公开(公告)号：US20080152561A1

公开(公告)日：2008-06-26

申请号：US12043486

申请日：2008-03-06

申请人： Robert Corriu ,  Ahmad Mehdi ,  Catherine Reye ,  Henry Ledon ,  Roger Guilard ,  Stephane Brandes ,  Chloe Thieuleux

发明人： Robert Corriu ,  Ahmad Mehdi ,  Catherine Reye ,  Henry Ledon ,  Roger Guilard ,  Stephane Brandes ,  Chloe Thieuleux

IPC分类号： B01D53/46 ,  B01D53/38 ,  C01B13/02 ,  C07F7/02

CPC分类号： C07F1/005

摘要： The invention concerns a method for preparing organic-inorganic hybrid materials with controlled porosity and functionality comprising hydrolysis and condensation polymerization of a compound of formula (I): Z-R1—Si(OR)(OR′)(OR″), with an alkaline or alkaline-earth silicate in a mol ratio of (I)/(silicate)=1:9, in the presence of a non-ionic surfactant, to form a mesoporous silica represented by Z-R1—SiO1.5 9 SiO2, whereon is then anchored an organic compound, represented by (Δ)N—H, comprising a —NH— group capable of reacting with Z, to form a functionalized mesoporous silica represented by (Δ)N—R—SiO1.5 9 SiO2, which is optionally complexed with a metallic cation to form an organometallic complex. The invention also concerns the use of these materials to separate gases.

摘要翻译： 本发明涉及一种制备具有受控孔隙率和功能性的有机 - 无机杂化材料的方法，包括式（I）化合物的水解和缩聚：ZR 1 -Si（OR）（OR'）（OR'） OR“），在非离子表面活性剂的存在下，以（I）/（硅酸盐）= 1:9的摩尔比的碱土金属或碱土金属硅酸盐形成由ZR

公开(公告)号：US20080153168A1

公开(公告)日：2008-06-26

申请号：US11883393

申请日：2006-02-01

申请人： Lionel Hairault ,  Pierre Montmeat ,  Eric Pasquinet ,  Jean-Michel Barbe ,  Stephane Brandes ,  Franck Denat ,  Claude Gros ,  Roger Guilard

发明人： Lionel Hairault ,  Pierre Montmeat ,  Eric Pasquinet ,  Jean-Michel Barbe ,  Stephane Brandes ,  Franck Denat ,  Claude Gros ,  Roger Guilard

IPC分类号： G01N31/00

CPC分类号： G01N33/0026 ,  G01N33/0047 ,  G01N33/0049 ,  Y10T436/17 ,  Y10T436/18 ,  Y10T436/193333 ,  Y10T436/20 ,  Y10T436/212 ,  Y10T436/25875

摘要： The invention relates to the use of molecular tweezers as sensitive materials in chemical sensors intended to detect or assay organic compounds in the vapour state, and in particular nitro compounds.These molecular tweezers correspond to the general formula (I): in which: MC1 and MC2 represent macrocycles; p and q are equal to 0 or 1; X and Y are optionally substituted C1 to C10 alkylene groups; while E represents an optionally substituted cyclic or heterocyclic spacer group; and in which MC1 and MC2 are positioned facing each other. Fields of application: detection of explosives, control and monitoring of atmospheric pollution and of the quality of ambient air in relatively confined spaces, and monitoring of industrial sites.

摘要翻译： 本发明涉及在化学传感器中使用分子镊子作为敏感材料，其用于检测或测定蒸气状态的有机化合物，特别是硝基化合物。 这些分子镊子对应于通式（I）：其中：MC 1和MC 2代表大环; p和q等于0或1; X和Y任选被取代C 1至C 10亚烷基; 而E表示任选取代的环状或杂环型间隔基; 并且其中MC 1和MC 2 2定位成彼此面对。 应用领域：检测爆炸物，控制和监测大气污染和相对狭窄空间环境空气质量，监测工业场所。

公开(公告)号：US20060287195A1

公开(公告)日：2006-12-21

申请号：US10485935

申请日：2002-07-19

申请人： Francois Jerome ,  Geraud Dubois ,  Stephane Brandes ,  Gabriel Canard ,  Roger Bretigny ,  Bruno Roux-Fouillet ,  Henry Ledon

发明人： Francois Jerome ,  Geraud Dubois ,  Stephane Brandes ,  Gabriel Canard ,  Roger Bretigny ,  Bruno Roux-Fouillet ,  Henry Ledon

IPC分类号： B01J31/00 ,  C07D487/22

CPC分类号： C07D487/22 ,  B01D53/02 ,  B01D2257/502 ,  B01J20/103 ,  B01J20/223 ,  B01J20/28083 ,  B01J20/3204 ,  B01J20/3217 ,  B01J20/3219 ,  B01J20/3257 ,  B01J20/3259 ,  B01J20/3261 ,  B01J20/3265 ,  C01B3/56 ,  C01B13/0262 ,  C01B2203/042 ,  C01B2203/047 ,  C01B2210/005 ,  C07F7/1804 ,  C07F15/025 ,  C07F15/065

摘要： The invention concerns compounds of formula (I), wherein: R1, R2, R3 and R4 represent a hydrogen atom, an alkyl radical comprising 1 to 4 carbon atoms, a phenyl radical optionally substituted by one or several groups selected among vinyl, hydroxy, nitro, amino, bromo, chloro, fluoro, iodo, benzyloxy radicals, alkyl or alkyloxy radicals comprising 1 to 4 carbon atoms optionally substituted by one or several bromo, chloro, fluoro or iodo groups; R5, R6, R7 and R8 represent a hydrogen atom or an alkyl radical comprising 1 to 4 carbon atoms; Ra, Rb, and Rc represent a hydrogen atom, a phenyl radical optionally substituted by one or several groups selected among the vinyl, hydroxy, nitro, amino, bromo, chloro, fluoro, iodo, benzyloxy radicals, alkyl or alkyloxy radicals comprising 1 to 4 carbon atoms, optionally substituted by one or several bromo, chloro, fluoro or iodo groups. The invention also concerns a silica modified by a compound of formula (I); a sole-gel material derived from a compound of formula (I); a mesoporous silica modified by a compound of formula (I). The invention further concerns the use of said materials for selective trapping of carbon monoxide.

摘要翻译： 本发明涉及式（I）化合物，其中：R 1，R 2，R 3和R 4