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公开(公告)号:US5473003A
公开(公告)日:1995-12-05
申请号:US361012
申请日:1994-12-21
申请人: Rita Pitteloud , Paul Dubs , Bernard Gilg
发明人: Rita Pitteloud , Paul Dubs , Bernard Gilg
IPC分类号: C07C39/16 , C07C39/15 , C07C39/17 , C08K5/13 , C08L101/00 , C09K15/08 , C07C39/12 , C08K5/34
摘要: Compositions comprising an organic material which is sensitive to thermal, oxidative and/or actinic degradation and at least one compound of the formula I ##STR1## in which Z.sub.1 and Z.sub.2 independently of one another are C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.8 cycloalkyl, phenyl, phenyl-C.sub.1 -C.sub.4 alkyl or (C.sub.1 -C.sub.4 alkyl)phenyl andp is a number from 4 to 18,with the proviso that Z.sub.1 and Z.sub.2 are not simultaneously tertiary alkyl radicals. Some of the compounds of the formula I are novel.The compounds of the formula I can also be employed as stabilizers as a mixture with compounds of the formula VI and/or of the formula VII ##STR2## in which n and the radicals R.sup.1, R .sup.1 ' and A are as defined in claims 14 and 15.
摘要翻译: 包含对热,氧化和/或光化学降解敏感的有机材料和至少一种其中Z 1和Z 2彼此独立地为C 1 -C 18烷基,C 5 -C 8环烷基, 苯基,苯基-C 1 -C 4烷基或(C 1 -C 4烷基)苯基,p是4至18的数,条件是Z 1和Z 2不是同时是叔烷基。 一些式I的化合物是新的。 式I的化合物也可以用作与式VI和/或式VII的化合物的混合物作为稳定剂,其中n和基团R 1,R 1'和A如权利要求14中所定义 和15。
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公开(公告)号:US5602196A
公开(公告)日:1997-02-11
申请号:US562774
申请日:1995-11-27
申请人: Bernard Gilg , Rita Pitteloud
发明人: Bernard Gilg , Rita Pitteloud
IPC分类号: C07D249/08 , C07C37/02 , C07C37/14 , C07C39/12 , C07C39/16 , C07C39/42 , C07C43/205 , C07C69/017 , C07C69/66 , C07C69/708 , C07C219/00 , C07C229/12 , C07C229/16 , C07C229/34 , C07C233/00 , C07C239/20 , C07C251/00 , C07C251/22 , C07C255/20 , C07C317/44 , C07C321/12 , C07C323/50 , C07D211/40 , C07D211/42 , C07D211/46 , C07D211/58 , C07D211/76 , C07D213/00 , C07D233/00 , C07D233/60 , C07D249/16 , C07D249/18 , C07D277/60 , C07D277/74 , C07D295/14 , C07D295/15 , C07D307/12 , C07D521/00 , C08K5/10 , C08K5/134 , C08K5/16 , C08K5/17 , C08K5/29 , C08K5/32 , C08K5/33 , C08K5/3432 , C08K5/3445 , C08K5/3447 , C08K5/37 , C08K5/41 , C08K5/46 , C08L59/00 , C09K15/08 , C07C69/76
CPC分类号: C07D295/15 , C07C229/12 , C07C229/16 , C07C239/20 , C07C317/44 , C07C69/017 , C07C69/708 , C07D211/46 , C07D211/58 , C07D211/76 , C07D231/12 , C07D233/56 , C07D249/08 , C07D249/18 , C07D277/74 , C07D307/12 , C08K5/134 , C08K5/16 , C07C2101/14
摘要: Stabilisers of formula I ##STR1## wherein R.sub.1 and R.sub.2 may be C.sub.1 -C.sub.5 alkyl, the substituents R.sub.3 to R.sub.8 may be hydrogen, the variable n may be 1 or 2, and, when n is 1, A may be an alkoxy radical, and, when n is 2, A may be a diamine radical.
