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    Method for the production of fibres with a high content of colloidal particles and composite fibres obtained thus
    1.
    发明授权
    Method for the production of fibres with a high content of colloidal particles and composite fibres obtained thus 有权
    用于生产具有高含量胶体颗粒的纤维和由此获得的复合纤维的方法

    公开(公告)号：US07867421B2

    公开(公告)日：2011-01-11

    申请号：US10554911

    申请日：2004-04-28

    申请人： Philippe Poulin ,  Stephane Badaire ,  Cecile Zakri ,  Maryse-Marie-Therese Maugey

    发明人： Philippe Poulin ,  Stephane Badaire ,  Cecile Zakri ,  Maryse-Marie-Therese Maugey

    IPC分类号： D01D5/30 ,  B29C47/88

    CPC分类号： D01D5/00 ,  D01F9/12 ,  Y10T428/2913

    摘要： The invention relates to a method for the production of composite fibers with an increased content of colloidal particles, made from a pre-fiber, comprising a polymeric binder and colloidal particles, during which the chemical structure of the polymeric binder is degraded at a temperature of the order of ambient temperature such as to at least partially eliminate the above. The invention further relates to a fiber comprising a polymeric binder and colloidal particles, combining an excellent mechanical strength and a content of colloidal particles greater than 70% by mass.

    摘要翻译： 本发明涉及一种用于生产具有增加的胶体颗粒含量的复合纤维的方法，所述胶体颗粒由预纤维制成，包括聚合物粘合剂和胶体颗粒，在此期间，聚合物粘合剂的化学结构在 环境温度的顺序，至少部分地消除上述情况。 本发明还涉及包含聚合物粘合剂和胶体颗粒的纤维，其结合优异的机械强度和大于70质量％的胶体颗粒的含量。

    CONTINUOUS METHOD FOR OBTAINING COMPOSITE FIBRES CONTAINING COLLOIDAL PARTICLES AND RESULTING FIBRE
    4.
    发明申请
    CONTINUOUS METHOD FOR OBTAINING COMPOSITE FIBRES CONTAINING COLLOIDAL PARTICLES AND RESULTING FIBRE 审中-公开
    用于获得含有胶体颗粒和结晶纤维的复合纤维的连续方法

    公开(公告)号：US20100196250A1

    公开(公告)日：2010-08-05

    申请号：US12677619

    申请日：2008-03-18

    申请人： Alain Derre ,  Antoine Lucas ,  Philippe Poulin

    发明人： Alain Derre ,  Antoine Lucas ,  Philippe Poulin

    IPC分类号： D01F9/12 ,  D01F1/00

    CPC分类号： D01F9/08 ,  C04B35/62231 ,  C04B35/62245 ,  C04B35/62272 ,  C04B35/62281 ,  C04B35/6229 ,  C04B35/63416 ,  C04B35/636 ,  C04B35/6365 ,  C04B2235/5264 ,  D01D5/06 ,  D01F2/00 ,  D01F9/12

    摘要： The invention relates to a method for obtaining composite fibers, that comprises dispersing colloidal particles in a solvent, injecting the dispersion into a co-flow of a polymer coagulation solution for forming a pre-fiber, circulating the pre-fiber in a duct, extracting, optionally washing and drying the pre-fiber in order to obtain a fiber, and winding the fiber thus obtained, characterized in that the minimum retention time of the fiber within the duct is adjusted so that it has a mechanical strength sufficient to be extracted from the duct, and in that its extraction is vertical and continuous. The invention also relates to composite fibers that can be made according to said method.

    摘要翻译： 本发明涉及一种获得复合纤维的方法，其包括将胶体颗粒分散在溶剂中，将分散体注入聚合物凝结溶液的共流中以形成预纤维，将管道中的预纤维循环，萃取 ，任选地洗涤和干燥预纤维以获得纤维，并缠绕由此获得的纤维，其特征在于调节纤维在管道内的最短保留时间，使得其具有足以从 导管，并且其提取是垂直和连续的。 本发明还涉及可以根据所述方法制造的复合纤维。

    Method for obtaining macroscopic fibres and strips from colloidal particles and in particular carbon nanotubes
    5.
    发明授权
    Method for obtaining macroscopic fibres and strips from colloidal particles and in particular carbon nanotubes 有权
    从胶体颗粒特别是碳纳米管获得宏观纤维和条带的方法

