利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

24 条记录 (耗时 0.176 秒)

    Process for treating a catalytic component, resultant component, and polymerization of ethylene using such component
    3.
    发明授权
    Process for treating a catalytic component, resultant component, and polymerization of ethylene using such component 失效
    使用这种组分处理催化组分，所得组分和乙烯聚合的方法

    公开(公告)号：US5484754A

    公开(公告)日：1996-01-16

    申请号：US6619

    申请日：1993-01-21

    申请人： Roger Spitz ,  Maryse Patin ,  Jean Malinge

    发明人： Roger Spitz ,  Maryse Patin ,  Jean Malinge

    IPC分类号： C08F4/658 ,  C01F5/34 ,  C08F4/60 ,  C08F4/654 ,  C08F10/00 ,  C08F10/02

    CPC分类号： C01F5/34 ,  C08F10/02

    摘要： A process for the polymerization of ethylene or the copolymerization of ethylene with an alpha-olefin, in suspension or in gas phase, in the presence of a catalyst consisting essentially of a cocatalyst and a catalytic component based on at least Mg, Ti and Cl, with the catalytic component being constituted of at least one derivative of magnesium and one chlorinated derivative of titanium in its form III and/or IV, which was subjected, prior to its use, to a reduction treatment and then to treatment with a chlorinated transition metal compound, with the said catalytic component being characterized in that the magnesium derivative is in the form MgCl.sub.2.MgO.

    摘要翻译： 在基本上由至少基于Mg，Ti和Cl的助催化剂和催化组分组成的催化剂存在下，乙烯聚合或乙烯与α-烯烃在悬浮液或气相中的共聚合的方法， 其催化组分由至少一种镁衍生物和一种其形式为III和/或IV的钛的一种氯化衍生物构成，其在使用前经受还原处理，然后用氯化过渡金属 化合物，所述催化组分的特征在于镁衍生物为MgCl 2 .MgO形式。

    Process for the polymerization of ethylene and catalytic component therefor
    4.
    发明授权
    Process for the polymerization of ethylene and catalytic component therefor 失效
    乙烯及其催化组分的聚合方法

    公开(公告)号：US5563225A

    公开(公告)日：1996-10-08

    申请号：US320053

    申请日：1994-10-07

    申请人： Roger Spitz ,  Jean Malinge ,  Jean-Francois Joly

    发明人： Roger Spitz ,  Jean Malinge ,  Jean-Francois Joly

    IPC分类号： C08F4/658 ,  C08F4/60 ,  C08F4/615 ,  C08F4/642 ,  C08F4/652 ,  C08F10/00 ,  C08F10/02 ,  C08F4/64

    CPC分类号： C08F10/02

    摘要： A catalytic component having controlled structure for use in combination with a cocatalyst for the polymerization of ethylene, and being the product of the process of subjecting a component consisting essentially of titanium, magnesium, and chlorine to a reduction treatment and after such treatment contacting the component with a transition metal chlorine-containing compound and process of polymerizing ethylene using such catalytic component to produce polymers having a broad molecular weight distribution.

    摘要翻译： 具有控制结构的催化组分，其与用于乙烯聚合的助催化剂组合使用，并且是将基本上由钛，镁和氯组成的组分进行还原处理的过程的产物，并且在这样的处理之后，使组分 使用过渡金属含氯化合物和使用这种催化组分聚合乙烯的方法来生产具有宽分子量分布的聚合物。

    Process for the polymerization of ethylene and catalytic component therefor
    5.
    发明授权
    Process for the polymerization of ethylene and catalytic component therefor 失效
    乙烯和其催化组分的聚合方法

