公开(公告)号：US4563191A

公开(公告)日：1986-01-07

申请号：US647269

申请日：1984-09-04

申请人： Manfred Hahnke ,  Reinhard Mohr ,  Kurt Hohmann

发明人： Manfred Hahnke ,  Reinhard Mohr ,  Kurt Hohmann

IPC分类号： D06P3/76 ,  C09B69/00 ,  D01F1/06 ,  D01F6/18 ,  D06P3/70 ,  C09B23/16 ,  D06F1/06 ,  D06P1/41

CPC分类号： D06P3/702 ,  C09B69/001 ,  D01F1/06 ,  D01F6/18 ,  Y10S8/927

摘要： Fiber material composed of acid-modified homopolymers or copolymers of acrylonitrile (PAC fibers) which has been obtained by a wet spinning process, has not been dried and is still in a swollen condition (gel form), can be dyed advantageously and in fast colors by means of soluble dyes, the molecule of which contains several groups, namely more than one quaternary grouping and/or a strongly basic grouping carrying no charge, which exert a basic action towards the acid groups of the fiber substance. The chromophore of this colorant can belong to the category of monoazo or diazo dyes, methine, azamethine or diazamethine dyes or naphthalactam dyes.In accordance with the invention, after substantially removing the non-aqueous spinning solvent by washing, the spun material, as a moist gel, is dyed continuously or discontinuously from an aqueous dyebath; the fibers can be stretched before the dye is applied, during the dyeing process itself or immediately afterwards.By virtue of their special nature, the dyes of the type designated above, which have a strong fixing action, produce optimum fixing rates when dyeing PAC gels and, in the subsequent production stages, do not cause any noticeable soiling, as a result of dye which has bled out, on components of machines and operating baths, such as stretching or after-treatment baths. Investigations of penetration of the fiber by the dye, of the fixing rate and of the resulting fastness properties, such as fastness to wet processing, have shown no disadvantages compared with conventional dyes.

摘要翻译： 由湿法纺丝法得到的酸改性均聚物或丙烯腈共聚物（PAC纤维）所组成的纤维材料未经干燥，仍处于溶胀状态（凝胶形式），可以有利地以快速染色 通过可溶性染料，其分子含有几个基团，即多于一个四元组和/或不带电荷的强碱基，其对纤维物质的酸基发挥基本作用。 这种着色剂的发色团可以属于单偶氮或重氮染料，次甲基，氮杂酮或二氮杂吗啉染料或萘胺染料。 根据本发明，通过洗涤基本上除去非水性纺丝溶剂后，作为湿凝胶的纺丝材料从水性染浴中连续或不连续地染色; 在染色过程本身之前或之后，纤维可以在施加染料之前被拉伸。 由于其特殊性质，具有强固定作用的上述类型的染料在染色PAC凝胶时产生最佳定影率，并且在随后的生产阶段中不会引起明显的污染，因为染料 已经排出了机器和操作浴的部件，如拉伸或后处理浴。 通过染料对纤维的渗透性，定影率和所得到的坚牢度性能的研究，例如湿法加工的坚牢度，与常规染料相比，没有显示出缺点。

公开(公告)号：US3966405A

公开(公告)日：1976-06-29

申请号：US558783

申请日：1975-03-17

申请人： Reinhard Mohr ,  Manfred Hahnke

发明人： Reinhard Mohr ,  Manfred Hahnke

IPC分类号： C09B51/00 ,  D06P1/42 ,  D06P1/92 ,  D06P3/76 ,  D06P5/00

CPC分类号： C09B51/00 ,  D06P1/42 ,  D06P1/924 ,  D06P3/76 ,  Y10S8/922 ,  Y10S8/924 ,  Y10S8/927

摘要： Dyestuffs of the formula ##EQU1## IN WHICH Alk is lower alkyl and in which the phenyl nucleus may be further substituted by nonionic substituents, n is 2 to 6 and x is a number of 1 up to but excluding 2, are useful for dyeing polymers containing acidic groups. These dyestuffs yield stable compositions containing 20 to 40 % by weight of one or more of said dyestuffs, 20 to 40 % by weight of an organic solvent, 20 to 40 % by weight of a nonionic dispersant of the alkylphenolpolyglycolether or fat alcohol polyglycolether type and up to 20 % by weight of water.

