摘要:
The present invention relates to a substrate-supported process for continuous and automated manufacturing of microfibrous fuel cells and other electrochemical cells. Specifically, a removable substrate layer is formed around an inner current collector, followed by sequentially coating multiple structure layers, such as the inner catalyst layer, the membrane separator, and the outer catalyst layer, over such removable substrate layer, and subsequent removing such removable substrate layer, so as to form a lumen around the inner current collector, to allow passage of fluid therethrough. The removable substrate layer preferably comprises a water-soluble polymer, such as polyvinyl pyrrolidone (PVP), polyvinyl alcohol (PVA), or polyethylene glycol (PEG).
摘要:
Fabrication process for manufacture of microcell structures and assemblies, in which a microcell precursor is contacted with one or more of electrolytes, electrocatalysts, electrocatalyst reducing agents, and hydrophicity-imparting materials. The process may derive the precursor from a high rate extrusion process in which the electrocatalyst is impregnated, coated or extruded on a fibrous substrate to form an electrode. The process of the invention permits the high volume production of fibrous microcell elements for correlative high volume production of highly compact, small footprint electrochemical cells useful for a variety of vehicular, consumer and industrial applications.
摘要:
The present invention relates to a gas storage and dispensing system, which comprising a carrier material for a target gas and multiple microtubular elements in contact with such carrier material. Each microtubular element comprises a tubular wall that defines a bore side and a shell side that are sealed from each other, preferably by one or more potting members. The carrier material is either at the bore sides or at the shell sides of the microtubular elements, and it can be either a solid sorbent material for the target gas, or a liquid carrier therefor. Such gas storage and dispensing system is particular useful for hydrogen storage, when the carrier material can be a hydrogen-sorbent that contains hydrogen gas, or liquefied hydrogen, or an organic hydrogen solution, or a metal hydride solution capable of generating hydrogen gas. Such microtubular elements can further be designed as microfibrous fuel cells, while each microfibrous fuel cell comprises a carrier material at its bore side.
摘要:
The present invention relates to a substrate-supported process for continuous and automated manufacturing of microfibrous fuel cells and other electrochemical cells. Specifically, a removable substrate layer is formed around an inner current collector, followed by sequentially coating multiple structure layers, such as the inner catalyst layer, the membrane separator, and the outer catalyst layer, over such removable substrate layer, and subsequent removing such removable substrate layer, so as to form a lumen around the inner current collector, to allow passage of fluid therethrough. The removable substrate layer preferably comprises a water-soluble polymer, such as polyvinyl pyrrolidone (PVP), polyvinyl alcohol (PVA), or polyethylene glycol (PEG).
摘要:
The subject invention relates to a battery cell structure fabricated from a single fiber containing an electrode or active material of an electrode, a membrane separator, the electrolyte, the active material of a second electrode or a second electrode. Further, the subject invention relates to a cell design fabricated from two single fibers in contact with each other, one containing an electrode, a membrane separator, electrolyte, and the other, a second electrode. The two electrodes here, represent the positive and negative electrodes of a cell. The invention further relates to the process of inserting one fibrous electrode inside a fibrous membrane separator or insulator and to the process of forming one fibrous cell which contains an electrode, porous insulator, the electrolyte, the active material of a second electrode or a second electrode.
摘要:
The subject invention relates to an electrochemical cell in which a fiber containing electrode, a membrane separator, the electrolyte, the second electrode or electrocatalyst of the second electrode complete an electrochemical cell. Further, to a process for fabricating a fiber cell in which the cell is completed by two fibers, one containing, an electrode, a membrane separator, the electrolyte, and the other a second electrode. The two electrodes represent the positive and negative electrodes of an electrochemical cell.
摘要:
A process for fabricating a fibrous electrochemical cell is disclosed. The process results in a fibrous cell comprising a single-fiber inner electrode, a hollow membrane separator with bore and shell sides surrounding said inner electrode, an electrolyte, and a second outer electrode material completing the electrochemical cell. The cell has an outside diameter in the range from about 100 micrometers to 10 millimeters. Further, a process for fabricating a fibrous electrochemical cell comprising two fibers is disclosed. In this instance, the second fiber forms the outer electrode.
摘要:
The present invention relates to microfibrous fuel cell sub-bundle structures, fuel cell bundles and fuel cell assemblies formed by such fuel cell sub-bundles and bundles. Specifically, a fuel cell sub-bundle is provided, which comprises multiple microfibrous fuel cells. Each microfibrous fuel cell comprises: (a) a hollow microfibrous membrane separator comprising an electrolyte medium, (b) an inner electrocatalyst layer in contact with an inner surface of such membrane separator, (c) an outer electrocatalyst layer in contact with an outer surface of such membrane separator, and (d) an individual current collector in electrical contact with the inner surface of such membrane separator. Each of such multiple microfibrous fuel cells is in electrical contact with a common current collector at the outer surface of its membrane separator.
摘要:
A microcell assembly wherein water is generated by electrochemical reaction and sorptive channeling elements are provided in the assembly to remove excess water from the locus of electrochemical reaction. The water management techniques of the invention enhance electrochemical generation/conversion of energy, and facilitate high voltage, high power density outputs for applications such as fuel cell and battery systems.
摘要:
A fibrous microcell structure comprising at least one electrically conductive fibrous element circumscribed by a porous membrane separator having coated, impregnated or extruded at an inner surface thereof a first electrocatalyst layer having an electrically conductive hydrogen- or oxygen-permselective membrane thereon, with an electrolyte disposed in porosity of the porous membrane separator. The structure includes a central lumen, at least one electrically conductive fibrous element and interstitial volume accommodating flow of feed through the lumen, at least one electrically conductive fibrous element in contact with the second electrocatalyst layer, and the porous membrane separator at its outer surface being in contact with an electrocatalyst and at least one electrically conductive fiber.