Abstract:
Certain fatty acid amide-based surfactants such as cocamide DEA (also known as “coco(nut) diethanolamide” or “coco(nut) DEA”) when dissolved or dispersed in a cutting oil (diesel, light cycle oil, naphtha, and such other petroleum distillates) produce a petroleum distillate having significantly enhanced solvency for heavy residuals. Such solutions or dispersions are especially useful for cleaning vessels and similar equipment in refineries by circulating the solution or dispersion in the vessel, optionally with the application of heat.
Abstract:
Pyrophoric material such as iron sulfide is frequently found in refinery equipment. When the equipment is opened to the atmosphere for maintenance, an exothermic reaction can take place that may cause injury to personnel and catastrophic damage to equipment. A process used to treat pyrophoric material uses sodium nitrite injected into a gaseous carrier stream to oxidize iron sulfides to elemental sulfur and iron oxides. The sodium nitrite solution may be buffered to a pH of about 9 with disodium phosphate or monosodium phosphate. A chemical additive that provides a quantitative measure of reaction completion may be added to the treatment solution.
Abstract:
A process for quickly removing hydrocarbon contaminants and noxious gases in a safe and effective manner from catalytic reactors, other media packed process vessels and associated equipment in the vapor phase without using steam. The cleaning agent contains one or more solvents, such as terpenes or other organic solvents. The cleaning agent is injected into contaminated equipment, along with a carrier gas, in the form of a cleaning vapor.
Abstract:
A process for quickly removing hydrocarbon contaminants and noxious gases in a safe and effective manner from catalytic reactors, other media packed process vessels and associated equipment in the vapor phase without using steam. The cleaning agent contains one or more solvents, such as terpenes or other organic solvents. The cleaning agent is injected into contaminated equipment, along with a carrier gas, in the form of a cleaning vapor.
Abstract:
A process for quickly removing hydrocarbon contaminants and noxious gases in a safe and effective manner from catalytic reactors, other media packed process vessels and associated equipment in the vapor phase without using steam. The cleaning agent contains one or more solvents, such as terpenes or other organic solvents. The cleaning agent is injected into contaminated equipment, along with a carrier gas, in the form of a cleaning vapor.
Abstract:
Compositions, systems and methods for treating stainless steel vessels to prevent polythionic acid stress corrosion cracking are described. Compositions include pre-mixed K2CO3 solutions that can be diluted on-site to desired K2CO3 concentrations via in-line mixing with water prior to placement within a stainless steel vessel to be treated.
Abstract:
Methods and compositions for the removal of metal sulfides from spent catalysts in reactor vessels and associated equipment are described herein. Using the methods described herein, metal sulfides of a spent catalysts are converted to metal oxides and gaseous and liquid by-products when reacted with a formulation having one or more oxidizing agents. Also, using the methods described herein, metal sulfides and sulfides in the process equipment are oxidized, eliminating the potential formation of polythionic and thionic acids protecting materials from polythionic stress corrosion cracking. Also, using the methods described herein, halides (including chloride) and halide containing compounds and salts in the process equipment are removed, eliminating the potential formation of halide acids and further neutralized via pH buffering, and protecting materials from halide stress corrosion cracking.
Abstract:
Pyrophoric material such as iron sulfide is frequently found in refinery equipment. When the equipment is opened to the atmosphere for maintenance, an exothermic reaction can take place that may cause injury to personnel and catastrophic damage to equipment. A process used to treat pyrophoric material uses sodium nitrite injected into a gaseous carrier stream to oxidize iron sulfides to elemental sulfur and iron oxides. The sodium nitrite solution may be buffered to a pH of about 9 with disodium phosphate or monosodium phosphate. A chemical additive that provides a quantitative measure of reaction completion may be added to the treatment solution.
Abstract:
Pyrophoric material such as iron sulfide is frequently found in refinery equipment. When the equipment is opened to the atmosphere for maintenance, an exothermic reaction can take place that may cause injury to personnel and catastrophic damage to equipment. A process used to treat pyrophoric material uses sodium nitrite injected into a gaseous carrier stream to oxidize iron sulfides to elemental sulfur and iron oxides. The sodium nitrite solution may be buffered to a pH of about 9 with disodium phosphate or monosodium phosphate. A chemical additive that provides a quantitative measure of reaction completion may be added to the treatment solution.
Abstract:
Pyrophoric material such as iron sulfide is frequently found in refinery equipment. When the equipment is opened to the atmosphere for maintenance, an exothermic reaction can take place that may cause injury to personnel and catastrophic damage to equipment. A process used to treat pyrophoric material uses sodium nitrite injected into a gaseous carrier stream to oxidize iron sulfides to elemental sulfur and iron oxides. The sodium nitrite solution may be buffered to a pH of about 9 with disodium phosphate or monosodium phosphate. A chemical additive that provides a quantitative measure of reaction completion may be added to the treatment solution.