公开(公告)号：US4973716A

公开(公告)日：1990-11-27

申请号：US449340

申请日：1989-12-11

Applicant: Pierangelo Calini ,  Silvana Modena

Inventor： Pierangelo Calini ,  Silvana Modena

IPC: B01J27/12 ,  B23K35/38 ,  C07B61/00 ,  C07C41/00 ,  C07C41/22 ,  C07C43/12 ,  C07C67/00 ,  C07D307/18 ,  C07D319/12

CPC classification number: C07D307/18 ,  B23K35/386 ,  C07C41/22 ,  C07D319/12

Abstract: A process for fluorinating hydrogenated ethereal compounds by direct reaction with elemental F.sub.2 diluted with an inert gas, wherein the starting compound is in the liquid phase, said fluorination being carried out in the presence of a per fluoropolyetheral compound and of an alkaline metal fluoride.

Abstract translation: 通过与用惰性气体稀释的元素F2直接反应来氟化氢化醚化合物的方法，其中起始化合物处于液相，所述氟化在全氟聚醚化合物和碱金属氟化物存在下进行。

公开(公告)号：US07208638B2

公开(公告)日：2007-04-24

申请号：US11044022

申请日：2005-01-28

Applicant: Vito Tortelli ,  Stefano Millefanti ,  Pierangelo Calini

Inventor： Vito Tortelli ,  Stefano Millefanti ,  Pierangelo Calini

IPC: C07C41/18

CPC classification number: C07C41/48 ,  C07C43/313 ,  C07C43/315

Abstract: A process for preparing (per)fluorohalogenethers having general formula: wherein: A and A′, equal to or different from each other, are selected among Cl, Br and H; m=1, 2; n=0, 1; R′ is a C1 to C3 (per)fluoroalkyl substituent; R is a (per)fluoropolyether substituent; z and z′ are 1 or zero, X1=F, CF3; by reaction of carbonyl compounds having formula: (R′)n—C(O)(F)q(CFX1(CF2)z(CH2)z′OR1)  (II) wherein: R′ and n are as above; q=0, 1; X1=F or CF3; z=0 or 1; R1 is a (per)fluoropolyether substituent; in liquid phase, with elemental fluorine and with olefinic compounds of formula: CAF=CA′F2   (III) wherein A and A′ are as above, at temperatures from −120° C. to −20° C., preferably from −100° C. to −40° C.

Abstract translation: 制备具有以下通式的（全）氟卤醚的方法：其中：A和A'彼此相同或不同，选自Cl，Br和H; m = 1,2; n = 0,1; R'是C 3〜C 3（全）氟烷基取代基的C 1〜C 3。 R是一个（全）氟聚醚取代基; z和z'为1或0，X 1 = F，CF 3 3; 通过具有下式的羰基化合物的反应：<？in-line-formula description =“In-line formula”end =“lead”→（R'）n -C（O）（F） （CF 2）（CF 2）2（CF 2）2（CF 2）（CH 2）_{其中：R'和n分别为 以上; q = 0,1; X 1 = F或CF 3 N; z = 0或1; R 1是一个（全）氟聚醚取代基; 在液相中使用元素氟和具有下式的烯属化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> CAF = CA'F 2 III）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中A和A'如上所述，在-120℃至-20℃的温度下，优选地 -100°C至-40°C}