摘要翻译: 式I的稳定剂(I)其中R 1和R 2可以是C 1 -C 5烷基,取代基R 3至R 8可以是氢,变量n可以是1或2,并且当n是1时,A可以是烷氧基 当n为2时,A可以是二胺基团。
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公开(公告)号:US5616780A
公开(公告)日:1997-04-01
申请号:US594199
申请日:1996-01-31
申请人: Rita Pitteloud , Bernard Gilg
发明人: Rita Pitteloud , Bernard Gilg
IPC分类号: C07D493/08 , C07C69/00 , C07C69/74 , C07C69/753 , C07C235/62 , C07C255/47 , C07C323/10 , C07D307/00 , C07D498/08 , C08K5/13 , C08K5/134 , C08L9/00 , C08L21/00 , C08L23/00 , C08L53/00 , C08L53/02 , C07C261/00
CPC分类号: C07D307/00 , C07C69/753 , C08K5/134 , C07C2102/42
摘要: The novel compounds of the formula I ##STR1## in which A is a group of the formula IIa or IIb, ##STR2## Y is oxygen, methylene, ethylidene or a >C.dbd.C(CH.sub.3).sub.2 group, Z is nitrogen, ##STR3## R.sub.1 and R.sub.2 are, for example C.sub.1 -C.sub.5 alkyl, R.sub.3 and R.sub.4 are, for example, hydrogen or methyl, and R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, R.sub.10, R.sub.11, R.sub.12, R.sub.13 and R.sub.14 are, for example, hydrogen, are suitable for stabilizing organic material against oxidative, thermal or light-induced degradation.
摘要翻译: 其中A是式IIa或IIb的基团,其中A是式I(I)的新化合物,其中A是式IIa或IIb的基团,其中Y是氧,亚甲基,亚乙基或者C = C(CH 3)2基,Z为氮,R 1和R 2为例如C 1 -C 5烷基,R 3和R 4为例如氢或甲基,R 5,R 6,R 7,R 8,R 9,R 10, R11,R12,R13和R14例如为氢,适于稳定有机材料以防止氧化,热或光诱导的降解。
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公开(公告)号:US5356976A
公开(公告)日:1994-10-18
申请号:US90836
申请日:1993-07-12
申请人: Paul Dubs , Rita Pitteloud
发明人: Paul Dubs , Rita Pitteloud
IPC分类号: C07C37/14 , C07C39/06 , C07C39/15 , C08K5/13 , C09K15/08 , C10M129/10 , C10N30/08 , C10N30/10
摘要: Compounds of formula I ##STR1## wherein R.sub.1 is C.sub.1 -C.sub.4 n-alkyl, isopropyl, s-butyl, cyclopentyl, cyclohexyl or .alpha.-methylbenzyl, R.sub.2 is C.sub.4 -C.sub.18 tert-alkyl or .alpha.,.alpha.-dimethylbenzyl, R.sub.3 is C.sub.1 -C.sub.28 alkyl, and R.sub.4 s methyl or ethyl, with the proviso that the --CHR.sub.3 R.sub.4 group contains at least 4 carbon atoms, are suitable for stabilizing organic material which is susceptible to degradation induced by heat, oxidation or actinic light.
摘要翻译: 式I化合物其中R 1是C 1 -C 4烷基,异丙基,仲丁基,环戊基,环己基或α-甲基苄基,R 2是C 4 -C 18叔烷基或α,α-二甲基苄基,R 3是C 1 -C28烷基和R4的甲基或乙基,条件是-CHR3R4基团含有至少4个碳原子,适于稳定易受热,氧化或光化性光诱导的降解的有机材料的稳定化。
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公开(公告)号:US5175312A
公开(公告)日:1992-12-29
申请号:US754180
申请日:1991-08-27
申请人: Paul Dubs , Rita Pitteloud
发明人: Paul Dubs , Rita Pitteloud
IPC分类号: C07D307/83 , C08J7/06 , C08K5/1535
CPC分类号: C08J7/065 , C07D307/83 , C08K5/1535
摘要: Novel compounds of the formula I ##STR1## in which R.sub.1 is C.sub.13 -C.sub.30 alkyl, R.sub.2 is hydrogen, C.sub.1 -C.sub.10 alkyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.5 -C.sub.7 cycloalkyl which is substituted by C.sub.1 -C.sub.4 alkyl, or is phenyl or C.sub.7 -C.sub.12 phenylalkyl, R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl and Z is phenyl, phenyl which is substituted by C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.4 alkoxy or chlorine, a group ##STR2## in which n is 1 or 2 or a group ##STR3## in which the radicals A independently of one another are C.sub.1 -C.sub.8 alkyl, methoxy or ethoxy, are suitable for stabilizing organic material against oxidative, thermal and actinic degradation.