摘要翻译： 式NO2Alk ||NH-（CH2）n-N - （CH2）n-NH2x2-x IN的染料其中Alk是低级烷基，其中苯基可以被非离子取代基进一步取代，n是2〜 6和x是1至数量2但不包括2，可用于染色含酸性基团的聚合物。 这些染料产生稳定的组合物，其含有20至40重量％的一种或多种所述染料，20至40重量％的有机溶剂，20至40重量％的烷基酚聚乙二醇醚或脂肪醇聚乙二醇醚型非离子分散剂，以及 高达20重量％的水。

公开(公告)号：US4607071A

公开(公告)日：1986-08-19

申请号：US734442

申请日：1985-05-15

申请人： Manfred Hahnke ,  Reinhard Mohr ,  Kurt Hohmann

发明人： Manfred Hahnke ,  Reinhard Mohr ,  Kurt Hohmann

IPC分类号： C08K5/00 ,  C09B69/06 ,  D01F6/54 ,  C08K5/22 ,  C08J3/20 ,  D01F6/18

CPC分类号： D01F6/54 ,  C08K5/0041 ,  C09B69/06 ,  Y10S8/927

摘要： Improvement of a process for spin-dyeing acid-modified polymers or copolymers of acrylonitrile in which cationic quaternary dyestuffs are added to the spinning mass and spun according to the wet-spinning procedure. The improvement is characterized by using dyestuffs characterized by a migration factor M of 20 or less than 20, by a combination index K of less than 2.5 and a cation weight of more than 310. Migration factor M and combination index K are known values in the dyestuff field or can be determined. The dyestuff to be used according to the invention can belong to the most different classes of dyestuffs; they fix rapidly on the polymer, and thus they do not color, or color only to a minor extent, the coagulation, stretching and washing baths although they are soluble in water and aqueous solutions of these baths. The fibers and filaments obtained by the process of the invention have outstanding fastnesses to wet processing and, owing to the absence of dyestuff aggregates at the surface of the fiber such as occur when spin-dyeing with pigments, very good fastnesses to dry and wet rubbing. The fibers are intense, absolutely transparent and free from specks.

摘要翻译： 改进将染色酸改性聚合物或丙烯腈的共聚物的方法改进，其中将阳离子季染料加入到纺丝织物中并根据湿纺丝方法纺丝。 改进的特征在于使用迁移因子M为20或小于20的染料，组合指数K小于2.5，阳离子重量大于310.迁移因子M和组合指数K为 染料领域或可以确定。 根据本发明使用的染料可以属于最不同类型的染料; 它们快速固定在聚合物上，因此它们不会在凝固，拉伸和洗涤浴中颜色不浅或仅在较小程度上着色，尽管它们可溶于水和这些浴的水溶液。 通过本发明的方法获得的纤维和细丝具有优异的湿法加工牢度，并且由于在用颜料旋转染色时在纤维表面没有染料聚集体，因此具有非常好的干湿摩擦牢度 。 纤维是强烈的，绝对透明的，没有斑点。

