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公开(公告)号:US12119444B2
公开(公告)日:2024-10-15
申请号:US18153305
申请日:2023-01-11
发明人: Arnold Allenic , Cheng-Chieh Chao , Lei Cheng , Niall Donnelly , William H. Gardner , Timothy Holme , Sriram Iyer , Shuang Li
IPC分类号: H01M10/0562 , C04B35/488 , C04B35/622 , H01M10/052 , H01M10/056 , H01M10/0565 , H01M10/058 , H01M50/403 , H01M50/409
CPC分类号: H01M10/0562 , C04B35/4885 , C04B35/62218 , H01M10/052 , H01M10/056 , H01M10/0565 , H01M10/058 , H01M50/403 , H01M50/409 , C04B2235/3203 , C04B2235/3227 , C04B2235/6025 , C04B2235/6567 , C04B2235/764
摘要: Set forth herein are pellets, thin films, and monoliths of lithium-stuffed garnet electrolytes having engineered surfaces. These engineered surfaces have a list of advantageous properties including, but not limited to, low surface area resistance, high Li+ ion conductivity, low tendency for lithium dendrites to form within or thereupon when the electrolytes are used in an electrochemical cell. Other advantages include voltage stability and long cycle life when used in electrochemical cells as a separator or a membrane between the positive and negative electrodes. Also set forth herein are methods of making these electrolytes including, but not limited to, methods of annealing these electrolytes under controlled atmosphere conditions. Set forth herein, additionally, are methods of using these electrolytes in electrochemical cells and devices. The instant disclosure further includes electrochemical cells which incorporate the lithium-stuffed garnet electrolytes set forth herein.
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公开(公告)号:US11165096B2
公开(公告)日:2021-11-02
申请号:US17019134
申请日:2020-09-11
发明人: Arnold Allenic , Cheng-Chieh Chao , Lei Cheng , Niall Donnelly , William H. Gardner , Tim Holme , Sriram Iyer , Shuang Li
IPC分类号: H01M10/0562 , H01M10/052 , H01M10/056 , H01M10/058 , H01M50/403 , H01M10/0565 , C04B35/488 , C04B35/622 , H01M50/409
摘要: Set forth herein are pellets, thin films, and monoliths of lithium-stuffed garnet electrolytes having engineered surfaces. These engineered surfaces have a list of advantageous properties including, but not limited to, low surface area resistance, high Li+ ion conductivity, low tendency for lithium dendrites to form within or thereupon when the electrolytes are used in an electrochemical cell. Other advantages include voltage stability and long cycle life when used in electrochemical cells as a separator or a membrane between the positive and negative electrodes. Also set forth herein are methods of making these electrolytes including, but not limited to, methods of annealing these electrolytes under controlled atmosphere conditions. Set forth herein, additionally, are methods of using these electrolytes in electrochemical cells and devices. The instant disclosure further includes electrochemical cells which incorporate the lithium-stuffed garnet electrolytes set forth herein.
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公开(公告)号:US11855251B2
公开(公告)日:2023-12-26
申请号:US18152566
申请日:2023-01-10
发明人: Zhebo Chen , Tim Holme , Marie Mayer , Nick Perkins , Eric Tulsky , Cheng-Chieh Chao , Christopher Dekmezian , Shuang Li
IPC分类号: H01M10/0525 , H01M4/505 , H01M4/525 , H01M10/0562 , H01M50/431 , H01M50/489 , H01M50/494 , H01M50/491
CPC分类号: H01M10/0525 , H01M4/505 , H01M4/525 , H01M10/0562 , H01M50/431 , H01M50/489 , H01M50/491 , H01M50/494 , H01M2300/0068 , H01M2300/0094
摘要: Set forth herein are compositions comprising A·(LiBH4)·B·(LiX)·C·(LiNH2), wherein X is fluorine, bromine, chloride, iodine, or a combination thereof, and wherein 0.1≤A≤3, 0.1≤13≤4, and 0≤C≤9 that are suitable for use as solid electrolyte separators in lithium electrochemical devices. Also set forth herein are methods of making A·(LiBH4)·B·(LiX)·C·(LiNH2) compositions. Also disclosed herein are electrochemical devices which incorporate A·(LiBH4)·B·(LiX)·C·(LiNH2) compositions and other materials.