公开(公告)号：US20070004940A1

公开(公告)日：2007-01-04

申请号：US11044021

申请日：2005-01-28

Applicant: Vito Tortelli ,  Stefano Millefanti ,  Pierangelo Calini

Inventor： Vito Tortelli ,  Stefano Millefanti ,  Pierangelo Calini

IPC: C07C43/02 ,  C07C43/20

CPC classification number: C07C43/123 ,  C07C41/01 ,  C07C43/126

Abstract: A process for preparing (per)fluorohalogenethers having general formula: wherein: A and A′, equal to our different from each other, are selected among Cl, Br, H; m=1, 2; n=0, 1; R1 is a fluorinated substituent, preferably perfluorinated, selected from the following groups: C1-C20 linear or branched alkylic; C3-C7 cycloalkylic; aromatic, C6-C10 arylalkyl; heterocyclic or C5-C10-alkylheterocyclic; preferably perfluoroalkyl; R′ is as defined in the application; by reaction of carbonyl compounds having formula: wherein: R1 and n are as above; u=0, 1; R′ is as defined in the application; in liquid phase, with elemental fluorine and with olefinic compounds of formula: CAF═CA′F2  (III) wherein A and A′ are as above, at temperatures from −120° C. to −20° C., preferably from −100° C. to −40° C., optionally in the presence of an inert solvent under the reaction conditions.

Abstract translation: 制备具有以下通式的（全）氟卤醚的方法：其中：A和A'等于我们彼此不同，选自Cl，Br，H; m = 1,2; n = 0,1; R 1是优选全氟化的氟化取代基，其选自以下基团：C 1 -C 20直链或支链烷基; C 3 -C 7环烷基; 芳族C 6 -C 10芳基烷基; 杂环或C 5 -C 10 - 烷基杂环; 优选全氟烷基; R'如申请中所定义; 通过具有下式的羰基化合物的反应：其中：R 1和n如上所述; u = 0，1; R'如申请中所定义; 在液相中使用元素氟和具有下式的烯属化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> CAF-CA'F 2 III）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中A和A'如上所述，在-120℃至-20℃的温度下，优选地 -100℃至-40℃，任选在惰性溶剂存在下，在反应条件下进行。

公开(公告)号：US20070149827A1

公开(公告)日：2007-06-28

申请号：US11634145

申请日：2006-12-06

Applicant: Vito Tortelli ,  Pierangelo Calini ,  Alberto Zompatori ,  Emanuela Antenucci

Inventor： Vito Tortelli ,  Pierangelo Calini ,  Alberto Zompatori ,  Emanuela Antenucci

IPC: C07C41/22

CPC classification number: C07C41/06 ,  C07C41/22 ,  C07C41/24 ,  C07C43/123 ,  C07C43/17

Abstract: A process for preparing fluorovinylethers having general formula: RfO—CF═CF2   (IA) wherein Rf is a fluorinated or perfluorinated alkyl or cycloalkyl substituent; comprising the following reaction steps: 1) reaction of a hypofluorite of formula RfOF, wherein Rf is as above, with an olefin of formula: CY″Y═CY′CI   (II) wherein Y, Y′ and Y″, equal to or different from each other, are H, Cl, Br, with the proviso that Y, Y′ and Y″ are not contemporaneously hydrogen; 2) dehalogenation or dehydrohalogenation of the fluorohalogenethers obtained in step 1) and obtainment of vinyl ethers of formula: RfO—CYI═CYIIF   (IV) wherein YI and YII, equal to or different from each other, have the meaning of H, Cl, Br with the proviso that YI and YII are not both H; 3) fluorination with fluorine of the vinyl ethers (IV) and obtainment of fluorohalogenethers of formula: RfO—CFYI—CF2YII   (I) wherein YI, YII, equal to or different from each other, are Cl, Br, H with the proviso that YI and YII cannot be contemporaneously equal to H; 4) dehalogenation or dehydrohalogenation of the fluorohalogenethers (I) and obtainment of the fluorovinylethers (IA).