公开(公告)号：US4344879A

公开(公告)日：1982-08-17

申请号：US204323

申请日：1980-11-05

申请人： Reinhard Mohr ,  Manfred Hahnke

发明人： Reinhard Mohr ,  Manfred Hahnke

IPC分类号： C09B23/00 ,  C08K5/3417 ,  C09B23/16 ,  C09B26/02 ,  C09B26/04 ,  C09B69/06 ,  D06P1/38 ,  C07D209/14

CPC分类号： C09B26/02 ,  C08K5/3417 ,  C09B23/162 ,  C09B26/04 ,  C09B69/06

摘要： Novel azamethine compounds of the formula (1) ##STR1## in which R is alkyl of from 1 to 4 carbon atoms optionally substituted, Alk is alkyl of from 1 to 4 carbon atoms, Y is the methine radical or a nitrogen atom, R.sub.1 is hydrogen or alkyl of from 1 to 4 carbon atoms optionally substituted, alkylene is an alkylene group of from 2 to 6 carbon atoms, Z is a group of the formula (2a) or 2(b) ##STR2## in which R.sub.2 is alkyl of from 1 to 4 carbon atoms optionally substituted, R.sub.3 is alkyl of from 1 to 4 carbon atoms optionally substituted, or is phenyl unsubstituted or substituted by chlorine, alkyl of from 1 to 4 carbon atoms, alkoxy of from 1 to 4 carbon atoms, nitro, carbalkoxy of from 2 to 5 carbon atoms and/or carbamoyl, R.sub.4 is hydrogen or alkyl of from 1 to 4 carbon atoms optionally substituted, or R.sub.2 and R.sub.3 together with the nitrogen atom form a heterocyclic ring containing optionally nitrogen, oxygen or sulfur as a further hetero atom, or R.sub.2 and R.sub.3 or R.sub.2, R.sub.3 and R.sub.4 together with the positive nitrogen form a heterocyclic ring containing optionally nitrogen, oxygen or sulfur as a further hetero atom, the benzene nucleus A is unsubstituted or substituted by halogen, nitro, cyano, sulfamoyl, alkyl of from 1 to 4 carbon atoms, alkoxy of from 1 to 4 carbon atoms and/or carbalkoxy of from 2 to 5 carbon atoms, the benzene nucleus B is unsubstituted or substituted by halogen, nitro, alkyl of from 1 to 4 carbon atoms, alkoxy of from 1 to 4 carbon atoms and/or carbalkoxy of from 2 to 5 carbon atoms, n is the integer 1 or 2, and X.sup.(-) is the equivalent of a colorless anion.These novel compounds can be prepared in usual manner analogously to known processes using the corresponding indoline and alkoxyaniline derivatives as starting compounds with optional subsequent alkylation.The novel azamethine compounds are well suitable as dyestuffs, soluble in water and in acids as well as in various organic solvents, for the dyeing of preferably acid-modified aromatic polyesters, acid-modified polyamides and acid-modified polyacrylonitrile materials, especially those in the form of fibres or in the mass by means of a spin-dyeing procedure.

公开(公告)号：US4046752A

公开(公告)日：1977-09-06

申请号：US594111

申请日：1975-07-08

申请人： Kurt Hohmann ,  Reinhard Mohr ,  Manfred Hahnke

发明人： Kurt Hohmann ,  Reinhard Mohr ,  Manfred Hahnke

IPC分类号： C09B29/042 ,  C09B29/00 ,  C09B29/36 ,  C09B41/00 ,  C09B44/10 ,  C09B44/20

CPC分类号： C09B44/10 ,  C09B29/0085 ,  C09B29/3691 ,  C09B44/20

摘要： A process for the direct preparation of pure thiazolazo compounds had been found with the use of a 2-aminothiazole as diazo or azo component in a coupling process wherein the 2-aminothiazole used therein is subjected to the usual coupling reaction, if used as diazocomponent after diazotation, without intermediate isolation after its preparation in known manner. This process avoids the preparation of the 2-aminothiazoles as starting compounds in its solid form and the expensive purification of these instable compounds and yields now very pure azo products.

摘要翻译： 已经发现使用2-氨基噻唑作为重氮或偶氮组分的偶联或偶氮组分直接制备纯的噻唑偶氮化合物的方法，其中使用的2-氨基噻唑进行通常的偶联反应， 重氮化，其以其已知方式制备后无需中间分离。 该方法避免了2-固体形式的起始化合物的2-氨基噻唑的制备和这些不稳定的化合物的昂贵的纯化，并且现在产生非常纯的偶氮产物。

