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1.
公开(公告)号:US20220223905A1
公开(公告)日:2022-07-14
申请号:US17485641
申请日:2021-09-27
发明人: Oleh KARPENKO , Niall Donnelly , Tim HOLME , Will HUDSON , Sriram IYER , Dong Hee Anna CHOI , Mohit SINGH , Adrian WINOTO
IPC分类号: H01M10/0562 , C04B35/486 , C04B35/495 , C04B35/645 , H01M10/0525 , C04B35/626 , C04B35/65 , H01M10/0585 , C01G25/00 , C04B35/488 , C04B35/622 , C04B35/64 , C04B41/00 , C04B41/50 , C04B35/117
摘要: Set forth herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also set forth herein are lithium-stuffed garnet thin films having fine grains therein. Disclosed herein are novel and inventive methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are novel electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also set forth herein are methods for preparing novel structures, including dense thin (
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公开(公告)号:US20230282873A1
公开(公告)日:2023-09-07
申请号:US18152566
申请日:2023-01-10
发明人: Zhebo CHEN , Tim HOLME , Marie MAYER , Nick PERKINS , Eric TULSKY , Cheng-Chieh CHAO , Christopher DEKMEZIAN , Shuang LI
IPC分类号: H01M10/0525 , H01M4/505 , H01M4/525 , H01M10/0562 , H01M50/431 , H01M50/489 , H01M50/494 , H01M50/491
CPC分类号: H01M10/0525 , H01M4/505 , H01M4/525 , H01M10/0562 , H01M50/431 , H01M50/489 , H01M50/494 , H01M50/491 , H01M2300/0068 , H01M2300/0094
摘要: Set forth herein are compositions comprising A·(LiBH4)·B·(LiX)·C·(LiNH2),
wherein X is fluorine, bromine, chloride, iodine, or a combination thereof, and
wherein 0.1≤A≤3, 0.1≤B≤4, and 0≤C≤9 that are suitable for use as solid electrolyte separators in lithium electrochemical devices. Also set forth herein are methods of making A·(LiBH4)·B·(LiX)·C·(LiNH2) compositions. Also disclosed herein are electrochemical devices which incorporate A·(LiBH4)·B·(LiX)·C·(LiNH2) compositions and other-
3.
公开(公告)号:US20220344704A1
公开(公告)日:2022-10-27
申请号:US17709390
申请日:2022-03-30
发明人: Oleh KARPENKO , Niall Donnelly , Tim HOLME , Will HUDSON , Sriram IYER , Dong Hee Anna CHOI , Mohit SINGH , Adrian WINOTO
IPC分类号: H01M10/0562 , C04B35/486 , C04B35/645 , H01M10/0525 , C04B41/00 , C04B35/626 , C04B35/622 , C04B35/488 , C04B35/65 , C04B35/495 , C01G25/00 , C04B35/117 , C04B41/50 , H01M10/0585 , C04B35/64
摘要: Set forth herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also set forth herein are lithium-stuffed garnet thin films having fine grains therein. Disclosed herein are novel and inventive methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are novel electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also set forth herein are methods for preparing novel structures, including dense thin (
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公开(公告)号:US20230123228A1
公开(公告)日:2023-04-20
申请号:US17867845
申请日:2022-07-19
发明人: Tim HOLME , Kim VAN BERKEL , William HUDSON , Kian KERMAN , Sunil MAIR , Amal MEHROTRA , Zhebo CHEN
IPC分类号: H01M10/056 , C01D15/00 , H01M10/0562 , H01M10/0525
摘要: The present disclosure sets forth battery components for secondary and/or traction batteries. Described herein are new solid-state lithium (Li) conducting electrolytes including monolithic, single layer, and bi-layer solid-state sulfide-based lithium ion (Li+) conducting catholytes or electrolytes. These solid-state ion conductors have particular chemical compositions which are arranged and/or bonded through both crystalline and amorphous bonds. Also provided herein are methods of making these solid-state sulfide-based lithium ion conductors including new annealing methods. These ion conductors are useful, for example, as membrane separators in rechargeable batteries.
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公开(公告)号:US20220190382A1
公开(公告)日:2022-06-16
申请号:US17488187
申请日:2021-09-28
发明人: Arnold ALLENIC , Cheng-Chieh CHAO , Lei CHENG , Niall DONNELLY , William H. GARDNER , Tim HOLME , Sriram IYER , Shuang LI
IPC分类号: H01M10/0562 , H01M10/052 , H01M10/056 , H01M10/058 , C04B35/488 , C04B35/622 , H01M50/403 , H01M50/409 , H01M10/0565
摘要: Set forth herein are pellets, thin films, and monoliths of lithium-stuffed garnet electrolytes having engineered surfaces. These engineered surfaces have a list of advantageous properties including, but not limited to, low surface area resistance, high Li+ ion conductivity, low tendency for lithium dendrites to form within or thereupon when the electrolytes are used in an electrochemical cell. Other advantages include voltage stability and long cycle life when used in electrochemical cells as a separator or a membrane between the positive and negative electrodes. Also set forth herein are methods of making these electrolytes including, but not limited to, methods of annealing these electrolytes under controlled atmosphere conditions. Set forth herein, additionally, are methods of using these electrolytes in electrochemical cells and devices. The instant disclosure further includes electrochemical cells which incorporate the lithium-stuffed garnet electrolytes set forth herein.
