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公开(公告)号：US12074281B2
公开(公告)日：2024-08-27
申请号：US17961195
申请日：2022-10-06
发明人： Larry Beck , Cheng-Chieh Chao , Lei Cheng , Niall Donnelly , William H. Gardner , Tim Holme , Will Hudson , Sriram Iyer , Oleh Karpenko , Yang Li , Gengfu Xu
IPC分类号： H01M10/0562 , C01G25/00 , H01M10/0525
CPC分类号： H01M10/0562 , C01G25/006 , H01M10/0525 , C01P2002/36 , C01P2002/74 , C01P2004/61 , H01M2220/20 , H01M2300/0071
摘要： The instant disclosure sets forth multiphase lithium-stuffed garnet electrolytes having secondary phase inclusions, wherein these secondary phase inclusions are material(s) which is/are not a cubic phase lithium-stuffed garnet but which is/are entrapped or enclosed within a lithium-stuffed garnet. When the secondary phase inclusions described herein are included in a lithium-stuffed garnet at 30-0.1 volume %, the inclusions stabilize the multiphase matrix and allow for improved sintering of the lithium-stuffed garnet. The electrolytes described herein, which include lithium-stuffed garnet with secondary phase inclusions, have an improved sinterability and density compared to phase pure cubic lithium-stuffed garnet having the formula Li7La3Zr2O12.
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公开(公告)号：US11962002B2
公开(公告)日：2024-04-16
申请号：US18463208
申请日：2023-09-07
发明人： Cheng-Chieh Chao , Sarah Chavez , Hyeseung Chung , Seitaro Ito , Yuki Katoh , Konstantin Lokshin , Akinari Ohash , Jessa Silver , Yaosen Tian , Virgil Xu , Zhenfeng Yu
CPC分类号： H01M4/366 , C01G53/50 , H01M4/525 , H01M4/5825 , C01P2002/02 , C01P2002/50 , C01P2002/85 , C01P2004/04 , C01P2004/80 , C01P2006/40 , H01M2004/028
摘要： The present disclosure concerns lithium zirconium phosphate (LZP) chemical oxides for coated cathode active materials, which are useful in cathodes (i.e., positive electrodes) of rechargeable lithium-batteries for reversibly storing lithium ions (Li+).
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公开(公告)号：US11581576B2
公开(公告)日：2023-02-14
申请号：US17488187
申请日：2021-09-28
发明人： Arnold Allenic , Cheng-Chieh Chao , Lei Cheng , Niall Donnelly , William H. Gardner , Tim Holme , Sriram Iyer , Shuang Li
IPC分类号： H01M10/0562 , H01M10/052 , H01M10/056 , H01M10/058 , H01M50/403 , H01M50/409 , H01M10/0565 , C04B35/488 , C04B35/622
摘要： Set forth herein are pellets, thin films, and monoliths of lithium-stuffed garnet electrolytes having engineered surfaces. These engineered surfaces have a list of advantageous properties including, but not limited to, low surface area resistance, high Li+ ion conductivity, low tendency for lithium dendrites to form within or thereupon when the electrolytes are used in an electrochemical cell. Other advantages include voltage stability and long cycle life when used in electrochemical cells as a separator or a membrane between the positive and negative electrodes. Also set forth herein are methods of making these electrolytes including, but not limited to, methods of annealing these electrolytes under controlled atmosphere conditions. Set forth herein, additionally, are methods of using these electrolytes in electrochemical cells and devices. The instant disclosure further includes electrochemical cells which incorporate the lithium-stuffed garnet electrolytes set forth herein.
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公开(公告)号：US20220029168A1
公开(公告)日：2022-01-27
申请号：US17387737
申请日：2021-07-28
IPC分类号： H01M4/62 , H01M4/131 , H01M10/0525 , H01M4/36 , H01M10/056 , H01M50/46 , H01M10/0562 , H01M4/136 , H01M4/505 , H01M4/525 , H01M4/58 , C01B33/00
摘要： The present invention provides an energy storage device comprising a cathode region or other element. The device has a major active region comprising a plurality of first active regions spatially disposed within the cathode region. The major active region expands or contracts from a first volume to a second volume during a period of a charge and discharge. The device has a catholyte material spatially confined within a spatial region of the cathode region and spatially disposed within spatial regions not occupied by the first active regions. In an example, the catholyte material comprises a lithium, germanium, phosphorous, and sulfur (“LGPS”) containing material configured in a polycrystalline state. The device has an oxygen species configured within the LGPS containing material, the oxygen species having a ratio to the sulfur species of 1:2 and less to form a LGPSO material. The device has a protective material formed overlying exposed regions of the cathode material to substantially maintain the sulfur species within the catholyte material. Also included is a novel dopant configuration of the LiaMPbSc (LMPS) [M=Si,Ge, and/or Sn] containing material.