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公开(公告)号:US11581612B2
公开(公告)日:2023-02-14
申请号:US17229680
申请日:2021-04-13
发明人: Zhebo Chen , Tim Holme , Marie Mayer , Nick Perkins , Eric Tulsky , Cheng-Chieh Chao , Christopher Dekmezian , Shuang Li
IPC分类号: H01M50/431 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M10/0562
摘要: Set forth herein are compositions comprising A.(LiBH4).B.(LiX).C.(LiNH2), wherein X is fluorine, bromine, chloride, iodine, or a combination thereof, and wherein 0.1≤A≤3, 0.1≤B≤4, and 0≤C≤9 that are suitable for use as solid electrolyte separators in lithium electrochemical devices. Also set forth herein are methods of making A.(LiBH4).B.(LiX).C.(LiNH2) compositions. Also disclosed herein are electrochemical devices which incorporate A.(LiBH4).B.(LiX).C.(LiNH2) compositions and other materials.
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公开(公告)号:US12046712B2
公开(公告)日:2024-07-23
申请号:US15734188
申请日:2019-06-06
IPC分类号: H01M10/0562 , H01M4/04 , H01M4/36 , H01M4/38 , H01M4/62 , H01M10/052 , H01M10/0585
CPC分类号: H01M10/0562 , H01M4/0404 , H01M4/366 , H01M4/382 , H01M4/62 , H01M10/052 , H01M10/0585 , H01M2220/20 , H01M2300/0071 , H01M2300/0094
摘要: Provided herein solid-state battery architectures that include an oxide electrolyte in contact with the anode of an electrochemical cell and a sulfide electrolyte in contact with the cathode of an electrochemical cell.
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公开(公告)号:US11581576B2
公开(公告)日:2023-02-14
申请号:US17488187
申请日:2021-09-28
发明人: Arnold Allenic , Cheng-Chieh Chao , Lei Cheng , Niall Donnelly , William H. Gardner , Tim Holme , Sriram Iyer , Shuang Li
IPC分类号: H01M10/0562 , H01M10/052 , H01M10/056 , H01M10/058 , H01M50/403 , H01M50/409 , H01M10/0565 , C04B35/488 , C04B35/622
摘要: Set forth herein are pellets, thin films, and monoliths of lithium-stuffed garnet electrolytes having engineered surfaces. These engineered surfaces have a list of advantageous properties including, but not limited to, low surface area resistance, high Li+ ion conductivity, low tendency for lithium dendrites to form within or thereupon when the electrolytes are used in an electrochemical cell. Other advantages include voltage stability and long cycle life when used in electrochemical cells as a separator or a membrane between the positive and negative electrodes. Also set forth herein are methods of making these electrolytes including, but not limited to, methods of annealing these electrolytes under controlled atmosphere conditions. Set forth herein, additionally, are methods of using these electrolytes in electrochemical cells and devices. The instant disclosure further includes electrochemical cells which incorporate the lithium-stuffed garnet electrolytes set forth herein.
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公开(公告)号:US20210234230A1
公开(公告)日:2021-07-29
申请号:US17229680
申请日:2021-04-13
发明人: Zhebo CHEN , Tim Holme , Marie Mayer , Nick Perkins , Eric Tulsky , Cheng-Chieh Chao , Christopher Dekmezian , Shuang Li
IPC分类号: H01M50/431 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M10/0562
摘要: Set forth herein are compositions comprising A.(LiBH4).B.(LiX).C.(LiNH2), wherein X is fluorine, bromine, chloride, iodine, or a combination thereof, and wherein 0.1≤A≤3, 0.1≤B≤4, and 0≤C≤9 that are suitable for use as solid electrolyte separators in lithium electrochemical devices. Also set forth herein are methods of making A.(LiBH4).B.(LiX).C.(LiNH2) compositions. Also disclosed herein are electrochemical devices which incorporate A.(LiBH4).B.(LiX).C.(LiNH2) compositions and other materials.
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