摘要翻译: 新的式I化合物其中R 1是C 13 -C 30烷基,R 2是氢,C 1 -C 10烷基,C 5 -C 12环烷基,被C 1 -C 4烷基取代的C 5 -C 7环烷基,或者是苯基或C 7 -C 12苯基烷基 R 3是氢或C 1 -C 4烷基,Z是苯基,被C 1 -C 8烷基,C 1 -C 4烷氧基或氯取代的苯基,其中n是1或2的基团,或基团“IMAGE”,其中基团 A彼此独立的是C 1 -C 8烷基,甲氧基或乙氧基,适于稳定有机材料以防止氧化,热和光化学降解。
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公开(公告)号:US4820756A
公开(公告)日:1989-04-11
申请号:US65226
申请日:1987-06-22
申请人: Rita Pitteloud , Paul Dubs
发明人: Rita Pitteloud , Paul Dubs
IPC分类号: C08K5/36 , C07C67/00 , C07C313/00 , C07C319/14 , C07C323/16 , C07C323/52 , C08K5/37 , C08K5/375 , C09K15/14 , C09K15/28 , C10M135/24 , C10M135/26 , C10M135/30 , C10N30/10 , C07C149/273
CPC分类号: C10M135/26 , C07C323/00 , C08K5/375 , C09K15/14 , C10M135/24 , C10M2219/084 , C10M2219/085
摘要: Novel compounds of the formula I ##STR1## in which R.sub.1, R.sub.2, R.sub.8, R.sub.9 and R.sub.10 are independently alkyl, alkenyl, cycloalkyl, phenyl, naphthyl, alkylphenyl or aralkyl and R.sub.1 and R.sub.2 may also be independently hydrogen or alkoxycarbonylmethyl, are described.The novel phenols are suitable as stabilizers in organic polymers and lubricants.
摘要翻译: R1,R2,R8,R9和R10独立地是烷基,烯基,环烷基,苯基,萘基,烷基苯基或芳烷基以及R1和R2的新的式I化合物(I)也可以独立地是氢或烷氧基羰基甲基, 被描述。 新型酚类适用于有机聚合物和润滑剂中的稳定剂。
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公开(公告)号:US5098945A
公开(公告)日:1992-03-24
申请号:US654415
申请日:1991-02-11
申请人: Rita Pitteloud , Paul Dubs
发明人: Rita Pitteloud , Paul Dubs
IPC分类号: B01J31/08 , C07B61/00 , C07C37/14 , C07C37/20 , C07C37/50 , C07C37/68 , C07C37/74 , C07C37/84 , C07C39/00 , C07C39/06 , C07C39/16 , C08K5/13 , C08L9/02 , C08L25/04 , C08L29/14 , C08L71/00 , C08L75/04 , C08L101/00 , C09K15/08
CPC分类号: C07C39/06 , C07C37/20 , C07C37/50 , C07C37/74 , C07C37/84 , C08K5/13 , C09K15/08 , Y02P20/52
摘要: A composition containing a) a polystyrene, substituted polystyrene, copolymer or terpolymer of styrene or of a substituted styrene, polycarbonate, polyester-carbonate, polyurethane, polyamide copolyamide, polyacetyl or polyphenylene oxide and b) at least one compound of the formula I ##STR1## in which R.sub.1 is methyl or ethyl and R.sub.2 is C.sub.2 -C.sub.30 alkyl.Compounds of the formula I in which R.sub.2 is C.sub.8 -C.sub.30 alkyl are novel and are suitable for stabilizing organic materials against thermal, oxidative and actinic degradation.
