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    ACTIVITY MONITORING AND POLYMERIZATION PROCESS CONTROL
    5.
    发明申请
    ACTIVITY MONITORING AND POLYMERIZATION PROCESS CONTROL 有权
    活动监测和聚合过程控制

    公开(公告)号：US20140058050A1

    公开(公告)日：2014-02-27

    申请号：US13878255

    申请日：2011-09-23

    申请人： Ursula Tracht ,  Ricarda Leiberich ,  Michael Berger ,  Hanns-Ingolf Paul ,  Udo Wiesner

    发明人： Ursula Tracht ,  Ricarda Leiberich ,  Michael Berger ,  Hanns-Ingolf Paul ,  Udo Wiesner

    IPC分类号： C08F236/08

    CPC分类号： C08F236/08 ,  B01J19/0033 ,  B01J19/18 ,  B01J2219/00164 ,  B01J2219/00186 ,  B01J2219/00198 ,  B01J2219/00209 ,  B01J2219/00231 ,  C08F210/12 ,  C08F2400/02 ,  C08F2/00

    摘要： The present invention relates to a method to control a liquid feed stream carried out by measuring at least one spectrum of the liquid feed stream comprising an initiator or catalyst, determining its activity using a predictive model on the basis of said spectrum and adjusting the feed streams and/or the preparation conditions of the feed stream comprising the initiators or catalysts in order to attain or maintain a desired level of total activity. In a further aspect the invention relates to a controlled process for the preparation of polymers in a polymerization reactor by contacting liquid feed streams comprising monomers and initiators or catalysts, whereby the control of the feed streams entering the polymerization reactor and/or the initiator or catalyst preparation is carried out by measuring at least one spectrum of the liquid feed stream comprising an initiator or catalyst, determining its activity using a predictive model on the basis of said spectrum and adjusting the feed streams and/or the preparation conditions of the feed stream comprising the initiators or catalysts in order to attain or maintain a desired level of total activity within the polymerization reactor. More particularly, the invention relates to a method for controlling the activity of aluminium containing initiators in a process for the co-polymerisation of isolefins and multiolefins, in particular isobutylene and isoprene. The present invention further to device and a chemical plant suitable to operate said process.

    摘要翻译： 本发明涉及一种控制液体进料流的方法，所述方法是通过测量包含引发剂或催化剂的至少一个光谱的液体进料物流，使用基于所述光谱的预测模型确定其活性并调节进料流 和/或包含引发剂或催化剂的进料流的制备条件以获得或保持期望的总活性水平。 在另一方面，本发明涉及通过使包含单体和引发剂或催化剂的液体进料流接触而在聚合反应器中制备聚合物的受控方法，由此控制进入聚合反应器和/或引发剂或催化剂的进料流 通过测量包含引发剂或催化剂的液体进料流的至少一个谱线，基于所述光谱使用预测模型确定其活性并调节进料流和/或进料流的制备条件来进行制备，所述进料流和/ 引发剂或催化剂，以获得或保持聚合反应器内所需的总活性水平。 更具体地说，本发明涉及在异烯烃和多烯烃，特别是异丁烯和异戊二烯的共聚合方法中控制含铝引发剂的活性的方法。 本发明还涉及适用于操作所述方法的装置和化学设备。

    Reactor and method for continuous polymerization
    6.
    发明授权
    Reactor and method for continuous polymerization 有权
    反应器和连续聚合方法

    公开(公告)号：US08747756B2

    公开(公告)日：2014-06-10

    申请号：US13381152

    申请日：2010-07-01

    申请人： Rolf Feller ,  Hanns-Ingolf Paul ,  Paul Wagner ,  John Lovegrove ,  Jörg Kirchhoff ,  Joachim Ritter ,  Ricarda Leiberich ,  Udo Wiesner

    发明人： Rolf Feller ,  Hanns-Ingolf Paul ,  Paul Wagner ,  John Lovegrove ,  Jörg Kirchhoff ,  Joachim Ritter ,  Ricarda Leiberich ,  Udo Wiesner

    IPC分类号： B01J19/00 ,  C08F2/00

    CPC分类号： C08F2/01 ,  B01J19/1887 ,  B01J19/20 ,  B01J2219/00094 ,  B01J2219/00159 ,  B01J2219/00166 ,  B01J2219/00189 ,  B01J2219/00247 ,  B01J2219/182 ,  B01J2219/187

    摘要： The present invention relates to a reactor (10) and a process for continuous polymerization, where the reactor (10) has an essentially tubular reactor housing (16). The reactor housing (16) has a drive (38) which runs along the geometric central axis (12) in the flow direction (22) and is configured as a central shaft. A rotatably arranged scraper or wiper (36) is provided within the reactor housing (16); the scraper or wiper (36) has at least one scraper or wiper blade (42) to run along an interior side (44) of the reactor housing (16). The rotational movement of the scraper or wiper (36) results in radial mixing of a stream within the reactor housing (16) which dominates gravity effects and, by virtue of shaping of the scrapers or wipers, optionally makes plug flow or backflow within the reactor (10) possible. This allows the reaction conditions in the axial direction of the reactor housing (16) to be predicted and individually suitable reaction conditions to be set and controlled along the reactor housing, so that, in particular, a desired molecular weight distribution can be set.