公开(公告)号：US20050171388A1

公开(公告)日：2005-08-04

申请号：US11044022

申请日：2005-01-28

Applicant: Vito Tortelli ,  Stefano Millefanti ,  Pierangelo Calini

Inventor： Vito Tortelli ,  Stefano Millefanti ,  Pierangelo Calini

IPC: C07C41/18 ,  C07C41/05 ,  C07C41/24 ,  C07C41/48 ,  C07C43/12 ,  C07C43/17 ,  C07C43/313 ,  C07C43/315 ,  C07C41/16

CPC classification number: C07C41/48 ,  C07C43/313 ,  C07C43/315

Abstract: A process for preparing (per)fluorohalogenethers having general formula: wherein: A and A′, equal to or different from each other, are selected among Cl, Br and H; m=1, 2; n=0, 1; R′ is a C1-C3 (per)fluoroalkyl substituent; R is a (per)fluoropolyether substituent; z and z′ are 1 or zero, X1=F, CF3; by reaction of carbonyl compounds having formula: (R′)n—C(O)(F)q(CF2ORI)   (II) wherein: R′ and n are as above; q=0, 1; RI is a (per)fluoro-polyether substituent; in liquid phase, with elemental fluorine and with olefinic compounds of formula: CAF=CA′F2   (III) wherein A and A′ are as above, at temperatures from −120° C. to −20° C., preferably from −100° C. to −40° C.

Abstract translation: 制备具有以下通式的（全）氟卤醚的方法：其中：A和A'彼此相同或不同，选自Cl，Br和H; m = 1,2; n = 0,1; R'是C 1 -C 3 -C 3（全）氟烷基取代基; R是一个（全）氟聚醚取代基; z和z'为1或0，X 1 = F，CF 3 3; 通过具有下式的羰基化合物的反应：<？in-line-formula description =“In-line formula”end =“lead”→（R'）n -C（O）（F） （II）（II）<？in-line-formula description =“In-line Formulas”end =“tail 其中：R'和n如上所述; q = 0,1; R 1是（全）氟 - 聚醚取代基; 在液相中使用元素氟和具有下式的烯属化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> CAF = CA'F 2 III）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中A和A'如上所述，在-120℃至-20℃的温度下，优选地 -100°C至-40°C

公开(公告)号：US4801741A

公开(公告)日：1989-01-31

申请号：US93040

申请日：1987-09-04

Applicant: Giorgio Guglielmo ,  Guglielmo Gregorio ,  Pierangelo Calini

Inventor： Giorgio Guglielmo ,  Guglielmo Gregorio ,  Pierangelo Calini

IPC: B01J27/12 ,  B01J27/00 ,  C07B61/00 ,  C07C20060101 ,  C07C41/06 ,  C07C41/22 ,  C07C43/12 ,  C07C67/00 ,  C07C71/00 ,  C07C201/00 ,  C07D20060101

CPC classification number: C07C71/00

Abstract: Process for the preparation of chloro-oxy-halo-compounds by means of the direct reaction between FCl and organic compounds having a molecular structure wherein an oxygen atom is directly linked to a carbon atom in the carbonyl form, in the presence of a catalyst constituted by an alkali metal or alkali-earth metal fluoride, preferably selected from K, Rb, Cs, Ba, Sr, the reaction being carried out in the gas phase and in continuous.

Abstract translation: 通过FCl与具有分子结构的有机化合物之间的直接反应制备氯 - 氧 - 卤代化合物的方法，其中氧原子直接与羰基形式的碳原子连接，在催化剂存在下，构成 通过优选选自K，Rb，Cs，Ba，Sr的碱金属或碱土金属氟化物，反应在气相和连续进行。

公开(公告)号：US07795477B2

公开(公告)日：2010-09-14

申请号：US11636509

申请日：2006-12-11

Applicant: Vito Tortelli ,  Pierangelo Calini ,  Alberto Zompatori ,  Emanuela Antenucci

Inventor： Vito Tortelli ,  Pierangelo Calini ,  Alberto Zompatori ,  Emanuela Antenucci

IPC: C07C41/22

CPC classification number: C07C41/06 ,  C07C17/04 ,  C07C17/23 ,  C07C17/25 ,  C07C41/24 ,  C07C19/12 ,  C07C19/14 ,  C07C21/18 ,  C07C43/123 ,  C07C43/17