    公开(公告)号：US07655164B2

    公开(公告)日：2010-02-02

    申请号：US10204794

    申请日：2001-02-23

    申请人： Philippe Poulin ,  Brigitte Vigolo ,  Alain Penicaud ,  Claude Coulon

    发明人： Philippe Poulin ,  Brigitte Vigolo ,  Alain Penicaud ,  Claude Coulon

    IPC分类号： D01F1/00 ,  D01F9/12

    CPC分类号： D01D5/06 ,  B82Y15/00 ,  D01D5/00 ,  D01F1/10 ,  D01F9/12 ,  Y10S977/742 ,  Y10T428/30

    摘要： The invention concerns a method for obtaining fibers and strips from colloidal particles, characterized in that it consists in: 1) dispersing said particles in a solvent optionally using a surfactant; 2) injecting the resulting dispersion solution through at least an orifice emerging into a flow of an external solution, preferably, having a higher viscosity than said dispersion, the viscosity levels being measured in the same temperature and pressure conditions, so as to cause said particles to agglomerate into fibers or strips by destabilizing the particle dispersions and optionally aligning said particles.

    摘要翻译： 本发明涉及从胶体颗粒获得纤维和条带的方法，其特征在于其包括：1）将所述颗粒分散在任选使用表面活性剂的溶剂中; 2）将所得到的分散溶液注入至少出现在外部溶液流中的孔口，优选地具有比所述分散体更高的粘度，在相同的温度和压力条件下测量粘度水平，从而使所述颗粒 通过使颗粒分散体不稳定并任选地对准所述颗粒而聚集成纤维或条带。

    Composite Fibers and Asymmetrical Fibers Obtained from Carbon Nanotubes and Colloidal Particles
    8.
    发明申请
    Composite Fibers and Asymmetrical Fibers Obtained from Carbon Nanotubes and Colloidal Particles 有权
    从碳纳米管和胶体颗粒获得的复合纤维和不对称纤维

    公开(公告)号：US20080118753A1

    公开(公告)日：2008-05-22

    申请号：US11666118

    申请日：2005-10-26

    申请人： Philippe Poulin ,  Thibaud Vaugien

    发明人： Philippe Poulin ,  Thibaud Vaugien

    IPC分类号： D01F11/12 ,  D01F9/12

    CPC分类号： B82Y30/00 ,  D01F11/12 ,  D06M15/00 ,  D06M23/16 ,  D06M2101/40 ,  Y10T428/2913 ,  Y10T428/2924 ,  Y10T428/2927

    摘要： A method of manufacturing composite fibers comprising two distinct layers having different compositions and physico-chemical properties and controlled, homogenous thicknesses, wherein one of two layers comprises carbon nanotubes and the composite fibers are obtained from carbon nanotube fibers and a first solution of a selected concentration of colloidal particles intended to constitute the second layer, comprising the following steps: placing the fibers in contact, by lateral surfaces thereof, with a surface of a second solution which is adapted to chemically cause aggregation of the colloidal particles and is completely or partially immersed in the second solution, the immersed thickness of the fibers defining the immersion area, placing the thus pre-coated fibers in contract, on the same lateral surface, with a surface of the first colloidal particle solution and immersed in it at most up to the immersion area to locally form a colloidal gel with a fixed thickness determined by the concentration of the first solution, separating the fibers covered in the first solution, and drying and/or evaporating the solvent of the first solution.

    摘要翻译： 一种制造复合纤维的方法，其包含具有不同组成和物理化学性质以及受控均匀厚度的两个不同的层，其中两层中的一层包含碳纳米管，复合纤维由碳纳米管纤维和选定浓度的第一溶液 旨在构成第二层的胶体颗粒，包括以下步骤：通过其侧表面将纤维与第二溶液的表面接触，第二溶液的表面适于化学引起胶体颗粒的聚集，并且完全或部分浸没 在第二溶液中，限定浸渍区域的纤维的浸入厚度将由此预先涂覆的纤维收缩在相同的侧表面上，并与第一胶态颗粒溶液的表面一起浸入其中，最多浸入 浸渍区域局部形成固定厚度的胶体凝胶 浓缩第一溶液，分离第一溶液中覆盖的纤维，并干燥和/或蒸发第一溶液的溶剂。