摘要翻译: 包含a)聚苯乙烯,取代的聚苯乙烯,苯乙烯或取代苯乙烯的共聚物或三元共聚物,聚碳酸酯,聚酯 - 碳酸酯,聚氨酯,聚酰胺共聚酰胺,聚乙酰基或聚苯醚的组合物和b)至少一种式I化合物 (I)其中R1是甲基或乙基,R2是C2-C30烷基。 其中R 2为C 8 -C 30烷基的式I化合物是新的并且适用于稳定有机材料以防止热,氧化和光化学降解。
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公开(公告)号:US5510402A
公开(公告)日:1996-04-23
申请号:US158177
申请日:1993-11-24
申请人: Paul Dubs , Rita Pitteloud
发明人: Paul Dubs , Rita Pitteloud
IPC分类号: C07C39/11 , C07C39/17 , C07C69/007 , C07C323/51 , C07C69/34 , C07C69/708 , C08K5/03 , C08K5/11 , C08K5/134 , C08K5/15 , C08K5/36
CPC分类号: C07C39/11 , C07C39/17 , C07C69/007
摘要: The novel compounds of the formula I ##STR1## in which n is an integer from the range from 4 to 8 and m is an integer from the range from 1 to 4,A is the aliphatic, aromatic, araliphatic or heterocyclic radical of a monobasic to tetrabasic carboxylic acid, andR.sup.1 and R.sup.1', independently of one another, are C.sub.1 -C.sub.24 alkyl or C.sub.5 -C.sub.8 cycloalkyl, are suitable for stabilizing organic material against thermal, oxidative or actinic degradation.
摘要翻译: 式I的新型化合物(I)其中n是4至8的整数,m是1至4的整数,A是脂族,芳族,芳脂族或杂环基 的单碱性至四元羧酸,R 1和R 1'彼此独立地为C 1 -C 24烷基或C 5 -C 8环烷基,适于稳定有机材料以防止热,氧化或光化降解。
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公开(公告)号:US4810740A
公开(公告)日:1989-03-07
申请号:US73786
申请日:1987-07-15
申请人: Paul Dubs , Rita Pitteloud
发明人: Paul Dubs , Rita Pitteloud
摘要: Composition containing an organic material sensitive to oxidative, thermal and/or actinic degradation and a compound of the formula I ##STR1##
摘要翻译: 含有对氧化,热和/或光化学降解敏感的有机材料的组合物和式I化合物(I)
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公开(公告)号:US5177246A
公开(公告)日:1993-01-05
申请号:US752171
申请日:1991-08-23
申请人: Rita Pitteloud
发明人: Rita Pitteloud
IPC分类号: C08K5/134
CPC分类号: C08K5/1345
摘要: The novel compounds of the formulae Ia and Ib ##STR1## in which the radicals R are identical or different and are a group of the formula II ##STR2## in which X is a direct bond, methylene, ethylene or a group ##STR3## and Y is C.sub.1 -C.sub.8 alkyl, R.sub.1 and R.sub.2 independently of one another are C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.5 -C.sub.7 cycloalkyl which is substituted by C.sub.1 -C.sub.4 alkyl, or are phenyl or C.sub.7 -C.sub.10 phenylalkyl, and R.sub.2 is additionally hydrogen, are suitable for stabilizing organic material against thermal, oxidative or actinic degradation.
摘要翻译: 式Ia和Ib(Ia)的新化合物其中基团R是相同或不同的,并且是式II的基团(II),其中X是直接的 键,亚甲基,亚乙基或基团,且Y为C1-C8烷基,R1和R2彼此独立地为C1-C18烷基,C5-C12环烷基,被C1-C4烷基取代的C5-C7环烷基,或为苯基或C7 -C 10苯基烷基,R 2另外是氢,适于稳定有机材料以防止热,氧化或光化学降解。
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