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1.发明授权Low temperature-flexible radiation-curable unsaturated polysiloxane coated fiber optic 失效低温柔性辐射固化不饱和聚硅氧烷涂层光纤
公开(公告)号：US4496210A
公开(公告)日：1985-01-29
申请号：US398161
申请日：1982-07-19
IPC分类号： C08L83/04 , C03C25/10 , C03C25/24 , C08F290/00 , C08F299/00 , C08F299/08 , C08G18/61 , C08G18/81 , C08G77/388 , C08G77/392 , C08L83/08 , C09D183/04 , G02B6/44 , B05D5/06 , G02B5/172
CPC分类号： C08L83/08 , C03C25/106 , C08G18/61 , C08G18/8175 , C08G77/388 , C08G77/392 , Y10T428/31612
摘要： Optical fibers are coated with a radiation-curable liquid, polyethylenically unsaturated coating composition consisting essentially of an organic polysiloxane having from 2 to 6 reactive side chains each of which carry a functional group providing one reactive site which has been reached to provide a single radiation-curable monoethylenically unsaturated side chain. There are about one such side chain for every 500 to 5,000 units of molecular weight. This provides a prime coating which has a modulus of elasticity at room temperature and at -60.degree. C. below 3000.
摘要翻译： 用可辐射固化液体，多烯属不饱和涂层组合物涂覆光纤，该组合物基本上由具有2-6个反应性侧链的有机聚硅氧烷组成，每个反应性侧链带有提供一个反应部位的官能团， 可固化单烯属不饱和侧链。 每500-5,000个分子量单位有约一个侧链。 这提供了一种初始涂层，其在室温和-60℃以下在3000以下具有弹性模量。
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公开(公告)号：US4932750A
公开(公告)日：1990-06-12
申请号：US448252
申请日：1982-12-09
IPC分类号： C03C25/10 , C08F299/06 , C08G18/10 , C08G18/67
CPC分类号： C08G18/671 , C03C25/106 , C08F299/065 , C08G18/10
摘要： Radiation-curable coating compositions particularly adapted for the single coat coating of optical fibers are disclosed. These comprise (1) from 65% to 85% of a diethylenic-terminated polyurethane, which may contain urea groups, the polyurethane being based on a diisocyanate having an average molecular weight of from 400 to 5000; and (2) from 5% to 25% of an ether of a C.sub.2 -C.sub.4 alkylene glycol monoester of a monoethylenically unsaturated monocarboxylic acid, the ether being selected from the group consisting of ethoxyethyl, dicyclopentenyl, phenyl, and mixtures thereof. Ethoxyethoxyethyl acrylate is particularly preferred. A triacrylate ester, such as trimethylol propane triacrylate, is also desirably present.
摘要翻译： 公开了特别适用于光纤的单涂层涂层的可辐射固化涂料组合物。 这些包括（1）65％至85％的可含有尿素基团的二亚乙基封端的聚氨酯，所述聚氨酯基于平均分子量为400至5000的二异氰酸酯; 和（2）5％至25％的单烯属不饱和一元羧酸的C 2 -C 4亚烷基二醇单酯的醚，所述醚选自乙氧基乙基，二环戊烯基，苯基及其混合物。 特别优选丙烯酸乙氧基乙氧基乙酯。 还希望存在三丙烯酸酯，如三羟甲基丙烷三丙烯酸酯。
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公开(公告)号：US4472021A
公开(公告)日：1984-09-18
申请号：US447181
申请日：1982-12-10
CPC分类号： C03C25/106 , G02B6/02395 , Y10T428/31612
摘要： Radiation-curable coating compositions particularly adapted to reduce the adhesion of the radiation-cured coatings to glass optical fibers (and thereby enhance strippability) are disclosed. These comprise a radiation-curable polyethylenic organic compound and from about 2% to about 20% of the coating composition of an organic polysiloxane carrying a plurality of hydroxy-terminated groups which are joined to some of the silicon atoms in the polysiloxane chain by a carbon-to-silicon bond. The polysiloxane reduces the adhesion of the radiation-cured coating to the glass surface of the fiber. Ultraviolet cures using acrylates as the ethylenic group are preferred.
