.sup.2 together or R.sup.2 and R.sup.3 together form a C 3 to 6 alkylene chain; R.sup.4 and R.sup.5, which may be the same or different, each represent hydrogen, C 1 to 6 alkyl, C 2 to 6 alkenyl, C 2 to 6 alkynyl, phenyl, a group --O(.dbd.O)R.sup.10 or a group --SO.sub.2 R.sup.11 ; R.sup.6, R.sup.7 and R.sup.8, which may be the same or different, each represent hydrogen, C 1 to 6 alkyl, halogen, cyano, C 2 to 6 carboxylic acyl, or C 1 to 4 alkoxy; R.sup.9 represents C 1 to 6 alkyl, phenyl or C 7 to 10 phenylalkyl (each of which may be unsubstituted or substituted by one or more chlorine or bromine atoms, C 1 to 4 alkyl groups, C 1 to 4 alkoxy groups or nitro groups), C 5 to 7 cycloalkyl, C 1 to 4 alkylamino, or dialkylamino wherein each alkyl moiety has from 1 to 4 carbon atoms; R.sup.10 represents C 1 to 6 alkyl or alkoxy, C 2 to 6 alkenyl or alkenyloxy, C 2 to 6 alkynyl or alkynyloxy, phenyl, phenoxy, phenylamino, C 1 to alkylamino alylamino or dialkylamino wherein each alkyl moiety has from 1 to 6 carbon atoms, each of the groups which R.sup.10 may represent being unsubstituted or substituted by one or more halogen atoms or C 1 to 4 alkoxy groups; R.sup.11 represents C 1 to 6 alkyl, phenyl, C 1 to 6 alkylamino or dialkylamino each of the alkyl moieties thereof having from 1 to 6 carbon atoms, each of the groups which R.sup.11 may represent being unsubstituted or substituted by one or more halogen atoms or C 1 to 4 alkoxy groups; Z represents a group of formula--S(.dbd.O)n, --CR.sup.12 R.sup.13 or --P(.dbd.Q)(OR.sup.14)--;n represents 1 or 2; R.sup.12 and R.sup.13, which may be the same or different, each represent hydrogen, C 1 to 6 alkyl or alkoxy, C 2 to 6 alkenyl or alkynyl, phenyl, phenoxy, cyano or (C 1 to 6 alkoxy)carbonyl, or R.sup.12 and R.sup.13 together represent an oxygen atom, a sulphur atom, a C 3 to 6 alkylene chain or a C 1 to 6 alkylimino group or a phenylimino group; and R.sup.14 represents C 1 to 6 alkyl; and Q represents oxygen or sulphur, together with processes for their preparation and herbicidal compositions containing them.

    Herbicides
    9.
    发明授权
    Herbicides 失效
    除草剂

    公开(公告)号:US4795483A

    公开(公告)日:1989-01-03

    申请号:US43370

    申请日:1987-04-28

    申请人: Peter S. Gates

    发明人: Peter S. Gates

    CPC分类号: C07D513/04 A01N43/90

    摘要: The invention provides certain herbicidal thiazolotriazole sulphonamides, processes for their preparation, and compositions containing them, the compounds being of the formula: ##STR1## where: R.sup.1 and R.sup.2, which may be the same or different, each represent hydrogen, hydroxy, halo, cyano, substituted or unsubstituted alkyl, alkoxy, alkenyloxy, alkynyloxy, aryl, aralkyl, heteroaryl or carbamoyl, or a group --COR.sup.a or --CO.sub.2 R.sup.a or where R.sup.a is hydrogen or alkyl; or R.sup.1 and R.sup.2 together represent an alkylene chain of 3 or 4 carbon atoms;R.sup.3 represents a substituted or unsubstituted aryl, heterocyclyl or benzheterocyclyl group; andR.sup.4 represents hydrogen, an alkali-metal atom, an ammonium group, a substituted or unsubstituted alkyl, alkenyl, alkynyl, acyl, alkoxycarbonyl or aralkyl group, a heterocyclic group, or a group of the formula: ##STR2## where R.sup.1 and R.sup.2 are as defined hereinbefore.

    摘要翻译: 本发明提供了某些除草噻唑并三唑磺酰胺,其制备方法和含有它们的组合物,该化合物具有下式:其中:R 1和R 2可以相同或不同,各自代表氢,羟基 卤素,氰基,取代或未取代的烷基,烷氧基,烯氧基,炔氧基,芳基,芳烷基,杂芳基或氨基甲酰基,或基团-CORa或-CO 2 R a,或其中R a为氢或烷基; 或R 1和R 2一起表示3或4个碳原子的亚烷基链; R3表示取代或未取代的芳基,杂环基或苯并杂环基; 和R 4表示氢,碱金属原子,铵基,取代或未取代的烷基,烯基,炔基,酰基,烷氧基羰基或芳烷基,杂环基或下式的基团:其中 R1和R2如上文所定义。

    Fungicidal and plant growth regulant triazole and imidazole sulfide
compounds
    10.
    发明授权
    Fungicidal and plant growth regulant triazole and imidazole sulfide compounds 失效
    杀菌剂和植物生长调节剂三唑和咪唑硫化物

    公开(公告)号:US4549027A

    公开(公告)日:1985-10-22

    申请号:US479060

    申请日:1983-03-25

    申请人: Peter S. Gates

    发明人: Peter S. Gates

    摘要: Compounds of formula ##STR1## where Az is 1-imidazolyl or 1-(1,2,4-triazolyl); R.sup.1 is aryl or optionally substituted alkyl; R.sup.2 and R.sup.3, which may be the same or different, are hydrogen or alkyl or, together with the carbon to which they are attached, form a 5 to 7 membered ring which may contain one or more oxygen atoms and which may be substituted, or when Az is 1-(1,2,4-triazolyl) can together with the carbon to which they attached form a carbonyl group; R.sup.4 is aryl, substituted alkyl or aryloxy, or when R.sup.2 and R.sup.3 form an oxygen containing ring, can be hydrogen or unsubstituted alkyl; and n is 0, 1 or 2; together with acid addition salts, quaternary ammonium salts and complexes of these compounds with metal salts have fungicidal and plant growth regulant activity.

    摘要翻译: 其中Az为1-咪唑基或1-(1,2,4-三唑基)的式(Ⅰa)化合物; R1是芳基或任选取代的烷基; R 2和R 3可以相同或不同,为氢或烷基,或与它们所连接的碳一起形成可含有一个或多个氧原子且可被取代的5至7元环,或 当Az为1-(1,2,4-三唑基)时,它们与它们所连接的碳一起形成羰基; R 4是芳基,取代的烷基或芳氧基,或当R 2和R 3形成含氧环时,可以是氢或未取代的烷基; 且n为0,1或2; 与酸加成盐,这些化合物与金属盐的季铵盐和络合物具有杀真菌和植物生长调节活性。