    公开(公告)号：US5151396A

    公开(公告)日：1992-09-29

    申请号：US436059

    申请日：1989-11-13

    申请人： Roger Spitz ,  Jean Malinge ,  Jean-Francois Joly

    发明人： Roger Spitz ,  Jean Malinge ,  Jean-Francois Joly

    IPC分类号： C08F4/658 ,  C08F4/60 ,  C08F4/615 ,  C08F4/642 ,  C08F4/652 ,  C08F10/00 ,  C08F10/02

    CPC分类号： C08F10/02

    摘要： A catalytic component having controlled strucuture for use in combination with a cocatalyst for the polymerization of ethylene, and being the product of the process of subjecting a component consisting essentially of titanium, magnesium, and chlorine to a reduction treatment and after such treatment contacting the component with a transition metal chlorine-containing compound and process of polymerizing ethylene using such catalytic component to produce polymers having a broad molecular weight distribution.

    摘要翻译： 具有控制结构的催化组分，其用于与用于乙烯聚合的助催化剂组合使用，并且是将基本上由钛，镁和氯组成的组分进行还原处理的过程的产物，并且在这样的处理使组分 使用过渡金属含氯化合物和使用这种催化组分聚合乙烯的方法来生产具有宽分子量分布的聚合物。

    Activator solid support for metallocene catalysts in the polymerization of olefins, a process for preparing such a support, and the corresponding catalytic system and polymerization process
    6.
    发明授权
    Activator solid support for metallocene catalysts in the polymerization of olefins, a process for preparing such a support, and the corresponding catalytic system and polymerization process 失效
    在烯烃聚合中的茂金属催化剂的活化剂固体载体，制备这种载体的方法以及相应的催化体系和聚合方法

    公开(公告)号：US06780946B2

    公开(公告)日：2004-08-24

    申请号：US10402939

    申请日：2003-04-01

    申请人： Thierry Saudemont ,  Roger Spitz ,  Jean-Pierre Broyer ,  Jean Malinge ,  Nathalie Verdel

    发明人： Thierry Saudemont ,  Roger Spitz ,  Jean-Pierre Broyer ,  Jean Malinge ,  Nathalie Verdel

    IPC分类号： C08F464

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65922 ,  C08F110/02 ,  C08F110/06 ,  Y10S526/943 ,  C08F4/025 ,  C08F4/65916

    摘要： Activator solid support for metallocenes as catalysts in the polymerization of olefins, characterized in that it consists of a group of support particles for a solid catalytic component, which are formed from at least one porous mineral oxide, the said particles having been modified in order to carry, on the surface, aluminum and/or magnesium Lewis-acid sites of formula: groups coming from a functionalization agent having reacted with —OH radicals carried by the base particles of the support, the functionalization reaction having been followed by a fluorination reaction. The catalytic system according to the invention comprises (a) a metallocene catalyst, which has, if required, been subjected to a prealkylation treatment; (b) a cocatalyst; and (c) an activator solid support for metallocene, as defined above, it being possible for the cocatalyst (b) to be absent if the metallocene catalyst (a) has been prealkylated.

    摘要翻译： 在烯烃聚合中作为催化剂的金属茂的活化剂固体支持物，其特征在于它由一组由至少一种多孔矿物氧化物形成的固体催化组分的载体颗粒组成，所述颗粒已被修饰以便 在表面上携带下式的铝和/或镁路易斯酸位点：来自与由载体的基础颗粒携带的-OH自由基反应的官能化试剂的基团，官能化反应随后进行氟化反应。 根据本发明的催化体系包括（a）茂金属催化剂，如果需要，其进行预烷基化处理; （b）助催化剂; 如上所述，如果茂金属催化剂（a）已经被烷基化，则助催化剂（b）可能不存在，而且（c）金属茂的活化剂固体载体。

    Activator solid support for metallocene catalysts in the polymerization of olefins, a process for preparing such a support, and the corresponding catalytic system and polymerization process
    7.
    发明授权
    Activator solid support for metallocene catalysts in the polymerization of olefins, a process for preparing such a support, and the corresponding catalytic system and polymerization process 有权
    在烯烃聚合中的茂金属催化剂的活化剂固体载体，制备这种载体的方法以及相应的催化体系和聚合方法

