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1.发明授权Polyazacycloalkanes, tri, tetra- or penta-azamacrocyclic complexes, processes for the production of these substituted or unsubstituted polyazacycloalkanes grafted to a support and uses of polyazacycloalkanes and the aforementioned complexes 失效多氮杂环烷烃，三，四或五氮杂十环配合物，用于制备接枝到载体上的这些取代或未取代的多氮杂环烷烃的方法和多氮杂环烷烃和上述络合物的用途公开(公告)号：US06265483B1
公开(公告)日：2001-07-24
申请号：US09190144
申请日：1998-11-12
IPC分类号： C07D25502
CPC分类号： G21F9/12 , B01D53/1493 , B01D2253/106 , B01D2259/4583 , B01J45/00 , C08F12/32 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998
摘要： The invention relates to polyazacycloalkanes having 3, 4 or 5 nitrogen atoms, tri-, tetra- or penta-azamacrocyclic transition metal complexes and processes for the production of said polyazacycloalkanes. The object of the invention is to form polyazacycloalkanes able to trap metal cations and in particular U, Pu, Am, Ce, Eu, Al, Gd, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ag, Cd, Sn, Au, Mg or Pb or complexes able to trap in particular oxygen in a gaseous mixture. The invention more particularly applies to the treatment of liquid effluents from nuclear power stations.
摘要翻译： 本发明涉及具有3,4或5个氮原子的多氮杂环烷烃，三，四或五氮杂十八烷基过渡金属络合物以及用于制备所述多氮杂环烷烃的方法。本发明的目的是形成能够捕获金属阳离子的多氮杂环烷烃， 特别是U，Pu，Am，Ce，Eu，Al，Gd，Cr，Mn，Fe，Co，Ni，Cu，Zn，Ag，Cd，Sn，Au，Mg或Pb或能够特别吸留氧的络合物 气体混合物。本发明更特别适用于处理来自核电站的液体流出物。
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2.发明授权POLYAZACYCLOALKANES, TRI-, TETRA- OR PENTA-AZAMACROCYCLIC COMPLEXES, PROCESSES FOR THE PRODUCTION OF THESE SUBSTITUTED OR UNSUBSTITUTED POLYAZACYCLOALKANES GRAFTED TO A SUPPORT AND USES OF POLYAZACYCLOALKANES AND THE AFOREMENTIONED COMPLEXES 失效聚氮杂环戊烷，三异氰酸酯，四环戊基或三甲基环烷基复合物，生产这些取代或未取代的聚氨基甲酸酯的方法，用于支持和使用聚氨基甲酸酯和已制备的复合物公开(公告)号：US06410143B1
公开(公告)日：2002-06-25
申请号：US09667506
申请日：2000-09-22
IPC分类号： B32B516
CPC分类号： G21F9/12 , B01D53/1493 , B01D2253/106 , B01D2259/4583 , B01J45/00 , C08F12/32 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998
摘要： The invention relates to polyazacycloalkanes having 3, 4 or 5 nitrogen atoms, tri-, tetra- or penta-azamacrocyclic transition metal complexes and processes for the production of said polyazacycloalkanes. The object of the invention is to form polyazacycloalkanes able to trap metal cations and in particular U, Pu, Am, Ce, Eu, Al, Gd, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ag, Cd, Sn, Au, Mg or Pb or complexes able to trap in particular oxygen in a gaseous mixture. The invention more particularly applies to the treatment of liquid effluents from nuclear power stations.
摘要翻译： 本发明涉及具有3,4或5个氮原子的多氮杂环烷烃，三，四或五氮杂十八烷基过渡金属络合物以及用于制备所述多氮杂环烷烃的方法。本发明的目的是形成能够捕获金属阳离子的多氮杂环烷烃， 特别是U，Pu，Am，Ce，Eu，Al，Gd，Cr，Mn，Fe，Co，Ni，Cu，Zn，Ag，Cd，Sn，Au，Mg或Pb或能够特别吸留氧的络合物 气体混合物。本发明更特别适用于处理来自核电站的液体流出物。
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3.发明授权Material comprising polyazacycloalkanes, grafted on polypropylene fibres, its process of preparation, and process for removing metal cations from a liquid 有权包含聚氮杂环烷烃，接枝在聚丙烯纤维上的材料，其制备方法和从液体中除去金属阳离子的方法公开(公告)号：US08841384B2
公开(公告)日：2014-09-23
申请号：US12523330
申请日：2008-01-14
申请人： Frédéric Rascalou , Franck Denat , Roger Guilard , Jean-Louis Babouhot , Hervé Chollet , Michel Meyer
发明人： Frédéric Rascalou , Franck Denat , Roger Guilard , Jean-Louis Babouhot , Hervé Chollet , Michel Meyer
IPC分类号： C08F255/02 , C08J7/16 , C08F8/30 , D06M14/10 , D06M14/28
摘要： Material composed of a polyazacycloalkane grafted on polypropylene fibres.Process for the preparation of this material.Process for removing metal cations present in a liquid by bringing this liquid into contact with the said material.
摘要翻译： 由在聚丙烯纤维上接枝的多氮杂环烷烃组成的材料。 制备该材料的方法。 通过使该液体与所述材料接触来除去存在于液体中的金属阳离子的方法。
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4.发明授权Method and installation for removal of metal cations from a liquid by resins with polyazacycloalkanes grafted on a support 失效用支撑体上接枝聚氮杂环烷烃的树脂从液体中除去金属阳离子的方法和装置公开(公告)号：US07083732B1
公开(公告)日：2006-08-01
申请号：US10069565
申请日：2000-08-25
CPC分类号： B01J45/00 , G21F9/12 , Y10S210/911 , Y10S210/912 , Y10S210/913 , Y10S210/914
摘要： The invention is related to a method and an installation for removal of metal cations contained in a liquid, in which said liquid is brought into contact at a temperature greater than or equal to 60° C. with a chelating ion exchange resin formed from a polyazacycloalkane grafted on a solid support, said resin having been conditioned, previously to said contacting, at a pH of 4 to 6.
摘要翻译： 本发明涉及一种用于除去液体中所含的金属阳离子的方法和装置，其中所述液体以大于或等于60℃的温度与由多氮杂环烷烃形成的螯合离子交换树脂接触 接枝在固体载体上，所述树脂预先在4至6的pH下进行所述接触。
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5.发明授权公开(公告)号：US07492454B2
公开(公告)日：2009-02-17
申请号：US10530608
申请日：2003-10-07
CPC分类号： G01J3/28 , G01J3/0208 , G01J3/024
摘要： This system collects light emitted by at least one light source (52) and focuses it onto at least one light detection device (54). Preferably, it comprises a first mirror (58) that collects light emitted by the source and focuses it on a second mirror (60) that focuses it in turn onto the device. The system is provided with a chamber that is opaque to all light, particularly ultraviolet radiation, and in which the light source, the light detection device and the mirrors are placed, and means of creating a vacuum in this chamber and filling it with a gas that is transparent to ultraviolet radiation.
摘要翻译： 该系统收集由至少一个光源（52）发射的光并将其聚焦到至少一个光检测装置（54）上。 优选地，其包括第一反射镜（58），其收集由源发射的光并将其聚焦在第二反射镜（60）上，所述第二反射镜将其依次聚焦到所述装置上。 该系统设置有对所有光，特别是紫外线辐射是不透明的室，其中放置有光源，光检测装置和反射镜，以及在该室中产生真空并用气体填充的装置 对紫外线辐射是透明的。
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