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公开(公告)号：US11211611B2
公开(公告)日：2021-12-28
申请号：US16421383
申请日：2019-05-23
IPC分类号： H01M4/62 , H01M4/131 , H01M10/0525 , H01M4/36 , H01M10/056 , H01M50/46 , H01M10/0562 , H01M4/136 , H01M4/505 , H01M4/525 , H01M4/58 , C01B33/00
摘要： The present invention provides an energy storage device comprising a cathode region or other element. The device has a major active region comprising a plurality of first active regions spatially disposed within the cathode region. The major active region expands or contracts from a first volume to a second volume during a period of a charge and discharge. The device has a catholyte material spatially confined within a spatial region of the cathode region and spatially disposed within spatial regions not occupied by the first active regions. In an example, the catholyte material comprises a lithium, germanium, phosphorous, and sulfur (“LGPS”) containing material configured in a polycrystalline state. The device has an oxygen species configured within the LGPS containing material, the oxygen species having a ratio to the sulfur species of 1:2 and less to form a LGPSO material. The device has a protective material formed overlying exposed regions of the cathode material to substantially maintain the sulfur species within the catholyte material. Also included is a novel dopant configuration of the LiaMPbSc (LMPS) [M=Si, Ge, and/or Sn] containing material.
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公开(公告)号：US20210234230A1
公开(公告)日：2021-07-29
申请号：US17229680
申请日：2021-04-13
发明人： Zhebo CHEN , Tim Holme , Marie Mayer , Nick Perkins , Eric Tulsky , Cheng-Chieh Chao , Christopher Dekmezian , Shuang Li
IPC分类号： H01M50/431 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M10/0562
摘要： Set forth herein are compositions comprising A.(LiBH4).B.(LiX).C.(LiNH2), wherein X is fluorine, bromine, chloride, iodine, or a combination thereof, and wherein 0.1≤A≤3, 0.1≤B≤4, and 0≤C≤9 that are suitable for use as solid electrolyte separators in lithium electrochemical devices. Also set forth herein are methods of making A.(LiBH4).B.(LiX).C.(LiNH2) compositions. Also disclosed herein are electrochemical devices which incorporate A.(LiBH4).B.(LiX).C.(LiNH2) compositions and other materials.
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公开(公告)号：US12119444B2
公开(公告)日：2024-10-15
申请号：US18153305
申请日：2023-01-11
发明人： Arnold Allenic , Cheng-Chieh Chao , Lei Cheng , Niall Donnelly , William H. Gardner , Timothy Holme , Sriram Iyer , Shuang Li
IPC分类号： H01M10/0562 , C04B35/488 , C04B35/622 , H01M10/052 , H01M10/056 , H01M10/0565 , H01M10/058 , H01M50/403 , H01M50/409
CPC分类号： H01M10/0562 , C04B35/4885 , C04B35/62218 , H01M10/052 , H01M10/056 , H01M10/0565 , H01M10/058 , H01M50/403 , H01M50/409 , C04B2235/3203 , C04B2235/3227 , C04B2235/6025 , C04B2235/6567 , C04B2235/764
摘要： Set forth herein are pellets, thin films, and monoliths of lithium-stuffed garnet electrolytes having engineered surfaces. These engineered surfaces have a list of advantageous properties including, but not limited to, low surface area resistance, high Li+ ion conductivity, low tendency for lithium dendrites to form within or thereupon when the electrolytes are used in an electrochemical cell. Other advantages include voltage stability and long cycle life when used in electrochemical cells as a separator or a membrane between the positive and negative electrodes. Also set forth herein are methods of making these electrolytes including, but not limited to, methods of annealing these electrolytes under controlled atmosphere conditions. Set forth herein, additionally, are methods of using these electrolytes in electrochemical cells and devices. The instant disclosure further includes electrochemical cells which incorporate the lithium-stuffed garnet electrolytes set forth herein.
