摘要:
A process for the deposition of a thin film of a desired material on a surface comprising: (i) providing a continuous stream of amorphous solid particles of desired material suspended in at least one carrier gas, the solid particles having a volume-weighted mean particle diameter of less than 500 nm, at an average stream temperature below the glass transition temperature of the solid particles of desired material, (ii) passing the stream provided in (i) into a heating zone, and heating the stream in the heating zone to elevate the average stream temperature to above the glass transition temperature of the solid particles of desired material, wherein no substantial chemical transformation of the desired material occurs due to heating of the desired material, (iii) exhausting the heated stream from the heating zone through at least one distributing passage, at a rate substantially equal to its rate of addition to the heating zone in step (ii), wherein the carrier gas does not undergo a thermodynamic phase change upon passage through heating zone and distribution passage, and (iv) exposing a receiver surface that is at a temperature below the temperature of the heated stream to the exhausted flow of the heated stream, and depositing particles of the desired material to form a thin uniform layer of the desired material on the receiver surface.
摘要:
A process for the preparation of a self assembled superlattice thin film of organic nanocrystal particles is described comprising: (i) combining one or more functional organic material to be precipitated as nanocrystal particles and one or more surface active material in a compressed CO2 phase with a density of at least 0.1 g/cc, where the functional material is substantially insoluble in the compressed CO2 in the absence of the surfactant, the surfactant comprises a compressed CO2-philic portion and a functional material-philic portion, and the compressed CO2 phase, functional material and surfactant interact to form an aggregated system having a continuous compressed CO2 phase and a plurality of aggregates comprising surfactant and functional material molecules of average diameter less than 50 nanometers dispersed therein; (ii) rapidly depressurizing the compressed CO2 phase thereby precipitating the dispersed functional and surfactant materials in the form of composite organic nanocrystals of average diameter less than 50 nanometers, and (iii) depositing the organic nanocrystals on a substrate surface, wherein the organic nanocrystals form a thin film having an ionic content of less than 0.001 M in equivalent sodium chloride concentration on the substrate surface, and the thin film exhibits a long range periodicity in the arrangement of the organic nanocrystals in a self assembled superlattice structure, as evidenced by x-ray diffraction.
摘要:
Authentication systems, apparatus, and methods authenticate an identification marking including a nanocrystalline material. One or more properties of the marking are ascertained to provide a measured profile. The measured profile is compared to at least one member of a closed set of reference profiles. Each reference profile has predetermined values of one or more properties. Each reference profile is unique within the set. At least one reference profile is characteristic of an indicator material in a nanocrystalline morphology and non-characteristic of the same indicator material in a bulk morphology.
摘要:
A process for forming a film of the facial-isomer of an aluminum trisquinoline complex comprises depositing a film of an aluminum trisquinoline complex on a support, depositing an inert barrier layer over the layer of aluminum trisquinoline complex that encapsulates aluminum trisquinoline complex to form a multilayer composite, and then heating the composite at a temperature below the melting point temperature of the complex for a time sufficient to convert the aluminum trisquinoline complex to at least 99 mol % of the facial-isomer that fluoresces with a maximum emission intensity below 510 nm. The product has a blue hue.
摘要:
The invention relates to An X-ray exposure indicator device comprising a solid X-ray sensitive material that upon X-ray exposure undergoes a chromatic change, wherein the exposure indicator device does not significantly change color when subjected to UV or visible radiation.
摘要:
A process for forming the facial isomer of an aluminum trisquinoline complex comprises heating the solid aluminum trisquinoline complex material at a temperature at least 50° C. below the melting point temperature of the solid for a time sufficient to convert the aluminum trisquinoline complex to at least 99 mol % of one polymorph of thefacial-isomer that fluoresces with a maximum intensity below 510 nm.
摘要:
The present disclosure relates to aqueous dispersions of silver (carboxylate-azine toner) particles wherein the azine content of the particles is from about 0.01 to 10% by weight relative to silver carboxylate. The carboxylates are typically silver salts of long chain fatty acids and the azine toners are the compounds that function as development accelerators and toning agents such as phthalazine. These silver (carboxylate-azine) particles can be used to formulate imaging forming compositions that are useful in aqueous thermographic or photothermographic imaging elements.
摘要:
The present invention relates to a nanocomposite composition comprising a clay material splayed with an inorganic particle having a diameter equal to or less than 30 nanometers. Another embodiment of the invention includes a splayed material comprising a layered material splayed with a particle, wherein the particle comprises a diameter equal to or less than 30 nanometers. Another embodiment relates to a method for preparing an exfoliated nanocomposite composition comprising the steps of preparing an inorganic particle, mixing the particle with a layered material dispersed in a medium, and splaying the layered material to produce a nanocomposite, wherein the inorganic particle comprises a diameter equal to or less than 30 nanometers.
摘要:
A process for characterizing the phase of an organic material in a thin film comprises employing a reference spectrum library for potential phases, subjecting the film to a vibrational spectroscopy measurement to obtain a resulting spectrum; and comparing the resulting spectrum to those in the reference library to characterize the phase of the organic material.
摘要:
The present disclosure relates to aqueous dispersions of silver (carboxylate-azine toner) particles wherein the azine content of the particles is from about 0.01 to 10% by weight relative to silver carboxylate. The carboxylates are typically silver salts of long chain fatty acids and the azine toners are the compounds that function as development accelerators and toning agents such as phthalazine. These silver (carboxylate-azine) particles can be used to formulate imaging forming compositions that are useful in aqueous thermographic or photothermographic imaging elements.