    公开(公告)号：US06605561B1

    公开(公告)日：2003-08-12

    申请号：US09822840

    申请日：2001-04-02

    申请人： Thierry Saudemont ,  Roger Spitz ,  Jean-Pierre Broyer ,  Jean Malinge ,  Nathalie Verdel

    发明人： Thierry Saudemont ,  Roger Spitz ,  Jean-Pierre Broyer ,  Jean Malinge ,  Nathalie Verdel

    IPC分类号： B01J3116

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65922 ,  C08F110/02 ,  C08F110/06 ,  Y10S526/943 ,  C08F4/025 ,  C08F4/65916

    摘要： Activator solid support for metallocenes as catalysts in the polymerization of olefins, characterized in that it consists of a group of support particles for a solid catalytic component, which are formed from at least one porous mineral oxide, the said particles having been modified in order to carry, on the surface, aluminium and/or magnesium Lewis-acid sites of formula: or —Mg—F, the groups coming from a functionalization agent having reacted with —OH radicals carried by the base particles of the support, the functionalization reaction having been followed by a fluorination reaction. The catalytic system according to the invention comprises (a) a metallocene catalyst, which has, if required, been subjected to a prealkylation treatment; (b) a cocatalyst; and (c) an activator solid support for metallocene, as defined above, it being possible for the cocatalyst (b) to be absent if the metallocene catalyst (a) has been prealkylated.

    摘要翻译： 在烯烃聚合中作为催化剂的金属茂的活化剂固体支持物，其特征在于它由一组由至少一种多孔矿物氧化物形成的固体催化组分的载体颗粒组成，所述颗粒已被修饰以便 在表面上携带式：或-Mg-F的铝和/或镁路易斯酸位点，来自与由载体的基础颗粒携带的-OH自由基反应的官能化试剂的基团，官能化反应已经 随后进行氟化反应。 根据本发明的催化体系包括（a）茂金属催化剂，如果需要，其进行预烷基化处理; （b）助催化剂; 如上所述，如果茂金属催化剂（a）已经被烷基化，则助催化剂（b）可能不存在，而且（c）金属茂的活化剂固体载体。

    Solid catalytic component for the polymerization of olefins
    9.
    发明授权
    Solid catalytic component for the polymerization of olefins 失效
    用于烯烃聚合的固体催化组分

    公开(公告)号：US6057258A

    公开(公告)日：2000-05-02

    申请号：US104983

    申请日：1998-06-26

    申请人： Roger Spitz ,  Thierry Saudemont ,  Jean Malinge

    发明人： Roger Spitz ,  Thierry Saudemont ,  Jean Malinge

    IPC分类号： C08F2/34 ,  C08F4/02 ,  C08F4/639 ,  C08F4/64 ,  C08F4/642 ,  C08F4/646 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  B01J31/12 ,  B01J27/135

    CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F4/65912 ,  C08F4/6592

    摘要： The invention relates to a process for the preparation of a solid catalytic component of metallocene type for the polymerization of olefins comprising a stage of reaction between a support and a derivative of formula R.sup.1 M.sup.1 X.sup.1.sub.3, in which R.sup.1 represents a hydrocarbon radical, M.sup.1 represents a silicon, germanium or tin atom and X.sup.1 represents a halogen atom. The solid catalytic component according to the invention exhibits a high activity in the polymerization or copolymerization of olefins and can lead to polymers or copolymers of high molecular mass and of low polydispersity, for example less than 2.5.

    摘要翻译： 本发明涉及一种制备用于烯烃聚合的金属茂型固体催化组分的方法，包括载体与式R1M1X13的衍生物之间的反应阶段，其中R 1表示烃基，M 1表示硅， 锗或锡原子，X 1表示卤素原子。 根据本发明的固体催化组分在烯烃的聚合或共聚中表现出高活性，并且可以导致高分子量和低多分散性的聚合物或共聚物，例如小于2.5。