Abstract: A process for preparing perfluorovinylethers having general formula: RfO—CF═CF2  (IA) where Rf is a C1-C3 alkyl perfluorinated substituent, comprises the steps of: 1a) fluorinating olefins of formula: CY″Y═CY′Cl  (II) where Y, Y′ and Y″, equal to or different from each other, are H, Cl, Br, and are not contemporaneously hydrogen; and obtaining fluorohalogencarbons of formula: FCY″Y—CY′ClF  (III) where Y, Y′ and Y″ are as above; 2a) dehalogenating or dehydrohalogenating fluorohalogencarbons (III) and obtaining fluorohalogenolefins of formula: FCYI═CYIIF  (IV) where YI and YII, equal to or different from each other, are H, Cl, Br and are not contemporaneously H; 3a) reacting a hypofluorite of formula RfOF and a fluorohalogenolefin (IV), and obtaining the fluorohalogenethers of formula: RfO—CFYI—CF2YII  (I) where YI, YII, equal to or different from each other, are Cl, Br, H and are not be contemporaneously H; and 4a) dehalogenating or dehydrohalogenating compounds (I) and obtaining perfluorovinylethers (IA).

Abstract translation: 一种制备具有以下通式的全氟乙烯基醚的方法：RfO-CF = CF2（IA）其中Rf为C1-C3烷基全氟取代基，包括以下步骤：1a）氟化式：CY“Y = C''Cl（II） 其中Y，Y'和Y“彼此相同或不同，为H，Cl，Br，并非同时为氢; 并获得式：FCY“Y-CY'ClF（III）的氟代卤素，其中Y，Y'和Y”如上所述; 2a）脱卤或脱卤化氢氟代烃（III）并得到式（Ⅳ）的氟卤代烯烃，其中YI和YII彼此相同或不同，为H，Cl，Br，不同时为H; 3a）使式RfOF的次氟化物与氟代卤代烯烃（IV）反应，得到其中YI，YII彼此相同或不同的式RfO-CFYI-CF2YII（I）的氟代醚，为Cl，Br，H和 不是同时H 和4a）脱卤或脱卤化氢化合物（I）并获得全氟乙烯基醚（IA）。

公开(公告)号：US06835856B2

公开(公告)日：2004-12-28

申请号：US10633565

申请日：2003-08-05

Applicant: Vito Tortelli ,  Pierangelo Calini

Inventor： Vito Tortelli ,  Pierangelo Calini

IPC: C07C4106

CPC classification number: C07C41/06 ,  C07C43/123 ,  C07C43/126

Abstract: A process for preparing (per)fluorohalogenethers having general formula (I): (R)nC(F)mOCAF—CA′F2  (I) wherein: A and A′, equal to or different the one from the other, are Cl or Br or one is selected from A and A′ and hydrogen and the other is halogen selected from Cl, Br; R═F, or a fluorinated, preferably perfluorinated, substituent, selected from the following groups: linear or branched C1-C20 alkyl more preferably C1-C10; C3-C7 cycloalkyl; aromatic, C6-C10 arylalkyl, alkylaryl; C5-C10 heterocyclic or alkylheterocyclic; when R is fluorinated or perfluorinated alkyl, cycloalkyl, arylalkyl, alkylaryl, it can optionally contain in the chain one or more oxygen atoms; when R is fluorinated it can optionally contain one or more H atoms and/or one or more halogen atoms different from F: n is an integer and is 1 or 2; m=3-n; by reaction of carbonyl compounds having formula (II): (R)pC(F)q(O)  (II) wherein: p is an integer and is 1 or 2; q is an integer and is zero or 1, R is as above; in liquid phase with elemental fluorine and with olefinic compounds having formula (III): CAF═CA′F  (III) wherein A and A′ are as above, at temperatures in the range from −120° C. to −20° C.