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公开(公告)号:US20230050593A1
公开(公告)日:2023-02-16
申请号:US17961195
申请日:2022-10-06
发明人: Larry Beck , Cheng-Chieh CHAO , Lei CHENG , Niall DONNELLY , William H. GARDNER , Tim HOLME , Will HUDSON , Sriram IYER , Oleh KARPENKO , Yang LI , Gengfu XU
IPC分类号: H01M10/0562 , C01G25/00 , H01M10/0525
摘要: The instant disclosure sets forth multiphase lithium-stuffed garnet electrolytes having secondary phase inclusions, wherein these secondary phase inclusions are material(s) which is/are not a cubic phase lithium-stuffed garnet but which is/are entrapped or enclosed within a lithium-stuffed garnet. When the secondary phase inclusions described herein are included in a lithium-stuffed garnet at 30-0.1 volume %, the inclusions stabilize the multiphase matrix and allow for improved sintering of the lithium-stuffed garnet. The electrolytes described herein, which include lithium-stuffed garnet with secondary phase inclusions, have an improved sinterability and density compared to phase pure cubic lithium-stuffed garnet having the formula Li7La3Zr2O12.
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公开(公告)号:US20220328867A1
公开(公告)日:2022-10-13
申请号:US17709393
申请日:2022-03-30
发明人: Larry BECK , Cheng-Chieh CHAO , Lei CHENG , Niall DONNELLY , William H. GARDNER , Tim HOLME , Will HUDSON , Sriram IYER , Oleh KARPENKO , Yang LI , Gengfu XU
IPC分类号: H01M10/0562 , C01G25/00 , H01M10/0525
摘要: The instant disclosure sets forth multiphase lithium-stuffed garnet electrolytes having secondary phase inclusions, where-in these secondary phase inclusions are material(s) which is/are not a cubic phase lithium-stuffed garnet but which is/are entrapped or enclosed within a lithium-stuffed garnet. When the secondary phase inclusions described herein are included in a lithium-stuffed garnet at 30-0.1 volume %, the inclusions stabilize the multiphase matrix and allow for improved sintering of the lithium-stuffed garnet. The electrolytes described herein, which include lithium-stuffed garnet with secondary phase inclusions, have an improved sinterability and density compared to phase pure cubic lithium-stuffed garnet having the formula Li7La3Zr2O12.
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公开(公告)号:US20220250988A1
公开(公告)日:2022-08-11
申请号:US17588108
申请日:2022-01-28
发明人: Oleh KARPENKO , Gengfu XU , Niall DONNELLY , Sriram IYER , Tim HOLME
IPC分类号: C04B35/50 , H01M10/052 , C04B35/626 , B32B18/00 , C04B35/486 , C04B35/634 , B32B37/16 , C04B35/622 , C04B35/638 , C04B35/64 , H01M10/0525 , H01M10/0562
摘要: Set forth herein are processes and materials for making ceramic thin films by casting ceramic source powders and precursor reactants, binders, and functional additives into unsintered thin films and subsequently sintering the thin films under controlled atmospheres and on specific substrates.
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公开(公告)号:US20220021025A1
公开(公告)日:2022-01-20
申请号:US17477313
申请日:2021-09-16
发明人: Cheng-Chieh CHAO , Zhebo CHEN , Lei CHENG , Niall DONNELLY , Tim HOLME , Tommy HUANG , Sriram IYER , Kian KERMAN , Harsh MAHESHWARI , Jagdeep SINGH , Gengfu XU
IPC分类号: H01M10/0562 , H01M10/0525 , H01M10/052
摘要: Provided herein are detect-free solid-state separators which are useful as Li| ion-conducting electrolytes in electro-chemical cells and devices, such as, but not limited to, rechargeable batteries. In some examples, the separators have a Li+ ion-conductivity greater than 1*10−3 S/cm at room temperature.
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公开(公告)号:US20210344082A1
公开(公告)日:2021-11-04
申请号:US17281159
申请日:2019-10-01
发明人: Larry W. BECK , Cheng-Chieh CHAO , Niall DONNELLY , Tim HOLME , Shuang LI , Kim VAN BERKEL , Danielle GENDRON , Shawna SMITH , Karen SUGANO , Clarissa YAW
IPC分类号: H01M50/474 , H01M50/403 , H01M10/0525 , H01M50/46 , H01M50/483 , H01M50/431
摘要: Provided herein are electrochemical cells and/or electrode stacks comprising an interlayer disposed proximate to the negative electrode current collector and/or a metal negative electrode, wherein the interlayer is disposed between and in contact with a negative electrode current collector and a solid-state electrolyte separator or between and in contact with a metal negative electrode and a solid-state electrolyte separator.
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