摘要翻译： 公开了可辐射固化的涂料组合物，其特别适用于降低辐射固化涂层对玻璃光纤的粘附（从而提高剥离性）。 它们包括可辐射固化的聚亚乙基有机化合物和约2％至约20％的涂料组合物，其具有多个羟基封端的基团，该有机聚硅氧烷通过碳结合到聚硅氧烷链中的一些硅原子 硅键。 聚硅氧烷降低了辐射固化涂层对纤维玻璃表面的粘附性。 使用丙烯酸酯作为烯属基团的紫外线固化是优选的。
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公开(公告)号：US4754056A
公开(公告)日：1988-06-28
申请号：US938452
申请日：1986-12-05
申请人： Robert E. Ansel , Kevin P. Murray
发明人： Robert E. Ansel , Kevin P. Murray
IPC分类号： C08G18/83 , C09D4/00 , G11B5/702 , C07C69/54 , C07C102/06 , C07C103/14 , C07C103/24
CPC分类号： C08G18/833 , C09D4/00 , G11B5/7026
摘要： Liquid coating compositions adapted to be cured by exposure to ionizing radiation are disclosed in which a liquid vehicle of coating viscosity having an ethylenically unsaturated portion comprising one or more polyethylenically unsaturated materials adapted to cure on radiation exposure, pigment dispersed in the vehicle, and an acrylate-functional radiation-curable dispersant having free carboxyl group for wetting the pigment and assisting in the stable dispersion of the pigment in the vehicle. This dispersant is an acrylate-functional carboxylic acid amide carrying free carboxyl groups, especially an adduct of a polyacrylate and a stoichiometric deficiency of a primary amine to provide a secondary amine having acrylate functionality, the secondary amine functionality being reacted with a polycarboxylic acid anhydride to form amide groups therewith.
摘要翻译： 公开了适于通过暴露于电离辐射而固化的液体涂料组合物，其中具有烯属不饱和部分的涂料粘度的液体载体包含适于在辐射照射下固化的一种或多种多烯属不饱和物质，分散在载体中的颜料和丙烯酸酯 具有游离羧基的功能性可辐射固化分散剂，用于润湿颜料并有助于颜料在车辆中的稳定分散。 该分散剂是带有游离羧基的丙烯酸酯官能羧酸酰胺，特别是聚丙烯酸酯与伯胺的化学计量不足的加合物，以提供具有丙烯酸酯官能团的仲胺，仲胺官能团与多元羧酸酐反应生成 与其形成酰胺基。
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公开(公告)号：US4601757A
公开(公告)日：1986-07-22
申请号：US709203
申请日：1985-03-07
IPC分类号： A61K8/88 , A61Q3/02 , C08F8/30 , C09D201/00 , C08L1/08 , C07C101/02 , C08K5/16
CPC分类号： C08F8/30 , A61K8/88 , A61Q3/02 , C09D201/00
摘要： Nonvolatile plasticizers are provided which are the carboxyl-functional amide reaction product of: (1) a secondary amine-functional adduct of an acrylate compound, like 2-hydroxyethyl acrylate or a monohydric caprolactone monoacrylate, and about one amine equivalent per acrylate group in the acrylate compound, of an organic primary amine such as a polyoxypropylene monoprimary amine having a molecular weight in the range of about 50 to about 8000; with (2) a dicarboxylic acid anhydride, like phthalic anhydride. These plasticizers have improved wetting properties and are particularly useful in nitrocellulose compositions, such as nail polish.
摘要翻译： 提供了非挥发性增塑剂，其为羧基官能酰胺反应产物：（1）丙烯酸酯化合物如丙烯酸2-羟基乙酯或单羟基己内酯单丙烯酸酯的仲胺官能加成物和每个丙烯酸酯基团的约一个胺当量 丙烯酸酯化合物，有机伯胺如分子量在约50至约8000范围内的聚氧丙烯单主要胺; 与（2）二羧酸酐，如邻苯二甲酸酐。 这些增塑剂具有改善的润湿性能，特别适用于硝酸纤维素组合物，如指甲油。
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6.发明授权
公开(公告)号：US4183796A
公开(公告)日：1980-01-15
申请号：US876497
申请日：1978-02-09
申请人： Robert E. Ansel , John C. Graham
发明人： Robert E. Ansel , John C. Graham
IPC分类号： C08G63/00 , C07D251/34 , C08F2/50 , C08F299/04 , C08G18/46 , C08G18/81 , C08G63/685 , C08L67/06 , C08F4/00
CPC分类号： C08G18/4661 , C08G18/8158 , Y10T428/31935
摘要： A radiation curable oligomer which cures to provide a combination of improved elongation and tensile strength is constituted by a selected hydroxy functional polyester having its active hydrogen atoms end-capped by reaction with ethylenically unsaturated monoisocyanate. This polyester is the reaction product of one mole of tris (2-hydroxyethyl) isocyanurate with three moles of saturated dicarboxylic acid and three moles of diol, these proportions being variable within the limits of .+-.20%, the polyester reaction product having an acid value of less than 20, preferably less than 5, and providing hydroxyl-terminated branches having an average length corresponding to a calculated molecular weight of 100-1500.
