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公开(公告)号：US4126644A
公开(公告)日：1978-11-21
申请号：US732235
申请日：1976-10-14
IPC分类号： C10G35/095 , C10G59/06 , C10L1/06 , C07C3/62 , C07C1/02
CPC分类号： C10G59/06 , C10G35/095 , C10L1/06 , Y10S208/95
摘要： The product of Fischer-Tropsch synthesis is separated to recover a C.sub.5 -400.degree. F liquid fraction which is thereafter upgraded to a higher octane gasoline fraction and a low-pour, high diesel index fuel oil by a "dense phase" process using HZSM-5 and related zeolites as catalysts.
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公开(公告)号：US4111792A
公开(公告)日：1978-09-05
申请号：US767876
申请日：1977-02-11
IPC分类号： C10G35/095 , C10G59/06 , C10L1/06 , C07C15/02 , C10G37/02
CPC分类号： C10G59/06 , C10G35/095 , C10L1/06 , Y10S208/95
摘要： Fischer-Tropsch synthol naptha is upgraded to high octane gasoline with minimum yield loss in a multistep process comprising fractionating the synthol naptha to give a C.sub.5 + C.sub.6 fraction and C.sub.7.sup.+ fraction, processing the C.sub.5 + C.sub.6 fraction over a ZSM-5 catalyst under dense phase conditions, pretreating and reforming the C.sub.7.sup.+ fraction under conventional conditions, and blending the C.sub.5.sup.+ products from both the C.sub.5 + C.sub.6 and C.sub.7.sup.+ processing steps.
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公开(公告)号：US4049734A
公开(公告)日：1977-09-20
申请号：US566149
申请日：1975-04-08
CPC分类号： C10L1/06 , C07C2/62 , Y02P20/125 , Y10S585/934 , Y10S585/943
摘要： An integrated process for converting coal to high octane gasoline by gasifying the coal in such manner as to form a gas comprising carbon oxides, hydrogen and methane; contacting this gas in one or a series of steps with one or a series of catalysts, respectively comprising a special high silica to alumina ratio zeolite; converting the carbon oxides and hydrogen by such contact to a product comprising water, high octane aromatic gasoline and light hydrocarbon gases; alkylating the C.sub.3 and C.sub.4 olefins with the isobutane in the light gases to produce alkylate gasoline; admixing the aromatic and alkylate gasolines; and subjecting the C.sub.2.sup.- portion of the product to catalytic methanation via a nickel catalyst to produce synthetic natural gas.
摘要翻译： 通过气化煤以形成包含碳氧化物，氢气和甲烷的气体的方式将煤转化为高辛烷值汽油的综合方法; 将该气体与一种或一系列催化剂在一个或一系列步骤中接触，分别包含特殊的高二氧化硅与氧化铝比的沸石; 通过这样的接触将碳氧化物和氢气转化为包含水，高辛烷值芳烃汽油和轻烃气体的产品; 在轻质气体中用异丁烷烷基化C3和C4烯烃以产生烷基化汽油; 混合芳族和烷基化汽油; 并使产物的C2部分经由镍催化剂进行催化甲烷化以产生合成天然气。
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公开(公告)号：US3965205A
公开(公告)日：1976-06-22
申请号：US477728
申请日：1974-06-10
IPC分类号： C10G3/00 , C10G35/095 , C07C15/00
CPC分类号： C10G3/45 , C10G3/49 , C10G35/095 , C10G2300/1037 , C10G2300/305 , C10G2300/4018 , C10G2400/02 , C10G2400/06 , Y02P30/20 , Y10S585/943
摘要： It is known to convert methanol and/or other relatively low molecular weight organic compounds containing at least one oxygen, sulfur, nitrogen or halogen hetero atom to high octane gasoline by contacting such with a particular group of crystalline aluminosilicate zeolites at conversion conditions. The instant disclosure shows improvements in total gasoline production from such process by inclusion of natural gas liquid or other light hydrocarbons having low octane numbers, preferably paraffinic, in the feed to said process thereby converting at least a portion of these lighter materials as well to high octane gasoline boiling range components.