Abstract translation: 制备具有通式（I）的（全）氟卤醚的方法：其中：A和A'彼此相同或不同的是Cl或Br或一个选自A和A'，氢和另一个 是选自Cl，Br的卤素; R = F或氟化，优选全氟化的取代基，选自以下基团：直链或支链C 1 -C 20烷基，更优选C 1 -C 10; C3-C7环烷基; 芳基，C 6 -C 10芳基烷基，烷基芳基; C5-C10杂环或烷基杂环; 当R是氟化或全氟化的烷基，环烷基，芳基烷基，烷基芳基时，它可以任选地在链中含有一个或多个氧原子;当R是氟化时，它可任选地含有一个或多个H原子和/或一个或多个不同于 F：n为整数，为1或2; m = 3-n; 通过具有式（II）的羰基化合物的反应：其中：p为整数，为1或2; q为整数且为零或1，R如上所述;在液相中含有元素氟和具有式（III）的烯属化合物：其中A和A'如上所述，在-120℃的温度范围内 -20℃

公开(公告)号：US5457242A

公开(公告)日：1995-10-10

申请号：US148545

申请日：1993-11-08

Applicant: Pierangelo Calini ,  Guglielmo Gregorio ,  Giorgio Guglielmo

Inventor： Pierangelo Calini ,  Guglielmo Gregorio ,  Giorgio Guglielmo

IPC: C07C43/12 ,  C07C41/06

CPC classification number: C07C43/123

Abstract: A process for preparing the novel compound 2-bromo, 1', 2'-dichloroperfluoro diethyl ether of formula:BrCFhd 2--CF.sub.2 --O--CFCl--CF.sub.2 Clwhere BrCF.sub.2 --CF.sub.2 OF is reacted with the olefin CFCl.dbd.CFCl, with bromohypofluorite being introduced into the reaction mixture in the form of a solution in an inert solvent based on chlorofluorohydrocarbon.

Abstract translation: 制备式BrCF2-CF2-O-CFCl-CF2Cl的新化合物2-溴，1'，2'-二氯全氟二乙醚的方法，其中BrCF 2 -CF 2 OF与烯烃CFCl = CFCl与溴二氟化物反应为 在基于氯氟烃的惰性溶剂中以溶液的形式引入反应混合物。

公开(公告)号：US4356319A

公开(公告)日：1982-10-26

申请号：US226382

申请日：1981-01-19

Applicant: Paolo Roffia ,  Pierangelo Calini ,  Sergio Tonti

Inventor： Paolo Roffia ,  Pierangelo Calini ,  Sergio Tonti

IPC: C07C51/265 ,  B01J23/94 ,  B01J25/00 ,  B01J31/40 ,  B01J38/00 ,  C07C51/00 ,  C07C51/42 ,  C07C63/26 ,  C07C67/00 ,  C07C51/29

CPC classification number: B01J31/04 ,  B01J31/4015 ,  B01J31/403 ,  C07C51/42 ,  B01J2231/70 ,  B01J2531/72 ,  B01J2531/845 ,  Y02P20/52 ,  Y02P20/584

Abstract: A method of recovering the catalyst in active form from the acetic mother liquors from the synthesis of terephthalic acid. From said mother liquors, after removal of water, there is removed by evaporation an amount of from 70 to 90% of the CH.sub.3 COOH present therein. The concentrated liquor is cooled below 60.degree. C. and the solid which precipitates is collected and recycled for reuse in the systhesis. The liquid phase is extracted with water or with an aqueous acetic acid solution in the presence of particular coadjuvants such as isobutyl acetate, and the aqueous phase, which contains the recovered catalyst, is recycled to the original synthesis.

Abstract translation: 从对苯二甲酸的合成从乙酸母液中回收活性形式的催化剂的方法。 从所述母液中除去水后，通过蒸发除去其中存在的CH 3 COOH的70-90％。 将浓缩液冷却至60℃以下，收集析出的固体并将其循环再利用于合成。 在特殊的辅助剂如乙酸异丁酯存在下，用水或乙酸水溶液萃取液相，含有回收的催化剂的水相再循环到原始合成中。