摘要翻译： 通过选择的具有通过与烯键式不饱和单异氰酸酯反应封端的活性氢原子的羟基官能聚酯来构成固化以提供改进的伸长率和拉伸强度的组合的可辐射固化的低聚物。 该聚酯是1摩尔三（2-羟乙基）异氰脲酸酯与3摩尔饱和二羧酸和3摩尔二醇的反应产物，这些比例可在+/- 20％的范围内变化，聚酯反应产物具有 酸值小于20，优选小于5，并提供具有对应于计算分子量为100-1500的平均长度的羟基封端的支链。
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7.发明授权
公开(公告)号：US5011635A
公开(公告)日：1991-04-30
申请号：US353538
申请日：1989-05-18
IPC分类号： B29C67/00
CPC分类号： B29C67/0066
摘要： The present invention contemplates a stereolithographic apparatus and method having a liquid organic phase and a fluid phase separated by a membrane that inhibits contact between the phases.
摘要翻译： 本发明考虑了一种立体光刻设备和方法，其具有液体有机相和通过膜分离的流体相，其抑制相之间的接触。
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8.发明授权Stereolithography using repeated exposures to increase strength and reduce distortion 失效使用反复曝光进行立体光刻以增加强度并减少变形
公开(公告)号：US4945032A
公开(公告)日：1990-07-31
申请号：US429561
申请日：1989-10-31
CPC分类号： B29C67/0066 , G03F7/0037 , Y10S430/146
摘要： An improved stereolithographic process is provided in which the formation of a thin walled three-dimensional object in a reservoir of liquid ultraviolet-curable ethylenically unsaturated material using a support is positioned immediately beneath the upper surface of the liquid reservoir with that upper surface being exposed to ultraviolet light in a pattern to solidify the liquid at and near the upper surface in a series of cross-sections of the desired three-dimensional object, one atop the other. In this way there is formed a series of superposed layers which adhere to one another to build the desired three-dimensional object within the liquid reservoir. The improvement comprises, stopping the exposure at any portion of the surface in the formation of said layers and then repeating the exposure at least once again in the production of each surface layer so that the strength and solvent resistance of the formed object are increased and its distortion is minimized. The ultraviolet exposure of each surface layer is preferably carried out as a series of rapid repeated scans of a computer-directed focused laser.
摘要翻译： 提供了一种改进的立体光刻方法，其中使用支撑体在液体紫外线固化的烯属不饱和材料的储存器中形成薄壁三维物体位于液体储存器的上表面的正下方，该上表面暴露于 紫外光以图案的方式固化所需三维物体的一系列横截面中的上表面上和附近的液体，一个在另一个之上。 以这种方式形成一系列重叠的层，其彼此粘附以在液体储存器内构建所需的三维物体。 改进之处在于，在形成所述层的表面的任何部分处停止曝光，然后在每个表面层的制造中至少再次重复曝光，使得所形成的物体的强度和耐溶剂性增加， 失真最小化。 每个表面层的紫外线暴露优选作为计算机引导的聚焦激光器的一系列快速重复扫描进行。
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9.发明授权Method of forming a three-dimensional object by stereolithography and composition therefore 失效因此通过立体光刻法和组合物形成三维物体的方法
公开(公告)号：US4942001A
公开(公告)日：1990-07-17
申请号：US429568
申请日：1989-10-31
CPC分类号： B29C67/0062 , B29C35/08 , B29C39/006 , G03F7/0037 , B29K2025/00 , B29K2033/04 , B29K2055/00
摘要： A stereolithographic method which employs an ultraviolet-curable liquid composition adapted to cure rapidly to a lightly cross-linked solvent-swellable three-dimensional complexly-shaped polymeric thin-walled element constituted by heat-softenable solid polymer upon exposure to ultraviolet dosage in the range of about 0.1 to about 10 Joules per square centimeter and which possesses reduced distortion comprises, from 20 to 80 weight percent, of a resinous polyacrylate or polymethacrylate dissolved in a combination of 10 to 45 weight percent of a liquid polyacrylate or polymethacrylate, which is preferably trifunctional, and 10 to 45 weight percent of liquid N-vinyl monomer, preferably N-vinyl pyrrolidone. Thus, the weight ratio of polyacrylate: polymethacrylate: N-vinyl monomer is about 1:2:2 to about 8:1:1. One of the foregoing polyacrylates or polymethacrylates is a polyacrylate and the other is a polymethacrylate so that good cure speed is accompanied by good distortion resistance. In the method, a reservoir of the liquid composition is established and its exposed surface is irradiated to solidify the surface and build up a thin-walled element which is removed from the reservoir, drained of liquid adhering thereto and cured.