摘要翻译： 已知通过在转化条件下与特定的结晶硅铝酸盐基团接触，将含有至少一个氧，硫，氮或卤素杂原子的甲醇和/或其它相对低分子量的有机化合物转化成高辛烷值汽油。 本公开显示通过在所述方法的进料中包含天然气液体或具有低辛烷值（优选链烷烃）的其它轻质烃的天然气液体或其他轻烃，从而将这些较轻材料的至少一部分转化为高 辛烷值汽油沸程组分。
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公开(公告)号：US4048250A
公开(公告)日：1977-09-13
申请号：US566168
申请日：1975-04-08
IPC分类号： C07C29/151 , C10G3/00 , C10L1/06 , C07C3/52 , C07C3/54
CPC分类号： C10L1/06 , C07C29/1518 , C10G3/45 , C10G3/47 , C10G3/49 , C10G2300/1022 , C10G2300/1025 , C10G2300/4018 , C10G2300/4081 , C10G2300/807 , C10G2400/02 , C10G2400/28 , Y02P20/52 , Y02P30/20 , Y10S585/934 , Y10S585/943
摘要： Natural gas is steam reformed to a mixture of carbon monoxide, carbon dioxide and hydrogen which mixture is converted, over a methanol synthesis catalyst, to a mixture of methanol, carbon oxides and hydrogen which methanol is converted to C.sub.5.sup.+ hydrocarbon gasoline, light gas and water, the water is separated out and may be recycled as steam, the portion of the hydrocarbon fraction which comprises light olefins and isobutane is subjected to acid alkylation to product very high octane hydrocarbon gasoline which is admixed with the C.sub.5.sup.+ hydrocarbon gasoline from the methanol conversion. The light fuel gas (C.sub.1 to C.sub.2) produced in the methanol conversion is recycled to the steam reformer and the LPG (C.sub.3 + C.sub.4) produced therein is recovered and sold.
摘要翻译： 天然气是通过甲醇合成催化剂将混合物转化成一氧化碳，二氧化碳和氢气的混合物，转化为甲醇，碳氧化物和氢气的混合物，甲醇转化成C5 +烃汽油，轻质气体和水 ，水分离出来，可以作为蒸汽再循环，将含有轻质烯烃和异丁烷的烃馏分部分进行酸式烷基化，生成与甲醇转化成的C5 +烃汽油混合的高辛烷值汽油。 在甲醇转化中生产的轻质燃料气体（C1至C2）被再循环至蒸汽重整器，回收和销售其中生产的LPG（C3 + C4）。
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公开(公告)号：US4549396A
公开(公告)日：1985-10-29
申请号：US339962
申请日：1982-01-18
IPC分类号： F02B43/08
摘要： Utilizing air, rather than oxygen, to convert coal to synthesis gas containing very high proportions of inert nitrogen; subjecting this entire gas, possibly with intermediate cleanup, e.g., sulfur removal, to conversion over a special metal-zeolite catalyst to produce a product comprising C.sub.5 to C.sub.11 normally liquid hydrocarbons, a gas containing C.sub.1 to C.sub.4 hydrocarbons, carbon dioxide and large proportions of nitrogen, and an aqueous product comprising water; utilizing the gas product to run electric power generation equipment, such as a direct fired turbine, at base load levels; storing and accumulating the liquid product; and intermittently using the liquid product for electric power generation to meet higher than base loads, including peak load situations.
摘要翻译： 利用空气而不是氧将煤转化成含有非常高比例惰性氮的合成气; 对整个气体进行处理，可能进行中间清洗，例如除硫，通过特殊的金属 - 沸石催化剂进行转化，生产出包含C 1到C 11通常为液态烃的产物，含有C1至C4烃的气体，二氧化碳和大比例 氮气和包含水的含水产物; 利用气体产品以基本负载水平运行诸如直接燃烧的涡轮机的发电设备; 储存和积聚液体产品; 并间歇地使用液体产品进行发电，以满足高于基本负载，包括峰值负载情况。
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公开(公告)号：US3972958A
公开(公告)日：1976-08-03
申请号：US566153
申请日：1975-04-08
CPC分类号： C10G29/205 , C01B3/34 , C07C1/0485 , C07C2/62 , C07C29/1518 , C10G2/32 , C10J3/00 , C10K3/006 , C10L1/06 , C01B2203/0233 , C01B2203/062 , C10J2300/093 , C10J2300/0959 , C10J2300/0973 , C10J2300/1659 , Y02P20/125 , Y02P20/52 , Y10S585/905 , Y10S585/943
摘要： An integrated process for converting coal to high octane gasoline by gasifying the coal in such manner as to form a gas comprising carbon oxides, hydrogen and methane; contacting this gas in one or a series of steps with one or a series of catalysts, respectively comprising a special high silica to alumina ratio zeolite; converting the carbon oxides and hydrogen by such contact to a product comprising water, high octane aromatic gasoline and light hydrocarbon gases; alkylating the C.sub.3 and C.sub.4 olefins with the isobutane in the light gases to produce alkylate gasoline; admixing the aromatic and alkylate gasoline; and subjecting the C.sub.2 .sup.- portion of the product to steam reforming whereby additional synthesis gas to be admixed with the gas produced by coal gasification is formed.