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公开(公告)号：US11489193B2
公开(公告)日：2022-11-01
申请号：US16621659
申请日：2017-06-23
发明人： Larry Beck , Cheng-Chieh Chao , Lei Cheng , Niall Donnelly , William H Gardner , Tim Holme , Will Hudson , Sriram Iyer , Oleh Karpenko , Yang Li , Gengfu Xu
IPC分类号： H01M10/0562 , C01G25/00 , H01M10/0525
摘要： The instant disclosure sets forth multiphase lithium-stuffed garnet electrolytes having secondary phase inclusions, wherein these secondary phase inclusions are material(s) which is/are not a cubic phase lithium-stuffed garnet but which is/are entrapped or enclosed within a lithium-stuffed garnet. When the secondary phase inclusions described herein are included in a lithium-stuffed garnet at 30-0.1 volume %, the inclusions stabilize the multiphase matrix and allow for improved sintering of the lithium-stuffed garnet. The electrolytes described herein, which include lithium-stuffed garnet with secondary phase inclusions, have an improved sinterability and density compared to phase pure cubic lithium-stuffed garnet having the formula Li7La3Zr2O12.
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公开(公告)号：US11916200B2
公开(公告)日：2024-02-27
申请号：US16343361
申请日：2017-10-19
发明人： David Cao , Cheng-Chieh Chao , Zhebo Chen , Lei Cheng , Niall Donnelly , Wes Hermann , Tim Holme , Tommy Huang , Kian Kerman , Yang Li , Harsh Maheshwari
IPC分类号： H01M50/403 , H01M10/42 , H01M10/0562 , C04B35/495 , C04B35/486 , C04B35/622 , C04B35/44 , C04B35/645 , H01M50/431 , H01M50/46 , H01M50/489 , C01G25/00 , H01M4/04 , H01M10/0525 , H01M50/491 , H01M50/406
CPC分类号： H01M10/4235 , C01G25/006 , C04B35/44 , C04B35/486 , C04B35/495 , C04B35/62218 , C04B35/6455 , H01M4/0447 , H01M10/0525 , H01M10/0562 , H01M50/431 , H01M50/46 , H01M50/489 , C01P2002/30 , C01P2002/72 , C01P2004/02 , C01P2004/03 , C01P2004/52 , C01P2004/61 , C01P2006/16 , C01P2006/40 , C01P2006/90 , C04B2235/3203 , C04B2235/3217 , C04B2235/3227 , C04B2235/3244 , C04B2235/3251 , C04B2235/3255 , C04B2235/3839 , C04B2235/443 , C04B2235/5436 , C04B2235/5463 , C04B2235/764 , C04B2235/786 , C04B2235/963 , H01M50/403 , H01M50/406 , H01M50/491 , H01M2300/0071
摘要： The disclosure herein relates to rechargeable batteries and solid electrolytes therefore which include lithium-stuffed garnet oxides, for example, in a thin film, pellet, or monolith format wherein the density of defects at a surface or surfaces of the solid electrolyte is less than the density of defects in the bulk. In certain disclosed embodiments, the solid-state anolyte, electrolyte, and catholyte thin films, separators, and monoliths consist essentially of an oxide that conducts Li+ ions. In some examples, the disclosure herein presents new and useful solid electrolytes for solid-state or partially solid-state batteries. In some examples, the disclosure presents new lithium-stuffed garnet solid electrolytes and rechargeable batteries which include these electrolytes as separators between a cathode and a lithium metal anode.
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公开(公告)号：US11817551B2
公开(公告)日：2023-11-14
申请号：US17979083
申请日：2022-11-02
发明人： Cheng-Chieh Chao , Lei Cheng , Christopher Dekmezian , Tiffany Ho , Timothy Holme , Tommy Huang , Amal Mehrotra , Aram Yang
IPC分类号： H01M8/04 , H01M10/0562 , C01G25/00 , C09C1/40 , H01M10/0525 , H01M10/0585
CPC分类号： H01M10/0562 , C01G25/006 , C09C1/407 , H01M10/0525 , H01M10/0585 , C01P2002/30 , C01P2002/52 , C01P2002/85 , C01P2002/86 , C01P2006/40 , C01P2006/82 , H01M2300/0074
摘要： Set forth herein are processes for making lithium-stuffed garnet oxides (e.g., Li7La3Zr2O12, also known as LLZO) that have passivated surfaces comprising a fluorinate and/or an oxyfluorinate species. These surfaces resist the formation of oxides, carbonates, hydroxides, peroxides, and organics that spontaneously form on LLZO surfaces under ambient conditions. Also set forth herein are new materials made by these processes.
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