Abstract:
A continuous process for preparing perfluoroalkenyl sulfonyl fluorides (I)R.sub.f --CF.dbd.CF--SO.sub.2 F (I)wherein: R.sub.f is selected from the group consisting of F and a perfluoroalkyl radical of from 1 to 9 carbon atoms is disclosed, in which as the starting compound a sultone (II) ##STR1## is used. The starting compound is placed into contact with a reactant selected from the group consisting of oxides and carbonates of an element of the Groups IA, IIA and IIB, and of the oxides of an element of the Groups IIIA and IVA of the Periodic Table of the Elements, and their mixtures, at a temperature comprised within the range of from 150.degree. to 450.degree. C., and the compound (I) is recovered from the reaction effluent. and the compound (I) is recovered from the reaction effluent.
Abstract:
A process for the preparation of fluoroalkyl ethers of the formula: ##STR1## wherein: Y is Br or F;X is F, Cl or Br or their mixtures when n is equal to or higher than 2;n is within the range of from 0 to 4;R.sub.f represents a perfluoroalkylene radical containing from 1 to 8 carbon atoms.The process is characterized in that a fluoroalkoxy perfluoroacyl fluoride of the formula: ##STR2## is slowly heated with a salifying agent and a solvent, in the presence of a catalytic amount of N,N-dimethylformamide, with an end temperature within the range of from 60.degree. to 150.degree. C. being reached.
Abstract:
A process for preparing bromodifluoroacetylfluoride characterized in that a gaseous stream of oxygen-diluted ozone is reacted, at temperatures ranging from -100.degree. C. to +80.degree. C., with 1,4-dibromohexafluorobutene-2 optionally dissolved in a solvent which is inert under the reaction conditions, with consequent obtainment of the corresponding ozonide and, subsequently, the ozonide is subjected to a heat treatment at temperatures ranging from 100.degree. to 300.degree. C., with consequent obtainment of bromodifluoroacetylfluoride.
Abstract:
A surface treatment method for imparting -oil- and/or water-repellency, comprising the step of applying to the surface to be treated compositions comprising at least one compound having the formula III ACF2O—(CF2O)n(C2F4O)m—CF2—B III where n=1-20, m=1-20 and A and B are reactive functional groups chosen independently from the group constituted by: a) CONHR, where R=CnH2n+1 with n=1-30, b) CH2OH, c) CONH(X)SiR1n(OR′)3−n, where n=0-2, R1 and R′, identical or different, are CrH2r+1 alkyl radicals, where r=1-4, and X is a bifunctional alkyl spacer of the (CHR″)m type, where m=1-20, and R″ can be H or CH3, optionally containing heteroatoms, d) —[CH2O(R′″O)p]k—P(O)(OH)3−k, where R′″ is an alkylene radical, for example C2H4 or C3H6, p=1-10 and k=1, 2, the composition comprising the compound at a suitable concentration and being applied in an amount suitable to obtain substantially at least one monolayer of the compound on the surface to be treated, the reactive groups being chosen according to the nature of the surface to be treated so as to provide interaction with the surface to be treated.
Abstract translation:一种用于赋予油和/或拒水性的表面处理方法,包括将待处理组合物的表面施加至包含至少一种具有式III的化合物的步骤,其中n = 1-20,m = 1-20和A 和B是独立于由以下构成的基团选择的反应性官能团:a)CONHR,其中R = C n H 2n + 1,n = 1-30,b)CH 2 OH,c)CONH(X)SiR1n(OR')3-n, 其中n = 0-2,R1和R'相同或不同,是CrH2r + 1烷基,其中r = 1-4,X是(CHR“)m型的双官能烷基间隔基,其中m = 1-20,R“可以是H或CH 3,任选地含有杂原子,d) - [CH 2 O(R”O)p] kP(O)(OH)3-k,其中R“ 亚烷基,例如C 2 H 4或C 3 H 6,p = 1-10和k = 1,2,所述组合物包含适当浓度的化合物,并以适于在表面上获得基本上至少一种化合物单层的量施用 待处理的反应性基团是根据表面的性质来选择的 处理以提供与待处理表面的相互作用。
Abstract:
Fluoroelastomeric compositions peroxy-curable, endowed with improved characteristics of processability and compatibility, and with enhanced low-temperature properties, comprising, as additives, vinylidene fluoride cotelomers having the general formula:R[(CH.sub.2 CF.sub.2).sub.n (C.sub.3 F.sub.6).sub.m (C.sub.2 F.sub.4).sub.p (C.sub.2 F.sub.3 Cl).sub.q ]X (I)wherein:X=Br, I;R is a possible halogenated alkyl radical;n, m, p, q are integers, m, p, q may also be zero.