    摘要翻译： 本发明涉及反应器（10）和连续聚合方法，其中反应器（10）具有基本上管状的反应器壳体（16）。 反应器壳体（16）具有在流动方向（22）上沿几何中心轴线（12）延伸并被构造为中心轴的驱动器（38）。 在反应器壳体（16）内设置有可旋转地布置的刮刀（36）。 刮刀或擦拭器（36）具有至少一个沿着反应器壳体（16）的内侧（44）延伸的刮刀或刮片（42）。 刮刀或擦拭器（36）的旋转运动导致反应器壳体（16）内的流的径向混合，其支配重力作用，并且借助于刮板或刮水器的成形，可任选地使反应器内的塞流或回流 （10）可能。 这允许预测反应器壳体（16）的轴向方向的反应条件，并且可以沿着反应器壳体设置和控制各自适当的反应条件，使得特别地可以设定所需的分子量分布。

    Process for the continuous production of aryl carbonates
    7.
    发明授权
    Process for the continuous production of aryl carbonates 失效
    连续生产碳酸芳基酯的方法

    公开(公告)号：US5463102A

    公开(公告)日：1995-10-31

    申请号：US182867

    申请日：1994-01-18

    申请人： Norbert Schon ,  Johann Rechner ,  Paul Wagner ,  Hans-Josef Buysch ,  Hans-Erich Gasche ,  Ricarda Leiberich

    发明人： Norbert Schon ,  Johann Rechner ,  Paul Wagner ,  Hans-Josef Buysch ,  Hans-Erich Gasche ,  Ricarda Leiberich

    IPC分类号： C07B61/00 ,  C07C68/06 ,  C07C68/08 ,  C07C69/96

    CPC分类号： C07C68/06

    摘要： Organic carbonates containing at least one aromatic ester group can be obtained in a continuous manner from carbonates containing at least one aliphatic ester group and a phenolic compound in the presence of a transesterification catalyst known per se by carrying out the reaction in at least two stirred containers connected one behind the other in such a way that, in each case, the phenolic compound is metered in liquid form into the first stirred container and the carbonate containing at least one aliphatic ester group is metered in liquid form into one or more of the stirred containers. The carbonate containing at least one aromatic ester group is removed in liquid form from the last stirred container. Volatile reaction products, for example alcohol which has been cleaved out or a dialkyl carbonate are removed in gaseous form from one or more stirred containers.

    摘要翻译： 含有至少一个芳族酯基的有机碳酸酯可以在本体已知的酯交换催化剂存在下，通过在至少两个搅拌容器中进行反应，以含有至少一种脂肪族酯基和酚类化合物的碳酸酯连续获得 在每种情况下将酚类化合物以液体形式计量到第一搅拌容器中，并且将含有至少一种脂族酯基的碳酸酯以液体形式计量成一个或多个搅拌的 容器 含有至少一个芳族酯基的碳酸酯以液体形式从最后搅拌的容器中除去。 挥发性反应产物，例如已经被裂解的醇或碳酸二烷基酯从一种或多种搅拌容器中以气态形式除去。

    Activity monitoring and polymerization process control
    8.
    发明授权
    Activity monitoring and polymerization process control 有权
    活动监测和聚合过程控制

    公开(公告)号：US09562125B2

    公开(公告)日：2017-02-07

    申请号：US13878255

    申请日：2011-09-23

    申请人： Ursula Tracht ,  Ricarda Leiberich ,  Michael Berger ,  Hanns-Ingolf Paul ,  Udo Wiesner

    发明人： Ursula Tracht ,  Ricarda Leiberich ,  Michael Berger ,  Hanns-Ingolf Paul ,  Udo Wiesner

    IPC分类号： C08F236/08 ,  C08F2/00 ,  C08F210/12 ,  B01J19/18 ,  B01J19/00

    CPC分类号： C08F236/08 ,  B01J19/0033 ,  B01J19/18 ,  B01J2219/00164 ,  B01J2219/00186 ,  B01J2219/00198 ,  B01J2219/00209 ,  B01J2219/00231 ,  C08F210/12 ,  C08F2400/02 ,  C08F2/00

    摘要： The present invention relates to a method to control a liquid feed stream carried out by measuring at least one spectrum of the liquid feed stream comprising an initiator or catalyst, determining its activity using a predictive model on the basis of said spectrum and adjusting the feed streams and/or the preparation conditions of the feed stream comprising the initiators or catalysts in order to attain or maintain a desired level of total activity. In a further aspect the invention relates to a controlled process for the preparation of polymers in a polymerization reactor by contacting liquid feed streams comprising monomers and initiators or catalysts, whereby the control of the feed streams entering the polymerization reactor and/or the initiator or catalyst preparation is carried out by measuring at least one spectrum of the liquid feed stream comprising an initiator or catalyst, determining its activity using a predictive model on the basis of said spectrum and adjusting the feed streams and/or the preparation conditions of the feed stream comprising the initiators or catalysts in order to attain or maintain a desired level of total activity within the polymerization reactor. More particularly, the invention relates to a method for controlling the activity of aluminum containing initiators in a process for the co-polymerization of isolefins and multiolefins, in particular isobutylene and isoprene. The present invention further to device and a chemical plant suitable to operate said process.