公开(公告)号：US4557732A

公开(公告)日：1985-12-10

申请号：US538800

申请日：1983-10-04

申请人： Manfred Hahnke ,  Reinhard Mohr ,  Kurt Hohmann

发明人： Manfred Hahnke ,  Reinhard Mohr ,  Kurt Hohmann

IPC分类号： D06P1/41 ,  C08K5/00 ,  C09B69/06 ,  D01F6/54 ,  D06P3/76 ,  D06P7/00 ,  D06P3/70

CPC分类号： D01F6/54 ,  C08K5/0041 ,  C09B69/06 ,  Y10S534/01

摘要： Improvement of a process for spin-dyeing acid-modified polymers or copolymers of acrylonitrile in which cationic quaternary dyestuffs are added to the spinning mass and spun according to the wet-spinning procedure. The improvement is characterized by using dyestuffs characterized by a migration factor M of 20 or less than 20, by a combination index K of less than 2.5 and a cation weight of more than 310. Migration factor M and combination index K are known values in the dyestuff field or can be determined. The dyestuff to be used according to the invention can belong to the most different classes of dyestuffs; they fix rapidly on the polymer, and thus they do not color, or color only to a minor extent, the coagulation, stretching and washing baths although they are soluble in water and aqueous solutions of these baths. The fibers and filaments obtained by the process of the invention have outstanding fastnesses to wet processing and, owing to the absence of dyestuff aggregates at the surface of the fiber such as occur when spin-dyeing with pigments, very good fastnesses to dry and wet rubbing. The fibers are intense, absolutely transparent and free from specks.

摘要翻译： 改进将染色酸改性聚合物或丙烯腈的共聚物的方法改进，其中将阳离子季染料加入到纺丝织物中并根据湿纺丝方法纺丝。 改进的特征在于使用迁移因子M为20或小于20的染料，组合指数K小于2.5，阳离子重量大于310.迁移因子M和组合指数K为 染料领域或可以确定。 根据本发明使用的染料可以属于最不同类型的染料; 它们快速固定在聚合物上，因此它们不会在凝固，拉伸和洗涤浴中颜色不浅或仅在较小程度上着色，尽管它们可溶于水和这些浴的水溶液。 通过本发明的方法获得的纤维和细丝具有优异的湿法加工牢度，并且由于在用颜料旋转染色时在纤维表面没有染料聚集体，因此具有非常好的干湿摩擦牢度 。 纤维是强烈的，绝对透明的，没有斑点。

公开(公告)号：US5352246A

公开(公告)日：1994-10-04

申请号：US944050

申请日：1992-09-10

申请人： Manfred Hahnke ,  Marcos Segal ,  Werner H. Russ ,  Uwe Mrotzeck ,  Jutta Reiter ,  Christine Feuchtner

发明人： Manfred Hahnke ,  Marcos Segal ,  Werner H. Russ ,  Uwe Mrotzeck ,  Jutta Reiter ,  Christine Feuchtner

IPC分类号： C09B67/02 ,  C09B62/503 ,  C09B67/22 ,  D06P3/24 ,  D06P3/60 ,  D06P1/38 ,  C09B62/002 ,  C09B62/006

CPC分类号： C09B67/0041 ,  C09B62/503 ,  C09B67/0042 ,  Y10S8/918

摘要： The invention relates to dye compositions for obtaining level dyeings on carboxamido-containing and hydroxyl-containing fiber materials, which dyeings have comparably good light and wetlightfastness properties, the dye compositions containing dioxazine dyes (I) and disazo dyes (II) (one or more than one from IIa to IIf) in a weight ratio of 90:10 to 10:90, preferably 60:40 to 10:90, in particular 40:60 to 15:85.

摘要翻译： 本发明涉及用于在含羧酰氨基和含羟基的纤维材料上获得水平染色的染料组合物，其染色具有相当好的耐光牢度和耐光固性，染料组合物含有二恶嗪染料（I）和二偶氮染料（II）（一种或多种 比IIa至IIf的重量比）重量比为90:10至10:90，优选为60:40至10:90，特别是40:60至15:85。

公开(公告)号：US5167668A

公开(公告)日：1992-12-01

申请号：US617944

申请日：1990-11-26

申请人： Manfred Hahnke ,  Pablo Canora

发明人： Manfred Hahnke ,  Pablo Canora

IPC分类号： D06P1/00 ,  D06P3/66 ,  D06P3/86

CPC分类号： D06P3/66 ,  D06P1/0004 ,  Y10S8/918

摘要： In an existing isothermal dyeing process, the alkali required for dye fixation is added to the neutral dyebath under linear or progressive program control. In this process, the amount of alkali added per unit time is small at the beginning and is increased progressively and in accordance with a program. This process passes through a certain (non-controlable) initial phase until the start of dye fixation on the cellulose. As a consequence the rate of fixation passes through a maximum before gradually decreasing when the final state of the dyeing is reached. To shorten the initial phase (waiting time) of dye fixation and to slow down dye fixation during the steepest part, it has proved advantageous according to the invention to add the alkali in accordance with a parabolic program.