Abstract translation:具有改进的加工性能和相容性特征的氟弹性组合物,以及具有增强的低温性能,包括作为添加剂的具有以下通式的偏二氟乙烯调聚物:R [(CH 2 CF 2)n(C 3 F 6)m(C 2 F 4)p (C 2 F 3 Cl)q] X(I)其中:X = Br,I; R是可能的卤代烷基; n,m,p,q是整数,m,p,q也可以为零。
Abstract:
Perfluorobutadiene and higher alkandienes, with terminal double bonds, are obtained from .alpha.,.omega.-dibromo, .alpha., .omega.,bromo, iodo perfluoroalkanes by dehalofluorination carried out with the aid of an organometallic compounds, in the presence of aprotic solvent belonging to the class of hydrocarbons or polar aprotic solvent belonging to the class of ethers, with limited reaction times.
Abstract:
There are prepared compounds of general formula: ##STR1## wherein: R.sub.1 =H, or alkyl or acyl containing from 1 to 10 carbon atoms, R.sub.2, R.sub.3, like or unlike each other, may be H, or an alkyl containing from 1 to 10 carbon atoms and where R.sub.1 and R.sub.2 may form, together, an alkylene group containing from 2 to 10 carbon atoms, and optionally including up to 2 oxygen atoms in the chain, by means of addition reaction induced by radicalic starters of 1,2-dichlorodifluoroethylene to alcohols, ethers or esters of general formula: ##STR2## wherein: R.sub.1, R.sub.2, R.sub.3 are defined as above.
Abstract:
Cotelomers of vinylidene fluoride with one or more fluoro olefins, having the general formulaR[(CF.sub.2 CH.sub.2)n (C.sub.3 F.sub.6)m (C.sub.2 F.sub.4)p (C.sub.2 F.sub.3 Cl)q]X (I)wherein:X is either Br or I, R is an alkyl radical eventually containing halogen atoms, n is an integer comprised within the range of from 1 to 30, m is an integer comprised within the range of from 0 to 10, p and q are integers comprised within the range of from 0 to 20, and wherein m+p+q is at least 1, obtained by cotelomerizing monomers in the presence of a telogen RX (wherein R and X have the abovesaid meaning) and of a free-radical polymerization initiator.
Abstract translation:偏氟乙烯与一种或多种氟烯烃的共聚物,具有通式R [(CF 2 CH 2)n(C 3 F 6)m(C 2 F 4)p(C 2 F 3 Cl)q] X(I)其中:X为Br或I,R为 最终含有卤素原子的烷基,n为1〜30的整数,m为0〜10的整数,p和q为0〜20的整数, 并且其中m + p + q至少为1,通过在开始端RX(其中R和X具有上述含义)存在下将单体和自由基聚合引发剂进行调聚获得。
Abstract:
A continuous process for preparing perfluoroalkenyl sulfonyl fluorides (I)R.sub.f --CF.dbd.CF--SO.sub.2 F (I)wherein R.sub.f is selected from the group consisting of F and a perfluoroalkyl of from 1 to 9 carbon atoms is disclosed, in which a perfluoroalkyl (sulfonyl fluoride) monofluoroacetyl fluoride of formulaR.sub.f --CF.sub.2 --CF(COF)SO.sub.2 F (II)is used as the starting product.The starting product is contacted with a reactant selected from the group consisting of the oxides of an element of the Groups IA, IIA, IIB, IIIA and IVA of the Periodic Table of the Elements, and of their mixtures, at a temperature comprised within the range of from 150.degree. to 450.degree. C., and the compound (I) is recovered from the reaction effluent.
Abstract:
A process for fluorinating hydrogenated ethereal compounds by direct reaction with elemental F.sub.2 diluted with an inert gas, wherein the starting compound is in the liquid phase, said fluorination being carried out in the presence of a per fluoropolyetheral compound and of an alkaline metal fluoride.