摘要翻译： 通过气化煤以形成包含碳氧化物，氢气和甲烷的气体的方式将煤转化为高辛烷值汽油的综合方法; 将该气体与一种或一系列催化剂在一个或一系列步骤中接触，分别包含特殊的高二氧化硅与氧化铝比的沸石; 通过这样的接触将碳氧化物和氢气转化为包含水，高辛烷值芳烃汽油和轻烃气体的产品; 在轻质气体中用异丁烷烷基化C3和C4烯烃以产生烷基化汽油; 混合芳烃和烷基化汽油; 并使产物的C2 - 部分进行蒸汽重整，从而形成与煤气化产生的气体混合的其它合成气。
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公开(公告)号：US3960705A
公开(公告)日：1976-06-01
申请号：US587760
申请日：1975-06-17
申请人： William E. Garwood , John J. Wise
发明人： William E. Garwood , John J. Wise
IPC分类号： C10G35/095 , C10G45/64 , C10G13/02 , C10G41/00 , C10L1/04
CPC分类号： C10G35/095 , C10G2400/10
摘要： Foots oil, the by-product left when high quality wax is recovered by a solvent dewaxing process, is usually used as cracker feed stock. There is disclosed a method of converting it to higher quality lubricant base stock by subjecting such to catalytic hydroprocessing utilizing a ZSM-5 or similarly behaving zeolite catalyst under hydrogen pressure followed by distillation of the product to remove light products such as naphtha, LPG and No. 2 fuel oil therefrom.
摘要翻译： 脚油是通过溶剂脱蜡过程回收高质量蜡时残留的副产物，通常用作裂化剂原料。 公开了通过在氢气压力下使用ZSM-5或类似行为的沸石催化剂进行催化加氢处理，然后蒸馏产物以除去轻质产物如石脑油，LPG和No的方法，将其转化为更高质量的润滑剂基料 2燃料油。
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公开(公告)号：US4101596A
公开(公告)日：1978-07-18
申请号：US758214
申请日：1977-01-10
申请人： Kenneth M. Mitchell , John J. Wise
发明人： Kenneth M. Mitchell , John J. Wise
CPC分类号： C07C5/2737 , Y02P20/52 , Y10S208/02 , Y10S585/954
摘要： Long on-stream periods of low pressure, vapor phase isomerization of xylenes is achieved in a system having tolerance of ethyl benzene in the charge by using a zeolite catalyst such as zeolite ZSM-5 at partial pressure of eight carbon atom aromatics below 100 pounds per square inch and temperature of 500.degree. F. to 800.degree. F.
摘要翻译： 通过使用沸石催化剂如沸石ZSM-5在8碳原子芳族化合物的分压低于100磅/分的系统中，在具有对电荷的乙苯耐受性的系统中实现长时间的二氧化碳气相异构化 平方英寸，温度500°F至800°F
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公开(公告)号：US4041094A
公开(公告)日：1977-08-09
申请号：US614587
申请日：1975-09-18
CPC分类号： C10G59/02 , C10G50/00 , C10G67/02 , C10L1/06 , Y10S208/95
摘要： Upgrading of Fischer-Tropsch synthesis product is obtained by separating a 560.degree. F minus hydrocarbon fraction from gaseous C.sub.5 rich material and a water phase comprising oxygenates. Alcohols may be recovered from the water phase for conversion to gasoline boiling components. C.sub.5 rich material is converted to gasoline boiling material with a ZSM-5 crystalline zeolite and upgrading of the 560.degree. F minus hydrocarbon fraction is accomplished with a ZSM-5 crystalline zeolite catalyst.
摘要翻译： 费 - 托合成产物的升级通过从气态C5富含材料和包含含氧化合物的水相中分离560°F减去烃馏分而获得。 醇可以从水相中回收以转化成汽油沸点组分。 使用ZSM-5结晶沸石将富C5的材料转化为汽油沸腾物质，并用ZSM-5结晶沸石催化剂完成560°F减去烃馏分的升级。
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