摘要翻译： 在现有的等温染色工艺中，在线性或逐步程序控制下，将染料固定所需的碱加入到中性染浴中。 在这个过程中，单位时间内添加的碱的量在开始时很小，并且按照程序逐渐增加。 该过程通过一定的（不可控制的）初始阶段，直到染料固定在纤维素上。 因此，当达到染色的最终状态时，定影速率在逐渐降低之前经过最大值。 为了缩短染色剂固定的初始阶段（等待时间）和减缓最陡部分的染色剂固定，根据本发明，根据抛物线程序添加碱是有利的。

公开(公告)号：US4769449A

公开(公告)日：1988-09-06

申请号：US11103

申请日：1987-02-05

申请人： Ulrich Buhler ,  Manfred Hahnke ,  Michael Kunze ,  Albert Bode

发明人： Ulrich Buhler ,  Manfred Hahnke ,  Michael Kunze ,  Albert Bode

IPC分类号： C09B29/085 ,  C09B29/01 ,  C09B29/08 ,  C09B67/22 ,  D06P1/18

CPC分类号： C09B67/0051 ,  C09B29/0003 ,  C09B29/0813 ,  D06P1/18 ,  Y10S534/01

摘要： Azo dyes of the formula ##STR1## wherein R.sup.1 is alkyl having 1 to 4 carbon atoms; R.sup.2 is alkyl having 1 to 3 carbon atoms; R.sup.3 is alkylcarbonyloxyethyl having 1 to 3 carbon atoms in the alkyl moiety, alkoxycarbonyloxyethyl having 1 to 4 carbon atoms in the alkoxy moiety, methoxyethoxycarbonyloxyethyl or ethoxyethoxycarbonyloxyethyl; and R.sup.4 is one of the definitions of R.sup.3 or cyanoethyl; or mixtures of at least two species of said formula are used for dyeing and printing hydrophobic fiber materials.

摘要翻译： 其中R 1是具有1至4个碳原子的烷基的式“IMAGE”的偶氮染料; R2是具有1至3个碳原子的烷基; R3是在烷基部分具有1至3个碳原子的烷基羰氧基乙基，在烷氧基部分具有1至4个碳原子的烷氧基羰氧基乙基，甲氧基乙氧基羰基氧基乙基或乙氧基乙氧基羰基氧基乙基; R4是R3或氰乙基的定义之一; 或至少两种所述配方的混合物用于染色和印刷疏水纤维材料。

公开(公告)号：US4765797A

公开(公告)日：1988-08-23

申请号：US58983

申请日：1987-06-08

申请人： Manfred Hahnke ,  Sierling Ong ,  Kurt Hohmann

发明人： Manfred Hahnke ,  Sierling Ong ,  Kurt Hohmann

IPC分类号： C09B67/22 ,  C09B67/32 ,  C09B67/34

CPC分类号： C09B67/0033 ,  C09B67/0075 ,  C09B67/0076

摘要： Liquid formulations of mixtures of cationic dyes frequently have a very short storage life. As a consequence, these formulations give rise to customer complaints concerning incorrect dyeing strengths and hues and concerning isoluble constituents. It has now been found according to the invention that powder formulations and in particular liquid formulations of cationic dyes or of mixtures of these dyes can be stabilized by adding selected oxidizing agents.

摘要翻译： 阳离子染料混合物的液体配方通常具有非常短的储存寿命。 因此，这些配方引起客户对不正确的染色强度和色调以及涉及可分离成分的投诉。 现在已经发现，根据本发明，可以通过加入选择的氧化剂来稳定粉末制剂，特别是阳离子染料的液体制剂或这些染料的混合物。