    摘要翻译： 本发明涉及一种控制液体进料流的方法，所述方法是通过测量包含引发剂或催化剂的至少一个光谱的液体进料物流，使用基于所述光谱的预测模型确定其活性并调节进料流 和/或包含引发剂或催化剂的进料流的制备条件以获得或保持期望的总活性水平。 在另一方面，本发明涉及通过使包含单体和引发剂或催化剂的液体进料流接触而在聚合反应器中制备聚合物的受控方法，由此控制进入聚合反应器和/或引发剂或催化剂的进料流 通过测量包含引发剂或催化剂的液体进料流的至少一个谱线，基于所述光谱使用预测模型确定其活性并调节进料流和/或进料流的制备条件来进行制备，所述进料流和/ 引发剂或催化剂，以获得或保持聚合反应器内所需的总活性水平。 更具体地说，本发明涉及在用于共聚烯烃和多烯烃，特别是异丁烯和异戊二烯的方法中控制含铝引发剂的活性的方法。 本发明还涉及适用于操作所述方法的装置和化学设备。

    REACTOR AND METHOD FOR CONTINUOUS POLYMERIZATION
    9.
    发明申请
    REACTOR AND METHOD FOR CONTINUOUS POLYMERIZATION 有权
    反应器和连续聚合方法

    公开(公告)号：US20140148561A1

    公开(公告)日：2014-05-29

    申请号：US13995246

    申请日：2011-12-29

    申请人： Hanns-Ingolf Paul ,  Rolf Feller ,  Paul Wagner ,  John Lovegrove ,  Joachim Ritter ,  Ricarda Leiberich ,  Jörg Kirchhoff ,  Udo Wiesner

    发明人： Hanns-Ingolf Paul ,  Rolf Feller ,  Paul Wagner ,  John Lovegrove ,  Joachim Ritter ,  Ricarda Leiberich ,  Jörg Kirchhoff ,  Udo Wiesner

    IPC分类号： C08F136/08 ,  B01J19/18

    CPC分类号： C08F136/08 ,  B01J19/18 ,  B01J19/1812 ,  B01J19/1887 ,  B01J19/20 ,  B01J2219/00094 ,  B01J2219/0011 ,  B01J2219/00159 ,  B01J2219/00166 ,  B01J2219/00189 ,  B01J2219/00245 ,  B01J2219/00254 ,  B01J2219/182 ,  C08F210/12 ,  C08F236/08 ,  C08F2/01

    摘要： The present invention relates to a reactor (10) and a process for continuous polymerization, where the reactor (10) has an essentially tubular reactor housing (16). The reactor housing (16) has a drive (38) which runs along the geometric central axis (12) in the flow direction (22) and is configured as a central shaft. A rotatably arranged scraper or wiper (36) is provided within the reactor housing (16); the scraper or wiper (36) has at least one scraper or wiper blade (42) to run along an interior side (44) of the reactor housing (16). The rotational movement of the scraper or wiper (36) results in radial mixing of a stream within the reactor housing (16) which dominates gravity effects and, by virtue of shaping of the scrapers or wipers, optionally makes plug flow or a loop flow or backflow within the reactor (10) or else via an additional external pumped circulation system (23) possible. This allows the reaction conditions in the axial direction of the reactor housing (16) to be predicted and individually suitable reaction conditions to be set and controlled along the reactor housing, so that, in particular, a desired molecular weight distribution can be set.

    摘要翻译： 本发明涉及反应器（10）和连续聚合方法，其中反应器（10）具有基本上管状的反应器壳体（16）。 反应器壳体（16）具有在流动方向（22）上沿几何中心轴线（12）延伸并被构造为中心轴的驱动器（38）。 在反应器壳体（16）内设置有可旋转地布置的刮刀（36）。 刮刀或擦拭器（36）具有至少一个沿着反应器壳体（16）的内侧（44）延伸的刮刀或刮片（42）。 刮刀或擦拭器（36）的旋转运动导致反应器壳体（16）内的流的径向混合，其支配重力作用，并且借助刮板或刮水器的成形，可选地使塞子流或环流或 反应器（10）内的回流，或经由另外的外部泵送循环系统（23）。 这允许预测反应器壳体（16）的轴向方向的反应条件，并且可以沿着反应器壳体设置和控制各自适当的反应条件，使得特别地可以设定所需的分子量分布。