摘要翻译： 一种立体光刻方法，其采用可紫外线固化的液体组合物，其适于快速固化至在可暴露于范围内的紫外线剂量下由可热软化的固体聚合物构成的轻度交联的溶剂可膨胀的三维复合形状的聚合物薄壁元件 约0.1至约10焦耳每平方厘米并且具有减小的变形的组合包含20至80重量％的以10至45重量％的液体聚丙烯酸酯或聚甲基丙烯酸甲酯的组合溶解的树脂聚丙烯酸酯或聚甲基丙烯酸酯，其优选 三官能和10至45重量％的液体N-乙烯基单体，优选N-乙烯基吡咯烷酮。 因此，聚丙烯酸酯：聚甲基丙烯酸酯：N-乙烯基单体的重量比为约1:2:2至约8:1:1。 上述聚丙烯酸酯或聚甲基丙烯酸酯之一是聚丙烯酸酯，另一种是聚甲基丙烯酸酯，因此良好的固化速度伴随着良好的抗变形性。 在该方法中，建立了液体组合物的储存器，并且照射其暴露的表面以固化表面并且形成从储存器中取出的薄壁元件，排出附着在其上并固化的液体。
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10.发明授权Radiation-curable phenoxy resins, production thereof, and electron beam-curable compositions containing the same 失效可辐射固化的苯氧基树脂，其制备方法和含有它们的电子束可固化组合物
公开(公告)号：US4818780A
公开(公告)日：1989-04-04
申请号：US185538
申请日：1988-04-25
IPC分类号： C08G18/08 , C08G18/00 , C08G18/48 , C08G18/64 , C08G18/67 , C08G18/72 , C08G18/81 , C08G18/04
CPC分类号： C08G18/6407 , C08G18/4879 , C08G18/8158
摘要： The reaction product of an adduct of an ethylenically unsaturated monohydric alcohol, such as 2-hydroxyethyl acrylate, with an organic diisocyanate in which one of the two isocyanate groups is more strongly reactive than the other, such as isophorone diisocyanate, is reacted with a phenoxy resin in solvent solution. The alcohol is used in a molar excess of at least about 3% up to 30% to insure the absence of any significant proportion of unreacted diisocyanate. The phenoxy resin which is reacted with is a high molecular weight hydroxy functional polyether having a number average molecular weight above 10,000 and an hydroxy functionality in the range of from about 20 to about 300. The adduct is used in an amount to introduce about 1.5 to about 20 ethylenically unsaturated groups per molecule of the polyether, and the reaction is continued to substantially eliminate unreacted isocyanate functionality. These unsaturated products are useful in electron beam coating compositions, especially in combination with unsaturated liquids which lower the glass transition temperature. They can also be used in combination with acrylate-terminated polyurethanes to provide films having greater handleability prior to cure.
摘要翻译： 烯丙基不饱和一元醇如丙烯酸2-羟乙酯与有机二异氰酸酯的加成物的反应产物，其中两个异氰酸酯基中的一个比另一个异氰酸酯反应性更强，例如异佛尔酮二异氰酸酯，与苯氧基 树脂在溶剂溶液中。 醇的摩尔过量使用至少约3％至30％，以确保不存在任何显着比例的未反应的二异氰酸酯。 与之反应的苯氧基树脂是数均分子量大于10,000且羟基官能度在约20至约300范围内的高分子量羟基官能聚醚。加合物的用量为约1.5至 每分子聚醚约20个烯属不饱和基团，继续反应基本上消除未反应的异氰酸酯官能度。 这些不饱和产物可用于电子束涂料组合物，特别是与降低玻璃化转变温度的不饱和液体组合使用。 它们也可以与丙烯酸酯封端的聚氨酯组合使用，以提供在固化前具有更高可操作性的膜。
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